EP4411013A1 - Tôle d'acier à haute résistance et épaisse dotée d'excellentes capacités d'expansion de trou et de ductilité et son procédé de fabrication - Google Patents

Tôle d'acier à haute résistance et épaisse dotée d'excellentes capacités d'expansion de trou et de ductilité et son procédé de fabrication Download PDF

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EP4411013A1
EP4411013A1 EP22873172.5A EP22873172A EP4411013A1 EP 4411013 A1 EP4411013 A1 EP 4411013A1 EP 22873172 A EP22873172 A EP 22873172A EP 4411013 A1 EP4411013 A1 EP 4411013A1
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Prior art keywords
steel sheet
less
excluding
ductility
strength
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German (de)
English (en)
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EP4411013A4 (fr
Inventor
Kyoung-Rae Cho
Sung-Kyu Kim
Jun-Ho Park
Sang-Ho Han
Jeong-Hun Kim
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Posco Holdings Inc
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Posco Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES, PROFILES OR LIKE SEMI-MANUFACTURED PRODUCTS OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C47/00—Winding-up, coiling or winding-off metal wire, metal band or other flexible metal material characterised by features relevant to metal processing only
    • B21C47/02—Winding-up or coiling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/185—Hardening; Quenching with or without subsequent tempering from an intercritical temperature
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • C21D1/22—Martempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236—Cold rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273—Final recrystallisation annealing
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/54—Furnaces for treating strips or wire
    • C21D9/56—Continuous furnaces for strip or wire
    • C21D9/573—Continuous furnaces for strip or wire with cooling
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/001—Austenite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/002—Bainite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/005—Ferrite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite

Definitions

  • the present disclosure relates to a steel suitable for an automotive material, and particularly, to a high-strength thick steel sheet having excellent hole expandability and ductility, and a method for manufacturing the same.
  • a high-strength steel having excellent strength is being adopted as a material of structural members such as a member, seat rail, and a pillar for improving impact resistance of a car body.
  • automotive parts have a complicated shape depending on stability and design thereof, and are manufactured by forming with a press mold, the automotive parts require to have a high level of formability together with high strength.
  • the steel As the strength of steel is high, the steel is favorable to energy absorption, but generally, when the strength is increased, elongation is decreased to reduce forming processability. Besides, when yield strength is excessively high, introduction of a material into a mold during forming is decreased to deteriorate formability and increase manufacturing costs.
  • high-strength steel used as an automotive material includes, representatively, a dual phase steel (DP steel), a transformation induced plasticity steel (TRIP steel), a complex phase steel (CP steel), a ferrite-bainite steel (FB steel), and the like.
  • DP steel dual phase steel
  • TRIP steel transformation induced plasticity steel
  • CP steel complex phase steel
  • FB steel ferrite-bainite steel
  • a DP steel which is an ultra-high tensile steel has a low yield ratio of about 0.5 to 0.6
  • the DP steel has an advantage in that it is easy to process, and has a second highest elongation after a TRIP steel.
  • it is mainly applied to a door outer, a seat rail, a seat belt, a suspension, an arm, a wheel disc, and the like.
  • TRIP steel Since TRIP steel has a yield ratio in a range of 0.57 to 0.67, it is characterized by having excellent formability (high ductility), and is suitable for components requiring high formability such as a member, a roof, a seat belt, a bumper rail, and the like.
  • a CP steel is applied to a side panel, an underbody reinforcing material, and the like by a high elongation and bending processability together with a low yield ratio, and a FB steel has excellent hole expandability and is mainly applied to a suspension lower arm, a wheel disc, and the like.
  • a DP steel is mainly formed of ferrite having excellent ductility and a hard phase having high strength (martensite phase, bainite phase), and a trace amount of residual austenite may exist therein.
  • the DP steel as such has low yield strength and high tensile strength to have a low yield ratio (YR), and has excellent characteristics such as a high processing hardening rate, high ductility, continuous yield behavior, aging resistance at room temperature, bake hardenability, and the like.
  • the steel may be manufactured as a high-strength steel having high hole expandability.
  • the fraction of a hard phase such as a martensite phase which is favorable to strength improvement should be increased, and in this case, yield strength is increased to cause defects such as cracks during press forming.
  • a DP steel for an automobile is manufactured into a final product by manufacturing a slab by steelmaking and continuous casting processes, subjecting the slab to [heating - rough rolling - finish hot rolling] to obtain a hot-rolled coil, and then performing an annealing process.
  • an annealing process is a process performed mainly in the manufacture of a cold-rolled steel sheet, and the cold-rolled steel sheet is manufactured by pickling a hot-rolled coil to remove a surface scale, performing cold rolling to a certain reduction rate at room temperature, and then performing an annealing process, and, if necessary, an additional temper rolling process.
  • a cold-rolled steel sheet (cold-rolled material) obtained by cold rolling is in a very hardened state itself and is unsuitable for manufacturing components requiring processability, it may be softened by a heat treatment in a continuous annealing furnace as a subsequent process to improve processability.
  • a steel sheet (cold-rolled material) is heated to about 650 to 850°C in a heating furnace and the temperature thereof is maintained for a certain amount of time, thereby lowering hardness and improving processability through recrystallization and phase transformation phenomena.
  • a steel sheet which is not subjected to the annealing process has a high hardness, in particular, a high surface hardness and lacks processability, while a steel sheet subjected to an annealing process has a recrystallization structure, thereby having lowered hardness, yield point, and tensile strength to promote improvement of processability.
  • ferrite is completely recrystallized in a heating process during continuous annealing to be manufactured into an equiaxed crystal form, so that austenite is produced and grows in a subsequent process to be the equiaxed crystal form, and thus, it is favorable for forming a small-sized and uniform austenite phase.
  • a thickness of a hot-rolled steel sheet should be secured to be relatively thick in order to secure a certain reduction rate, so there is a problem in that a load during subsequent cold rolling is large and operability is lowered. If the reduction rate is low when manufacturing thick materials, structural nonuniformity due to non-recrystallization of ferrite during annealing increases and yield strength increases, and there is a problem in that yield strength increases, and processability deteriorates as directionality of cold rolling is maintained in the microstructure. Therefore, in the case of thick materials, material deviation in a thickness direction is bound to be large due to nature of dimensional characteristics, so a technology for homogenizing a material as much as possible is required to improve processability and usable properties.
  • Patent Document 1 discloses that it is possible to secure hole expandability and elongation by forming fine precipitates using Ti, Mo, and the like, and including ferrite, bainite, and martensite phases as a microstructure.
  • the present document has problems with weldability and liquid metal embrittlement (LME) due to silicon excessively added to introduce carbon and bainite to form fine precipitates.
  • LME liquid metal embrittlement
  • Patent Document 1 Korean Patent Laid-Open Publication No. 10-2021-0095156 .
  • An aspect of the present disclosure is to provide, as a material suitable for an automotive structural member, or the like, a high-strength thick steel sheet having a low yield ratio and high strength, and excellent formability such as hole expandability through improved ductility, and a method for manufacturing the same.
  • An object of the present disclosure is not limited to the above description.
  • the object of the present disclosure will be understood from the entire content of the present specification, and a person skilled in the art to which the present disclosure pertains will understand an additional object of the present disclosure without difficulty.
  • a high-strength thick steel sheet having excellent hole expandability and ductility including, by weight: 0.05 to 0.12% of carbon (C), 2.0 to 3.0% of manganese (Mn), 0.5% or less (excluding 0%) of silicon (Si), 1.0% or less (excluding 0%) of chromium (Cr), 0.1% or less (excluding 0%) of niobium (Nb), 0.1% or less (excluding 0%) of titanium (Ti), 0.003% or less (excluding 0%) of boron (B), 0.02 to 0.05% of aluminum (sol.Al), 0.05% or less (excluding 0%) of phosphorus (P), 0.01% or less (excluding 0%) of sulfur (S), and 0.01% or less (excluding 0%) of nitrogen (N), with a remainder of Fe and other unavoidable impurities,
  • a steel sheet includes, by area fraction, 10 to 30% of ferrite, 10 to 25% of recrystallized ferrite bridge, and 20 to 30% of bainite, and residual martensite as a microstructure.
  • a method for manufacturing a high-strength thick steel sheet having excellent hole expandability and ductility including: preparing a steel slab; heating the steel slab at a temperature within a range of 1100 to 1300°C; hot rolling the heated steel slab to manufacture a hot-rolled steel sheet; coiling the hot-rolled steel sheet at a temperature within a range of 400 to 700°C; cooling the hot-rolled steel sheet to room temperature after the coiling; cold rolling the cooled hot-rolled steel sheet at a cold reduction rate of 55 to 80% to manufacture a cold-rolled steel sheet; continuously annealing the cold-rolled steel sheet; performing primary cooling to a temperature within a range of 650 to 700°C at an average cooling rate of 1 to 10°C/s after the continuous annealing; and performing secondary cooling to a temperature within a range of 450 to 500°C at an average cooling rate of 5 to 50
  • the continuous annealing is performed in an equipment equipped with a heating zone, a soaking zone, and a cooling zone, and the cold-rolled steel sheet passes through a recrystallization zone in which the cold-rolled steel sheet is maintained at a temperature within a range of 600 to 700°C for 1 to 3 minutes when the temperature of the cold-rolled steel sheet is raised to a temperature within a range of the heating zone.
  • a thick steel sheet having improved formability and collision resistance due to excellent hole expandability despite having high strength may be provided.
  • the steel sheet of the present disclosure having improved formability may prevent processing defects such as cracks, wrinkles, or the like, during processing forming, and is thus suitable for being applied to structural parts requiring being processed into a complex shape. Furthermore, it is also effective in manufacturing a material having improved collision resistance to prevent defects such as cracks, or the like, from being formed when a car to which such components are applied inevitably collides.
  • the inventors of the present disclosure conducted intensive research in order to develop a material having a formability level which may be suitably used in components and the like requiring processing to a complicated shape among automotive materials.
  • the present inventors confirmed that the goal may be achieved by deriving a composition of a structure that can increase crack resistance between hard phases and refining a hard phase favorable to preventing formation and propagation of voids and controlling a crystal grain shape, thereby completing the present disclosure.
  • the present disclosure introduces a recrystallized ferrite bridge having a structure connecting the hard phases to each other so that unidirectionality of the hard phases is removed, and has technical significance in optimizing an alloy composition and manufacturing conditions forming the structure.
  • a high-strength thick steel sheet having excellent hole expandability and ductility including, by weight: 0.05 to 0.12% of carbon (C), 2.0 to 3.0% of manganese (Mn), 0.5% or less (excluding 0%) of silicon (Si), 1.0% or less (excluding 0%) of chromium (Cr), 0.1% or less (excluding 0%) of niobium (Nb), 0.1% or less (excluding 0%) of titanium (Ti), 0.003% or less (excluding 0%) of boron (B), 0.02 to 0.05% of aluminum (sol.Al), 0.05% or less (excluding 0%) of phosphorus (P), 0.01% or less (excluding 0%) of sulfur (S), and 0.01% or less (excluding 0%) of nitrogen (N), with a remainder of Fe and other unavoidable impurities.
  • C carbon
  • Mn manganese
  • Mn manganese
  • Si silicon
  • Cr chromium
  • Nb niobium
  • Ti titanium
  • Ti
  • a content of each element is based on weight, and a ratio of structure is based on area.
  • Carbon (C) is an important element which is added for solid solution strengthening, and is bonded to a precipitation element to form a fine precipitate, thereby contributing to improving strength of steel.
  • C may be included in an amount of 0.05 to 0.12%. More favorably, C may be included in an amount of 0.06% or more and 0.10% or less.
  • Manganese (Mn) is an element which precipitates sulfur (S) in steel as MnS to prevent hot brittleness by production of FeS, and is favorable to solid solution strengthening of steel.
  • Mn-band Mn oxide band
  • a Mn oxide is eluted on the surface during annealing to greatly deteriorate plating properties.
  • Mn may be included in an amount of 2.0 to 3.0%, and more favorably, Mn may be included in an amount of 2.2% or more and 2.8% or less.
  • Silicon (Si) is a ferrite stabilizing element, and promotes ferrite transformation to be favorable to securing a target level of ferrite fraction. In addition, it has good solid solution strengthening ability to be effective to increase strength of ferrite, and is an element useful for securing strength while not decreasing ductility.
  • Si may be included in an amount of 0.5% or less, and 0% may be excluded. More favorably, Si may be included in an amount of 0.1% or more.
  • Chromium (Cr) is an element facilitating formation of a bainite phase by exerting a hardenability effect during cooling, and is an element which forms a fine carbide while suppressing formation of a martensite phase during an annealing heat treatment, thereby contributing to strength improvement.
  • Cr acts as a ferrite stabilizing element during heating to delay of a reaction of austenite phase transformation and phase transformation begins at a higher temperature, Cr stays for a long time in a region (Trex ⁇ A1) where only recrystallization occurs during heating. As a result thereof, a recrystallized ferrite bridge structure may be secured.
  • the recrystallized ferrite bridge which is intended may not be formed, thereby reducing ductility and hole expandability of steel, and when a carbide is formed at a grain boundary, strength and an elongation may be deteriorated. In addition, manufacturing costs may be increased.
  • Cr may be included in an amount of 1.0% or less, and 0% may be excluded. More favorably, Cr may be included in an amount of 0.01% or more.
  • Niobium (Nb) is an element which is segregated at an austenite grain boundary, and suppresses coarsening of austenite crystal grains during an annealing heat treatment, and forms a fine carbide to contribute to strength improvement.
  • Nb may be included in an amount of 0.1% or less, and 0% may be excluded.
  • Titanium (Ti) is an element forming a microcarbide, and contributes to securing yield strength and tensile strength.
  • Ti precipitates N in steel as TiN to suppress the formation of AlN by Al which is unavoidably present in steel, and thus, reduces the possibility of cracks during continuous casting.
  • a content of Ti exceeds 0.1%, a coarse carbide is precipitated, and strength and an elongation may be decreased by a reduced carbon amount in steel.
  • nozzle clogging may occur during continuous casting, and manufacturing costs may be increased.
  • Ti may be included in an amount of 0.1% or less, and 0% may be excluded.
  • Boron (B) is an element which delays transformation of austenite into pearlite during a cooling process after an annealing heat treatment, but when a content of B exceeds 0.003%, B may excessively concentrate on the surface, resulting in deterioration of plating adhesion.
  • B may be included in an amount of 0.003% or less, and 0% may be excluded considering an avoidably added level.
  • Aluminum (sol.Al) is an element added for an effect of refining a grain size of steel and for deoxidation.
  • a content of aluminum (sol.Al) is less than 0.02%, aluminum killed steel may not be manufactured in a stable state.
  • the aluminum content exceeds 0.05%, crystal grains are refined and the strength is improved, but a risk of surface defects in a plated steel sheet increases due to excessive formation of inclusions during steelmaking.
  • aluminum (sol.Al) may be included in an amount of 0.02 to 0.05%.
  • Phosphorus (P) is a substitutional element having the greatest solid solution strengthening effect, and is an element which improves in-plane anisotropy and is favorable for securing strength without significantly reducing formability.
  • P is excessively added, a possibility of brittle fraction occurrence is greatly increased, so that a possibility of sheet fracture of a slab during hot rolling is increased and plating surface properties are deteriorated.
  • the P content may be controlled to be 0.05% or less, and 0% may be excluded considering an avoidably added level.
  • S is an element which is unavoidably added as an impurity element in steel, and deteriorates ductility, and thus, it is preferred to manage the content as low as possible.
  • S has a problem of increasing a possibility of red brittleness occurrence, it is preferred to control the content to be 0.01% or less.
  • 0% may be excluded.
  • Nitrogen (N) is a solid solution strengthening element, but a content of nitrogen (N) exceeds 0.01%, a risk of brittleness occurrence increases, and is bonded to Al in steel and precipitates as TiN to deteriorate casting quality.
  • N may be included in an amount of 0.01 or less, and considering the unavoidably added level during the manufacturing process, 0% may be excluded.
  • the remaining component of the present disclosure is iron (Fe).
  • Fe iron
  • the component since in the common manufacturing process, unintended impurities may be inevitably incorporated from raw materials or the surrounding environment, the component may not be excluded. Since these impurities are known to any person skilled in the common manufacturing process, the entire contents thereof are not particularly mentioned in the present specification.
  • the steel sheet of the present disclosure having the above-described alloy composition may have a microstructure including ferrite, which is a soft phase, and bainite and martensite phases, which are hard phases, and a recrystallized ferrite bridge structure formed by connecting the hard phases.
  • the biggest change in microstructure due to formation of the recrystallized ferrite bridge is a loss of rolling directionality of existing ferrite and a degree of connection around the hard phases is large.
  • a formation location of reverse transformation austenite is reduced during formation of a recrystallized ferrite bridge during heating and formation of austenite at high temperatures is delayed, a secondary phase having a smaller size after cooling may be generated.
  • a non-recrystallized ferrite region is an elongated structure with rolling directionality and remains as an irregular rough interface, and a recrystallized ferrite bridge grain boundary has a smooth interface having a polygonal shape.
  • a method of determining the recrystallized ferrite bridge may be divided into, for example, an electron backscatter diffraction orientation (EBSD), or may be optically divided by etching with an aqueous hydrogen peroxide solution (ex. 140 ml of distilled water, 100 ml of hydrogen peroxide, 4 g of oxalic acid, 2 ml of sulfuric acid, 1.5 ml of hydrofluoric acid).
  • EBSD electron backscatter diffraction orientation
  • the steel sheet of the present disclosure may include a ferrite phase in an area fraction of 10 to 30%, a recrystallized ferrite bridge phase in an area fraction of 10 to 25%, and 20 to 30% of bainite, which is a hard phase, and a remainder of martensite phase.
  • the steel sheet may include a trace amount of residual austenite phase.
  • the recrystallized ferrite bridge phase is a structure that is advantageous in suppressing propagation of voids generated along a grain boundary of the hard phase by resolving the unidirectionality of the hard phase, and is a structure that is separated from existing polygonal ferrite.
  • the recrystallized ferrite bridge is a structure that is separated from general recrystallized ferrite, and is relatively coarse, preferably having an average size of 1 to 6 ⁇ m based on an equivalent circular diameter.
  • the size of the recrystallized ferrite bridge phase is less than 1 pm, it is difficult to resolve directionality of the hard phase, so the desired effect may not be obtained.
  • the size thereof exceeds 6 pm the recrystallized ferrite bridge phase becomes an excessively coarse structure, so that there is a concern that physical properties such as strength, or the like, may be impaired.
  • the hard phase when the hard phase is formed to have directionality (a), connection of voids formed along the grain boundaries becomes easier, thereby facilitating the propagation of cracks.
  • the structure (b) intended in the present disclosure especially, the recrystallized ferrite bridge phase is formed as a structure connecting he hard phases to each other while removing the unidirectionality of the hard phases, it becomes difficult for voids to coalesce along the grain boundaries, which has an effect of greatly suppressing occurrence and propagation of cracks.
  • the recrystallized ferrite bridge phase When a fraction of this recrystallized ferrite bridge phase is excessively high, the fraction of the hard phase becomes relatively low, making it impossible to secure the target level of strength. Considering this, the recrystallized ferrite bridge phase may be included in an amount of 25% or less. On the other hand, when the fraction is less than 10%, the above-described effects (removal of hard phase unidirectionality, suppression of void propagation, and the like) cannot be sufficiently obtained, resulting in inferior hole expandability.
  • the present invention has technical significance in that formability may be further improved by introducing a recrystallized ferrite bridge phase in addition to the soft ferrite phase and the hard phase bainite phase and martensite phase and controlling the shape and distribution of the recrystallized ferrite bridge phase.
  • a fraction of the martensite phase is not specifically limited, but in order to secure ultra-high strength of 980 MPa or more, the martensite phase may be included in an area fraction of 15% or more. However, when the fraction of the martensite phase exceeds 60%, ductility decreases, making it difficult to secure the target level of formability.
  • the high-strength thick steel sheet of the present disclosure having the above-described microstructure may have high strength and high ductility having a tensile strength of 980 MPa or more, a yield strength of 550 to 700 MPa, and an elongation (total elongation) of 14% or more.
  • the steel plate has a hole expansion ratio (HER) of 30% or more, thereby providing excellent resistance to cracks that may occur during processing and resistance to impact fracture.
  • HER hole expansion ratio
  • the high-strength thick steel sheet of the present disclosure may have a thickness of 1 to 3 mm, and more preferably 1.5 to 2.5 mm.
  • a target steel sheet may be manufactured by performing processes of [steel slab heating - hot rolling - coiling - cold rolling - continuous annealing], and each process will be described in detail.
  • a steel slab satisfying the alloy composition described above may be prepared, and then heated.
  • the present process is performed to smoothly perform a subsequent hot rolling process, and is performed to sufficiently obtain physical properties of the target steel sheet.
  • conditions of the heating process are not particularly limited, and may be common conditions.
  • the heating process may be performed at a temperature within a range of 1100 to 1300°C.
  • the steel slab heated as described above may be hot rolled to manufacture a hot-rolled steel sheet, and herein, finish hot rolling may be performed at an outlet temperature of Ar3 or higher to 1000°C or lower.
  • the finish hot rolling may be performed at a temperature within a range of 760 to 940°C.
  • the hot-rolled steel sheet manufactured as described above may be coiled to a coil shape.
  • the coiling may be performed at a temperature within a range of 400 to 700°C.
  • a coiling temperature is lower than 400°C, an increase in excessive strength of the hot-rolled steel sheet is caused due to excessive formation of martensite or recrystallized ferrite bridge phases, and problems such as poor shape due to a load during subsequent cold rolling may be caused.
  • the coiling temperature is higher than 700°C, a surface scale is increased to deteriorate pickling properties.
  • the coiled hot-rolled steel sheet is cooled to room temperature at an average cooling rate of 0.1°C/s or less (excluding 0°C/s).
  • the coiled hot-rolled steel sheet may be cooled after being subjected to processes such as transfer and stacking, and it should be noted that the process before cooling is not limited thereto.
  • the coiled hot-rolled steel sheet is cooled at a constant speed, thereby obtaining a hot-rolled steel sheet in which a carbide which is a nucleation site of austenite is finely dispersed.
  • the hot-rolled steel sheet coiled as described above may be cold rolled to manufacture a cold-rolled steel sheet, and in the present disclosure, the cold rolling may be performed at a cold reduction rate of 55 to 80%.
  • recrystallization of ferrite may be further promoted in a heating section during a subsequent continuous annealing process while applying an appropriate level of cold reduction rate during cold rolling, and therefrom, formation of fine ferrite may be induced so that austenite formed at a ferrite grain boundary may also be formed to be small and uniform.
  • the cold rolling may be performed at a cold reduction rate of 78% or less.
  • the cold reduction rate may be realized not only with a high rolling capacity of ZRM equipment (e.g., at a level of 5000KN/mm) from a hot-rolled thick material having a certain thickness, but also include a process of achieving a target reduction rate by repeated rolling by using a reversing mill.
  • the hot-rolled thick material may have a thickness of 4 to 8 mm, and when the hot-rolled thick material has a thickness of 6 mm or more, it should be noted that a cold rolling process using a reversing mill may be performed.
  • the reversing mill is a type of rolling mill generally used for rolling thin materials, and refers to a rolling mill that rolls while reciprocating a material between a pair of rolls, and when reciprocating the material, one way may be set 1 pass.
  • the hot-rolled steel sheet may be picked before the cold rolling, and it should be noted that the pickling treatment process may be performed by a conventional method.
  • the cold-rolled steel sheet manufactured as described above is continuously annealed.
  • the continuous annealing treatment may be performed in a continuous annealing line (CAL), as an example.
  • the continuous annealing line may be formed of [heating zone -soaking zone - cooling zone (slow cooling zone and rapid cooling zone) - overaging zone], and after the cold-rolled steel sheet is charged into the continuous annealing line as such, the steel sheet is heated to a certain temperature in the heating section, and after a target temperature is reached, the steel sheet is maintained in the soaking zone for a certain period of time.
  • a temperature of the heating zone and the soaking zone may be controlled to be the same during the continuous annealing, which means that an end temperature of the heating zone and a starting temperature of the soaking zone are controlled to be the same ( FIG. 1 ).
  • the temperature of the heating zone and the soaking zone can be controlled to be 790 to 850°C.
  • the fraction of the hard phase in the final structure is increased to increase a yield strength, and the same time, a difference in hardness between the phases is lowered by introducing bainite to improve a hole expansion ratio.
  • an effect of improving processability may be obtained by strengthening crack toughness, that is crack resistance, while maintaining the strength.
  • the cold-rolled steel sheet subjected to continuous annealing as described above may be cooled, thereby forming a target structure, and in this case, it is preferred to perform cooling stepwise.
  • the stepwise cooling may be formed of primary cooling - secondary cooling, and specifically, primary cooling may be performed at a temperature within a range of 650 to 700°C at an average cooling rate of 1 to 10°C/s after the continuous annealing, and then secondary cooling may be performed at a temperature within a range of 400 to 500°C at an average cooling rate of 5 to 50°C/s.
  • the primary cooling may be performed more slowly than the secondary cooling, thereby suppressing plate shape defects due to a rapid temperature drop during the secondary cooling, which is a relatively rapid cooling section.
  • the primary cooling may be performed at an average cooling rate of 1°C/s or more.
  • rapid cooling may be performed at a cooling rate at or above a certain level.
  • secondary cooling when the secondary cooling end temperature is lower than 450°C, a cooling deviation in a width direction and a length direction of the steel sheet occur, so that a plate shape may be deteriorated.
  • the temperature when the temperature is higher than 500°C, a hard phase may not be sufficiently secured, so that the strength may be lowered.
  • the average cooling rate in the secondary cooling is less than 5°C/s, a fraction of a soft phase may be excessive, but when the average cooling rate exceeds 50°C/s, the hard phase may be rather insufficient.
  • an overaging treatment may be performed.
  • the overaging treatment is a process of maintaining for a certain period of time after the secondary cooling end temperature, and a uniform heat treatment in a width direction and a length direction of the coil is performed, thereby improving shape quality. To this end, the overaging treatment may be performed for 200 to 800 seconds.
  • the temperature may be the same as the secondary cooling end temperature, may be performed within the secondary cooling end temperature range, or may be performed at a lower temperature thereof. More favorably, it should be noted that the overaging treatment may be performed at a temperature within a range of 300 to 450 °C.
  • the high-strength thick steel sheet of the present disclosure manufactured as described above is formed of a hard phase and a soft phase as a microstructure, and in particular, ferrite recrystallization is excessively increased by an optimized cold rolling and annealing process, thereby having a structure in which a martensite phase, which is a hard phase is uniformly distributed in a finally recrystallized ferrite matrix.
  • ferrite recrystallization is excessively increased by an optimized cold rolling and annealing process, thereby having a structure in which a martensite phase, which is a hard phase is uniformly distributed in a finally recrystallized ferrite matrix.
  • a relatively coarse recrystallized ferrite bridge phase to connect the hard phase, crack resistance during processing may be increased.
  • the thick steel sheet of the present disclosure may secure excellent formability such as hole expandability, or the like, by securing a low yield ratio and high ductility, even with a high strength of a tensile strength of 980 MPa or more.
  • each steel slab was heated at 1200°C for 1 hour and then subjected to finish hot rolling at a finish rolling temperature of 880 to 920°C to manufacture a hot-rolled steel sheet. Thereafter, each hot-rolled steel sheet was coiled at 650°C, and then cooled to room temperature at a cooling rate of 0.1°C/s. Thereafter, the coiled hot-rolled steel sheet was subjected to cold rolling and continuous annealing under the conditions shown in the following Table 2, was then subjected to stepwise cooling (first - second), and was then subjected to an overaging treatment at 360°C for 520 seconds to manufacture a final steel sheet having a thickness of 1.8mm.
  • first cooling was performed at an average cooling rate of 3°C/s
  • second cooling was performed at an average cooling rate of 20°C/s, in the stepwise cooling.
  • a tensile test for each specimen was performed at a strain rate of 0.01/s after collecting a tensile specimen of a JIS No. 5 size in a vertical direction to a rolling direction.
  • a test of measuring a hole expansion ratio was performed in accordance with an ISO 16630 standard. Specifically, when a circular hole was punched in a test specimen and then expanded using a conical punch, an amount of hole expansion until cracks occurring at an edge of the hole penetrated in a thickness direction was expressed as a ratio to an initial hole.
  • a specimen dimension was 120 mm ⁇ 120 mm
  • a clearance was 12%
  • a diameter of a punched hole was 10 mm
  • a load of a punched hole was 20 tons
  • a test speed was 12 mm/min.
  • a bainite phase corresponding to a hard phase, was observed through pircral etching, and a martensite phase was observed at 2000X magnification and 5000X magnification by SEM after nital etching.
  • a hard phase was formed by being connected thereto by a recrystallized ferrite bridge phase due to sufficient recrystallization of ferrite in an annealing process after cold rolling. Accordingly, it had high strength, yield strength appropriate for plate processing, and excellent elongation. In addition, it could be confirmed that the hole expandability was excellent due to homogeneous distribution of the hard phase, so that a target level of formability may be secured.
  • Comparative Examples 11 to 14 in which a second cooling temperature was very low, had an excessively high yield strength, resulting in a high risk of cracks occurring during processing, and the elongation was inferior due to the absence of a recrystallized ferrite bridge phase.
  • FIG. 3 illustrates images of the microstructure of Comparative Examples 1, 4 to 5, and 9, and FIG. 4 illustrates images of the microstructure of Inventive Examples 1, 3 to 4, and 6.

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EP22873172.5A 2021-09-27 2022-09-21 Tôle d'acier à haute résistance et épaisse dotée d'excellentes capacités d'expansion de trou et de ductilité et son procédé de fabrication Pending EP4411013A4 (fr)

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