EP4345117A1 - Émulsion aqueuse de polyuréthane (wpu) et son procédé de préparation - Google Patents
Émulsion aqueuse de polyuréthane (wpu) et son procédé de préparation Download PDFInfo
- Publication number
- EP4345117A1 EP4345117A1 EP23150796.3A EP23150796A EP4345117A1 EP 4345117 A1 EP4345117 A1 EP 4345117A1 EP 23150796 A EP23150796 A EP 23150796A EP 4345117 A1 EP4345117 A1 EP 4345117A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- wpu
- parts
- gloves
- emulsion
- chain extender
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000839 emulsion Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000004814 polyurethane Substances 0.000 title claims abstract description 7
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 7
- 238000004945 emulsification Methods 0.000 title claims description 6
- 239000004970 Chain extender Substances 0.000 claims abstract description 20
- 239000012948 isocyanate Substances 0.000 claims abstract description 19
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 19
- 229920005862 polyol Polymers 0.000 claims abstract description 18
- 150000003077 polyols Chemical class 0.000 claims abstract description 18
- 229920002678 cellulose Polymers 0.000 claims abstract description 15
- 239000001913 cellulose Substances 0.000 claims abstract description 15
- 239000002562 thickening agent Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003054 catalyst Substances 0.000 claims abstract description 11
- 239000002270 dispersing agent Substances 0.000 claims abstract description 11
- 239000000080 wetting agent Substances 0.000 claims abstract description 11
- 239000003085 diluting agent Substances 0.000 claims abstract description 10
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical group CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 15
- 238000007598 dipping method Methods 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 238000005507 spraying Methods 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 5
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 5
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 229910052797 bismuth Inorganic materials 0.000 claims description 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 4
- 125000005375 organosiloxane group Chemical group 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical group OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 2
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 claims description 2
- 229920001610 polycaprolactone Polymers 0.000 claims description 2
- 239000004632 polycaprolactone Substances 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 229920005906 polyester polyol Polymers 0.000 claims description 2
- -1 polysiloxane Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 238000005299 abrasion Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- 230000006872 improvement Effects 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229920006173 natural rubber latex Polymers 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- PMKQSEYPLQIEAY-YWNRKNDBSA-N Phaseolic acid Chemical compound OC(=O)C[C@@H](C(O)=O)OC(=O)\C=C\C1=CC=C(O)C(O)=C1 PMKQSEYPLQIEAY-YWNRKNDBSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002421 finishing Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 238000009396 hybridization Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- PMKQSEYPLQIEAY-UHFFFAOYSA-N trans-caffeoyl-L-malic acid Natural products OC(=O)CC(C(O)=O)OC(=O)C=CC1=CC=C(O)C(O)=C1 PMKQSEYPLQIEAY-UHFFFAOYSA-N 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
- C08G18/722—Combination of two or more aliphatic and/or cycloaliphatic polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/08—Processes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
- C08G18/246—Catalysts containing metal compounds of tin tin salts of carboxylic acids containing also tin-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
- C08G18/3231—Hydrazine or derivatives thereof
-
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
- C08G18/348—Hydroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/6692—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/34
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/24—Derivatives of hydrazine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/26—Cellulose ethers
- C08L1/28—Alkyl ethers
- C08L1/286—Alkyl ethers substituted with acid radicals, e.g. carboxymethyl cellulose [CMC]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2401/08—Cellulose derivatives
- C08J2401/26—Cellulose ethers
- C08J2401/28—Alkyl ethers
Definitions
- the present disclosure relates to the technical field of glove processing, and in particular, to a waterborne polyurethane (WPU) emulsion and a preparation method therefor.
- WPU waterborne polyurethane
- Dipped gloves also known as latex gloves, are one of the gloves. Different from ordinary gloves, the dipped gloves are made of latex. The dipped gloves are comfortable to wear after special surface treatment, and are necessary hand protection products, that have been widely used in industrial and agricultural production, medical treatment, beauty treatment and daily life.
- Benzene, methanol, and acetic acid have short-term exposure concentrations of 404.1 mg/m 3 , 186.5 mg/m 3 , and 45.5 mg/m 3 respectively and time weighted average exposure concentrations of 212.2 mg/m 3 , 76.4 mg/m 3 , and 29.2 mg/m 3 respectively.
- most factories use transparent plastic sheets to encapsulate the production line, which greatly reduces the concentration of chemical substances in the workshop, but does not fundamentally solve the problem of organic volatile pollution.
- at least 40% of the organic solvents in the rubber are directly discharged into the air without treatment throughout the production process, causing serious environmental pollution.
- the rubber used for labor protection gloves is gradually transferred to waterborne materials, most commonly latex gloves (i.e., natural rubber latex (NRL) gloves) and nitrile gloves.
- NRL gloves themselves contain proteins that can cause skin allergies.
- the nitrile gloves contain no protein and will not cause allergies to wearers, oligomers or part of monomers contained in nitrile latex are difficult to completely polymerize in the process of hot vulcanization, which is likely to cause odor and secondary pollution.
- the WPU with water as a dispersion medium is non toxic, environmentally friendly, uninflammable, safe and reliable, not easy to damage the coated surface, energy saving, easy to operate, and easy to modify, and also has good solvent resistance, abrasion resistance, flexibility, and thermal stability, such that it is widely applied in leather finishing, fabrics, adhesives, and coatings.
- the WPU has superior comprehensive performance and strong designability of molecular structure.
- the WPU has surpassed other waterborne polymers in film formation, aging resistance, friction resistance, and strength.
- the WPU has incomparable advantages over other waterborne materials, and is the preferred material for manufacturing high-performance labor protection glue gloves.
- the core technical problems of low solid content, low curing speed, poor water resistance, and low initial viscosity of the WPU material for fabric core glue gloves are solved.
- Foreign technology monopoly is broken through and surpassed. Environment-friendly production is realized. High value-added properties such as environmental protection, air permeability, waterproofness, high elasticity, hand feeling, and water resistance of the glue gloves are improved.
- an objective of the present disclosure is to provide a WPU emulsion, which is prepared by adding a cellulose thickener at an emulsification stage to form a hydrogen bond between the cellulose thickener and water molecules at an initial stage of formation of polyurethane particles, so as to limit movement of the water molecules and make the particles collide and combine, thereby improving the abrasion resistance and flexibility, and prolonging the life of dipped gloves.
- the WPU emulsion provided by the present disclosure includes the following raw materials in part by weight: 230-250 parts of polyol, 50-60 parts of isocyanate, 5-10 parts of a hydrophilic chain extender, 60-80 parts of a diluent, 5-9 parts of a neutralizer, 500-600 parts of water, 15-20 parts of a post chain extender, 0.01-0.05 parts of a catalyst, 3-7 parts of a cellulose thickener, 0.5-1.5 parts of a wetting agent, and 3-5 parts of a dispersant.
- the polyol is one or more selected from the group consisting of polyester polyols, polyether polyols, polycaprolactone polyols, polycarbonate polyols, polysiloxane polyols, and polytetrahydrofuran (PTHF).
- polyester polyols polyether polyols, polycaprolactone polyols, polycarbonate polyols, polysiloxane polyols, and polytetrahydrofuran (PTHF).
- the isocyanate is one or two selected from the group consisting of isophorone diisocyanate (IPDI) and hexamethylene diisocyanate (HDI).
- IPDI isophorone diisocyanate
- HDI hexamethylene diisocyanate
- the hydrophilic chain extender is 2,2-dimethylol propionic acid (DMPA).
- DMPA 2,2-dimethylol propionic acid
- the diluent is any one selected from the group consisting of dimethylacetamide (DMAC), acetone, N, N-dimethylformamide (DMF), and N-methylpyrrolidone (NMP).
- DMAC dimethylacetamide
- DMF N-dimethylformamide
- NMP N-methylpyrrolidone
- the neutralizer is triethylamine (TEAM).
- the post chain extender is one or two selected from the group consisting of diethylenetriamine, ethylenediamine, isophorone diamine, and hydrazine hydrate.
- the catalyst is organic tin or organic bismuth.
- the cellulose thickener is carboxymethyl cellulose.
- the wetting agent is polyether modified organosiloxane.
- the dispersant is aryl ethyl phenyl polyethylene glycol ether.
- the organic tin used in the present disclosure is dibutyltin dilaurate, which is T12 purchased from Shanghai Huihua Industrial Co., Ltd.
- the organic bismuth is an organic bismuth catalyst, purchased from BiCAT of Xindian Chemistry Materials (Shanghai) Co., Ltd.
- the cellulose thickener is carboxymethyl cellulose, purchased from CMC of Weifang Lude Chemical Co., Ltd.
- the wetting agent is polyether modified organosiloxane, purchased from BYK348 of BYK Chemical.
- the dispersant is aryl ethyl phenyl polyethylene glycol ether, the model of which is Fabricamul RL of H.J.Unkel (Shanghai) International Trading Co., Ltd.
- Another objective of the present disclosure is to provide a preparation method for the WPU emulsion, including the following steps:
- Knitted gloves are dipped with the WPU emulsion, and specific steps are as follows:
- the present disclosure provides a WPU emulsion and a preparation method therefor.
- the WPU emulsion is prepared by adjusting the raw materials, defining the particle size in the composition, and adding the cellulose thickener at the emulsification stage to form a hydrogen bond between the cellulose thickener and water molecules at an initial stage of formation of polyurethane particles, so as to limit movement of the water molecules and make the particles collide and combine.
- the dipped gloves prepared with the above emulsion are perfectly combined with the fabric glove core, which has the characteristics of more excellent abrasion resistance and flexibility and long service life, and achieves more excellent wearing comfort than simple knitted gloves.
- the dipped gloves prepared by the present disclosure have simple preparation process, short production cycle, high production capacity, and high cost-effectiveness.
- a WPU emulsion included the following raw materials in part by weight: 270.74 parts of polyol, 50.56 parts of isocyanate, 7.82 parts of a hydrophilic chain extender, 36 parts of a diluent, 5.9 parts of a neutralizer, 541.66 parts of water, 17.21 parts of a post chain extender, 0.02 parts of a catalyst, 3.6 parts of a cellulose thickener, 2.2 parts of a wetting agent, and 1.8 parts of a dispersant.
- the polyol was PTHF 1000.
- the isocyanate consisted of 25.56 parts of IPDI and 25 parts of HDI.
- the hydrophilic chain extender was 2,2-dimethylol propionic acidDMPA.
- the diluent was acetone.
- the neutralizer was TEAM.
- the post chain extender was hydrazine hydrate.
- the catalyst was dibutyltin dilaurate.
- the cellulose thickener was carboxymethyl cellulose.
- the wetting agent was polyether modified organosiloxane.
- the dispersant was aryl ethyl phenyl polyethylene glycol ether.
- a preparation method for the WPU emulsion included the following steps.
- the polyol and the hydrophilic chain extender were put into a reactor, The isocyanate was added while stirring at 150 r/min. The catalyst was added after a temperature rose to 80°C. Nitrogen was introduced. Heat preservation was conducted for 3 h to obtain the isocyanate terminated prepolymer.
- the diluent and the neutralizer were added to neutralize the isocyanate terminated prepolymer to obtain a neutralized prepolymer.
- Step III emulsification
- the neutralized prepolymer in step II was added into the water to obtain a mixture, and the mixture was stirred at 3,200 r/min (high speed stirring) for 30 min to form a dispersion.
- the post chain extender was added to the dispersion in step III, and stirred for 30 min to obtain a WPU dispersion.
- a particle size was limited to 20-30 ⁇ m during chain extension.
- Step V preparation of emulsion
- the cellulose thickener, the wetting agent, and the dispersant were added into the WPU dispersion, and stirred for 30 min to obtain the WPU emulsion.
- a method for preparing dipped gloves with the above WPU emulsion included the following specific steps.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Gloves (AREA)
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| CN202211211903.5A CN115558077A (zh) | 2022-09-30 | 2022-09-30 | 一种水性聚氨酯乳液及其制备方法 |
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| EP23150796.3A Pending EP4345117A1 (fr) | 2022-09-30 | 2023-01-09 | Émulsion aqueuse de polyuréthane (wpu) et son procédé de préparation |
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| Country | Link |
|---|---|
| US (1) | US11958934B1 (fr) |
| EP (1) | EP4345117A1 (fr) |
| JP (1) | JP7462083B1 (fr) |
| CN (1) | CN115558077A (fr) |
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| WO2025219697A1 (fr) * | 2024-04-15 | 2025-10-23 | Tilsatec Ltd | Revêtement |
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| CN117016890A (zh) * | 2023-08-10 | 2023-11-10 | 恒劢安全防护用品（南通）有限公司 | 一种具有透气透湿性能的聚氨酯手套及其制备方法 |
| CN118930804B (zh) * | 2024-08-27 | 2025-04-29 | 旭川化学（苏州）有限公司 | 一种水性聚氨酯浸胶乳液及其制备方法和应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030068534A (ko) * | 2000-07-20 | 2003-08-21 | 노베온 아이피 홀딩스 코프. | 가소화된 수성 폴리우레탄 분산제 및 이를 제조하는 방법 |
| CN106380829A (zh) * | 2016-08-25 | 2017-02-08 | 山东天庆科技发展有限公司 | 一种水性聚氨酯手套浆料及其制备方法以及由其制得的水性聚氨酯手套 |
| CN110452351A (zh) * | 2019-08-22 | 2019-11-15 | 山东星宇手套有限公司 | 一种水性聚氨酯乳液、制备方法和浸胶手套 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3970955B2 (ja) * | 1995-04-25 | 2007-09-05 | 三井化学ポリウレタン株式会社 | ポリウレタン水性組成物 |
| US6322851B1 (en) * | 1998-06-30 | 2001-11-27 | Kuraray Co., Ltd. | Manufacturing process for leather-like sheet |
| JP4132416B2 (ja) * | 1999-06-10 | 2008-08-13 | 株式会社クラレ | 複合樹脂エマルジョンの製造方法 |
| JP2002061079A (ja) * | 2000-08-11 | 2002-02-28 | Kuraray Co Ltd | 皮革様シートの製造方法 |
| CN102504167B (zh) | 2011-10-10 | 2013-07-10 | 嘉兴禾欣化学工业有限公司 | 硝化纤维素改性水性聚氨酯树脂的制备方法 |
| CN104193948A (zh) * | 2014-09-15 | 2014-12-10 | 山东天庆科技发展有限公司 | 聚氨酯手套用水性树脂及其制备方法 |
| CN108753139B (zh) | 2018-06-19 | 2020-09-18 | 广州康狄夫环保科技有限公司 | 复配水性涂料及其制备方法和应用 |
| CN108978252A (zh) * | 2018-08-23 | 2018-12-11 | 江苏恒辉安防股份有限公司 | 一种双层pu手套的加工方法 |
| CN110016251A (zh) | 2019-04-16 | 2019-07-16 | 汕头市金平区五星油墨实业有限公司 | 一种水性凹印油墨 |
| KR20220117220A (ko) | 2019-12-13 | 2022-08-23 | 주식회사 쿠라레 | 폴리우레탄, 연마층, 연마 패드 및 연마 방법 |
| CN112500776A (zh) | 2020-11-19 | 2021-03-16 | 明新孟诺卡(江苏)新材料有限公司 | 一种零溶剂水性聚氨酯外消光皮革涂饰剂及其制备方法 |
| KR102349984B1 (ko) | 2021-01-13 | 2022-01-11 | 권석임 | 장갑코팅용 폴리우레탄 수계 컬러 분산액, 이를 포함하는 컬러 코팅액 제조방법 및 이로 구현된 컬러 코팅장갑 |
| CN113736061B (zh) * | 2021-09-06 | 2023-02-21 | 山东星宇手套有限公司 | 用于浸胶劳保用品的免凝固剂水性聚氨酯乳液及制备方法 |
| CN113845641B (zh) * | 2021-10-22 | 2023-04-28 | 旭川化学（苏州）有限公司 | 一种大粒径水性聚氨酯乳液、制备方法及其在含浸手套中的应用 |
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- 2022-09-30 CN CN202211211903.5A patent/CN115558077A/zh active Pending
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- 2023-01-09 EP EP23150796.3A patent/EP4345117A1/fr active Pending
- 2023-02-01 JP JP2023013815A patent/JP7462083B1/ja active Active
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030068534A (ko) * | 2000-07-20 | 2003-08-21 | 노베온 아이피 홀딩스 코프. | 가소화된 수성 폴리우레탄 분산제 및 이를 제조하는 방법 |
| CN106380829A (zh) * | 2016-08-25 | 2017-02-08 | 山东天庆科技发展有限公司 | 一种水性聚氨酯手套浆料及其制备方法以及由其制得的水性聚氨酯手套 |
| CN110452351A (zh) * | 2019-08-22 | 2019-11-15 | 山东星宇手套有限公司 | 一种水性聚氨酯乳液、制备方法和浸胶手套 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025219697A1 (fr) * | 2024-04-15 | 2025-10-23 | Tilsatec Ltd | Revêtement |
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| CN115558077A (zh) | 2023-01-03 |
| JP2024052475A (ja) | 2024-04-11 |
| US20240110001A1 (en) | 2024-04-04 |
| JP7462083B1 (ja) | 2024-04-04 |
| US11958934B1 (en) | 2024-04-16 |
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