EP2956529A1 - Wirbelschichtvergaser - Google Patents
WirbelschichtvergaserInfo
- Publication number
- EP2956529A1 EP2956529A1 EP14705731.9A EP14705731A EP2956529A1 EP 2956529 A1 EP2956529 A1 EP 2956529A1 EP 14705731 A EP14705731 A EP 14705731A EP 2956529 A1 EP2956529 A1 EP 2956529A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fluidized bed
- bed gasifier
- gasifier
- heating
- carburettor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000010438 heat treatment Methods 0.000 claims abstract description 16
- 210000003850 cellular structure Anatomy 0.000 claims abstract description 10
- 239000000919 ceramic Substances 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 5
- 238000010926 purge Methods 0.000 claims description 7
- 239000000446 fuel Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 3
- 229910002060 Fe-Cr-Al alloy Inorganic materials 0.000 claims description 3
- -1 Al 2 O 3 Chemical class 0.000 claims description 2
- 229910016006 MoSi Inorganic materials 0.000 claims description 2
- 238000007792 addition Methods 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims description 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 2
- 150000002602 lanthanoids Chemical class 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 229910052755 nonmetal Inorganic materials 0.000 claims description 2
- 229910052706 scandium Inorganic materials 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- 239000007789 gas Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000002309 gasification Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
- C10J3/56—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/726—Start-up
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/12—Radiant burners
- F23D14/125—Radiant burners heating a wall surface to incandescence
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0989—Hydrocarbons as additives to gasifying agents to improve caloric properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1223—Heating the gasifier by burners
Definitions
- the invention is directed to a fluidized bed gasifier, in particular high temperature Winkler carburettor, with a cyclone separator associated with the gasifier head and with a solids return line from the cyclone to the bottom of the gasifier.
- Winkler carburettors are known, for example, EP 0 264 810 or DE 11 2009 000 287 or WO 2009/145724.
- a fluidized bed is generated and at least a portion of the dust discharged with the raw gas a cyclone separated and returned to the carburetor (DE 44 13 923 AI).
- heating torches are provided in the lower funnel area, which serves for the ash discharge, which bring the refractory lining of the carburetor to the necessary temperature.
- the storage heat of the lining makes it possible to ignite a fluidized bed material (charcoal, hearth furnace coke) and thus to enable the starting process.
- the object of the present invention is to avoid the disadvantages described above, i. to make an expansion of Auffilbrenner dispensable.
- this object is achieved according to the invention in that in particular in the lower region of the carburetor planar Auffilbrenner are provided which have a metallic or ceramic cellular structure.
- the invention also provides in an embodiment that the flat heating torch are positioned further up in the cylindrical portion of the carburetor.
- the burners can be positioned in the post-gasification zone, so that less purge gas is required, because there the solids content is lower.
- the AufMapnner can advantageously for example from a Metal fabric may be formed from a high-temperature steel or else, as the invention also provides in an embodiment, of a ceramic with a cellular structure.
- a high temperature steel may be Fe-Cr-Al based alloys that have high corrosion and high temperature resistance.
- the resistance is improved by the presence of an oxide layer on the surface, in particular by Al 2 O 3, whereby this oxide layer forms spontaneously on the surface due to the oxidation of Al to Al 2 O 3 on its own.
- Temperatures between 1000 ° C and 1200 ° C are preferred for such pre-oxidation.
- a further embodiment of the burner according to the invention may consist in that for the formation of the burner metal oxides, such as Al2O3, as already mentioned above, or CaO, CeO, Cr 2 0 3 , Fe 2 0 3 , Hf0 2 , MgO, Si0 2 , Zr0 2nd as single components or as a mixture, non-metal oxides such as BN, BC, MoSi 2 or SiN as single components or as a mixture or metals based on Fe-Cr-Al with additions of Sc, Y, Ti, Zr, Hf, V, Nb, Ta and Lanthanides are used.
- the burner metal oxides such as Al2O3, as already mentioned above, or CaO, CeO, Cr 2 0 3 , Fe 2 0 3 , Hf0 2 , MgO, Si0 2 , Zr0 2nd as single components or as a mixture
- non-metal oxides such as BN, BC, MoSi 2 or SiN as single components or as a mixture or
- the burners may be designed according to the invention, for example, as rectangular or trapezoidal surface elements for installation in the funnel wall of the reactor, without the invention being limited to this particular shape.
- the combustion media can be air, oxygen and moderator (C02, N 2 ), which can be provided as flushing media eg C0 2 , N 2 , synthesis gas or flue gas.
- the burners can be stoichiometric or substoichiometric.
- 1 is a simplified representation of a section through a high-temperature Winkler carburetor and in
- Fig. 2 shows an enlarged detail of the ash hopper with AufMultibrennern in a simplified representation.
- a high temperature Winkler carburetor is formed by a carburetor body 2 of refractory masonry, which is provided in the direction of gravity at the bottom with a conical outlet region 2a.
- a supply line 3 is positioned to a cyclone 4, wherein the cyclone 4 passes the separated solid particles via a return line 5 in the lower portion 2a of the carburetor 2.
- Feed lines for introducing gasification components and for exit into a fluidized bed are shown in FIG. 1 only indicated and designated 6 to 8.
- the heating torches 9 according to the invention are positioned, this region in FIG. 2 enlarged, but also simplified.
- the AufMapnner 9 have on their surface on a cellular structure 10, through which flow the combustion gases or, depending on the operation, purge gases which are supplied via lines 11 to the flat burners.
- This cellular Structure may be provided, for example, by a metal mesh formed of high-temperature steel or also of ceramic having a corresponding cellular structure.
- the flat burners may be rectangular or trapezoidal, without the invention being limited to these specific designs.
- Fig. 1 is still indicated that the burner 9a can be positioned further up in the cylindrical part of the carburetor body 2, as described above.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Combustion Of Fluid Fuel (AREA)
- Fluidized-Bed Combustion And Resonant Combustion (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102013101368.6A DE102013101368B4 (de) | 2013-02-12 | 2013-02-12 | Wirbelschichtvergaser |
| PCT/EP2014/052427 WO2014124875A1 (de) | 2013-02-12 | 2014-02-07 | Wirbelschichtvergaser |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2956529A1 true EP2956529A1 (de) | 2015-12-23 |
Family
ID=50151260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP14705731.9A Withdrawn EP2956529A1 (de) | 2013-02-12 | 2014-02-07 | Wirbelschichtvergaser |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP2956529A1 (de) |
| CN (1) | CN105102591A (de) |
| BR (1) | BR112015019147A2 (de) |
| DE (1) | DE102013101368B4 (de) |
| TW (1) | TW201432043A (de) |
| WO (1) | WO2014124875A1 (de) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102017219780A1 (de) * | 2017-11-07 | 2019-05-09 | Thyssenkrupp Ag | Vorrichtung und Verfahren zum HTW-Vergasen von Einsatzstoffen mit Ringleitungs-Anordnung sowie Verwendung |
| CN111288490B (zh) * | 2020-03-23 | 2024-06-14 | 上海电力大学 | 一种分散凸台处高温回流区的燃烧室装置 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012074942A2 (en) * | 2010-11-29 | 2012-06-07 | Synthesis Energy Systems, Inc. | Method and apparatus for particle recycling in multiphase chemical reactors |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1939606U (de) * | 1962-09-28 | 1966-06-02 | Clare Brothers Ltd | Infrarot-strahlungsbrenner. |
| US3925024A (en) * | 1971-09-10 | 1975-12-09 | Borden Inc | Grid burner system |
| US4673349A (en) * | 1984-12-20 | 1987-06-16 | Ngk Insulators, Ltd. | High temperature surface combustion burner |
| DE3636024A1 (de) | 1986-10-23 | 1988-05-05 | Rheinische Braunkohlenw Ag | Kraftwerksprozess mit einer gasturbine |
| DE3727146C1 (de) * | 1987-08-14 | 1988-09-22 | Rheinische Braunkohlenw Ag | Verfahren zum Anfahren eines Vergasers |
| US4919609A (en) * | 1989-05-02 | 1990-04-24 | Gas Research Institute | Ceramic tile burner |
| DE4041061A1 (de) * | 1989-12-22 | 1991-06-27 | Siemens Ag | Brennerplatte fuer einen flaechenbrenner |
| DE4322109C2 (de) | 1993-07-02 | 2001-02-22 | Franz Durst | Brenner für ein Gas/Luft-Gemisch |
| DE4413923C2 (de) | 1994-04-21 | 2001-11-29 | Rheinische Braunkohlenw Ag | Verfahren zum Erzeugen von Synthese- und/oder Brenngas in einem Hochtemperatur-Winkler-Vergaser |
| AU3512399A (en) * | 1998-04-28 | 1999-11-16 | Bruno Berger | Waste to energy method for producing electricity, water and/or hydrogen and/or methanol from biomass and/or organic waste |
| US7846226B2 (en) | 2008-02-13 | 2010-12-07 | General Electric Company | Apparatus for cooling and scrubbing a flow of syngas and method of assembling |
| SE0801266A0 (sv) | 2008-05-29 | 2009-12-21 | Blasiak Wlodzimierz | Tvåstegsförgasare som använder förupphettad ånga av hög temperatur |
| IT1391443B1 (it) * | 2008-10-28 | 2011-12-23 | Ansaldo Ricerche S P A | Gassificatore e metodo di accensione di detto gassificatore |
| DE102009028624A1 (de) * | 2009-08-18 | 2011-02-24 | Sandvik Intellectual Property Ab | Strahlungsbrenner |
| DE102009039920A1 (de) * | 2009-09-03 | 2011-03-10 | Karl-Heinz Tetzlaff | Verfahren und Vorrichtung zur Nutzung von Sauerstoff bei der Dampfreformierung von Biomasse |
-
2013
- 2013-02-12 DE DE102013101368.6A patent/DE102013101368B4/de active Active
-
2014
- 2014-02-07 EP EP14705731.9A patent/EP2956529A1/de not_active Withdrawn
- 2014-02-07 BR BR112015019147A patent/BR112015019147A2/pt not_active IP Right Cessation
- 2014-02-07 CN CN201480020702.4A patent/CN105102591A/zh active Pending
- 2014-02-07 TW TW103104060A patent/TW201432043A/zh unknown
- 2014-02-07 WO PCT/EP2014/052427 patent/WO2014124875A1/de not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012074942A2 (en) * | 2010-11-29 | 2012-06-07 | Synthesis Energy Systems, Inc. | Method and apparatus for particle recycling in multiphase chemical reactors |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112015019147A2 (pt) | 2017-07-18 |
| TW201432043A (zh) | 2014-08-16 |
| WO2014124875A1 (de) | 2014-08-21 |
| CN105102591A (zh) | 2015-11-25 |
| DE102013101368B4 (de) | 2023-04-27 |
| DE102013101368A1 (de) | 2014-08-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20150810 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| AX | Request for extension of the european patent |
Extension state: BA ME |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: WERNER, THOMAS Inventor name: PAVONE, DOMENICO Inventor name: ABRAHAM, RALF Inventor name: TOPOROV, DOBRIN |
|
| DAX | Request for extension of the european patent (deleted) | ||
| 17Q | First examination report despatched |
Effective date: 20170411 |
|
| RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: THYSSENKRUPP INDUSTRIAL SOLUTIONS AG |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 20181201 |