EP3303536B1 - Composition de détergent pour lessive - Google Patents

Composition de détergent pour lessive Download PDF

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Publication number
EP3303536B1
EP3303536B1 EP16718686.5A EP16718686A EP3303536B1 EP 3303536 B1 EP3303536 B1 EP 3303536B1 EP 16718686 A EP16718686 A EP 16718686A EP 3303536 B1 EP3303536 B1 EP 3303536B1
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EP
European Patent Office
Prior art keywords
laundry detergent
detergent composition
protease
composition according
alkoxylated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP16718686.5A
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German (de)
English (en)
Other versions
EP3303536A1 (fr
Inventor
Stephen Norman Batchelor
Jayne Michelle Bird
Dietmar Andreas LANG
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever NV
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Unilever NV
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Publication date
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Publication of EP3303536A1 publication Critical patent/EP3303536A1/fr
Application granted granted Critical
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

Definitions

  • Protease enzymes are used in laundry detergent formulations to remove protein containing stains from fabrics.
  • amyloliquefaciens Bacillus pumilus and Bacillus gibsonii described in US7262042 and WO09/021867 , and subtilisin lentus, subtilisin Novo, subtilisin Carlsberg, Bacillus licheniformis, subtilisin BPN', subtilisin 309, subtilisin 147 and subtilisin 168 described in WO89/06279 and protease PD138 described in WO 93/18140 .
  • Other useful proteases may be those described in WO92/175177 , WO01/016285 , WO02/026024 and WO02/016547 .
  • trypsin-like proteases are trypsin (e.g.
  • two or more anionic surfactant are present, preferably linear alkyl benzene sulphonate together with an alkyl ether sulphate.
  • precipitating builder materials examples include sodium orthophosphate and sodium carbonate.
  • the laundry detergent formulation is a non-phosphate built laundry detergent formulation, i.e., contains less than 1 wt% of phosphate.
  • the powder laundry detergent formulation is carbonate built.
  • the composition preferably comprises a fluorescent agent (optical brightener).
  • fluorescent agents are well known and many such fluorescent agents are available commercially. Usually, these fluorescent agents are supplied and used in the form of their alkali metal salts, for example, the sodium salts.
  • the total amount of the fluorescent agent or agents used in the composition is generally from 0.005 to 2 wt %, more preferably 0.01 to 0.1 wt %.
  • Preferred classes of fluorescer are: Di-styryl biphenyl compounds, e.g. Tinopal (Trade Mark) CBS-X, Di-amine stilbene disulphonic acid compounds, e.g. Tinopal DMS pure Xtra and Blankophor (Trade Mark) HRH, and Pyrazoline compounds, e.g.
  • the composition comprises a perfume.
  • the perfume is preferably in the range from 0.001 to 3 wt %, most preferably 0.1 to 1 wt %.
  • CTFA Cosmetic, Toiletry and Fragrance Association

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (10)

  1. Composition de détergent de lessive comprenant :
    (i) de 5 à 50 % en masse d'un tensioactif, différent d'un dispersant de di ou tri arylphénol alcoxylé, choisi parmi : des tensioactifs anioniques et non-ioniques,
    dans laquelle la fraction massique de tensioactif non-ionique/ tensioactif anionique est de 0 à 0,3 ;
    (ii) de 0,5 à 20 % en masse d'un dispersant de di ou tri arylphénol alcoxylé dans laquelle le dispersant de di ou tri arylphénol alcoxylé est de la structure :
    Figure imgb0011
     dans laquelle R1 sont des groupes styryle, X sont des groupes éthoxy ; n est de 6 à 70, T est H ; et,
    (iii) de 0,0005 à 0,2 % en masse d'une enzyme de protéase.
  2. Composition de détergent de lessive selon la revendication 1, dans laquelle le tensioactif anionique est choisi parmi :
    des benzènesulfonates d'alkyle linéaires ; des sulfates d'alkyle; des sulfates d'alkyléthers ; et des mélanges de ceux-ci, et le tensioactif non-ionique est choisi parmi : des alkyléthers avec de 7 à 9 groupes éthoxy.
  3. Composition de détergent de lessive selon la revendication 1 ou 2, dans laquelle la protéase est une protéase à sérine.
  4. Composition de détergent de lessive selon la revendication 3, dans laquelle la protéase est une protéase à sérine de type subtilase.
  5. Composition de détergent de lessive selon la revendication 3 ou 4, dans laquelle la protéase est présente à de 0,002 à 0,02 % en masse.
  6. Composition de détergent de lessive selon l'une quelconque des revendications précédentes, dans laquelle la composition est un détergent liquide de lessive aqueux.
  7. Composition de détergent de lessive selon l'une quelconque des revendications précédentes, dans laquelle le(s) tensioactif(s) anionique et non-ionique est/sont présent(s) dans l'intervalle de 8 à 20 % en masse.
  8. Composition de détergent de lessive selon l'une quelconque des revendications précédentes, dans laquelle la fraction massique de tensioactif non-ionique/tensioactif anionique est de 0,05 à 0,12.
  9. Composition de détergent de lessive selon l'une quelconque des revendications précédentes, dans laquelle le dispersant de di ou tri arylphénol alcoxylé est présent dans l'intervalle de 1,5 à 10 % en masse.
  10. Procédé domestique de traitement d'un textile, le procédé comprenant les étapes de :
    (i) traitement d'un textile avec 1 g/l d'une solution aqueuse de la composition de détergent de lessive selon l'une quelconque des revendications précédentes ; et,
    (ii) laisser ladite solution de détergent de lessive aqueuse rester en contact avec le textile pendant de 10 minutes à 2 jours puis rinçage et séchage du textile.
EP16718686.5A 2015-06-02 2016-04-26 Composition de détergent pour lessive Active EP3303536B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP15170341 2015-06-02
PCT/EP2016/059313 WO2016192905A1 (fr) 2015-06-02 2016-04-26 Composition détergente pour lessive

Publications (2)

Publication Number Publication Date
EP3303536A1 EP3303536A1 (fr) 2018-04-11
EP3303536B1 true EP3303536B1 (fr) 2019-04-17

Family

ID=53269413

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16718686.5A Active EP3303536B1 (fr) 2015-06-02 2016-04-26 Composition de détergent pour lessive

Country Status (6)

Country Link
EP (1) EP3303536B1 (fr)
CN (1) CN107835851B (fr)
AR (1) AR104843A1 (fr)
BR (1) BR112017025607B1 (fr)
TR (1) TR201906836T4 (fr)
WO (1) WO2016192905A1 (fr)

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Also Published As

Publication number Publication date
BR112017025607A2 (en) 2018-08-07
TR201906836T4 (tr) 2019-05-21
EP3303536A1 (fr) 2018-04-11
CN107835851B (zh) 2020-03-20
BR112017025607B1 (pt) 2022-08-30
AR104843A1 (es) 2017-08-16
WO2016192905A1 (fr) 2016-12-08
CN107835851A (zh) 2018-03-23

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