EP3536852A1 - Fibre cellulosique et de type lyocell a degre de blanc reglable - Google Patents
Fibre cellulosique et de type lyocell a degre de blanc reglable Download PDFInfo
- Publication number
- EP3536852A1 EP3536852A1 EP18160115.4A EP18160115A EP3536852A1 EP 3536852 A1 EP3536852 A1 EP 3536852A1 EP 18160115 A EP18160115 A EP 18160115A EP 3536852 A1 EP3536852 A1 EP 3536852A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fiber
- pulp
- lyocell
- whiteness
- hemicelluloses
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920000433 Lyocell Polymers 0.000 title claims abstract description 86
- 239000000835 fiber Substances 0.000 title claims abstract description 68
- 229920002488 Hemicellulose Polymers 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 43
- 230000008569 process Effects 0.000 claims description 31
- 238000004519 manufacturing process Methods 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 24
- 230000008859 change Effects 0.000 claims description 19
- 229920000057 Mannan Polymers 0.000 claims description 18
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 claims description 12
- 229920001221 xylan Polymers 0.000 claims description 12
- 150000004823 xylans Chemical class 0.000 claims description 12
- 238000005259 measurement Methods 0.000 claims description 11
- 239000004753 textile Substances 0.000 claims description 11
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 claims description 10
- 238000012545 processing Methods 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 8
- 230000008646 thermal stress Effects 0.000 claims description 7
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 claims description 5
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 claims description 5
- 230000009467 reduction Effects 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000004745 nonwoven fabric Substances 0.000 claims description 3
- 230000009469 supplementation Effects 0.000 claims description 3
- 230000001939 inductive effect Effects 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 description 23
- 229920002678 cellulose Polymers 0.000 description 16
- 235000010980 cellulose Nutrition 0.000 description 16
- 239000001913 cellulose Substances 0.000 description 14
- 238000009987 spinning Methods 0.000 description 14
- 239000000243 solution Substances 0.000 description 12
- 238000002845 discoloration Methods 0.000 description 10
- 238000011282 treatment Methods 0.000 description 8
- 230000006978 adaptation Effects 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 4
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 4
- 238000004061 bleaching Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 229920005610 lignin Polymers 0.000 description 4
- 235000000346 sugar Nutrition 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000011436 cob Substances 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000007380 fibre production Methods 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000007669 thermal treatment Methods 0.000 description 3
- QGGOCWIJGWDKHC-FSIIMWSLSA-N (2s,3s,4r,5r)-2,4,5-trihydroxy-3-methoxy-6-oxohexanoic acid Chemical compound OC(=O)[C@@H](O)[C@@H](OC)[C@H](O)[C@@H](O)C=O QGGOCWIJGWDKHC-FSIIMWSLSA-N 0.000 description 2
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 2
- 229920001503 Glucan Polymers 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 description 2
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 description 2
- QGGOCWIJGWDKHC-UHFFFAOYSA-N O4-Methyl-D-glucuronsaeure Natural products OC(=O)C(O)C(OC)C(O)C(O)C=O QGGOCWIJGWDKHC-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 2
- 125000000089 arabinosyl group Chemical group C1([C@@H](O)[C@H](O)[C@H](O)CO1)* 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 238000007385 chemical modification Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 229930182830 galactose Natural products 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- LUEWUZLMQUOBSB-GFVSVBBRSA-N mannan Chemical class O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](O[C@H]3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-GFVSVBBRSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 238000009896 oxidative bleaching Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- CZMRCDWAGMRECN-UHFFFAOYSA-N 2-{[3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy}-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound OCC1OC(CO)(OC2OC(CO)C(O)C(O)C2O)C(O)C1O CZMRCDWAGMRECN-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000001891 gel spinning Methods 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/02—Synthetic cellulose fibres
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
Definitions
- the fibers provided within the scope of the present invention preferably have an adjustable whiteness defined as follows:
- the fiber exhibits a reduction in whiteness of 5% or more, preferably 10, after exposure to 195 ° C. for less than 1 minute, preferably 45 seconds % or more, such as 20% or more, as compared to a lyocell fiber having a hemicellulose content of less than 5% by weight.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Paper (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18160115.4A EP3536852A1 (fr) | 2018-03-06 | 2018-03-06 | Fibre cellulosique et de type lyocell a degre de blanc reglable |
| TW108107357A TW201942445A (zh) | 2018-03-06 | 2019-03-06 | 白度可調的木漿和萊纖纖維 |
| PCT/EP2019/055581 WO2019170754A1 (fr) | 2018-03-06 | 2019-03-06 | Cellulose et lyocell à degré de blancheur ajustable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18160115.4A EP3536852A1 (fr) | 2018-03-06 | 2018-03-06 | Fibre cellulosique et de type lyocell a degre de blanc reglable |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3536852A1 true EP3536852A1 (fr) | 2019-09-11 |
Family
ID=61622320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP18160115.4A Withdrawn EP3536852A1 (fr) | 2018-03-06 | 2018-03-06 | Fibre cellulosique et de type lyocell a degre de blanc reglable |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP3536852A1 (fr) |
| TW (1) | TW201942445A (fr) |
| WO (1) | WO2019170754A1 (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111676525B (zh) * | 2020-06-19 | 2024-09-06 | 当阳市鸿阳新材料科技有限公司 | 一种Lyocell纺丝中提高丝束白度的温控系统及方法 |
Citations (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4246221A (en) | 1979-03-02 | 1981-01-20 | Akzona Incorporated | Process for shaped cellulose article prepared from a solution containing cellulose dissolved in a tertiary amine N-oxide solvent |
| WO1993019230A1 (fr) | 1992-03-17 | 1993-09-30 | Lenzing Aktiengesellschaft | Procede de fabrication d'elements moules cellulosiques et dispositif de mise en oeuvre dudit procede |
| WO1994008217A1 (fr) | 1992-10-05 | 1994-04-14 | Hans Paluschinski | Appareil pour le prelevement d'echantillons de boues et d'eaux usees et procede de prelevement de ces echantillons |
| WO1994028214A1 (fr) | 1993-05-24 | 1994-12-08 | Courtaulds Fibres (Holdings) Limited | Tremie de stockage et de pre-melange |
| WO1995002082A1 (fr) | 1993-07-08 | 1995-01-19 | Lenzing Aktiengesellschaft | Fibres cellulosiques |
| WO1996033221A1 (fr) | 1995-04-19 | 1996-10-24 | Lenzing Aktiengesellschaft | Procede de production d'une suspension de cellulose |
| WO1996033934A1 (fr) | 1995-04-25 | 1996-10-31 | Lenzing Aktiengesellschaft | Dispositif pour maintenir et decharger une suspension homogene de cellulose |
| WO1997038153A1 (fr) | 1996-04-10 | 1997-10-16 | Courtaulds Fibres (Holdings) Limited | Procede de fabrication de filaments lyocellulaires |
| WO1998005702A1 (fr) | 1996-08-01 | 1998-02-12 | Lenzing Aktiengesellschaft | Procede de production d'une suspension de cellulose |
| JPH10158925A (ja) | 1996-11-27 | 1998-06-16 | Toyobo Co Ltd | 染色性に優れた再生セルロース繊維およびその製法 |
| WO1999047733A1 (fr) * | 1998-03-16 | 1999-09-23 | Weyerhaeuser Company | Fibres lyocel, et compositions pour leur fabrication |
| US6440523B1 (en) | 1996-08-23 | 2002-08-27 | Weyerhaeuser | Lyocell fiber made from alkaline pulp having low average degree of polymerization values |
| US6514613B2 (en) | 1996-08-23 | 2003-02-04 | Weyerhaeuser Company | Molded bodies made from compositions having low degree of polymerization values |
| US20030186055A1 (en) | 1999-02-24 | 2003-10-02 | Sealey James E. | Use of thinnings and other low specific gravity wood for lyocell products |
| US20090324926A1 (en) | 2008-06-30 | 2009-12-31 | Weyerhaeuser Co. | Nonwoven lyocell fiber webs for filtration |
| US20120043038A1 (en) * | 2010-08-20 | 2012-02-23 | Weyerhaeuser Nr Company | Dried Highly Fibrillated Cellulose Fiber |
| US20150184338A1 (en) * | 2013-12-31 | 2015-07-02 | Weyerhaeuser Nr Company | Treated kraft pulp compositions and methods of making the same |
| EP2929071A1 (fr) | 2012-12-06 | 2015-10-14 | Lenzing Aktiengesellschaft | Procédé de production d'un article façonné cellulosique |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5413631A (en) | 1993-05-24 | 1995-05-09 | Courtaulds (Holding) Limited | Formation of a cellulose-based premix |
-
2018
- 2018-03-06 EP EP18160115.4A patent/EP3536852A1/fr not_active Withdrawn
-
2019
- 2019-03-06 TW TW108107357A patent/TW201942445A/zh unknown
- 2019-03-06 WO PCT/EP2019/055581 patent/WO2019170754A1/fr not_active Ceased
Patent Citations (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4246221A (en) | 1979-03-02 | 1981-01-20 | Akzona Incorporated | Process for shaped cellulose article prepared from a solution containing cellulose dissolved in a tertiary amine N-oxide solvent |
| WO1993019230A1 (fr) | 1992-03-17 | 1993-09-30 | Lenzing Aktiengesellschaft | Procede de fabrication d'elements moules cellulosiques et dispositif de mise en oeuvre dudit procede |
| WO1994008217A1 (fr) | 1992-10-05 | 1994-04-14 | Hans Paluschinski | Appareil pour le prelevement d'echantillons de boues et d'eaux usees et procede de prelevement de ces echantillons |
| WO1994028214A1 (fr) | 1993-05-24 | 1994-12-08 | Courtaulds Fibres (Holdings) Limited | Tremie de stockage et de pre-melange |
| WO1995002082A1 (fr) | 1993-07-08 | 1995-01-19 | Lenzing Aktiengesellschaft | Fibres cellulosiques |
| WO1996033221A1 (fr) | 1995-04-19 | 1996-10-24 | Lenzing Aktiengesellschaft | Procede de production d'une suspension de cellulose |
| WO1996033934A1 (fr) | 1995-04-25 | 1996-10-31 | Lenzing Aktiengesellschaft | Dispositif pour maintenir et decharger une suspension homogene de cellulose |
| WO1997038153A1 (fr) | 1996-04-10 | 1997-10-16 | Courtaulds Fibres (Holdings) Limited | Procede de fabrication de filaments lyocellulaires |
| WO1998005702A1 (fr) | 1996-08-01 | 1998-02-12 | Lenzing Aktiengesellschaft | Procede de production d'une suspension de cellulose |
| US6440523B1 (en) | 1996-08-23 | 2002-08-27 | Weyerhaeuser | Lyocell fiber made from alkaline pulp having low average degree of polymerization values |
| US6514613B2 (en) | 1996-08-23 | 2003-02-04 | Weyerhaeuser Company | Molded bodies made from compositions having low degree of polymerization values |
| JPH10158925A (ja) | 1996-11-27 | 1998-06-16 | Toyobo Co Ltd | 染色性に優れた再生セルロース繊維およびその製法 |
| WO1999047733A1 (fr) * | 1998-03-16 | 1999-09-23 | Weyerhaeuser Company | Fibres lyocel, et compositions pour leur fabrication |
| US20030186055A1 (en) | 1999-02-24 | 2003-10-02 | Sealey James E. | Use of thinnings and other low specific gravity wood for lyocell products |
| US20090324926A1 (en) | 2008-06-30 | 2009-12-31 | Weyerhaeuser Co. | Nonwoven lyocell fiber webs for filtration |
| US20120043038A1 (en) * | 2010-08-20 | 2012-02-23 | Weyerhaeuser Nr Company | Dried Highly Fibrillated Cellulose Fiber |
| EP2929071A1 (fr) | 2012-12-06 | 2015-10-14 | Lenzing Aktiengesellschaft | Procédé de production d'un article façonné cellulosique |
| US20150184338A1 (en) * | 2013-12-31 | 2015-07-02 | Weyerhaeuser Nr Company | Treated kraft pulp compositions and methods of making the same |
Non-Patent Citations (1)
| Title |
|---|
| CABOHYDRATE POLYMERS, vol. 181, 2018, pages 893 - 901 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2019170754A1 (fr) | 2019-09-12 |
| TW201942445A (zh) | 2019-11-01 |
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