EP2751494A2 - Verfahren zum betrieb eines flüssigkeit-luft wärmeaustauschgeräts - Google Patents
Verfahren zum betrieb eines flüssigkeit-luft wärmeaustauschgerätsInfo
- Publication number
- EP2751494A2 EP2751494A2 EP12758795.4A EP12758795A EP2751494A2 EP 2751494 A2 EP2751494 A2 EP 2751494A2 EP 12758795 A EP12758795 A EP 12758795A EP 2751494 A2 EP2751494 A2 EP 2751494A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- air
- liquid
- heat exchange
- temperature
- exchange stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 18
- 239000003570 air Substances 0.000 claims description 78
- 239000007788 liquid Substances 0.000 claims description 56
- 238000005192 partition Methods 0.000 claims description 7
- 239000012080 ambient air Substances 0.000 claims description 5
- 238000012544 monitoring process Methods 0.000 claims description 2
- 230000001404 mediated effect Effects 0.000 claims 1
- 238000001816 cooling Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000010586 diagram Methods 0.000 description 8
- 238000009825 accumulation Methods 0.000 description 3
- 238000004891 communication Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 239000000110 cooling liquid Substances 0.000 description 2
- 230000005679 Peltier effect Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000005676 thermoelectric effect Effects 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F27/00—Control arrangements or safety devices specially adapted for heat-exchange or heat-transfer apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F11/00—Control or safety arrangements
- F24F11/70—Control systems characterised by their outputs; Constructional details thereof
- F24F11/80—Control systems characterised by their outputs; Constructional details thereof for controlling the temperature of the supplied air
- F24F11/83—Control systems characterised by their outputs; Constructional details thereof for controlling the temperature of the supplied air by controlling the supply of heat-exchange fluids to heat-exchangers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F11/00—Control or safety arrangements
- F24F11/70—Control systems characterised by their outputs; Constructional details thereof
- F24F11/80—Control systems characterised by their outputs; Constructional details thereof for controlling the temperature of the supplied air
- F24F11/83—Control systems characterised by their outputs; Constructional details thereof for controlling the temperature of the supplied air by controlling the supply of heat-exchange fluids to heat-exchangers
- F24F11/84—Control systems characterised by their outputs; Constructional details thereof for controlling the temperature of the supplied air by controlling the supply of heat-exchange fluids to heat-exchangers using valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F11/00—Control or safety arrangements
- F24F11/30—Control or safety arrangements for purposes related to the operation of the system, e.g. for safety or monitoring
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F11/00—Control or safety arrangements
- F24F11/62—Control or safety arrangements characterised by the type of control or by internal processing, e.g. using fuzzy logic, adaptive control or estimation of values
- F24F11/63—Electronic processing
- F24F11/65—Electronic processing for selecting an operating mode
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F13/00—Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
- F24F13/22—Means for preventing condensation or evacuating condensate
- F24F2013/221—Means for preventing condensation or evacuating condensate to avoid the formation of condensate, e.g. dew
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F13/00—Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
- F24F13/22—Means for preventing condensation or evacuating condensate
- F24F13/222—Means for preventing condensation or evacuating condensate for evacuating condensate
- F24F2013/225—Means for preventing condensation or evacuating condensate for evacuating condensate by evaporating the condensate in the cooling medium, e.g. in air flow from the condenser
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F2110/00—Control inputs relating to air properties
- F24F2110/10—Temperature
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F2110/00—Control inputs relating to air properties
- F24F2110/20—Humidity
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D21/00—Defrosting; Preventing frosting; Removing condensed or defrost water
- F25D21/04—Preventing the formation of frost or condensate
Definitions
- the invention relates to a method for operating a liquid-air heat exchange device. Background of the invention
- the method is suitable for operating a liquid-to-air heat exchange apparatus having a passive heat exchange stage in which the air is passed through a first flow channel extending in the vertical direction and the liquid through a second flow channel, the two flow channels in this stage are separated by a thermally passive partition.
- the term "thennisc h passive" means that the exchange of heat takes place without doing any work.
- the flow channels contain a plurality of fins, which are in good thermal communication with the thermally passive partition. The distances between the slats in the
- Flow channels for the air are small relative to the size of their surface, so that the heat exchange is efficient.
- the air has a high relative humidity, it may, especially on hot
- Gaps between the slats increasingly clogged and as a result of the resulting
- Air resistance makes the further effective cooling of the air impossible.
- a central heating system with at least one radiator which can also be used for cooling.
- cooling mode the liquid circulating through the radiator is deprived of heat by means of a heat exchanger.
- the extracted heat is released by means of a second heat exchanger to a heat storage.
- the two heat exchangers are part of a compressor-driven heat pump.
- the dew point of the air is detected and, as the detected dew point temperature approaches the temperature of the radiator, the cooling capacity is reduced.
- a method for controlling an air conditioner is known in which the temperature is determined in the cooling operation, in which occurs on a test element condensation of water, and then ensures that the temperature of the cooling liquid is higher than that
- Condensation temperature This is done, for example, by stopping the cooling operation.
- the solutions known from this prior art all have the aim of preventing the accumulation of condensate and achieve this by reducing the cooling capacity or interrupting the cooling operation.
- the invention has for its object to solve the above problem.
- the invention relates to the operation of a liquid-air heat exchange apparatus having a first flow channel for the air and a second flow channel for the liquid.
- the heat exchange apparatus includes a first passive heat exchange stage in which the first flow channel and the second flow channel are separated by a thermally passive partition, and optionally a second active heat exchange stage in which the air is actively cooled, i. by pumping heat from one side to the other, cooled or heated.
- the thermally passive partition consists of a heat-conducting material.
- a suitable condensate drainage system is advantageously installed.
- the first and second flow channels may also each be a plurality of parallel flow channels.
- the flow channel (s) for the air contain lamellae.
- the invention proposes a method for achieving the stated object.
- the method comprises two parts, namely a first part, in which it is determined whether the dew point temperature of theizit is higher than the temperature of the liquid. This is done by the following steps:
- the dew point temperature of the air can be determined, for example, by:
- the determination of the dew point temperature of the air from the measured temperature T and the measured humidity of the air can be done for example by means of a Mollier diagram.
- the dew point temperature, referred to as T pl may alternatively be calculated by means of the equation
- Humidity phi is to be used as relative humidity in percent.
- h-x diagram of the air h denotes the enthalpy, x the absolute humidity
- Pulse operation includes the following steps, which are repeated in the same order:
- the condition of whether the dew point temperature of the air is higher than the temperature of the liquid is checked periodically or aperiodically by performing the first part of the process.
- the heat exchange device is equipped with the necessary temperature and humidity sensors.
- the heat exchange device comprises a second, active stage, in the heat between the
- Liquid flows through the first heat exchange stage causes, according to a second variant, that the liquid at the first heat exchange stage is passed (bypass), so that they can still flow through the second heat exchange stage.
- Fig. 1, 2 show schematically in side view and in the plan for the understanding of
- FIG. 3 shows three diagrams for illustrating the method according to the invention.
- the first heat exchange stage 2 comprises at least one, preferably a plurality of flow channels 4 for the air and at least one, preferably a plurality of flow channels 5 for the liquid.
- Flow channels 4 for the air and the Strömungskanäie for the liquid 5 are arranged in alternating order and separated by thermally passive, heat well conducting partitions.
- the flow ducts 4 for the air contain a plurality of fins 6, which are in good thermal communication with the thermally passive partitions. The distances between the fins 6 are small so that the heat exchange between the air and the liquid is efficient.
- the flow channels 4 for the air in this example extend in the vertical direction.
- the optional second, active heat exchange stage 3 can be designed in various ways. It may for example contain a refrigeration cycle with a compressor in which a
- Cooling liquid circulates, with the air exchanging heat with the cooling circuit.
- the second heat exchange stage 3 is designed so that heat can be exchanged between the liquid and the air by supplying electrical energy, namely by means of at least one Peltier element 10.
- the second heat exchange stage 3 contains at least one Flow channel 7 for the air, at least one flow channel 8 for the liquid and the at least one interposed Peltier element 10, the heat from the liquid to the air pumps when the air is to be heated, and the heat from the air to the liquid pumps when the Air should be cooled.
- the liquid in this example does not undergo any change in state of aggregation.
- the air flows between parallel blades 9, which are in good thermal contact with the at least one Peltier element 10.
- the heat exchange device 1 also comprises a valve 11 and optionally a bypass line 12, whose purpose is described below.
- thermoelectric element or the term “Peltier heat pump” used.
- thermoelectric elements are based in particular on the Peltier effect, but they can also be based on another thermoelectric effect such as the thermo-tunneling (English, “thermo tunneling") known principle.
- the heat exchange device 1 has a Einiass 13 and an outlet 14 which can be connected to an external fluid circuit.
- the circulating liquid in the liquid circuit is heated or cooled by an external, central device to a predetermined temperature.
- the liquid used is usually water or a water-based liquid; but it can also be used any other suitable liquid.
- the flow channels 4 for the air extend in the vertical direction.
- the flow channels for the liquid are designed as a conduit system which connects the Einiass 13 and the outlet 14 with each other.
- the heat exchange device 1 also includes a fan and the necessary baffles and guide elements for the positive guidance of the air through the first heat exchange stage 2 and, if present, the second heat exchange stage 3, as well as a
- Drain 15 for accumulating in the second heat exchange stage 3 condensate.
- the flow direction of the liquid is represented by arrows 16, the flow direction of the air by arrows 17.
- the heat exchange device 1 further comprises the sensors necessary for the operation according to the invention, namely at least one temperature sensor 18 for measuring the temperature and a humidity sensor 19 for measuring the humidity of the air before the first
- Heat exchanger stage 2 are arranged, a temperature sensor 20 for measuring the temperature of the air, which is arranged after the first heat exchanger stage 2, and a control unit 21.
- the temperature of the liquid is measured either by means of a arranged for example Einiass temperature sensor 22 or from the external, central Device transmitted to the control unit 21.
- the control unit 21 evaluates the data transmitted by the sensors and controls both the flow of the liquid through the first heat exchange stage 2 and the at least one Peitiereiement 10th
- FIG. 3 shows three superimposed diagrams which, as a function of time t, illustrate the following features of the method according to the invention by way of example.
- the middle diagram shows the flow of the liquid through the first heat exchanger stage 2.
- the flow of the liquid through the first heat exchanger stage 2 is respectively allowed for a predetermined period of time ⁇ and then interrupted, wherein the interruption of the
- the lower diagram shows the current flowing through the at least one plowing element 10 in the event that the interruption of the flow of the liquid through the first heat exchange stage also causes the interruption of the flow of the liquid through the second heat exchange stage 3.
- the flowing through the at least one Peitiereiement 10 current is in each case when the
- Flow of the liquid is interrupted by the first heat exchange stage 2, either simultaneously or with a time delay turned off, so that at least one
- Peitiereiement 10 not overheated. In the other case, that the flow of the liquid through the second heat exchange stage 3 is not interrupted, the at least one Peitiereiement 10 is not turned off.
- the upper diagram shows the course of the temperature of the air after exiting the first heat exchanger stage 2, i. the course of the temperature sensor 20 measured temperature.
- first temperature increase 23 in the example from 18 ° C to about 22 ° C
- second temperature rise 25 in the example from about 22 ° C to about 27 ° C.
- Phase A The flow of liquid through the first heat exchanger stage 2 is not interrupted: The air is cooled, in the example to about 18 ° C. Over time, water condenses between the fins 6, which increasingly increases the flow resistance of the air.
- Phases B to D The flow of the liquid through the first heat exchanger stage 2 is interrupted.
- Phase B The temperature of the air rises to the approximately constant level 24.
- Phase C The temperature of the air remains at level 24, since that between the fins 6 accumulated water evaporates while the air cools adiabatically.
- Phase D The temperature of the air continues to rise as soon as the water between the lamellae 6 has evaporated.
- the pulse operation is very clearly visible. Since the duration of the individual cycles (one cycle comprises a sequence of phases A-D) is typically in the range of a few or several tens of minutes and the dew point temperature of the air usually changes only slowly, the duration of the individual cycles (one cycle comprises a sequence of phases A-D) is typically in the range of a few or several tens of minutes and the dew point temperature of the air usually changes only slowly, the
- Dew point temperature during pulse operation only occasionally be measured again, for example, once every half an hour or per hour, or at other intervals.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Investigating Or Analyzing Materials Using Thermal Means (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Air Conditioning Control Device (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH01423/11A CH705453B1 (de) | 2011-08-31 | 2011-08-31 | Verfahren zum Betrieb eines Flüssigkeit-Luft-Wärmeaustauschgeräts. |
| PCT/EP2012/066409 WO2013030080A2 (de) | 2011-08-31 | 2012-08-23 | Verfahren zum betrieb eines flüssigkeit-luft wärmeaustauschgeräts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2751494A2 true EP2751494A2 (de) | 2014-07-09 |
| EP2751494B1 EP2751494B1 (de) | 2015-12-30 |
Family
ID=46845710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP12758795.4A Not-in-force EP2751494B1 (de) | 2011-08-31 | 2012-08-23 | Verfahren zum betrieb eines flüssigkeit-luft wärmeaustauschgeräts |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20140216710A1 (de) |
| EP (1) | EP2751494B1 (de) |
| JP (1) | JP2014529054A (de) |
| KR (1) | KR20140059215A (de) |
| CN (1) | CN103765121B (de) |
| BR (1) | BR112014004693A2 (de) |
| CH (1) | CH705453B1 (de) |
| ES (1) | ES2565815T3 (de) |
| RU (1) | RU2014112116A (de) |
| WO (1) | WO2013030080A2 (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3026349B1 (fr) * | 2014-09-30 | 2018-01-12 | Valeo Systemes Thermiques | Echangeur de chaleur d'un dispositif de climatisation et de chauffage en particulier d'un vehicule automobile |
| CN111939421A (zh) * | 2020-07-24 | 2020-11-17 | 天津怡和嘉业医疗科技有限公司 | 通气治疗设备 |
| CN114383285B (zh) * | 2021-12-06 | 2023-10-20 | 青岛海尔空调器有限总公司 | 用于空调控制的方法、装置、空调及存储介质 |
| JP2025527193A (ja) * | 2022-08-03 | 2025-08-20 | バルチモア、エアコイル、カンパニー、インコーポレーテッド | ドリフト検出装置、システム、及び方法 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4006500A1 (de) * | 1990-03-02 | 1991-09-05 | Bayerische Motoren Werke Ag | Vorrichtung zur verhinderung des beschlags an den innenflaechen von fahrzeugfensterscheiben |
| FI88650C (fi) * | 1991-04-09 | 1993-06-10 | Halton Oy | Foerfarande vid reglering av en luftkonditioneringsanlaeggning och en luftkonditioneringsanlaeggning enligt detta foerfarande |
| JPH06307679A (ja) * | 1993-04-27 | 1994-11-01 | Matsushita Electric Ind Co Ltd | 輻射冷房装置 |
| JP3351307B2 (ja) * | 1997-08-08 | 2002-11-25 | 日立プラント建設株式会社 | 冷媒自然循環式熱交換システム |
| US6470697B2 (en) * | 2000-04-27 | 2002-10-29 | Denso Corporation | Air-conditioning system for vehicles |
| JP3565138B2 (ja) * | 2000-05-31 | 2004-09-15 | ダイキン工業株式会社 | 空調装置 |
| JP4043756B2 (ja) * | 2001-10-29 | 2008-02-06 | 三菱電機株式会社 | 空気調和装置及びその制御方法 |
| US6705089B2 (en) * | 2002-04-04 | 2004-03-16 | International Business Machines Corporation | Two stage cooling system employing thermoelectric modules |
| KR20040017920A (ko) * | 2002-08-22 | 2004-03-02 | 엘지전자 주식회사 | 열교환기의 응축수 배출장치 |
| JP4014491B2 (ja) * | 2002-11-07 | 2007-11-28 | シャープ株式会社 | 空気調和装置 |
| JP2005178405A (ja) * | 2003-12-16 | 2005-07-07 | Zexel Valeo Climate Control Corp | 空調装置 |
| JP3709482B2 (ja) * | 2004-03-31 | 2005-10-26 | ダイキン工業株式会社 | 空気調和システム |
| CN101044358B (zh) * | 2004-07-21 | 2010-04-14 | 欧文斯科宁知识产权资产有限公司 | 用于垂直设施的利用冷凝物毛细作用的保温系统 |
| US7574871B2 (en) * | 2004-10-27 | 2009-08-18 | Research Products Corporation | Systems and methods for whole-house dehumidification based on dew point measurements |
| CN2844754Y (zh) * | 2005-12-19 | 2006-12-06 | 上海约顿机房设备有限公司 | 一种精确控制温湿度的空调 |
| US8301335B2 (en) * | 2008-05-28 | 2012-10-30 | Chrysler Group Llc | Efficient AC operation using dew-point temperature |
| GB0812169D0 (en) * | 2008-07-03 | 2008-08-13 | Lester Stephen | Water and room heater |
| US8297069B2 (en) * | 2009-03-19 | 2012-10-30 | Vette Corporation | Modular scalable coolant distribution unit |
| JP5296655B2 (ja) * | 2009-10-23 | 2013-09-25 | 株式会社日立ハイテクノロジーズ | ガスの温湿度調節方法及びガス供給装置 |
| US20110259573A1 (en) * | 2010-04-26 | 2011-10-27 | Gac Corporation | Cooling system |
| US7905096B1 (en) * | 2010-05-26 | 2011-03-15 | International Business Machines Corporation | Dehumidifying and re-humidifying air cooling for an electronics rack |
| US20120090808A1 (en) * | 2010-10-18 | 2012-04-19 | Alcatel-Lucent Usa, Incorporated | Liquid cooling of remote or off-grid electronic enclosures |
| CH704462B1 (de) * | 2011-02-14 | 2015-01-15 | Mentus Holdig Ag | Flüssigkeit-Luft-Wärmeaustauschgerät mit Peltierelementen. |
| JP2013088031A (ja) * | 2011-10-18 | 2013-05-13 | Hitachi Plant Technologies Ltd | 冷却システムとその制御方法 |
-
2011
- 2011-08-31 CH CH01423/11A patent/CH705453B1/de not_active IP Right Cessation
-
2012
- 2012-08-23 WO PCT/EP2012/066409 patent/WO2013030080A2/de not_active Ceased
- 2012-08-23 EP EP12758795.4A patent/EP2751494B1/de not_active Not-in-force
- 2012-08-23 KR KR1020147005384A patent/KR20140059215A/ko not_active Withdrawn
- 2012-08-23 CN CN201280042463.3A patent/CN103765121B/zh not_active Expired - Fee Related
- 2012-08-23 BR BR112014004693A patent/BR112014004693A2/pt not_active IP Right Cessation
- 2012-08-23 JP JP2014527593A patent/JP2014529054A/ja not_active Ceased
- 2012-08-23 US US14/342,363 patent/US20140216710A1/en not_active Abandoned
- 2012-08-23 ES ES12758795.4T patent/ES2565815T3/es active Active
- 2012-08-23 RU RU2014112116/12A patent/RU2014112116A/ru not_active Application Discontinuation
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2013030080A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2751494B1 (de) | 2015-12-30 |
| WO2013030080A3 (de) | 2013-06-06 |
| BR112014004693A2 (pt) | 2017-03-28 |
| KR20140059215A (ko) | 2014-05-15 |
| CN103765121A (zh) | 2014-04-30 |
| JP2014529054A (ja) | 2014-10-30 |
| CN103765121B (zh) | 2016-07-06 |
| WO2013030080A2 (de) | 2013-03-07 |
| ES2565815T3 (es) | 2016-04-07 |
| CH705453B1 (de) | 2015-06-30 |
| CH705453A1 (de) | 2013-03-15 |
| US20140216710A1 (en) | 2014-08-07 |
| RU2014112116A (ru) | 2015-10-10 |
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