EP3868770A4 - Composé de métal de transition et composition de catalyseur le comprenant - Google Patents

Composé de métal de transition et composition de catalyseur le comprenant Download PDF

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Publication number: EP3868770A4
Authority: EP; European Patent Office
Prior art keywords: metal compound; catalyst composition; composition including; transitional metal; transitional
Prior art date: 2018-11-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP19887735.9A

Other languages

German (de)

English (en)

Other versions

EP3868770A1 (fr

EP3868770B1 (fr

Inventor

Jae Kwon Jang

Seung Hyo Kim

Seung Hwan Jung

A Rim KIM

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

LG Chem Ltd

Original Assignee

LG Chem Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2018-11-22

Filing date

2019-11-22

Publication date

2022-01-05

2019-11-22 Application filed by LG Chem Ltd filed Critical LG Chem Ltd

2019-11-22 Priority claimed from PCT/KR2019/016167 external-priority patent/WO2020106107A1/fr

2021-08-25 Publication of EP3868770A1 publication Critical patent/EP3868770A1/fr

2022-01-05 Publication of EP3868770A4 publication Critical patent/EP3868770A4/fr

2022-11-09 Application granted granted Critical

2022-11-09 Publication of EP3868770B1 publication Critical patent/EP3868770B1/fr

Status Active legal-status Critical Current

2039-11-22 Anticipated expiration legal-status Critical

Links

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/10—Heteroatom-substituted bridge, i.e. Cp or analog where the bridge linking the two Cps or analogs is substituted by at least one group that contains a heteroatom
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Crystallography & Structural Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

EP19887735.9A 2018-11-22 2019-11-22 Composé de métal de transition et composition de catalyseur le comprenant Active EP3868770B1 (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
KR20180145546		2018-11-22
KR1020190149757A KR102531561B1 (ko)	2018-11-22	2019-11-20	전이금속 화합물 및 이를 포함하는 촉매 조성물
PCT/KR2019/016167 WO2020106107A1 (fr)	2018-11-22	2019-11-22	Composé de métal de transition et composition de catalyseur le comprenant

Publications (3)

Publication Number	Publication Date
EP3868770A1 EP3868770A1 (fr)	2021-08-25
EP3868770A4 true EP3868770A4 (fr)	2022-01-05
EP3868770B1 EP3868770B1 (fr)	2022-11-09

Family

ID=70912105

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP19887735.9A Active EP3868770B1 (fr)	2018-11-22	2019-11-22	Composé de métal de transition et composition de catalyseur le comprenant

Country Status (4)

Country	Link
US (1)	US12234252B2 (fr)
EP (1)	EP3868770B1 (fr)
KR (1)	KR102531561B1 (fr)
CN (1)	CN113039190B (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN114763392B (zh) *	2021-01-15	2023-07-14	万华化学集团股份有限公司	一种茂金属负载催化剂及其制备方法、乙烯和α烯烃共聚弹性体的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2009085124A1 (fr) *	2007-12-28	2009-07-09	Chevron Phillips Chemical Company Lp	Compositions de catalyseur de métallocène à nano-liaison et leurs produits polymères
US20120071615A1 (en) *	2010-09-14	2012-03-22	Lg Chem, Ltd.	Bi-Nuclear Metallocene Compound and the Preparation Method of Polyolefin Using the Same
WO2018046566A1 (fr) *	2016-09-08	2018-03-15	Total Research & Technology Feluy	Composés bis (métallocène) et compositions de catalyseur utilisant de tels composés

Family Cites Families (12)

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US5064802A (en)	1989-09-14	1991-11-12	The Dow Chemical Company	Metal complex compounds
CA2646567A1 (fr)	1999-12-10	2001-06-14	Dow Global Technologies Inc.	Complexes metalliques groupe 4 substitues, catalyseurs et procede de polymerisation olefinique
JP2002206006A (ja) *	2000-11-13	2002-07-26	Basell Technology Co Bv	オレフィンポリマーの製造方法
DE10357374A1 (de)	2003-12-09	2005-07-14	Knorr-Bremse Systeme für Nutzfahrzeuge GmbH	Scheibenbremse, insbesondere mit elektromotorischer Nachstellvorrichtung, und Verfahren zur Ansteuerung derartiger Scheibenbremsen
JP2005200453A (ja) *	2004-01-13	2005-07-28	Mitsui Chemicals Inc	α−オレフィン（共）重合体の製造方法
US7064225B2 (en)	2004-06-25	2006-06-20	Chevron Phillips Chemical Company, L.P.	Synthesis of ansa-metallocenes and their parent ligands in high yield
US8932975B2 (en)	2010-09-07	2015-01-13	Chevron Phillips Chemical Company Lp	Catalyst systems and methods of making and using same
US8877672B2 (en)	2013-01-29	2014-11-04	Chevron Phillips Chemical Company Lp	Catalyst compositions and methods of making and using same
KR101785705B1 (ko)	2015-02-05	2017-10-16	주식회사 엘지화학	촉매 조성물 및 이를 이용한 폴리올레핀의 제조방법
DE102016116815A1 (de)	2016-09-08	2018-03-08	Dr. Ing. H.C. F. Porsche Aktiengesellschaft	Verfahren zur Beschichtung eines Zylinders einer Verbrennungskraftmaschine und Zylinder für eine Verbrennungskraftmaschine
CN108530492B (zh)	2018-05-17	2021-03-30	中国石油天然气股份有限公司	一种桥联双核茂金属化合物及其制备方法与应用
CN108530490A (zh)	2018-06-05	2018-09-14	长春海谱润斯科技有限公司	一种金属配合物及其有机发光器件

2019
- 2019-11-20 KR KR1020190149757A patent/KR102531561B1/ko active Active
- 2019-11-22 US US17/294,522 patent/US12234252B2/en active Active
- 2019-11-22 CN CN201980075794.9A patent/CN113039190B/zh active Active
- 2019-11-22 EP EP19887735.9A patent/EP3868770B1/fr active Active

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2009085124A1 (fr) *	2007-12-28	2009-07-09	Chevron Phillips Chemical Company Lp	Compositions de catalyseur de métallocène à nano-liaison et leurs produits polymères
US20120071615A1 (en) *	2010-09-14	2012-03-22	Lg Chem, Ltd.	Bi-Nuclear Metallocene Compound and the Preparation Method of Polyolefin Using the Same
WO2018046566A1 (fr) *	2016-09-08	2018-03-15	Total Research & Technology Feluy	Composés bis (métallocène) et compositions de catalyseur utilisant de tels composés

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2020106107A1 *

Also Published As

Publication number	Publication date
EP3868770A1 (fr)	2021-08-25
US20220024951A1 (en)	2022-01-27
CN113039190B (zh)	2023-11-24
EP3868770B1 (fr)	2022-11-09
CN113039190A (zh)	2021-06-25
US12234252B2 (en)	2025-02-25
KR20200060279A (ko)	2020-05-29
KR102531561B1 (ko)	2023-05-15

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