EP3258122A1 - Injecteur a disques de portions individuelles comprenant un durcisseur reticule micro-encapsule - Google Patents
Injecteur a disques de portions individuelles comprenant un durcisseur reticule micro-encapsule Download PDFInfo
- Publication number
- EP3258122A1 EP3258122A1 EP16174784.5A EP16174784A EP3258122A1 EP 3258122 A1 EP3258122 A1 EP 3258122A1 EP 16174784 A EP16174784 A EP 16174784A EP 3258122 A1 EP3258122 A1 EP 3258122A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- injector
- anchor bolt
- piston
- filling
- anchor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000011049 filling Methods 0.000 claims abstract description 85
- 229920005989 resin Polymers 0.000 claims abstract description 62
- 239000011347 resin Substances 0.000 claims abstract description 62
- 150000001875 compounds Chemical class 0.000 claims abstract description 43
- 239000003094 microcapsule Substances 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 35
- 238000007789 sealing Methods 0.000 claims description 29
- 239000004848 polyfunctional curative Substances 0.000 claims description 23
- 238000002156 mixing Methods 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 14
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000758 substrate Substances 0.000 description 23
- 150000002978 peroxides Chemical class 0.000 description 14
- 238000004873 anchoring Methods 0.000 description 12
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 9
- -1 allyl ethers Chemical class 0.000 description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229920001567 vinyl ester resin Polymers 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 238000003825 pressing Methods 0.000 description 5
- 239000011257 shell material Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229920006337 unsaturated polyester resin Polymers 0.000 description 4
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical class C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- 229940106691 bisphenol a Drugs 0.000 description 3
- 150000002118 epoxides Chemical class 0.000 description 3
- 239000001530 fumaric acid Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 3
- 150000001451 organic peroxides Chemical class 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 229920006332 epoxy adhesive Polymers 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 150000002432 hydroperoxides Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- DJKGDNKYTKCJKD-BPOCMEKLSA-N (1s,4r,5s,6r)-1,2,3,4,7,7-hexachlorobicyclo[2.2.1]hept-2-ene-5,6-dicarboxylic acid Chemical compound ClC1=C(Cl)[C@]2(Cl)[C@H](C(=O)O)[C@H](C(O)=O)[C@@]1(Cl)C2(Cl)Cl DJKGDNKYTKCJKD-BPOCMEKLSA-N 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- BPRJQFIHEGORJE-UHFFFAOYSA-N 2-(1-hydroxypropan-2-yloxy)propan-1-ol 1-(2-hydroxypropoxy)propan-2-ol Chemical compound CC(O)COCC(C)O.CC(CO)OC(C)CO BPRJQFIHEGORJE-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000005698 Diels-Alder reaction Methods 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- SYKNUAWMBRIEKB-UHFFFAOYSA-N [Cl].[Br] Chemical compound [Cl].[Br] SYKNUAWMBRIEKB-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- DJKGDNKYTKCJKD-UHFFFAOYSA-N chlorendic acid Chemical compound ClC1=C(Cl)C2(Cl)C(C(=O)O)C(C(O)=O)C1(Cl)C2(Cl)Cl DJKGDNKYTKCJKD-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 150000002976 peresters Chemical group 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 150000004978 peroxycarbonates Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 235000021081 unsaturated fats Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16B—DEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
- F16B13/00—Dowels or other devices fastened in walls or the like by inserting them in holes made therein for that purpose
- F16B13/14—Non-metallic plugs or sleeves; Use of liquid, loose solid or kneadable material therefor
- F16B13/141—Fixing plugs in holes by the use of settable material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16B—DEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
- F16B13/00—Dowels or other devices fastened in walls or the like by inserting them in holes made therein for that purpose
- F16B13/14—Non-metallic plugs or sleeves; Use of liquid, loose solid or kneadable material therefor
- F16B13/141—Fixing plugs in holes by the use of settable material
- F16B13/143—Fixing plugs in holes by the use of settable material using frangible cartridges or capsules containing the setting components
- F16B13/144—Fixing plugs in holes by the use of settable material using frangible cartridges or capsules containing the setting components characterised by the shape or configuration or material of the frangible cartridges or capsules
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16B—DEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
- F16B13/00—Dowels or other devices fastened in walls or the like by inserting them in holes made therein for that purpose
- F16B13/14—Non-metallic plugs or sleeves; Use of liquid, loose solid or kneadable material therefor
- F16B13/141—Fixing plugs in holes by the use of settable material
- F16B13/143—Fixing plugs in holes by the use of settable material using frangible cartridges or capsules containing the setting components
- F16B13/145—Fixing plugs in holes by the use of settable material using frangible cartridges or capsules containing the setting components characterised by the composition of the setting agents contained in the frangible cartridges or capsules
Definitions
- the invention relates to an injector for filling an annular space formed around an anchor bolt, a fastening arrangement with such an injector, a container with such an injector and a method for installing an armature using such an injector.
- the annular space which is formed around the anchor bolt anchored in a hole mechanical anchor, in particular expansion anchor, to fill with a filling material which cures in the annulus.
- the armature can be supported in the radial direction in the hole and also in the attachment, which can improve the load values.
- the filling of the annulus takes place from the center of the hole ago, namely by a filling channel formed in the anchor bolt.
- the nozzle of an injection device is sealingly attached to the filling channel and filling compound filled into the filling channel.
- the filled filling material exits through a transverse hole in the bolt.
- the filling of the annular space via a washer with a through hole, where an injection device is attached takes place.
- This single-portion Scheibeninjektor has a piston disc with a through hole for the anchor bolt and an upstream of the piston disc amount of a filling compound, wherein the piston disc forms a piston for displacing at least a portion of the amount of filling material in the annular space.
- the injector is placed around the anchor bolt like a washer. When setting the anchor, the piston disc is pressed against the substrate and in this case at least a portion of the amount of filling material is pressed into the annular space around the anchor bolt around.
- each filling for a single hole and since the injectors each have a washer-like piston disc, such an injector may also be referred to as a single-portion Scheibeninjektor.
- the EP 2597322 A2 relates to a threaded part, in particular a screw or nut.
- the thread of the threaded portion is provided with a coating containing microcapsules, at least a portion of the microcapsules containing a polymerizable adhesive.
- an unsaturated methacrylate can be used as adhesive for the generation of the adhesive effect.
- the hardener used in this case is a free-radical former, in particular a peroxide, which initiates the radical polymerization of the methacrylate.
- the object of the invention is to provide a particularly simple and quick to use and at the same time cheap and reliable injector for filling an annular bolt formed around an anchor bolt, wherein the injector in particular has a particularly good storage stability and allows a particularly high performance of the set anchor, and further to provide a mounting assembly with such an injector, a container with such an injector and a method for installing an anchor using such an injector.
- an injector for filling an annular space formed around an anchor bolt with a piston disc, which has a passage opening for the anchor bolt, and an upstream of the piston disc amount of a particular curable filling material, wherein the piston disc a piston for displacing at least one Forming part of the amount of the filling material in the annulus, wherein the filling material comprises a resin component containing as curable ingredient at least one free-radically curable resin, and a present in the form of microcapsules hardener component containing at least one curing agent for the radically curable resin of the resin component ,
- the invention has recognized that in a single-portion disc injector in comparison to other types of injectors special boundary conditions can be given.
- the receiving space for the filling compound is often comparatively small.
- the mixing effect of the injector on the filling material is often comparatively low, since relatively short flow paths are given, which often do not allow multi-stage mixer arrangements.
- the invention has further recognized that these particular constraints may limit the performance of conventional formulations and arrangements of the fill mass under some circumstances.
- a two-component epoxy adhesive with layered components is used with regard to the small receiving space of the injector, it will often be necessary to select a layer sequence with comparatively thin layers. Because usually in view of the relatively low mixing effect, as they typically have single-portion Scheibeninjektoren, only with comparatively thin layers useful mixing and thus a useful for the performance of the set anchor hardening behavior of the epoxy adhesive can be obtained. With such a reduction of the layer thickness, however, an undesirable decrease in storage stability often accompanies. Because small layer thicknesses usually contain correspondingly large contact surfaces with the other component, but also with the environment. Due to the low stability, a layered arrangement of the components, in particular in the case of free-radically curing adhesives, is frequently scarcely possible. Because with conventional free-radically curing adhesives, so many radicals in the hardener component often form even at low temperatures that it would come to premature crosslinking of the resin component due to the proximity to the resin component, which is inevitably given in a layered arrangement.
- the invention comes in and provides a composition and arrangement of the filling compound, which is particularly well suited in view of the boundary conditions, which sets up a single-portion Scheibeninjektor.
- the invention provides for the use of a free-radically curing resin component into which a microencapsulated hardener component is incorporated. By means of the microencapsulation, premature contact of the radicals from the hardener component with the resin with corresponding adverse effects on the storage stability can be avoided in a particularly simple and effective manner.
- the comparatively simple mixer arrangements of single-portion disk injectors are also sufficient here to ensure good curing behavior to achieve.
- curable fillers available, which are particularly well suited for the regularly comparatively simple mixer assemblies of single-portion Scheibeninjektoren and here allow a particularly good curing behavior.
- the fillers are particularly storage stable, despite the fact that the comparatively compact designs of single-portion Scheibeninjektoren often associated with a particularly close contact of the components of the fillers.
- the filling compound forms a flowable, hardenable mass, which can be displaced fluidly from the injector into the annular space around the armature and hardens in the annular space.
- the hardener component is microencapsulated, that is it is in the form of microcapsules. This may preferably be understood in the usual way in the art that the hardener component is present in the smallest portions in which it is immobilized by means of at least one wrapping material.
- a core-shell encapsulation may be provided, in which the hardener component is enveloped by the shell material, so that capsules are each provided with at least one shell.
- the microcapsules containing the hardener component are embedded in the filling compound in the resin component, that is to say the resin component forms a matrix which contains the microencapsulated hardener component distributed.
- the resin component and the hardener component of the filling compound are separated from each other by the shell material of the microcapsules, so that no reaction of the hardener component with the resin component takes place during storage and before displacement of the filling compound from the injector into the annular space.
- the microcapsules are opened so that the curing agent can henceforth act on the resin. As a result, the curing of the resin is started.
- the mechanically opening microcapsules should preferably not be too small, as this can ensure that the capsules are opened before they enter the annulus, so that a particularly effective curing process is given.
- the resin is polymerizable by means of the curing agent, which causes the curing of the filling compound.
- the resin component may also contain further constituents, for example an accelerator or a filler.
- the hardener component may additionally comprise, in addition to the hardening agent, further constituents, for example an inorganic filler.
- the filling material can be pressed out automatically into the annular space around the anchor bolt as part of the installation of the anchor
- the injector according to the invention is simply attached to the anchor and the anchor nut is tightened as usual and then the system is ready.
- no additional operation and no further tool such as a separate injection device, which would have to be connected consuming, needed.
- a particularly simple, faster, safer, more reliable and cost-effective filling process is given. Since according to the invention no supply line is needed, the amount of waste can be kept very small.
- the piston disc according to the invention forms a piston for displacing at least part of the quantity of filling compound from the injector into the annular space and for pressing at least part of the quantity of filling compound out of the injector into the annular space.
- filling compound can be pressed out of the injector by axially pressing the piston disk onto a surface, in particular by axially pressing the piston disk against the surface of the attachment but also against the surface of the substrate, these two surfaces forming the hole into which the anchor bolt is inserted, ring surrounded.
- a piston chamber which is reduced in volume by approaching the piston disk to the substrate and / or to the attachment under extrusion of filling compound.
- the piston disc is axially approximated to the substrate and / or to the attachment, that is, the piston disc is in particular at least approximately parallel to the passage opening in the piston disc and / or in particular moved at least approximately parallel to the longitudinal axis of the anchor bolt.
- this may in particular relate to the longitudinal axis of the anchor bolt and / or the longitudinal axis of the injector, the latter being able to be defined in particular by the passage opening in the piston disk.
- the piston disc is usually only a part, although often a large part, displace the amount of filling material in the annulus.
- the anchor on whose anchor bolt the injector according to the invention is arranged, may preferably be an expansion anchor, in particular an expansion anchor of the bolt type.
- An expansion anchor may in particular comprise a wedge gear which converts a pulling movement of the anchor bolt relative to the substrate into a radial movement of a spreading element arranged on the anchor bolt, in particular an expansion sleeve arranged on the anchor bolt, relative to the anchor bolt and thus anchors the anchor to the substrate.
- the anchor could in principle also be a chemical anchor, which is anchored in the substrate by means of a further filling compound, wherein this further filling compound can be chemically identical or different to the filling compound of the injector.
- the piston disc may preferably consist of a metal material. It can be manufactured, for example, in a stamping process, which can be advantageous in terms of cost.
- the radical-curable resin is a (meth) acrylate resin.
- ethylenically unsaturated compounds compounds having carbon-carbon triple bonds and thiol-Yne / Ene resins are suitable in the present invention, as known in the art.
- ethylenically unsaturated compounds comprising styrene and derivatives thereof, (meth) acrylates, vinyl esters, unsaturated polyesters, vinyl ethers, allyl ethers, itaconates, dicyclopentadiene compounds and unsaturated fats, of which in particular unsaturated polyester resins and vinyl ester resins are suitable and for example in the applications EP 1 935 860 A1 . DE 195 31 649 A1 and WO 10/108939 A1 are described. Vinyl ester resins are most preferred because of their hydrolytic resistance and excellent mechanical properties.
- DCPD resins can be distinguished as unsaturated polyester resins.
- the class of DCPD resins is obtained either by modification of one of the above resin types by Diels-Alder reaction with cyclopentadiene, or alternatively by a first reaction of a diacid, e.g. Maleic acid, with dicyclopentadiene, and then by a second reaction, the usual preparation of an unsaturated polyester resin, the latter being referred to as a DCPD maleate resin.
- a diacid e.g. Maleic acid
- vinyl ester resins are oligomers or polymers having at least one (meth) acrylate end group, so-called (meth) acrylate-functionalized resins (also referred to herein as (meth) acrylate resin), including urethane (meth) acrylate resins and epoxy (meth) acrylates count.
- Vinyl ester resins which have unsaturated groups only in the terminal position are obtained, for example, by reaction of epoxide oligomers or polymers (eg bisphenol adigylcidyl ether, epoxides of the phenol novolak type or epoxide oligomers based on tetrabromobisphenol A) with, for example, (meth) acrylic acid or (meth) acrylamide.
- Preferred vinyl ester resins are (meth) acrylate-functionalized resins and resins obtained by reacting an epoxy oligomer or polymer with methacrylic acid or methacrylamide, preferably with methacrylic acid. Examples of such compounds are from the applications US 3297745 A . US 3772404 A . US 4618658 A . GB 2217722 A1 . DE 3744390 A1 and DE 4131457 A1 known.
- the curing agent is conveniently at 20 ° C, ie at room temperature, liquid.
- the curing agent may in particular be a free-radical generator, preferably a peroxide.
- peroxides any of the peroxides known to those skilled in the art used to cure radically curable resins can be used.
- Such peroxides include organic and inorganic peroxides.
- suitable peroxides are peroxycarbonates (of the formula OC (O) O-), peroxyesters (of the formula -C (O) OO-), diacyl peroxides (of the formula -C (O) OOC (O) -), dialkyl peroxides (of the formula -OO-) and the like. These may be present as oligomer or polymer.
- a comprehensive set of examples of suitable peroxides is, for example, in the application US 2002/0091214-A1 , Paragraph [0018].
- the peroxides are preferably selected from the group of organic peroxides.
- Suitable organic peroxides are: tertiary alkyl hydroperoxides such as tert-butyl hydroperoxide and other hydroperoxides such as cumene hydroperoxide, peroxyesters or peracids such as tert-butyl peresters, benzoyl peroxide, peracetates and perbenzoates, lauryl peroxide including (di) peroxyesters, perethers such as peroxy diethyl ether, perketones, such as methyl ethyl ketone peroxide.
- the organic peroxides used as curing agents are often tertiary peresters or tertiary hydroperoxides, i. Peroxide compounds having tertiary carbon atoms bonded directly to an -O-O-acyl or -OOH group. But mixtures of these peroxides with other peroxides can be used according to the invention.
- the peroxides may also be mixed peroxides, i. Peroxides which have two different peroxide-carrying units in one molecule.
- benzoyl peroxide (BPO) is preferably used for curing.
- the amount of filling material is arranged in a reservoir.
- the reservoir may for example be a foil bag.
- the reservoir may in particular have a passage opening aligned with the passage opening of the piston disk in order to ensure passage of the anchor bolt through the injector without impairing the filling compound.
- the filling compound has a very high viscosity, so that the filling material is sufficiently dimensionally stable solely because of its viscosity, or if the injector completely encloses the amount of filling material, the reservoir can also be omitted.
- a further preferred embodiment of the invention is that the injector has a sealing disk, wherein the amount of filling material is at least partially, in particular completely, disposed between, in particular axially between, the piston disk and the sealing disk.
- a sealing disk can channel the flow of the filling compound when the injector is pressed out and thus ensure in a particularly simple manner that the filling compound is pressed into the annular space particularly reliably and, in particular, is not simply pushed away radially.
- the amount of filling material can be positioned in a particularly simple manner, since the amount of filling material between the piston disk and the sealing disk can be housed.
- the amount of filling material, in particular the reservoir be connected to the sealing disc, which may be advantageous manufacturing technology and can further facilitate the positioning of the amount of filling material.
- the sealing disc can also form mixing channels, which can further improve the mixing of the filling compound. It can be provided that the sealing disc is destroyed during the Auspressvorgangs the filling compound.
- the sealing disc may for example consist of plastic, which may be advantageous in terms of manufacturing costs.
- the gasket can be made by injection molding.
- the injector it is expedient for the injector to have mixing bodies which project toward the quantity of the filling compound, in particular towards the reservoir.
- mixing bodies which may be formed, for example, peg-shaped, can define and / or limit mixing channels and thus improve the mixing of the filling compound during pressing out of the injector in a particularly simple manner, so that the reliability can be further increased.
- the mixing bodies can be arranged on the piston disk and / or on the sealing disk, as far as the latter is present.
- the injector has recesses for receiving at least a part of the mixing bodies when displacing the at least part of the quantity of filling material by means of the piston disk
- the invention also relates to a fastening arrangement with an inventive injector and with an anchor with an anchor bolt, which passes through the passage opening of the injector, in particular the piston disc.
- the injector and in particular its piston disc is mounted on the anchor bolt of the armature.
- the armature may have an armature nut arranged on the armature bolt, which forms a thrust bearing for the injector and thus fixes the injector axially in one direction on the armature bolt.
- the invention also relates to a container containing an inventive injector and an anchor.
- Under a container can be understood in the usual way in particular the entirety of packaging and the packaged goods.
- the invention also relates to a method for installing an anchor with an anchor bolt, wherein in the method the anchor bolt of the anchor is arranged in a hole and by means of an inventive injector filling compound, in particular from the injector, is introduced into an annular space surrounding the anchor bolt in the hole.
- an inventive injector filling compound in particular from the injector, is introduced into an annular space surrounding the anchor bolt in the hole.
- the piston disk of the injector by tightening an anchor nut arranged on the anchor bolt to a surface, in particular to a surface of the substrate, in which the annular space is formed at least partially, or in particular to a surface of an attachment, in which the annulus at least is partially formed, is pressed and in this case the filling material displaced by means of the piston disc and introduced into the annular space.
- the injector according to the invention will be positioned between the attachment and the anchor nut, but in principle the injector could also be arranged between the substrate and the attachment.
- FIGS. 1 to 3 An embodiment of a fastening arrangement is in the FIGS. 1 to 3 shown.
- the fastening arrangement has an armature 1 with an anchor bolt 10 and an injector 3.
- the armature 1 In the front region of the armature 1, the armature 1 has an anchoring zone 12, in which the anchor bolt 10 can be anchored to the wall 98 of a hole 99.
- the armature 1 is exemplified as an expansion anchor of the bolt type.
- the anchor 1 in the anchoring zone 12 has an expansion sleeve and an expansion cone formed on the anchor bolt 10 for radially pressing the expansion sleeve against the wall 98 of the hole 99 at a tensile load in the anchor bolt 10.
- the configuration of the armature 1 as an expansion anchor of the bolt type is only to be seen as an example, and the armature 1 may also have differently acting anchoring zones 12.
- the anchoring zone 12 is preferably a mechanical anchoring zone, that is to say an anchoring zone which effects an anchoring that is at least predominantly positive or frictional.
- the anchoring zone 12 could also be a chemical anchoring zone, that is to say an anchoring zone which effects an anchoring that is at least predominantly cohesive.
- the anchor bolt 10 is provided with an external thread 18.
- an anchor nut 8 is screwed with an external thread 18 corresponding internal thread.
- the fastening arrangement further has an injector 3 explained in more detail below, the anchor bolt 10 of the armature 1 passing through the injector 3.
- FIG. 1 Accordingly, the front end of the anchor bolt 10 of the armature 1 is inserted into a hole 99 in a fixture 6 and an adjacent to the fixture 6 substrate 5, for example, concrete substrate.
- the anchor bolt 10 surrounding the injector 3 is located between the anchor nut 8 and the voltage applied to the substrate 5 attachment 6 and thus also between the anchor nut 8 and the substrate 5.
- an annular space 97 is formed, which differs from Attachment 6 extends into the substrate 5.
- the injector 3 of the embodiment of the FIGS. 1 to 3 has a metallic piston disc 31 with a through opening 41, through which the anchor bolt 10 passes.
- the piston disk 31 is preceded by a reservoir 33, for example a foil bag, which contains a quantity 30 of a filling compound.
- the reservoir 33 is annular and surrounds the anchor bolt 10.
- the reservoir 33 is preceded by a sealing washer 51, which also has a through hole 61 through which the anchor bolt 10 passes.
- the reservoir 33 is thus located between the piston disc 31 and the sealing disc 51, the piston disc 31 of the anchor nut 8 and the sealing disc 51 facing the substrate 5 and the attachment 6.
- the sealing disk 51 has a sealing lip 55 on its outer side facing away from the piston disk 31, that is to say on its outer side facing away from the quantity 30 of the filling compound.
- the filling compound comprises a resin component A having at least one free-radically curable resin and a present in the form of microcapsules hardener component B with a radical-forming curing agent for the radically curable resin of the resin component A.
- the hardener component B is in the form of microcapsules, wherein the microcapsules have a shell material 50, which encloses in each case a portion of the hardener component.
- the microcapsules containing the hardener component B are dispersed in the resin component A.
- the resin component A thus forms a matrix for the microcapsules with the hardener component B.
- FIG. 5 is the operation of the injector 3 in a method according to the invention indicated by arrows.
- the anchor nut 8 is tightened on the external thread 18 of the anchor bolt 10. Since the anchor bolt 10 anchored to its anchoring zone 12 in the substrate 5, the anchor nut 8 approaches in this case to the substrate 5. Since the anchor nut 8 is larger in cross-section than the passage opening 41 in the piston disk 31, in this case the piston disk 31 is carried along by the armature nut 8.
- the reservoir 33 is pressed containing the amount 30 of the filling material, and filling material passes from the injector 3 in the annular space 97 to the anchor bolt 10.
- the microcapsules are opened with the hardener component B, so that the curing agent contained herein on the Resin of the resin component A can act and the curing process of the filling compound is started.
- the filling compound hardens completely in the annular space 97 and solidifies there. It is therefore displaced filling compound between the piston piston acting as a piston 31 and the attachment 6 from the injector 3 in the annular space 97 to the anchor bolt 10.
- the piston disk 31 of the injector 3 of the embodiment of FIGS. 1 to 3 Blending body 37 and 37 ' which project towards the amount 30 of the filling material, in particular towards the reservoir 33, from the piston disk 31.
- the mixing bodies 37 are peg-shaped and the mixing bodies 37 'are arc-shaped.
- the provided for carrying out the anchor bolt 10 through opening 41 in the piston disk 31 may be performed, for example, circular.
- the passage opening 61 of the sealing disc 51 has a cross-sectional shape deviating from a circular shape, so that mixing laps for the filling compound are formed on the passage opening 61 of the sealing disc 51.
- the injector 3 of the embodiment of the FIGS. 1 to 3 a sealing sleeve 59, in which the piston disc 31 is slidably disposed, and which seals the injector 3, in particular its reservoir 33, in the radial direction.
- the preferably cylindrical sealing sleeve 59 is fixedly arranged on the sealing disc 51 and in particular formed integrally with the sealing disc 51.
- the sealing sleeve 59 and the sealing washer 51 but also be separate parts.
- the sealing disc 51 and / or the sealing sleeve 59 may in particular consist of a plastic material.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Joining Of Building Structures In Genera (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16174784.5A EP3258122A1 (fr) | 2016-06-16 | 2016-06-16 | Injecteur a disques de portions individuelles comprenant un durcisseur reticule micro-encapsule |
| PCT/EP2017/063933 WO2017216026A1 (fr) | 2016-06-16 | 2017-06-08 | Injecteur de doses unitaires à disque comprenant un durcisseur microencapsulé pour polymérisation radicalaire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16174784.5A EP3258122A1 (fr) | 2016-06-16 | 2016-06-16 | Injecteur a disques de portions individuelles comprenant un durcisseur reticule micro-encapsule |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3258122A1 true EP3258122A1 (fr) | 2017-12-20 |
Family
ID=56292455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP16174784.5A Withdrawn EP3258122A1 (fr) | 2016-06-16 | 2016-06-16 | Injecteur a disques de portions individuelles comprenant un durcisseur reticule micro-encapsule |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP3258122A1 (fr) |
| WO (1) | WO2017216026A1 (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114457818A (zh) * | 2022-02-16 | 2022-05-10 | 哈尔滨工业大学 | 双壁挡土墙—注射式真空锚索协同护坡体系施工方法 |
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| US3297745A (en) | 1962-04-05 | 1967-01-10 | Robertson Co H H | Ethylenically unsaturated di-and tetra-urethane monomers |
| US3469490A (en) * | 1967-10-18 | 1969-09-30 | Loctite Corp | Self-sealing mechanical fastener |
| US3772404A (en) | 1971-01-08 | 1973-11-13 | Ici Ltd | Resins |
| GB1425852A (en) * | 1972-02-04 | 1976-02-18 | Hilti Ag | Dowel or anchoring means |
| DE2910083A1 (de) * | 1979-03-15 | 1980-09-18 | Fischer Artur Dr H C | Verankerung eines befestigungselementes mittels einer klebemasse |
| US4618658A (en) | 1985-05-16 | 1986-10-21 | The Dow Chemical Company | Polymer modified epoxy resin compositions |
| DE3744390A1 (de) | 1987-12-29 | 1989-07-13 | Basf Ag | Faserverbundwerkstoffe auf basis von modifizierten vinylesterurethanharzen |
| GB2217722A (en) | 1988-04-29 | 1989-11-01 | Scott Bader Co | Vinyl terminated urethane containing resins |
| DE4131457A1 (de) | 1991-09-21 | 1993-03-25 | Basf Ag | Patrone oder kartusche fuer die chemische befestigungstechnik |
| DE4208834A1 (de) * | 1992-03-19 | 1993-09-23 | Fischer Artur Werke Gmbh | Bolzenanker zum verankern in einem bohrloch eines bauteiles mittels einem klebstoffkoerper |
| DE19531649A1 (de) | 1995-08-29 | 1997-03-06 | Basf Ag | Dübelmasse für die chemische Befestigungstechnik |
| US20020091214A1 (en) | 2000-12-22 | 2002-07-11 | Waanders Petrus Paulus | Transportable and safely packaged organic peroxide formulations comprising reactive phlegmatisers |
| DE10111470A1 (de) | 2001-03-09 | 2002-09-12 | Hilti Ag | Unterlegscheibe für chemische Anker |
| DE10204591A1 (de) | 2002-02-05 | 2003-08-14 | Fischer Artur Werke Gmbh | Spreizanker |
| EP1935860A2 (fr) | 2006-12-21 | 2008-06-25 | HILTI Aktiengesellschaft | Résine réactive à deux composants et son utilisation |
| KR20080092193A (ko) * | 2007-04-11 | 2008-10-15 | 유인섭 | 못박음 균열 보강구 및 방법 |
| WO2010108939A1 (fr) | 2009-03-25 | 2010-09-30 | Dsm Ip Assets B.V. | Composition de résine d'ester vinylique |
| US20110071234A1 (en) | 2009-09-18 | 2011-03-24 | Gross Stephen M | Self-Healing dental restorative formulations and related methods |
| EP2597322A2 (fr) | 2011-11-23 | 2013-05-29 | GESI Gewindesicherungs-GmbH | Fixation de filetage |
-
2016
- 2016-06-16 EP EP16174784.5A patent/EP3258122A1/fr not_active Withdrawn
-
2017
- 2017-06-08 WO PCT/EP2017/063933 patent/WO2017216026A1/fr not_active Ceased
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|---|---|---|---|---|
| US3297745A (en) | 1962-04-05 | 1967-01-10 | Robertson Co H H | Ethylenically unsaturated di-and tetra-urethane monomers |
| US3469490A (en) * | 1967-10-18 | 1969-09-30 | Loctite Corp | Self-sealing mechanical fastener |
| US3772404A (en) | 1971-01-08 | 1973-11-13 | Ici Ltd | Resins |
| GB1425852A (en) * | 1972-02-04 | 1976-02-18 | Hilti Ag | Dowel or anchoring means |
| DE2910083A1 (de) * | 1979-03-15 | 1980-09-18 | Fischer Artur Dr H C | Verankerung eines befestigungselementes mittels einer klebemasse |
| US4618658A (en) | 1985-05-16 | 1986-10-21 | The Dow Chemical Company | Polymer modified epoxy resin compositions |
| DE3744390A1 (de) | 1987-12-29 | 1989-07-13 | Basf Ag | Faserverbundwerkstoffe auf basis von modifizierten vinylesterurethanharzen |
| GB2217722A (en) | 1988-04-29 | 1989-11-01 | Scott Bader Co | Vinyl terminated urethane containing resins |
| DE4131457A1 (de) | 1991-09-21 | 1993-03-25 | Basf Ag | Patrone oder kartusche fuer die chemische befestigungstechnik |
| DE4208834A1 (de) * | 1992-03-19 | 1993-09-23 | Fischer Artur Werke Gmbh | Bolzenanker zum verankern in einem bohrloch eines bauteiles mittels einem klebstoffkoerper |
| DE19531649A1 (de) | 1995-08-29 | 1997-03-06 | Basf Ag | Dübelmasse für die chemische Befestigungstechnik |
| US20020091214A1 (en) | 2000-12-22 | 2002-07-11 | Waanders Petrus Paulus | Transportable and safely packaged organic peroxide formulations comprising reactive phlegmatisers |
| DE10111470A1 (de) | 2001-03-09 | 2002-09-12 | Hilti Ag | Unterlegscheibe für chemische Anker |
| DE10204591A1 (de) | 2002-02-05 | 2003-08-14 | Fischer Artur Werke Gmbh | Spreizanker |
| EP1935860A2 (fr) | 2006-12-21 | 2008-06-25 | HILTI Aktiengesellschaft | Résine réactive à deux composants et son utilisation |
| KR20080092193A (ko) * | 2007-04-11 | 2008-10-15 | 유인섭 | 못박음 균열 보강구 및 방법 |
| WO2010108939A1 (fr) | 2009-03-25 | 2010-09-30 | Dsm Ip Assets B.V. | Composition de résine d'ester vinylique |
| US20110071234A1 (en) | 2009-09-18 | 2011-03-24 | Gross Stephen M | Self-Healing dental restorative formulations and related methods |
| EP2597322A2 (fr) | 2011-11-23 | 2013-05-29 | GESI Gewindesicherungs-GmbH | Fixation de filetage |
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| Title |
|---|
| M. MALIK ET AL., J. M. S. - REV. MACROMOL. CHEM. PHYS., vol. C40, no. 2, 3, 2000, pages 139 - 165 |
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|---|---|
| WO2017216026A1 (fr) | 2017-12-21 |
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