EP3924397A4 - Lewis-basenkatalysatoren und verfahren dafür - Google Patents

Lewis-basenkatalysatoren und verfahren dafür Download PDF

Info

Publication number: EP3924397A4
Authority: EP; European Patent Office
Prior art keywords: methods; lewis base; base catalysts; catalysts; lewis
Prior art date: 2019-02-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

EP20755183.9A

Other languages

English (en)

French (fr)

Other versions

EP3924397A1 (de

Inventor

Georgy P. GORYUNOV

Vladislav A. Popov

Dmitry V Uborsky

Alexander Z. Voskoboynikov

John R. Hagadorn

Irene C. Cai

Jo Ann M. Canich

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ExxonMobil Chemical Patents Inc

Original Assignee

ExxonMobil Chemical Patents Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2019-02-12

Filing date

2020-02-11

Publication date

2022-06-22

2020-02-11 Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc

2021-12-22 Publication of EP3924397A1 publication Critical patent/EP3924397A1/de

2022-06-22 Publication of EP3924397A4 publication Critical patent/EP3924397A4/de

Status Pending legal-status Critical Current

Links

239000002879 Lewis base Substances 0.000 title 1
239000003054 catalyst Substances 0.000 title 1
150000007527 lewis bases Chemical class 0.000 title 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

EP20755183.9A 2019-02-12 2020-02-11 Lewis-basenkatalysatoren und verfahren dafür Pending EP3924397A4 (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US201962804389P	2019-02-12	2019-02-12
EP19179810		2019-06-12
PCT/US2020/017757 WO2020167838A1 (en)	2019-02-12	2020-02-11	Lewis base catalysts and methods thereof

Publications (2)

Publication Number	Publication Date
EP3924397A1 EP3924397A1 (de)	2021-12-22
EP3924397A4 true EP3924397A4 (de)	2022-06-22

Family

ID=72044270

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP20755183.9A Pending EP3924397A4 (de)	2019-02-12	2020-02-11	Lewis-basenkatalysatoren und verfahren dafür

Country Status (4)

Country	Link
EP (1)	EP3924397A4 (de)
CN (1)	CN113423744B (de)
SG (1)	SG11202108010RA (de)
WO (1)	WO2020167838A1 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2021162747A1 (en) *	2020-02-11	2021-08-19	Exxonmobil Chemical Patents Inc.	Ethylene-alpha-olefin-diene monomer copolymers obtained using transition metal bis(phenolate) catalyst complexes and homogeneous process for production thereof
WO2021162746A1 (en) *	2020-02-11	2021-08-19	Exxonmobil Chemical Patents Inc.	Propylene polymers obtained using transition metal bis(phenolate) catalyst complexes and homogeneous process for production thereof
KR20220139378A (ko) *	2020-02-11	2022-10-14	엑손모빌 케미칼 패턴츠 인코포레이티드	전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법
KR102912885B1 (ko) *	2020-02-11	2026-01-14	엑손모빌 케미칼 패턴츠 인코포레이티드	전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 폴리에틸렌 조성물 및 그의 균질한 제조 방법
EP4232484A1 (de) *	2020-10-22	2023-08-30	ExxonMobil Chemical Patents Inc.	Mehrzähnige lewis-basen-katalysatoren und verfahren zur verwendung davon
CN116670188B (zh)	2020-12-29	2025-12-23	埃克森美孚化学专利公司	基于聚烯烃的离子聚合物及其制备
US12195563B2 (en)	2020-12-29	2025-01-14	Exxonmobil Chemical Patents Inc.	Polyolefin-based ionomers and production thereof
CA3241034A1 (en)	2021-12-17	2023-06-22	Exxonmobil Chemical Patents Inc.	Processes for making propylene-based copolymers having broad cds and mwds

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20080177020A1 (en) *	2006-09-21	2008-07-24	Theodor Agapie	Non-metallocene organometallic complexes and related methods and systems
US20160289351A1 (en) *	2014-05-15	2016-10-06	Chevron Phillips Chemical Company Lp	Synthesis of Aryl Coupled BIS Phenoxides and Their Use in Olefin Polymerization Catalyst Systems With Activator-Supports
KR20180022137A (ko) *	2016-08-23	2018-03-06	주식회사 엘지화학	신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20020002256A1 (en) *	1998-09-16	2002-01-03	Thomas Henry Peterson	Catalyst composition for the polymerization of olefins
US6897276B2 (en) *	2002-04-24	2005-05-24	Symyx Technologies, Inc.	Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
WO2013048848A2 (en) *	2011-09-30	2013-04-04	Exxonmobil Chemical Patents Inc.	Dynamic modulation of metallocene catalysts
US10329363B2 (en) *	2015-03-23	2019-06-25	Exxonmobil Chemical Patents Inc.	Group 6 transition metal catalyst compound and use thereof
EP3529287A1 (de) *	2016-10-19	2019-08-28	ExxonMobil Chemical Patents Inc.	Mischkatalysatorsysteme und verfahren zu deren verwendung

2020
- 2020-02-11 SG SG11202108010RA patent/SG11202108010RA/en unknown
- 2020-02-11 WO PCT/US2020/017757 patent/WO2020167838A1/en not_active Ceased
- 2020-02-11 EP EP20755183.9A patent/EP3924397A4/de active Pending
- 2020-02-11 CN CN202080013689.5A patent/CN113423744B/zh active Active

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20080177020A1 (en) *	2006-09-21	2008-07-24	Theodor Agapie	Non-metallocene organometallic complexes and related methods and systems
US20160289351A1 (en) *	2014-05-15	2016-10-06	Chevron Phillips Chemical Company Lp	Synthesis of Aryl Coupled BIS Phenoxides and Their Use in Olefin Polymerization Catalyst Systems With Activator-Supports
KR20180022137A (ko) *	2016-08-23	2018-03-06	주식회사 엘지화학	신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
GOLISZ S R ET AL: "Synthesis of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin Polymerization Catalysts", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, UNITED STATES, vol. 42, no. 22, 24 November 2009 (2009-11-24), pages 8751 - 8762, XP001552523, ISSN: 0024-9297, [retrieved on 20091029], DOI: 10.1021/MA901659Q *
See also references of WO2020167838A1 *
THEODOR AGAPIE ET AL: "Zirconium and Titanium Complexes Supported by Tridentate LX2 Ligands Having Two Phenolates Linked to Furan, Thiophene, and Pyridine Donors: Precatalysts for Propylene Polymerization and Oligomerization", ORGANOMETALLICS, AMERICAN CHEMICAL SOCIETY, US, vol. 27, no. 23, 8 December 2008 (2008-12-08), pages 6245 - 6256, XP002743333, ISSN: 0276-7333, [retrieved on 20081106], DOI: 10.1021/OM800136Y *

Also Published As

Publication number	Publication date
SG11202108010RA (en)	2021-08-30
CN113423744B (zh)	2023-05-05
CN113423744A (zh)	2021-09-21
EP3924397A1 (de)	2021-12-22
WO2020167838A1 (en)	2020-08-20

Legal Events

Date	Code	Title	Description
2020-08-22	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE
2021-11-19	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
2021-11-19	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE
2021-12-22	17P	Request for examination filed	Effective date: 20210909
2021-12-22	AK	Designated contracting states	Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
2022-05-18	DAV	Request for validation of the european patent (deleted)
2022-05-18	DAX	Request for extension of the european patent (deleted)
2022-06-22	A4	Supplementary search report drawn up and despatched	Effective date: 20220519
2022-06-22	RIC1	Information provided on ipc code assigned before grant	Ipc: C08F 10/00 20060101ALI20220513BHEP Ipc: C08F 4/64 20060101AFI20220513BHEP

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