Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
  • B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
  • B41M7/0045—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or film forming compositions cured by mechanical wave energy, e.g. ultrasonics, cured by electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams, or cured by magnetic or electric fields, e.g. electric discharge, plasma
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
  • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
  • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
  • B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
  • B42D25/29—Securities; Bank notes
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
  • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
  • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
  • B42D25/30—Identification or security features, e.g. for preventing forgery
  • B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/22—Di-epoxy compounds
  • C08G59/24—Di-epoxy compounds carbocyclic
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/22—Di-epoxy compounds
  • C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
  • C08G59/306—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen containing silicon
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/32—Epoxy compounds containing three or more epoxy groups
  • C08G59/3254—Epoxy compounds containing three or more epoxy groups containing atoms other than carbon, hydrogen, oxygen or nitrogen
  • C08G59/3281—Epoxy compounds containing three or more epoxy groups containing atoms other than carbon, hydrogen, oxygen or nitrogen containing silicon
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
  • C08G77/04—Polysiloxanes
  • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
  • C08G77/04—Polysiloxanes
  • C08G77/38—Polysiloxanes modified by chemical after-treatment
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
  • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
  • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/04—Oxygen-containing compounds
  • C08K5/15—Heterocyclic compounds having oxygen in the ring
  • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
  • C09D183/04—Polysiloxanes
  • C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups

Definitions

• the present invention lies in the field of security documents. Its main subject is the use of an epoxy-silicone copolymer, a crosslinkable fluid composition containing it and a bank note coated with this composition.
• those skilled in the art can choose, as mentioned in the example above, to test macroscopic characteristics intended to reflect the attacks encountered by the notes in circulation. But he can also choose to measure directly a physico-chemical quantity which will be able to characterize upstream the repulsive effects or the ability of a surface to be wet through, in particular, the measurement of the interfacial tension or surface energy.
• a state of the art of interest is constituted by documents W02015/091873, JPH11199673, US2016/060398 and W02001/53385.
• a surface coating formulation that is to say a varnish applicable to security documents and more particularly to bank notes, which not only presents the barrier properties mentioned above (resistance to dry dirt, water and grease), but also anti-writing properties which reflect the impossibility, or at least the difficulty, of writing on the previously varnished support, thus dissuading the man in the street to use notes as "Post-it” (registered trademark), reminders or "releases” towards a personality or a symbol of power.
• anti-writing properties is meant the ability of the coating applied to a substrate made of paper or plastic material for bank notes, to resist writing.
• the pen inks used during writing attempts tend to remain on the tips of the pens, to form droplets on the surface of the substrate (non-continuous line, water repellency) or to adhere with difficulty (continuous line but with low intensity and which can “drool” easily).
• this “anti-writing” property has been the subject of an instrumental and visual characterization based both on the ASTM D6578 standard entitled “Determination of Graffiti Resistance”, which is adapted to the particularity of the documents. security, and also on a specific test developed on this occasion to reflect the difficulty of writing on the media and therefore deter registration attempts. More precisely, the “anti-write” property is the subject of an anti-write note described below.
• the present invention relates firstly to the use of an epoxy-silicone copolymer, that is to say a polyorganosiloxane provided with branches comprising epoxy functions, for the manufacture of a coating anti-write surface of a bank note.
• R represent hydrocarbon groups that are identical or different from each other
• R 1 represent hydrogen atoms or hydrocarbon groups that are identical or different from each other
• R 2 represents a hydrocarbon group with at least one carbon atom, a group which can also contain an oxygen atom,
• R 3 represents a hydrocarbon group with at least one carbon atom
• R 4 is a methyl substituent or a bridging methylene inside the cyclohexyl and chemically stable, the combination of formula (b) and formula (c') being excluded, said polyorganosiloxane corresponds to formula (c).
• the invention relates to a fluid composition crosslinkable under ultraviolet radiation, characterized in that it comprises a matrix with cationic crosslinking, as well as an epoxy-silicone copolymer, that is to say a polyorganosiloxane provided with branches comprising epoxy functions.
• compositions are the following: said polyorganosiloxane corresponds to one of the following formulas: o formula b), formulas in which:
• R represent hydrocarbon groups that are identical or different from each other
• R 1 represent hydrogen atoms or hydrocarbon groups that are identical or different from each other
• R 2 represents a hydrocarbon group with at least one carbon atom, a group which can also contain an oxygen atom,
• R 3 represents a hydrocarbon group with at least one carbon atom
• X is a one-carbon atom and its index o is greater than or equal to 0, said polyorganosiloxane corresponds to one of the following formulas: rmule c'), formulas in which:
• R 4 is a methyl substituent or a bridging methylene inside the cyclohexyl and chemically stable, the combination of formula (b) and formula (c') being excluded, the cationically crosslinked matrix comprises a di-epoxide cycloaliphatic, preferably at least 50% by weight, said polyorganosiloxane is present in an amount of at least 5% by weight, preferably between 5 and 15% and even more preferably between 8 and 12%, the composition also comprises a PFPE-tetra urethane acrylate mixed with acetate of ethyl and butyl acetate, said PFPE-tetra urethane acrylate is present in an amount of at least 0.5% by weight, preferably between 0.5 and 5%, and even more preferably between 2 and 4%.
• the present invention relates to a banknote, at least one of its opposite faces of which carries an anti-writing surface coating formed of a composition according to at least one of the aspects explained above, and which has underwent crosslinking under ultraviolet radiation.
• a preferred, but non-limiting, aspect of such a banknote is the following: said anti-write surface coating has an anti-write note
• Spectrocolori meter marketed by the company DATACOLOR model DC45IR; Glossmeter (or Glossmeter) marketed by the company BYK model 4450 Micro TRI gloss;
• PentelPEN black indelible marker N 50 from PENTEL CO. LTD. (hereinafter MIN);
• SBB SOFTfeel MED blue ballpoint pen from BIC
• SMR Liquid Ink red microball pen
• MEV BIC
• tester pencils as well as the associated references/brands are not completely specified in the ASTM D6578 standard. In fact, it is indicated: indelible marker / erasable marker / microballpoint pen / spray paint / grease pencil for coloring.
• Gasoline mixture of C6-C7 alkanes whose proportion of n-hexane is less than 5%
• IPA Isopropyl Alcohol or Isopropyl Alcohol
• a surface of at least 1cm x 0.5cm is colored with each of the writing methods listed above.
• the lines must dry for at least 24 hours before carrying out the erasing test (do not exceed 48 hours of drying time).
• the spectrocolori meter is used to measure the following two characteristics for each mark made (i.e. a total of 30 measurement zones - 5 eraser pencil marks multiplied by 6 different cleaning agents (5 liquid + 1 dry):
• the AE colorimetric difference
• the ABrillance shine ratio measured at 60°: between the area of the sample chosen before making the mark and the residual mark after cleaning. Three measurements are taken at different points of the residual mark and the average is calculated. The ratio must be > 0.9 to consider that the varnish film has not been altered. iv. Rating scale
• the score is awarded on the quality of the “fresh” route, in particular on its continuity, its water repellency and its intensity, according to the following scenarios:
• Anti-Writing Rating (Modified ASTM D6578 Mark Erasure Test Score) + 2 x (Writing Difficulty Assessment Test Score).
• the dirt resistance was tested according to the Fritsch test well known in the world of banknote printing. This test uses a vibrating device where small glass beads spread and encrust on a paper test tube a dirty composition based on sand, peat, activated carbon, flour, and glycerin mono-oleate (fat present in particular in the sebum).
• the test lasts 15 minutes.
• the luminance of an initially white area is measured several times before and after exposure to the dirty composition.
• the gap obtained, or AL makes it possible to characterize the adhesion of the dirt to the banknote: the smaller it is, the better the resistance to dry dirt.
• Hydrophobicity is described as the resistance to the penetration of water but also its ability to repel the latter on the surface called water repellency.
• the resistance to water penetration is therefore measured using the Cobb test at 60 s. This is the quantity of water absorbed by the support in g/m 2 thanks to a cylindrical impregnation template during a period of 60 seconds. He This is a test that is also common in the paper industry to characterize the absorption of paper.
• Oleophobia or resistance to fats is measured using exposure tests to fatty substances.
• the “Kit Test” method uses a mixture of castor oil (fatty substance) and high-boiling point solvents, namely toluene (aromatic solvent) and n-heptane (aliphatic solvent).
• composition whose viscosity and surface tension vary inversely with its aggressiveness, that is to say its impregnation capacity.
• a composition rich in castor oil is at the bottom of the scale, while a composition rich in heavy solvents is at the top of the same scale.
• compositions There are 12 compositions. A score of 0 corresponds to no oleophobia and a score of 12 to maximum oleophobia.
• the samples are varnished in flexography with a 6 cm 3 /m 2 anilox (front/back) and dried under 1ST UV lamps with mercury spectrum 200 W/cm at 65% of their power.
• the present applicant already had a high-performance varnishing solution dedicated to banknotes, in an attempt to resolve the technical problem posed.
• the varnish in question known under the brand ULTRA, was therefore tested and compared with a reference known in the fiduciary market and widely used on banknotes, namely the SICPAPROTECT varnish (registered trademark) reference 889368 marketed by the company SICPA.
• the ULTRA varnish does not show the expected anti-writing properties.
• the ULTRA varnish has an anti-writing property superior to that of the reference varnish, but this improvement is very limited and therefore needs to be reinforced.
• the present applicant has therefore undertaken work to understand and test new formulations capable of presenting the desired anti-writing property and of providing a solution to the problem posed.
• Cationic polymerization varnishes offer generally effective protective coatings on banknotes (such as the reference varnish already mentioned above).
• barrier properties of cationic varnishes can be increased by choosing reaction additives in appropriate dosages.
• perfluoropolyether type compounds are very useful for significantly improving the barrier properties as mentioned previously but are not very effective in terms of anti-writing.
• silicon-based additives such as siloxanes, certain members of which have non-stick properties. These additives were not chosen at random. Indeed, in addition to their chemical properties, they present economic and ecological advantages and also in terms of safety of use, namely: they are classified as non-hazardous, their flash point is high, notably above 94° C, their transport by road does not require the Agreement for the Transport of Dangerous Goods by Road (or ADR), they do not produce Volatile Organic Compounds (or VOCs), and their cost is generally lower than that of compounds of the type perfluoropolyether. In order to carry out comparative tests on different silicon-based additives, a pre-test with a discriminative aim was carried out on a sampling of siloxane-based additives.
• TDS Technical Data Sheets
• SDS Safety Data Sheets
• the screening pre-test carried out here and presented below in Table 6 is based, in this upstream step, on the sole difficulty of writing and with only two pencils, namely the red microball pen and the pink fluorescent highlighter because the Results with these pencils are discriminating between the different varnishes tested.
• the reference varnish is the SICPAPROTECT 889368 cationic polymerization varnish.
• the ULTRA varnish is the second reference and incorporates a reactive perfluoropolyether urethane compound with acrylate endings, namely Fluorolink AD1700 (registered trademark, hereinafter AD1700) marketed by the company SOLVAY. Table 6
• the reference varnish has a predominantly cationic polymerization, it also includes compounds capable of reacting in radical mode for optimal three-dimensional crosslinking in particular. This is the reaction mode which is implemented with the perfluoropolyether-urethane acrylate additive which gives excellent barrier properties, but not the expected anti-writing property, or at least not in a truly significant dimension.
• Cationic initiation is obtained by means of a cationic photoinitiator with for example salts of triarylsulfonium hexafluorophosphate (for example reference Speedcure 992 from the company Lambson) or diphenyl (4-phenylthio) phenylsulfonium hexafluoroantimonate (for example reference DC 1176 from the company Comexim) which are irradiated under ultraviolet radiation.
• a cationic photoinitiator with for example salts of triarylsulfonium hexafluorophosphate (for example reference Speedcure 992 from the company Lambson) or diphenyl (4-phenylthio) phenylsulfonium hexafluoroantimonate (for example reference DC 1176 from the company Comexim) which are irradiated under ultraviolet radiation.
• the majority basic reactive compound is a cycloaliphatic di-epoxide with CAS number 2386-87-0 and full name 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate.
• This compound is available in particular from Cytec (under the brand UVACURE 1500), or from Comexim (under the name DOUBLEMER 420 P).
• the present applicant sought a “twin” compound in terms of chemical functionality, that is to say possessing reactive epoxy functions and always with a siloxane structure.
• polyorganosiloxane compounds functionalized with epoxides were tested.
• these compounds are used to form hydrophobic and non-stick film-forming coatings, for example on paper or synthetic plastic supports to promote the removal of adhesive materials attached to these supports, in particular in a reversible manner, such as labels, ribbons. adhesives, etc.
• Varnishes with 10% X-62-7660 and 10% X-62-7622 also give very interesting results: if the oil resistance result is 2 points lower than that of ULTRA, particularly for X-62-7660, water resistance is excellent and superior to ULTRA varnish without the use of perfluoropolyethers additives.
• the problem posed in the preamble was therefore solved thanks to the addition of an epoxidized polyorganosiloxane additive incorporated into a varnish cured by ultraviolet radiation, polymerizing mainly by the cationic route.
• the anti-writing property based both on the ease of erasing the lines produced as well as on the difficulty of making fresh inscriptions on the banknotes is satisfactory with relatively low percentages of additives, while retaining generally interesting barrier properties, with substantial environmental gains such as those mentioned above and finally, by containing the inflation of the cost of the formulation.

Landscapes

• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Organic Chemistry (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Health & Medical Sciences (AREA)
• Engineering & Computer Science (AREA)
• Wood Science & Technology (AREA)
• Life Sciences & Earth Sciences (AREA)
• Materials Engineering (AREA)
• General Chemical & Material Sciences (AREA)
• Business, Economics & Management (AREA)
• Accounting & Taxation (AREA)
• Finance (AREA)
• Physics & Mathematics (AREA)
• Electromagnetism (AREA)
• Mechanical Engineering (AREA)
• Plasma & Fusion (AREA)
• Paints Or Removers (AREA)
• Epoxy Resins (AREA)
• Compositions Of Macromolecular Compounds (AREA)

Applications Claiming Priority (2)

Publications (1)

Family

ID=82781340

Family Applications (1)

Country Status (6)

Citations (2)

Family Cites Families (4)

• 2022
  • 2022-06-17 FR FR2205969A patent/FR3136777B1/fr active Active
• 2023
  • 2023-06-13 KR KR1020257001838A patent/KR20250029139A/ko active Pending
  • 2023-06-13 EP EP23732547.7A patent/EP4540066A1/de active Pending
  • 2023-06-13 JP JP2024573791A patent/JP2025520510A/ja active Pending
  • 2023-06-13 WO PCT/EP2023/065855 patent/WO2023242220A1/fr not_active Ceased
• 2024
  • 2024-12-09 MX MX2024015244A patent/MX2024015244A/es unknown

Patent Citations (2)

Non-Patent Citations (7)

Also Published As

Similar Documents

Legal Events