EP2997172A2 - Acier à haute résistance manifestant une bonne ductilité et son procédé d'élaboration par traitement de trempe et de partitionnement en bain de zinc - Google Patents

Acier à haute résistance manifestant une bonne ductilité et son procédé d'élaboration par traitement de trempe et de partitionnement en bain de zinc

Info

Publication number
EP2997172A2
EP2997172A2 EP14729827.7A EP14729827A EP2997172A2 EP 2997172 A2 EP2997172 A2 EP 2997172A2 EP 14729827 A EP14729827 A EP 14729827A EP 2997172 A2 EP2997172 A2 EP 2997172A2
Authority
EP
European Patent Office
Prior art keywords
temperature
steel sheet
austenite
partitioning
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14729827.7A
Other languages
German (de)
English (en)
Other versions
EP2997172B1 (fr
Inventor
Grant Aaron THOMAS
Luis G. GARZA-MARTINEZ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cleveland Cliffs Steel Properties Inc
Original Assignee
AK Steel Properties Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AK Steel Properties Inc filed Critical AK Steel Properties Inc
Publication of EP2997172A2 publication Critical patent/EP2997172A2/fr
Application granted granted Critical
Publication of EP2997172B1 publication Critical patent/EP2997172B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/78—Combined heat-treatments not provided for above
    • C21D1/785—Thermocycling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/005—Heat treatment of ferrous alloys containing Mn
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • C23C2/0224—Two or more thermal pretreatments
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/024—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06—Zinc or cadmium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36—Elongated material
    • C23C2/40—Plates; Strips
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/001—Austenite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals

Definitions

  • the steel sheet is first heated to a peak metal temperature
  • niobium or other micro-alloying elements, such as
  • Example 5 The compositions of Example 5 were subjected to Gleeble dilatomety. Gleeble dilatomety.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Coating With Molten Metal (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)

Abstract

L'acier à haute résistance et aptitude à la mise en forme selon l'invention est élaboré à l'aide de compositions et de procédés permettant la formation d'une microstructure austénitique et martensitique dans l'acier. Le carbone, le manganèse, le molybdène, le nickel, le cuivre et le chrome peuvent favoriser la formation d'austénite stable (ou méta-stable) à température ambiante par des mécanismes tels que l'abaissement des températures de transformation pour les constituants non martensitiques et/ou l'accroissement de la trempabilité de l'acier. Des cycles thermiques utilisant un refroidissement rapide au-dessous de la température de départ de la martensite, suivi d'un réchauffage peuvent favoriser la formation d'une austénite stable à température ambiante en autorisant la diffusion du carbone dans l'austénite à partir de la martensite.
EP14729827.7A 2013-05-17 2014-05-16 Procédé de production d'un acier à haute résistance mécanique et à bonne ductilité par traitement de trempe et de partitionnement en bain de zinc Active EP2997172B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361824643P 2013-05-17 2013-05-17
US201361824699P 2013-05-17 2013-05-17
PCT/US2014/038425 WO2014186722A2 (fr) 2013-05-17 2014-05-16 Acier à haute résistance manifestant une bonne ductilité et son procédé d'élaboration par traitement de trempe et de partitionnement en bain de zinc

Publications (2)

Publication Number Publication Date
EP2997172A2 true EP2997172A2 (fr) 2016-03-23
EP2997172B1 EP2997172B1 (fr) 2020-08-26

Family

ID=50933550

Family Applications (2)

Application Number Title Priority Date Filing Date
EP14729827.7A Active EP2997172B1 (fr) 2013-05-17 2014-05-16 Procédé de production d'un acier à haute résistance mécanique et à bonne ductilité par traitement de trempe et de partitionnement en bain de zinc
EP14734592.0A Active EP2997168B1 (fr) 2013-05-17 2014-05-16 Procédé de fabrication d'une tôle d'acier galvanisée et ou galvannee par immersion à chaud, par tranché et partitionnement

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP14734592.0A Active EP2997168B1 (fr) 2013-05-17 2014-05-16 Procédé de fabrication d'une tôle d'acier galvanisée et ou galvannee par immersion à chaud, par tranché et partitionnement

Country Status (12)

Country Link
US (2) US20140338797A1 (fr)
EP (2) EP2997172B1 (fr)
JP (3) JP6843612B2 (fr)
KR (5) KR20170104159A (fr)
CN (3) CN113151735A (fr)
AU (2) AU2014265214B2 (fr)
BR (2) BR112015027901B1 (fr)
CA (2) CA2910012C (fr)
MX (2) MX378110B (fr)
RU (3) RU2669654C2 (fr)
TW (4) TWI616538B (fr)
WO (2) WO2014186689A2 (fr)

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KR20170104159A (ko) * 2013-05-17 2017-09-14 에이케이 스틸 프로퍼티즈 인코포레이티드 양호한 연성을 나타내는 고강도 스틸 그리고 용융 아연 욕 하류의 인-라인 열처리를 통한 생산 방법
WO2016020714A1 (fr) 2014-08-07 2016-02-11 Arcelormittal Procédé permettant de produire une tôle d'acier revêtue présentant une meilleure résistance, une meilleure ductilité et une meilleure aptitude au formage
CN104532126B (zh) * 2014-12-19 2017-06-06 宝山钢铁股份有限公司 一种低屈强比超高强度热轧q&p钢及其制造方法
UA119189C2 (uk) * 2015-01-14 2019-05-10 Ейкей Стіл Пропертіс, Інк. Двофазна сталь з покращеними властивостями
WO2019090109A1 (fr) 2017-11-02 2019-05-09 Ak Steel Properties, Inc. Acier trempé sous presse ayant des propriétés sur mesure
CA3093397C (fr) * 2018-03-30 2024-01-30 Ak Steel Properties, Inc. Acier a haute resistance de pointe de troisieme generation faiblement allie et procede pour la fabrication de celui-ci
CN109554621B (zh) * 2018-12-03 2020-11-27 东北大学 一种低密度Fe-Mn-Al-C热轧Q＆P钢及其制造方法
CN109554622B (zh) * 2018-12-03 2020-12-04 东北大学 淬火至贝氏体区获得Q＆P组织的热轧Fe-Mn-Al-C钢及制造方法
CN110055465B (zh) * 2019-05-16 2020-10-02 北京科技大学 一种中锰超高强度钢及其制备方法
CN112327970B (zh) * 2020-09-04 2022-04-12 凌云工业股份有限公司 一种热成型变强度工件过渡区强度的控制方法
EP4317511A4 (fr) * 2021-04-02 2024-10-02 Baoshan Iron & Steel Co., Ltd. Acier trempé et revenu faiblement allié à faible teneur en carbone ou acier trempé et revenu galvanisé à chaud ayant une résistance à la traction supérieure ou égale à 1 180 mpa, et son procédé de fabrication
CN114774652B (zh) * 2022-04-29 2024-07-23 重庆长征重工有限责任公司 一种17CrNiMo6材料预备热处理方法
WO2025255081A1 (fr) * 2024-06-07 2025-12-11 Cleveland-Cliffs Steel Properties Inc. Acier à haute résistance ayant une austénite résiduelle

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AU2014265214B2 (en) 2016-12-22
CN113151735A (zh) 2021-07-23
JP2016524038A (ja) 2016-08-12
CN105392906A (zh) 2016-03-09
WO2014186722A3 (fr) 2015-01-08
KR20190101504A (ko) 2019-08-30
KR101776241B1 (ko) 2017-09-07
JP2016526096A (ja) 2016-09-01
KR20170104159A (ko) 2017-09-14
KR20170104158A (ko) 2017-09-14
RU2018133682A (ru) 2020-03-25
KR20160007646A (ko) 2016-01-20
CA2908491A1 (fr) 2014-11-20
AU2014265262B2 (en) 2016-12-15
EP2997168B1 (fr) 2021-03-03
TW201502284A (zh) 2015-01-16
KR20160007647A (ko) 2016-01-20
RU2669654C2 (ru) 2018-10-12
MX2015015333A (es) 2016-06-23
CA2910012C (fr) 2020-02-18
US20140338798A1 (en) 2014-11-20
BR112015027447B1 (pt) 2020-04-22
CA2910012A1 (fr) 2014-11-20
WO2014186722A2 (fr) 2014-11-20
RU2015145865A3 (fr) 2018-03-29
MX2015015332A (es) 2016-07-15
RU2015141563A (ru) 2017-06-22
TWI627288B (zh) 2018-06-21
AU2014265214A1 (en) 2015-11-05
EP2997172B1 (fr) 2020-08-26
EP2997168A2 (fr) 2016-03-23
AU2014265262A1 (en) 2015-11-12
TWI616538B (zh) 2018-03-01
CN105247090A (zh) 2016-01-13
JP2018178262A (ja) 2018-11-15
TW201708562A (zh) 2017-03-01
WO2014186689A2 (fr) 2014-11-20
RU2632042C2 (ru) 2017-10-02
WO2014186689A3 (fr) 2015-01-22
BR112015027447A2 (pt) 2017-07-25
CA2908491C (fr) 2019-07-30
TWI564402B (zh) 2017-01-01
JP6843612B2 (ja) 2021-03-17
TWI560279B (en) 2016-12-01
KR101776242B1 (ko) 2017-09-07
TW201446974A (zh) 2014-12-16
US20140338797A1 (en) 2014-11-20
RU2018133682A3 (fr) 2020-03-25
MX378110B (es) 2025-03-10
RU2015145865A (ru) 2017-06-22
BR112015027901A2 (pt) 2017-07-25
TW201702397A (zh) 2017-01-16
BR112015027901B1 (pt) 2020-04-22

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