EP2935525A1 - Gazéification améliorée du charbon - Google Patents

Gazéification améliorée du charbon

Info

Publication number
EP2935525A1
EP2935525A1 EP12890529.6A EP12890529A EP2935525A1 EP 2935525 A1 EP2935525 A1 EP 2935525A1 EP 12890529 A EP12890529 A EP 12890529A EP 2935525 A1 EP2935525 A1 EP 2935525A1
Authority
EP
European Patent Office
Prior art keywords
gasification zone
entrained flow
fluidized
syngas
gasifier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12890529.6A
Other languages
German (de)
English (en)
Other versions
EP2935525A4 (fr
Inventor
Long Wu
Yunhui DENG
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Original Assignee
Linde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde GmbH filed Critical Linde GmbH
Publication of EP2935525A1 publication Critical patent/EP2935525A1/fr
Publication of EP2935525A4 publication Critical patent/EP2935525A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/485—Entrained flow gasifiers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C10J3/56—Apparatus; Plants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/026—Dust removal by centrifugal forces
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/15—Details of feeding means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C10J2300/0933—Coal fines for producing water gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C10J2300/0936—Coal fines for producing producer gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam

Definitions

  • Coal gasification technologies are mainly classified into three types: fixed bed gasifiers such as those made available from Lurgi, fluidized bed gasifiers such as those from UGAS and entrained flow gasifiers like those from Shell and General Electric.
  • the fixed bed gasifiers have disadvantages in terms of low throughput of single unit and costly syngas and water treatment systems.
  • the fluidized bed gasifiers have problems with dry bottom ash discharging, high fly ash carried over and low carbon conversions.
  • the major defects are narrow range of suitable types of coal feedstock and the particle size of the coal fed to the gasifier must be kept below 75 micron.
  • the invention seeks to overcome these limitations by combining normal fluidized bed and entrained flow coal gasification technologies to improve their operation, efficiencies and reduce costs.
  • a gasifier for producing syngas comprising an upper fluidized gasification zone in fluid communication through a Venturi throat with a lower entrained flow
  • the gasifier has refractory lining walls in the upper fluidized gasification zone and water membrane walls in the lower entrained flow gasification zone.
  • the two gasification zones have pipes and openings to allow for the injecting of materials for forming syngas, namely coal, coal fines and other reactants such as oxygen and steam.
  • the two gasification zones are connected by a Venturi throat which has a diameter that is narrower than both gasification zones.
  • the entrained flow gasification zone has an opening at the bottom to allow for the removal of liquid slag while the fluidized gasification zone has an opening at the top to allow for recovery of the syngas produced as well as fines and other product gases produced.
  • a method for producing syngas comprising the steps: a) Feeding coal fines, oxygen and steam simultaneously to a fluidized gasification zone and an entrained flow gasification zone; b) Reacting the coal fines in the presence of oxygen and steam to form syngas; c) Feeding syngas from the entrained gasification zone to the fluidized gasification zone; and d) Recovering syngas from the fluidized gasification zone.
  • the coal fines that are fed to the fluidized gasification zone are larger than those fed to the other zone and are greater than 75 micron in size.
  • the coal fines fed to the entrained flow gasification zone are less than 75 micron in size.
  • the fluidized gasification zone is at a temperature of about 1000°C or below the coal ash deformation temperature, while the entrained flow gasification zone is at a temperature of about 1500°C or above the coal ash fluid temperature.
  • the syngas that is produced in both gasification zones is fed through an opening at the top of the fluidized gasification zone at a temperature of about 900 to 1000°C to a first stage cyclone which will allow for recovery of the syngas as well as the recovery of unreacted coal fines which can be fed back to the fluidized gasification zone.
  • a second cyclone will capture smaller unreacted coal fines and these are recycled back to the entrained flow gasification zone.
  • gasifier and methods of the invention can be used in a variety of applications such as integrated gas combined cycle, coal to chemicals, production of synthetic natural gas, etc.
  • FIG. 1 The figure is a schematic of a two-stage coal gasifier according to the invention.
  • the two-stage coal gasifier is shown.
  • a fluidized gasification zone A sits above an entrained flow gasification zone B being connected by a Venturi throat C.
  • the fluidized gasification zone has walls that comprise a refractory material D.
  • the entrained flow gasification zone has wall that comprise by a water membrane wall E.
  • Gasification is occurring in both zones such that coal particles of various particle size distributions are contacted with oxygen and/or steam.
  • the resulting products include syngas and a measured amount of carbon dioxide plus methane.
  • Coal having a particle size below 75 microns and fines recycled from a second stage cyclone are injected through line 9 into the entrained flow gasification zone B.
  • the coal is transported in nitrogen or carbon dioxide.
  • the gasification temperature is controlled at around 1500 to 1600°C above the coal ash fluid temperature.
  • the operating pressure is about 3.0 to 4.0 MPa.
  • the steam that is injected into the entrained flow gasification zone B is used to control the gas temperature and flow rate entering the upper fluidized gasification zone A.
  • the water membrane wall E is essentially high- pressure tubes containing water which helps cool the entrained flow gasification zone B. Steam is also generated inside the tubes.
  • the tubes are provided with studs that act as anchors for a thin layer of castable refractory which is typically silicon carbide. During operation of the gasifier, the castable refractory will ideally be covered by a layer of solid slag, over which the liquid slag will run to the bottom 10 of the entrained flow gasification zone B.
  • the hot syngas that is generated enters the fluidized gasification zone A through a Venturi throat C where the local temperature above the Venturi throat C is maintained at about the coal ash softening temperature.
  • the Venturi throat C also functions as a "classifier" in the sense that agglomerate char particles with higher density could drop into the section below the Venturi throat C and carry out secondary reactions thereby becoming melting slag. The melting slag will exit the entrained flow
  • Coal having a larger particle size, above 75 microns and below 10 millimeter is fed into the dense phase of the fluidized bed section in the fluidized gasification zone A through line 1 .
  • the fluidizing gas is oxygen and steam.
  • the fines collected from the first stage cyclone (not shown) are recycled and reinjected into the fluidized gasification zone A through line 2.
  • the fluidizing oxygen and steam are injected through lines 3, 4, 5 and 6.
  • the raw syngas produced which is primarily hydrogen and carbon monoxide with some methane present as well will exit the fluidized gasification zone A through opening 1 1 to the first stage cyclone. This syngas reaction
  • the temperature is at a temperature of about 900 to 1000°C or below the coal ash deformation temperatures.
  • the discharged rate of reacted residues or char is controlled by the Venturi throat C.
  • the fluidized gasification zone A is typically constructed with a normal refractory wall which consists of an outer layer of insulating bricks to protect the outer steel shell of the reactor from high temperatures and an inner layer of more compact bricks that can better withstand the high temperatures and the erosive conditions inside the gasifier.
  • the cyclones that are used in the methods of the invention connect to the upper section of the gasifier, fluidized gasification zone through line 1 1 and the bottom part of the gasifier, entrained flow gasification zone B through line 9.
  • the first cyclone captures 98 to 99% of the fines carried over the top of the gasifier through line 1 1 . These fines contain significant amounts of carbon and are recycled to the fluidized gasification zone A through line 2 for secondary reactions in the gasifier.
  • the second cyclone captures the remainder of fines having a smaller particle size which will lower gasification reactivity. These smaller fines are recycled in to the bottom of the entrained flow gasification zone B through line 9 where they are reacted under more severe conditions to burnout the extra amount of carbon present in the smaller fines.
  • Advantages of the invention include an ash slagging and quench procedure to alleviate the problem of dry ash discharging of fluidized bed gasifiers.
  • the slag can simply be discharged through the bottom 10 of the entrained flow gasification zone B.
  • PSD coal particle size distribution
  • the carbon conversion of fluidized gasifiers can be improved by increasing the ash discharging temperature.
  • the thermal efficiency of entrained flow gasifiers can be improved by eliminating the recycle of cold syngas or extra steam. Also the amount of fly ash carried over from the fluidized bed gasifiers is reduced and with it there would be less disposal costs.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

Un gazéificateur bizone est utilisé en vue de la production de gaz de synthèse à partir de fines de charbon, d'oxygène et de vapeur d'eau. Ledit gazéificateur bizone comporte une zone de gazéification supérieure en lit fluidisé et une zone de gazéification inférieure à flux entraîné reliées par un goulot de Venturi. Il y aura production de gaz de synthèse dans les deux zones et le gaz de synthèse sera recueilli depuis le haut du gazéificateur.
EP12890529.6A 2012-12-18 2012-12-18 Gazéification améliorée du charbon Withdrawn EP2935525A4 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2012/086808 WO2014094217A1 (fr) 2012-12-18 2012-12-18 Gazéification améliorée du charbon

Publications (2)

Publication Number Publication Date
EP2935525A1 true EP2935525A1 (fr) 2015-10-28
EP2935525A4 EP2935525A4 (fr) 2016-10-05

Family

ID=50977516

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12890529.6A Withdrawn EP2935525A4 (fr) 2012-12-18 2012-12-18 Gazéification améliorée du charbon

Country Status (8)

Country Link
US (1) US20150315498A1 (fr)
EP (1) EP2935525A4 (fr)
CN (1) CN104995286A (fr)
AU (1) AU2012397141A1 (fr)
CA (1) CA2893970A1 (fr)
RU (1) RU2628390C2 (fr)
WO (1) WO2014094217A1 (fr)
ZA (1) ZA201504329B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2612580B1 (es) * 2017-03-24 2018-03-07 Af Ingenieria, S.L. Equipo de tratamiento de residuos
CN113278451A (zh) * 2021-06-15 2021-08-20 宋新朝 一种浆态床复合流化床煤气化系统及工艺

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB673648A (en) * 1948-01-08 1952-06-11 Directie Staatsmijnen Nl Improvements in or relating to the conversion of finely divided solid carbonaceous material into gas mixtures
SU77694A1 (ru) * 1949-01-04 1949-11-30 А.А. Лях Двухзонный газогенератор со швельшахтой
US3782913A (en) * 1972-03-23 1974-01-01 Us Interior Two-stage gasification of coal with forced reactant mixing and steam treatment of recycled char
GB2086411B (en) * 1980-10-27 1984-03-28 British Gas Corp Efg process
US4391612A (en) * 1981-05-28 1983-07-05 The Halcon Sd Group, Inc. Gasification of coal
FR2530796A1 (fr) * 1982-07-21 1984-01-27 Creusot Loire Dispositif de conversion et de recuperation thermique
FI80066C (fi) * 1986-01-22 1991-07-29 Ahlstroem Oy Foerfarande och anordning foer foergasning av kolhaltigt material.
CN2608507Y (zh) * 2003-02-12 2004-03-31 田原宇 两段粉煤循环流化床气化装置
CN101432400B (zh) * 2006-05-01 2012-11-14 国际壳牌研究有限公司 气化反应器及其应用
CN101440307B (zh) * 2008-12-23 2013-04-03 煤炭科学研究总院 一种固定床-流化床耦合气化方法及装置
CN201852134U (zh) * 2010-09-26 2011-06-01 安徽金鼎锅炉股份有限公司 一种应用于锅炉上的锅炉膜式水冷壁

Also Published As

Publication number Publication date
ZA201504329B (en) 2019-12-18
EP2935525A4 (fr) 2016-10-05
US20150315498A1 (en) 2015-11-05
RU2015129477A (ru) 2017-01-23
CN104995286A (zh) 2015-10-21
AU2012397141A1 (en) 2015-06-25
WO2014094217A1 (fr) 2014-06-26
CA2893970A1 (fr) 2014-06-26
RU2628390C2 (ru) 2017-08-16

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