EP4608997A1 - Bouchon de purge de gaz réfractaire et procédé de production d'un bouchon de purge de gaz réfractaire - Google Patents

Bouchon de purge de gaz réfractaire et procédé de production d'un bouchon de purge de gaz réfractaire

Info

Publication number
EP4608997A1
EP4608997A1 EP23798386.1A EP23798386A EP4608997A1 EP 4608997 A1 EP4608997 A1 EP 4608997A1 EP 23798386 A EP23798386 A EP 23798386A EP 4608997 A1 EP4608997 A1 EP 4608997A1
Authority
EP
European Patent Office
Prior art keywords
gas
refractory
purging plug
distribution chamber
channels
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP23798386.1A
Other languages
German (de)
English (en)
Inventor
Wolfgang Kirst
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Refractory Intellectual Property GmbH and Co KG
Original Assignee
Refractory Intellectual Property GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Refractory Intellectual Property GmbH and Co KG filed Critical Refractory Intellectual Property GmbH and Co KG
Publication of EP4608997A1 publication Critical patent/EP4608997A1/fr
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
    • B22D1/002—Treatment with gases
    • B22D1/005—Injection assemblies therefor
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28—Manufacture of steel in the converter
    • C21C5/30—Regulating or controlling the blowing
    • C21C5/35—Blowing from above and through the bath
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28—Manufacture of steel in the converter
    • C21C5/42—Constructional features of converters
    • C21C5/46—Details or accessories
    • C21C5/48—Bottoms or tuyéres of converters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00—Charging; Discharging; Manipulation of charge
    • F27D3/16—Introducing a fluid jet or current into the charge
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00—Charging; Discharging; Manipulation of charge
    • F27D3/16—Introducing a fluid jet or current into the charge
    • F27D2003/161—Introducing a fluid jet or current into the charge through a porous element

Definitions

  • Refractory gas purging plug and a method for the production of a refractory gas purging plug
  • the invention relates to a refractory gas purging plug and to a method for the production of a refractory gas purging plug.
  • Gas purging plugs are used for metallurgical treatment of molten metals. They are arranged in the bottom region of a metallurgical vessel, for example in a ladle for secondary metallurgical treatment of molten steel.
  • Refractory gas purging plugs comprise a body of refractory ceramic material through which gas can be passed. The body extends from a first end of the body to an opposite second end of the body. Gas may be introduced into the body at the first end. The gas introduced into the body flows through the body and exits the body at the opposite, second end of the body.
  • the gas purging plug is arranged in the bottom region of the metallurgical vessel, the first end is regularly arranged at the bottom and the second end at the top. The second end is in direct contact with a molten metal in the metallurgical vessel.
  • Gas can therefore be introduced into the molten metal through the gas purging plug, whereby a flow circulating the molten metal is created in the molten metal. This flow can remove harmful gases from the molten metal, transport oxide inclusions into the slag, and homogenize the composition and temperature in the molten metal.
  • the body comprises a porous, permeable refractory ceramic material through which gas can be passed. Since this natural gas permeability results from the random, chaotic arrangement of the pore structure in the refractory ceramic material, it is also referred to as "undirected" porosity.
  • a refractory ceramic gas purging plug having both such undirected porosity and such directed porosity, namely in the form of slit-shaped gas channels, is disclosed, for example, in EP 1 101 825 A1.
  • a high flow rate of gas through the gas purging plug is desired for homogenization of the molten metal, which can best be achieved through the gas channels. Harmful gases as well as oxidic inclusions in the molten metal, on the other hand, are best removed by many small gas bubbles, and such gas bubbles are best achieved at low flow rates of gas passing through the porous, permeable refractory ceramic material. In this respect, it is generally desirable that at low flow rates gas preferentially passes through the porous, permeable refractory ceramic material and at higher flow rates gas preferentially passes through the gas channels.
  • a conduction of gas through the gas channels at higher flow rates may be desired in particular also because the porous, permeable refractory ceramic material could be damaged by higher flow rates, in particular also a high mass flow rate of the gas.
  • prior art gas purging plugs regularly have a gas distribution chamber or a porous insert to which the gas is first conducted. From the gas distribution chamber or the porous insert, the gas supplied to the gas purging plug subsequently flows into the porous, permeable refractory ceramic material or into the gas channels.
  • a refractory gas purging plug comprising the following features: a body of refractory ceramic material; the body extends from a first end of the body, where gas can be introduced into the body, to a second end of the body, where gas can be discharged from the body, opposite the first end of the body; the body comprises a first part made of porous, permeable refractory ceramic material which extends from the first end of the body to the second end of the body, the first part providing a surface; the body comprises a second part made of refractory ceramic material which extends from the first end of the body to the second end of the body, the second part comprising gas channels extending through the second part; wherein the gas channels form at least one net; and wherein the at least one net at least partially extends directly on the surface of the first part.
  • the invention is based on the finding that with the gas purging plug according to invention, it is possible that at low flow rates gas preferentially passes through the porous, permeable refractory ceramic material and at higher flow rates gas preferentially passes through the gas channels.
  • the invention is based on the further finding that a net formed by the gas channels makes it possible to achieve a particularly advantageous homogenization of the molten metal.
  • the invention is based on the further finding that with the gas purging plug according to invention, it is possible that in particular at high mass flows of the gas channels are freed again from infiltrated molten metal.
  • the invention is based on the further finding that with the gas purging plug according to invention, it is possible that metal infiltrations can be removed very carefully, without damaging the sensitive porous, permeable refractory ceramic material.
  • gas flowing through the porous, permeable refractory ceramic material passes to some extent into the gas channels, blowing out metal infiltrations from the gas channels and then flowing through the gas channels.
  • the sensitive porous, permeable refractory ceramic material is not damaged.
  • a gas purging plug can be provided very easily in terms of manufacturing technology if the gas channels form at least one such net. This is because for this purpose, as explained in detail further below, a net-shaped combustible material can first be arranged very simply on the first part, for example by simply slipping the combustible net over the first part, which is then surrounded with refractory material.
  • the gas channels form a "net” in the sense of the invention, insofar as the gas channels have a net-like structure or run net-like.
  • the gas channels form at least one net consisting of groups of gas channels each running parallel to each other and crossing each other. This results in a symmetrical structure of the network which again leads to uniform injection of the gas in the steel melt, thereby reducing inconsistent wear of the plug.
  • the gas channels form at least one symmetrical net.
  • such a symmetrical net formed by the gas channels makes it possible to achieve a particularly advantageous homogenization of the molten metal. Furthermore, it was found that through such a symmetrical net gas can diffuse particularly uniformly into the first part, so that the first part can be freed particularly carefully from any metal infiltrations.
  • the gas channels extend linearly, i.e. , along a straight line. This allows a particularly uniform, in particular laminar, flow to be generated within the gas channels, whereby gas can be injected particularly uniformly both into the molten metal and diffuse into the first part which again can prevent inconsistent wear of the plug.
  • the net comprises meshes surrounded by the gas channels, and wherein the meshes have a mesh size in the range of 1 to 10 mm, more preferably in the range of 2 to 8 mm and even more preferably in the range of 3 to 5 mm.
  • a “mesh” within the sense of the present invention represents an area surrounded by gas channels.
  • the gas channels at least mainly have a constant cross-sectional area.
  • the cross- sectional area in this sense is the cross-section of the gas channels perpendicular to their longitudinal extension.
  • a constant cross-sectional area prevents wear compared to areas having non constant cross-sections.
  • the gas channels have a constant cross-sectional area beyond the nodes of the net of the gas channels.
  • the “nodes” of the net of gas channels are the points of the net where the gas channels cross.
  • the gas channels have a circular cross-sectional area. This is particularly preferable when a plurality of adjacent nets of gas channels are provided as the contact surface of said nets of gas channels is minimized and gas infiltration between said nets of gas channels is limited.
  • the gas channels have a diameter in the range of 0.1 to 2.0 mm, more preferably in the range of 0.1 to 1.0 mm and even more preferably in the range of 0.2 to 0.9 mm.
  • the diameter in this sense is the diameter of the gas channels perpendicular to their longitudinal extension. In case the gas channels do not have a circular cross-sectional area, the diameter is the maximum distance between the channel walls perpendicular to the longitudinal extension of the gas channels.
  • gas can be injected into the molten metal through the gas channels in a particularly advantageous manner, in particular also at a high mass flow of the gas, whereby good homogenization of the molten metal can be achieved, but at the same time infiltration of molten metal into the gas channels can be completely or largely prevented.
  • the refractory ceramic material of the second part has a lower permeability than the refractory ceramic material of the first part.
  • the refractory ceramic material of the second part is impermeable to gas, in particular to gas at the gas pressures prevailing in a refractory gas purging plug. According to one embodiment, it may be provided that the refractory ceramic material of the second part has a permeability of ⁇ 2 nPerm, preferably ⁇ 0.05 nPerm.
  • gas can be passed through the first part such that the gas flowing through the first part into the molten metal generates many small gas bubbles in the molten metal, through which harmful gases and oxidic inclusions can be removed from the molten metal advantageously. Furthermore, it was found that with such a permeability of the first part, gas can diffuse particularly well from the gas channels into the first part and free it from metal infiltrations, as previously explained.
  • the second part surrounds the first part.
  • the second part can be particularly advantageously freed from metal infiltration by the gas channels of the first part when the second part surrounds the first part.
  • the first part may have any shape.
  • the first part may have a circular cross-section, a polygonal-cross section or a combination of such cross-sections.
  • the polygonal cross-section may be, for example, a rectangular cross-section.
  • the first part may comprise at least one section having a circular cross-section and at least one section having a polygonal cross-section.
  • the first part may have, for example, have a cuboid, prismatic or wedge shape, with the longitudinal axis of these shapes extending from the first end of the body to the second end of the body.
  • the area of the cross-section tapers in the direction from the first end of the body to the second end of the body.
  • the first part is one-piece, in particular, comprised of one piece having uniform properties.
  • the first part comprises a first segment and a second segment, wherein these segments have different properties.
  • the first segment and the second segment differ in at least one of the following characteristics: shape or porosity.
  • the first part comprises a first segment disposed immediately adjacent the first end of the body of refractory ceramic material and a second segment disposed immediately adjacent the second end of the body of refractory ceramic material.
  • the first segment forms a part of the first end of the body and the second segment forms a part of the second end of the body.
  • the first segment may have the function of a wear indicator as known in the prior art. As is known, after removal of the molten metal from the melting vessel, the first segment may be visually recognizable and thereby indicates progressed wear of the gas purging plug.
  • the first segment and the second segment differ in porosity, it is preferably provided that the first segment comprises a porous permeable refractory ceramic material having a first permeability and the second segment comprises a porous permeable refractory ceramic material having a second permeability, wherein the first permeability and the second permeability are different.
  • the first permeability is greater than the second permeability.
  • the first permeability is in the range of 50 to 400 nPerm, preferably 60 to 250 nPerm and the second permeability is in the range of 50 to 400 nPerm, preferably 60 to 250 nPerm.
  • the first and second permeability are identical.
  • the advantage of such an embodiment also lies in particular in the fact that larger quantities of gas can be passed through the first segment than through the second segment. As a result, gas can be conducted from the first segment to the second segment as well as to gas channels directly adjacent thereto, as described further below. By the second segment simultaneously conducting a smaller amount of gas, the self-regulating effect described above results, whereby at low gas flow rates, gas flows through the porous permeable refractory material and at higher flow rates, gas flows through the gas channels.
  • the first segment has a surface that runs at a distance from the first end of the body.
  • this surface of the first segment runs "inside" the body.
  • this surface runs parallel to the first end of the body.
  • the first segment has a first contact surface and the second segment has a second contact surface, the first contact surface and the second contact surface abutting against each other.
  • the first segment and the segment section are directly adjacent to each other.
  • this also has the advantage that gas flowing through the first segment can flow directly from the first segment into the second segment .
  • the first contact surface and the second contact surface extend at a distance from the first end and the second end of the body, that is, "inside" the body.
  • the first and second contact surfaces run parallel to the first end of the body.
  • the gas channels which form at least one net which at least partially extends directly on the surface of the first part, extend through the second part.
  • the gas channels may extend through the second part for any distance between the first end of the body and the second end of the body.
  • the gas channels extend to the second end of the body. This has the advantage that gas can be released from the body into the molten metal via the gas channels at the second end of the body.
  • the gas channels extend to the first end of the body. This allows gas to be introduced into the body via the gas channels at the first end of the body.
  • the gas channels simultaneously extend to the second end of the body as set forth above.
  • the gas channels extend from the first end of the body to the second end of the body. This allows gas to pass through the body from the first end of the body to the second end of the body via the gas channels.
  • the gas channels are provided to extend through the second part at a distance from the first end of the body.
  • the gas channels do not extend to the first end but rather end spaced from the first end of the body.
  • the gas channels are provided to extend through the second part at a distance from the first end of the body the gas channels end spaced from the fist end of the body in region of the first part between the first end and the second end of the body.
  • the first part comprises a first segment and a second segment, as set forth herein, and wherein the gas channels are provided to extend through the second part at a distance from the first end of the body
  • gas is preferably supplied to the gas channels via the first part made of porous, permeable refractory ceramic material by introducing gas into the first part and, as explained above, via gas exchange between the first part and the gas channels, gas is conducted from the first part into the gas channels.
  • the first segment as set forth above, has a first contact surface at which the first segment abuts against the second segment, according to a further embodiment, it is provided that the gas channels extend from this contact surface through the second part in the direction towards the second end.
  • the gas channels are thus arranged with a distance towards the first end corresponding to the distance of the first contact surface towards the first end.
  • the gas channels are in contact with the first contact surface. This allows gas flowing through the first segment to flow directly from the first segment into the gas channels.
  • the second part and, hence, the gas channels can be particularly advantageously freed from infiltrated metal, in particular when the second part surrounds the first part.
  • the first part may be made of any porous, permeable refractory ceramic material.
  • the first part may be made of any porous, permeable refractory ceramic material known as porous, permeable refractory ceramic material for gas purge plugs.
  • the first part is made of a sintered porous permeable refractory ceramic material.
  • the first part may be made based on at least one of the following refractory ceramic materials, in particular materials sintered together: magnesia, alumina, spinel, mullite and fireclay.
  • the second part can be made of any refractory material, in particular a refractory ceramic material with a low permeability.
  • refractory materials known from the prior art can be used.
  • the refractory ceramic material of the second part is in the form of a refractory cement or a ceramic mass, i.e. , an unshaped refractory ceramic product.
  • the second part may be made based on at least one of the following refractory ceramic materials: magnesia, alumina, spinel, mullite and fireclay.
  • the gas channels can be created by first embedding a combustible material in refractory ceramic material, then heating this refractory ceramic material so that the combustible material burns out and subsequently forms the gas channels.
  • combustible material has the shape of one or more nets which, preferably, are arranged on the surface of the first part. For example, the at least one net from combustible material can be pulled over the surface of the first part.
  • the combustible material may be organic, preferably weavable, material, e.g., cotton, cellulose or plastic, for example one of the following plastics: soft polyethylene, soft polypropylene or polyethersulfone.
  • the gas channels take the place of a burned-out material.
  • the gas purging plug may comprise a metal shell or sleeve surrounding the body of refractory ceramic material.
  • the gas purging plug may preferably comprise one or more gas distribution chambers via which gas may be introduced into the first part and the second part.
  • the gas distribution chambers are arranged at the first end of the body of refractory ceramic material, as known from the prior art, so that gas from the gas distribution chambers can be introduced directly into the first part and into the gas channels of the second part.
  • the gas purging plug only comprises one gas distribution chamber via which gas is introduced into the first part only.
  • two or more gas distribution chambers may be provided, as set forth below.
  • the gas purging plug comprises a first gas distribution chamber disposed at the first end of the body; a second gas distribution chamber disposed at the first end of the body; wherein gas can be introduced into the first part via the first gas distribution chamber; and wherein gas can be introduced into the second part via the second gas distribution chamber.
  • the gas purging plug comprises such as a first and second gas distribution chamber disposed at the first end of the body.
  • the gas purging plug comprises such as a first and second gas distribution chamber disposed at the first end of the body.
  • first and second gas distribution chambers it is possible, in particular, to achieve a conduction of gas through the gas purging plug which is adapted to the flow behavior of the gas.
  • the provision of this first and second gas distribution chamber allows a targeted conduction of gas to the porous, permeable refractory ceramic material or to the gas channels according to the flow behavior of the gas.
  • first and second gas distribution chamber are in particular that gas can be selectively introduced into the first part via the first gas distribution chamber and thus into the porous, permeable refractory ceramic material and into the second part via the second gas distribution chamber and thus into the gas channels.
  • these two gas distribution chambers allow gas to be directed preferentially to the first gas distribution chamber and, hence, through the porous, permeable refractory ceramic material at low flow rates, on the one hand, and gas to be conducted preferentially through the second gas distribution chamber and, hence, through the gas channels at higher flow rates, on the other hand.
  • gas to be directed preferentially to the first gas distribution chamber and, hence, through the porous, permeable refractory ceramic material at low flow rates, on the one hand, and gas to be conducted preferentially through the second gas distribution chamber and, hence, through the gas channels at higher flow rates, on the other hand.
  • first gas distribution chamber and the second gas distribution chamber are separated from each other, for example by a wall.
  • first gas distribution chamber and the second gas distribution chamber are fluidically separated from each other. This has the particular advantage that the gas in the first gas distribution chamber and the gas in the second gas distribution chamber do not mix with each other, so that gas can be directed specifically into the first part via the first gas distribution chamber and into the second part via the second gas distribution chamber.
  • gas cannot be introduced into the second part via the first gas distribution chamber.
  • gas cannot be introduced into the first part via the second gas distribution chamber.
  • gas distribution chamber in the sense of the invention is, as known from the prior art, a space enclosed or defined, respectively, by walls.
  • the gas distribution chamber need not be completely enclosed by walls. Rather, the walls enclosing the gas distribution chamber may, for example, have openings, for example to direct gas into the gas distribution chamber.
  • the space defined by the first gas distribution chamber is partially defined by the first part.
  • the first part constitutes a portion of the wall defining the space enclosed by the first gas distribution chamber. Since the first gas distribution chamber is arranged at the first end of the body of refractory ceramic material of the gas purging plug according to the invention, this feature is particularly easy to achieve.
  • a particular advantage of this feature is that gas can be conducted to the first part particularly easily through the first gas distribution chamber when the first part constitutes a portion of the wall of the first gas distribution chamber.
  • the space defined by the second gas distribution chamber is partially defined by the second part.
  • the second part constitutes a portion of the wall defining the space enclosed by the second gas distribution chamber. Since the second gas distribution chamber is arranged at the first end of the body of refractory ceramic material of the gas purging plug according to the invention, this feature is particularly easy to achieve.
  • a particular advantage of this feature is, in particular, that gas can be conducted to the second part or to the gas channels formed in the second part particularly easily through the second gas distribution chamber if the second part constitutes a portion of the wall of the second gas distribution chamber.
  • the further parts of the wall of the first and second gas distribution chambers that are not defined by the first part and the second part may be formed of metal, such as known from the prior art. It may be provided that parts of the wall of the first and second gas distribution chambers can be part of the gas supply means via which gas can be conducted to the first part and the second part.
  • the first gas distribution chamber has at least one first gas supply opening via which gas can be introduced into the first gas distribution chamber.
  • the second gas distribution chamber has at least one second gas supply opening via which gas can be introduced into the second gas distribution chamber.
  • the gas purging plug further comprises gas supply means by which gas can be conducted to the first part and to the second part; wherein the gas supply means comprise control means by which the conduction of the gas to the first part and to the second part by the gas supply means is controllable.
  • gas can be conducted to the first part by the gas supply means via the first gas distribution chamber and wherein gas can be conducted to the second part by the gas supply means via the second gas distribution chamber.
  • gas can be introduced into the first gas distribution chamber through the gas supply means via the first opening.
  • gas can preferably be introduced into the second gas distribution chamber through the gas supply means via the second gas supply opening.
  • gas can be conducted better through a refractory gas purging plug if the gas purging plug comprises gas supply means through which gas can be conducted to the porous, permeable refractory ceramic material and to the gas channels, and if these gas supply means comprise control means by which the conduction of gas via the gas supply means can be controlled.
  • control means it is also possible, in particular, to achieve a conduction of gas through the gas purging plug which is adapted to the flow behavior of the gas.
  • these control means allow a targeted conduction of gas to the porous, permeable refractory ceramic material or to the gas channels according to the flow behavior of the gas.
  • control means allow gas to be directed preferentially through the porous, permeable refractory ceramic material at low flow rates, depending on the flow behavior of the gas, on the one hand, and gas to be conducted preferentially through the gas channels at higher flow rates, on the other hand. In this way, depending on the flow behavior of the gas, an optimum conduction of gas through the gas purge plug is possible in each case.
  • the controllability of the conduction of gas to the first part (i.e. , to the porous, permeable refractory ceramic material) or to the second part (i.e., to the gas channels) also has the particular advantage that the quantity of gas which is conducted to the first part or to the second part can be defined or adjusted.
  • this has the advantage that the amount of gas that can be directed to the first part or to the second part is controllably adjustable for a desired purging result of the gas purging plug.
  • the control means may be, for example, a valve by which the conduction of gas to the first part and/or to the second part is controllable.
  • the control means may be designed in the manner of a directional control valve.
  • the conduction of the gas to the first part and to the second part by the gas supply means is controllable by the control means dependent on the flow behavior of the gas.
  • the advantage of such controllability of the conduction of gas depending on the flow behavior of the gas is in particular that no additional or external control of the gas conduction is necessary. Rather, the conduction of gas line can be self-regulating depending on the flow behavior of the gas.
  • the particular advantage of this is that the proportion of gas that is conducted to the first part or to the second part in each case can be made dependent on the flow behavior of the gas.
  • the flow behavior of the gas itself can control which proportion of gas flows to the first part or to the second part.
  • the flow behavior of the gas in this sense can preferably be the flow behavior of the gas in the gas supply means, in particular in the area of the control means.
  • Such a controllability of the conduction of gas by means of the flow behavior can, for example, again be achieved very simply and effectively by means of a control means designed in the manner of a directional control valve, wherein the directional control valve can be actuated by the gas, i.e. , pneumatically, by the valve having an actuator (in particular a piston or a spool) which can be moved into different switching positions of the valve depending on the flow behavior of the gas.
  • the directional control valve can be actuated by the gas, i.e. , pneumatically, by the valve having an actuator (in particular a piston or a spool) which can be moved into different switching positions of the valve depending on the flow behavior of the gas.
  • this flow behavior of the gas is the mass flow of the gas.
  • the conduction of the gas to the first part and to the second part through the gas supply means is thus controllable by the control means depending on the mass flow of the gas.
  • mass flow is defined is the mass of a medium moving through a cross-section per period of time.
  • the mass flow of the gas in the present case is therefore the mass of the gas that moves through a cross-section per period of time.
  • the cross-section can preferably be a defined cross-section of the gas supply means, in particular in the area of the control means. According to the invention, it has been found that the conduction of gas to the first part and to the second part can be controlled particularly easily and effectively as a function of the mass flow of the gas.
  • the conduction of gas is controllable such that gas can be conducted via the gas supply means either to the first part or to the second part.
  • the first part i.e. , the porous, permeable refractory ceramic material
  • the second part i.e., the gas ducts
  • the conduction of the gas to the first part and to the second part by the gas supply means is controllable by the control means such that the gas can be conducted either to the first part but not to the second part or to the second part but not to the first part.
  • the conduction of gas to the first part and to the second part via the gas supply means is controllable by means of the control means in dependence on at least one range or value range, respectively, of the mass flow rate of the gas.
  • this controllability may depend on whether or not the mass flow rate of the gas is within or outside such a range or value range of the mass flow rate of the gas. This value for the mass flow rate of the gas is preferably defined.
  • the conduction of the gas to the first part and to the second part by the gas supply means is controllable by the control means dependent on the mass flow rate of the gas in such a way that, in case the mass flow rate lies within a first range, the gas can be conducted to the first part, and in case the mass flow rate lies within a second range, the gas can be conducted to the second part.
  • the first range is lower than the second range.
  • the conduction of the gas to the first part and to the second part by the gas supply means is controllable by the control means dependent on the mass flow rate of the gas in such a way that, in case the mass flow rate lies within a first range, the gas can be conducted to the first part but not to the second part, and in case the mass flow rate lies within a second range, the gas can be conducted to the second part but not to the first part, wherein the first range preferably is lower than the second range.
  • the gas is conducted to the porous permeable refractory ceramics material, while at higher mass flow rates of the gas, the gas is conducted to the gas channels.
  • the gas purging plug according to the present invention a particularly advantageous conduction of gas through the gas purging plug can be achieved.
  • the conduction of the gas to the first part and to the second part by the gas supply means is further controllable by the control means dependent on the mass flow rate of the gas in such a way that, in case the mass flow rate lies within a third range, the gas can be conducted to the first part and to the second part, wherein the third range is higher than the first range and lower than the second range.
  • the control means comprise an actuator, in particular a piston or spool.
  • the actuator may assume different positions.
  • the actuator can assume the different positions depending on the flow behavior of the gas.
  • the conduction of gas to the first part and to the second part is controllable in dependence on the positions of the actuator.
  • the actuator can be designed in the manner of a control piston or a spool in a directional control valve, wherein the positions of the actuator release or plug a gas path.
  • the actuator can assume at least a first position and a second position. It may further be provided that the actuator may assume a first position when the mass flow of the gas is in the aforementioned first range, and may assume the second position when the mass flow of the gas is in the aforementioned second range. According to a further embodiment, it may further be provided that the gas cannot be directed to the second part in the first position and cannot be directed to the first part in the second position.
  • the actuator assumes a third position when the mass flow rate of the gas lies within the third range, and wherein in the third position, the gas can be conducted to the first part and to the second part.
  • the actuator assumes this third position when the mass flow rate of the gas lies between the first range (i.e. , a lower mass flow rate of the gas) and the second range (i.e. , a higher mass flow rate of the gas), and in this position, the actuator can control the conduction of gas to the first part and to the second part such that gas can be conducted to both the first part and the second part.
  • the gas supply means can be any device through which gas can be conducted to the first part and to the second part.
  • the gas supply means are arranged in the region of the first end of the body of refractory ceramic material of the gas purging plug.
  • the gas supply means as also known from the prior art, are designed in the form of a nozzle or cap, respectively, which is arranged at the first end of the body of refractory ceramic material, i.e., at the gas inlet side of the gas purging plug.
  • the gas supply means are formed of metal.
  • the control means are arranged in the gas supply means, i.e., for example, in the gas supply means formed as a nozzle or as a cap.
  • the gas purging plug comprises a gas connection to which a gas line may be connected.
  • the gas line may be connected to a gas source. Gas can accordingly be conducted from the gas source via the gas line into the gas supply means, and the gas subsequently being conducted via the gas supply means to the first part and to the second part of the body of refractory ceramic material of the gas purging plug.
  • the gas supply means preferably comprise said a gas connection to which said gas line may be connected. Gas can accordingly be conducted from the gas source via the gas line into the gas supply means, and the gas subsequently being conducted via the gas supply means to the first part and to the second part of the body of refractory ceramic material of the gas purging plug.
  • the body of refractory ceramic material may be produced by a method, comprising the following steps:
  • the element extends from a first end of the element to a second end of the element opposite the first end of the element; the element comprises a first section made of a first refractory material which extends from the first end of the element to the second end of the element, the first section providing a surface; and the element comprises a second section made of a second refractory material which extends from the first end of the element to the second end of the element, the second section comprising combustible material embedded into the second refractory material and extending through the second section from the first end of the element to the second end of the element; wherein the combustible material forms at least one net; and wherein the at least one net at least partially extends directly on the surface of the first section; and heating the element.
  • the element of refractory ceramic material forms the body of refractory ceramic material of the gas purging plug of the invention.
  • the combustible material can be embedded into the second refractory material by applying combustible material, which forms at least one net, at least partially directly on the surface of the first section and afterwards applying the second section around the combustible material.
  • the combustible material can be pulled over first section such that it runs is at least partially directly on the surface of the first section before applying the second section around the combustible material.
  • the method for the production of a refractory gas purging plug might further comprise the step of applying stripes of combustible material on the surface of the first section from the first end of the element to the second end of the element before providing the second section.
  • the first section of the first refractory material forms the first part of the body made of porous, permeable refractory ceramic material.
  • the first section made of a refractory material preferably is a shaped body.
  • the first part is preferably in the form of a sintered body. Accordingly, the first section may be in the form of a sintered body.
  • the first section is a shaped green body, wherein the heating is preferably performed such that the first refractory material is sintered by the heating to form a porous permeable refractory ceramic material.
  • the first refractory material is preferably based on at least one of the following refractory ceramic materials: magnesia, alumina, spinel, mullite and fireclay.
  • the first section is in the form of a shaped product, in particular a pressed product, in particular in the form of a green body.
  • the second section of the second refractory material forms the second part of the body of refractory ceramic material of the gas purging plug according to the invention.
  • the second refractory material is preferably based on at least one of the following refractory ceramic materials: magnesia, alumina, spinel, mullite and fireclay.
  • magnesia, alumina, spinel, mullite and fireclay In order to form the gas channels in the second section during heating, combustible material embedded in the second refractory material is present. During heating, the combustible material burns out so that the gas channels take the place of the burned-out material after heating.
  • the combustible material in order to embed the combustible material in the second refractory material, is first arranged on the surface of the first section and then embedded in the second material.
  • the second refractory material can, for example, subsequently be placed, in particular poured, onto the combustible material arranged onto the first refractory material.
  • the first section with the combustible material arranged thereon may be arranged in a mold or template, for example.
  • the second refractory material can be present or applied for this purpose in the form of a refractory cement or in a ceramic mass, i.e., an unshaped refractory ceramic material.
  • the first section for this purpose is in the form of a shaped product, as explained above, so that the first section provides a surface on which the combustible material can be arranged particularly easily.
  • the combustible material thereby forms gas channels after heating in the form of at least one net, which at least partially extends directly on the surface of the first part.
  • a particular advantage of the use of at least one such net as combustible material is also that such nets can be arranged particularly easily on the surface of the first part by simply being drawn onto the first part.
  • the combustible material can be any material which burns out by heating, for example paper, cardboard or any synthetic material, in particular plastic.
  • the combustible material is present as plastic, particular preferable in the form of at least one of the following plastic materials: soft polyethylene, soft polypropylene or polyethersulfone.
  • the heating is carried out at such temperatures at which the combustible material burns out or incinerates, respectively.
  • the heating is carried out at temperatures in the range from 200 to 600°C, in particular in the range from 400 to 600°C, thereby preferably curing the second refractory material. Within this range, the aforementioned combustible material can be burned out or incinerated, respectively.
  • the method is carried out such that the second section surrounds the first section.
  • said gas supply means may subsequently be arranged on the obtained body.
  • first and second chambers may be arranged on the obtained body.
  • a shell or sleeve may be arranged on the body such that it surrounds the body of refractory ceramic material, as set forth above.
  • the refractory gas purging plug according to the invention may be used to be arranged in the bottom region of a metallurgical vessel.
  • it may be provided to use the refractory gas purging plug according to the invention in the bottom region of a vessel for receiving a molten metal, in particular molten steel.
  • it is provided to use the gas purging plug according to the invention to be arranged in the bottom region of a steel ladle, in particular in a continuous casting plant for treating molten steel.
  • a further subject of the present invention is to provide a metallurgical vessel with a gas purging plug according to the invention arranged in the bottom region of the metallurgical vessel.
  • the metallurgical vessel may in particular be a metallurgical vessel as described above.
  • the controlling of the conduction of gas to the first part and to the second part by the gas supply means may thereby be carried out as set forth herein.
  • Figure 1 a perspective view from below of an embodiment of a gas purging plug according to the invention
  • Figure 2 a sectional view of the gas purging plug according to Figure 1;
  • Figure 3 a detailed view of gas channels in the gas purging plug according to Figure 1;
  • Figure 4 a detailed view of the sectional view according to Figure 2 in the area of the gas supply means of the gas purging plug in a first switching position of the control means;
  • Figure 6 a detailed view according to Figure 4 in a third switching position of the control means
  • Figure 7 a perspective view from above of parts from which the of the gas purging plug shall be produced during a manufacturing step of the gas purging plug;
  • Figure 8 a portion of the net shown in Figure 7;
  • Figure 9 a sectional view of the gas purging plug of an alternative embodiment of a gas purging plug according to the invention.
  • Figure 10 a sectional view of the gas purging plug of a further alternative embodiment of a gas purging plug according to the invention.
  • Figure 11 a sectional view of the gas purging plug of a further alternative embodiment of a gas purging plug according to the invention.
  • the refractory gas purging plug 1 comprises a body 2 of refractory ceramic material, extending from a first end 3 of the body 2, where gas can be introduced into the body 2, to a second end 4 of the body 2, where gas can be discharged from the body 2, opposite the first end 3 of the body 2.
  • the body 2 has an overall frustoconical outer contour, which tapers along the longitudinal axis 5 of the body 2 from the first end 3 to the second end 4. At its radial outer contour, the body 2 is completely covered by a metal sleeve 6. As Figure 1 clearly shows, the gas purging plug 1 thus has an overall frustoconical outer contour which tapers along the longitudinal axis 5 of the body 2 from the first end 3 to the second end 4.
  • the body 2 comprises a first part 7 made of porous, permeable refractory ceramic material which extends from the first end 3 of the body 2 to the second end 4 of the body 2.
  • the first part 7 is comprised of two segments, a first segment 7.1 and a second segment 7.2.
  • the first segment 7.1 extends from the first end 3 in the direction of the second end 4 to an upper end 8; the second segment 7.2 immediately adjoins the first segment 7.1 and extends to the second end 4.
  • the upper end 8 acts as a first contact surface to contact the second segment 7.2.
  • the first segment 7.1 has the shape of a frustoconical, while the second segment 7.2 has the shape of a cuboid with a rectangular cross-section.
  • the first segment 7.1 also has the function of a wear indicator. In the area of the first segment
  • the first end 3 of the body 2 is defined by the gas inlet-side area 3.1 of the first segment
  • the first segment 7.1 and the second segment 7.2 are each made of sintered porous, permeable refractory ceramic material based on alumina and magnesia spinel.
  • the first segment 7.1 has a first permeability of 200 nPerm and the second segment 7.2 has a second permeability of 200 nPerm as well.
  • the first segment 7.1 is covered by a metal cap 17 on its side facing the first end 3.
  • the metal cap 17 has a substantially pot-like shape with side walls 17.1 and a bottom 17.2.
  • the side walls 17.1 surround the lower, radial edge of the first segment 7.1.
  • the bottom 17.2 extends at a distance from the gas inlet side region 3.1 of the first segment 7.1, so that a first gas distribution chamber 18 is formed between the metal cap 17 and the first segment 7.1.
  • the space defined by the first gas distribution chamber 18 is thus defined by the metal cap 17 and the first portion 7, namely the segment 7.1 of the first part 7.
  • the bottom 17.2 has a central through opening 19.
  • the body 2 further comprises a second part 9 made of refractory ceramic material which extends from the first end 3 of the body 2 to the second end 4 of the body 2 and which surrounds the first part 7 entirely and symmetrically.
  • the second part 9 has a frustoconical outer contour which, as described above, is covered on the radial outer surface by the metal sleeve 6.
  • the first end 3 of the body 2 is defined by the gas inlet side region 3.2 of the second part 9.
  • each of the nets 11 formed by the gas channels 10 are symmetrical nets 11, wherein the gas channels 10 within these nets 11 extend linearly.
  • the meshes 13 surrounded by the gas channels 10 have a mesh size of 4.0 mm.
  • the gas channels 10 have a constant, circular cross-sectional area with a diameter of 0.50 mm.
  • the second part 9 is covered by a metallic hood 15 on its side facing the first end 3.
  • the hood 15 is welded at the edge along a weld seam 16 to the lower edge of the metal sleeve 6. Leaving free a second gas distribution chamber 20, the hood 15 covers the gas inlet-side 3.1 of the second part 9 of the body 2 and the metal cap 17.
  • the space defined by the second gas distribution chamber 20 is thus defined by the metal cap 17, the hood 15 and the second part 9.
  • the hood 15 has a central through opening 21.
  • first gas distribution chamber 18 and the second gas distribution chamber 20 are separated from each other by a wall, namely, the metal cap 17.
  • the central through-opening 21 of the cap 15 and the central through-opening 19 of the base 17.2 of the metal cap 17 are aligned with each other, with the longitudinal axis 5 of the body 2 passing centrally through the through-opening 21 and the central through-opening 19.
  • the gas purging plug 1 further comprises gas supply means 13 by which gas can be conducted to the first part 7 and to the second part 9.
  • the gas supply means 13 comprise control means 14 by which the conduction of the gas to the first part 7 and to the second part 9 via the gas supply means 13 is controllable.
  • the gas supply means 13 are arranged in the region of the first end 3 of the body 2 and are shown in detail in Figures 4-6.
  • the tubular section 22 In the region of the second gas distribution chamber 20 between the bottom 17.2 and the hood 15, the tubular section 22 has a radially outwardly projecting collar 23 by means of which the tubular section 22 bears sealingly against the base 17.2 and the hood 15 and at the same time is positively secured between the metal cap 17 and the hood 15.
  • the tubular section 22 includes an internal bore 24 extending axially through the tubular section 22. Bores 25 are formed in the collar 23 to fluidically connect the bore 24 to the second gas distribution chamber 20.
  • a tubular body 26 of the gas supply means 13 is arranged in the tubular section 22, in which the control means 14 are arranged.
  • the tubular body 26 has an inner, axial bore 27 through which gas can be conducted from an inlet side 28 of the tubular body 26, through the bore 27 into the first gas distribution chamber 18 and into the second gas distribution chamber 20. From the first gas distribution chamber 18, gas can be directly directed into the first segment 7.1 of the first part 7. Furthermore, gas can be conducted from the second gas distribution chamber 20 directly into the gas channels 10 formed in the second part 9.
  • the tubular body 26 is configured to be inserted into the tubular section 22 in axial direction. In Figure 1 , the tubular body 26 is shown removed from the tubular section 22.
  • the actuator 29 is movable to three positions depending on the mass flow of the gas: if gas flows through the tubular body 26 at a mass flow rate within a first range, the actuator 29 assumes a first position, shown in Figure 4, in which the actuator 29 clears only one gas path through the tubular body 26 into the first gas distribution chamber 18 and blocks the gas path into the second gas distribution chamber 20.
  • a first position shown in Figure 4
  • the actuator 29 clears only one gas path through the tubular body 26 into the first gas distribution chamber 18 and blocks the gas path into the second gas distribution chamber 20.
  • the actuator 29 assumes a second position, shown in Figure 5 in which the actuator 29 clears only one gas path through the tubular body 26 and the bores 25 into the second gas distribution chamber 20 and blocks the gas path into the first gas distribution chamber 18.
  • the actuator 29 assumes a third position shown in Figure 6 in which the actuator 29 clears both a gas path through the tubular body 26 into the first gas distribution chamber 18 and a gas path through the tubular body 26 and the bores 25 into the second gas distribution chamber 20.
  • the gas paths are indicated by arrows. Accordingly, gas can be conducted by the gas supply means 13 to the first part 7 via the first gas distribution chamber 18 and to the second part 9 via the second gas distribution chamber 20. At the same time, gas cannot be introduced into the second part 9 via the first gas distribution chamber 18 and not into the first part 7 via the second gas distribution chamber 20.
  • the gas supply means 13 have a gas connection to which a gas line (not illustrated) can be connected.
  • the gas line in turn, can be connected to a gas source (not illustrated). Gas can accordingly be conducted from the gas source via the gas line into the gas supply means 13, and the gas subsequently being conducted via the gas supply means 13 to the first part 7 and to the second part 9 of the body 2.
  • the two components 107.1, 107.2 have then been assembled together as shown in Fig. 7 to form a first section 107.
  • This first section 107 has the shape of the first part 7 and will form the first part 7 of the refractory gas purging plug 1.
  • the first section 107 provides an outer, radial surface.
  • first section 107 with the nets 111 arranged thereon is placed into a mold (not shown) and a refractory ceramic mass (not shown) based on alumina spinel low cement castable is poured in the space between the first section 107 and the mold.
  • a refractory ceramic mass (not shown) based on alumina spinel low cement castable is poured in the space between the first section 107 and the mold.
  • the nets 111 are embedded into the second refractory material.
  • This part, formed by the refractory ceramic mass forms a second section, having has the shape of the second part 9 and, after burning, will form the second part 9 of the refractory gas purging plug 1.
  • the element, made of the first section 107 and the second section are heated in a furnace at temperatures of about 500°C, whereby the second refractory material is cured.
  • the body 5 is produced, wherein the first section 107 forms the first part 7 and the second section forms the second part 9. Further, during heating, the plastic nets 111 are burned out and the gas channels 110 take the place of the burned-out nets 111.
  • the refractory gas purging plug 1 is used to be arranged in the bottom region of a ladle in a continuous casting plant for treating molten steel.
  • the gas purging plug 201 in the embodiment according to Figure 9 is largely identical to the gas purging plug 1 according to Figures 1 to 8.
  • the elements of the gas purging plug 201 according to Figure 9 are identical to the elements of the gas purging plug 1 according to Figures 1 to 8, they are provided with the same reference signs.
  • One essential difference of the gas purging plug 201, in relation to the gas purging plug 1 according to Figures 1-8, is that the first part 7 is one-piece and, hence, not comprised of a first segment 7.1 and a second segment 7.2. Rather, the first part 7 is one-piece having uniform chemical and physical properties, namely, the physical chemical and physical properties according to the segment 7.2 according to Figures 1-8.
  • the gas purging plug 301 in the embodiment according to Figure 10 is largely identical to the gas purging plug 1 according to Figures 1 to 8.
  • the elements of the gas purging plug 301 according to Figure 10 are identical to the elements of the gas purging plug 1 according to Figures 1 to 8, they are provided with the same reference signs.
  • gas purging plug 301 in relation to the gas purging plug 1 according to figures 1 to 8, is that the gas channels 310 do not extend up to the first end 3 of the body 2, but end at a distance from the first end 3 in the body 2. Accordingly, there are no gas channels 310 at the first end 3 of the body 2.
  • the gas channels 310 are in contact with the upper end 8 of the first segment 7.1.
  • gas is supplied only into the first part 7, namely, into the first segment 7.1 of the first part 7, and gas is conducted to the gas channels 310 only from the first segment 7.1 into the gas channels 310.
  • the first end 3 is covered by a metallic hood 315.
  • the gas distribution chamber 318 is defined by the free space between the hood 315 and the first end 3.
  • the hood 315 includes a gas connection port 322.
  • Gas purging plug according to the embodiment of figure 11 is largely identical to the gas purging plug 301 according to Figure 10. Insofar as the elements of the gas purging plug 401 according to Figure 11 are identical to the elements of the gas purging plug 301 according to Figure 10, they are provided with the same reference signs.
  • the first part 7 is one-piece and, hence, not comprised of a first segment 7.1 and a second segment 7.2. Rather, the first part 7 is one-piece having uniform chemical and physical properties, namely, the physical chemical and physical properties according to the second segment 7.2 according to Figures 1-8.
  • gas channels 410 extend up to the first end 3 of the body 2. Accordingly, there are gas channels 410 at the first end 3 of the body 2.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

L'invention concerne un bouchon de purge de gaz réfractaire et un procédé de fabrication d'un bouchon de purge de gaz réfractaire.
EP23798386.1A 2022-10-27 2023-10-25 Bouchon de purge de gaz réfractaire et procédé de production d'un bouchon de purge de gaz réfractaire Pending EP4608997A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP22204226 2022-10-27
PCT/EP2023/079773 WO2024089097A1 (fr) 2022-10-27 2023-10-25 Bouchon de purge de gaz réfractaire et procédé de production d'un bouchon de purge de gaz réfractaire

Publications (1)

Publication Number Publication Date
EP4608997A1 true EP4608997A1 (fr) 2025-09-03

Family

ID=84044391

Family Applications (1)

Application Number Title Priority Date Filing Date
EP23798386.1A Pending EP4608997A1 (fr) 2022-10-27 2023-10-25 Bouchon de purge de gaz réfractaire et procédé de production d'un bouchon de purge de gaz réfractaire

Country Status (6)

Country Link
EP (1) EP4608997A1 (fr)
CN (1) CN120019169A (fr)
CA (1) CA3265496A1 (fr)
MX (1) MX2025003857A (fr)
TW (1) TW202417145A (fr)
WO (1) WO2024089097A1 (fr)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR90233E (fr) * 1966-06-27 1967-11-03 Air Liquide Perfectionnement aux injecteurs, tuyères et brûleurs pour fours métallurgiques
DE4014509A1 (de) * 1990-05-07 1991-11-14 Didier Werke Ag Gasspueler
RU2129165C1 (ru) * 1997-12-08 1999-04-20 Акционерное общество "Шибер" Устройство для донной продувки металла
RU2132395C1 (ru) * 1998-03-13 1999-06-27 Открытое акционерное общество "Шибер" Способ изготовления составной канальной пробки для продувки металла газом, огнеупорный материал для изготовления канальной пробки и способ изготовления каналообразующих элементов для выполнения каналов в пробке
DE19954918C2 (de) 1999-11-16 2001-09-20 Veitsch Radex Gmbh Wien Feuerfester keramischer Gasspülstein
ES2253701T3 (es) * 2002-06-07 2006-06-01 Vesuvius Crucible Company Dispositivo de inyeccion y procedimiento para inyeccion de un fluido.

Also Published As

Publication number Publication date
WO2024089097A1 (fr) 2024-05-02
MX2025003857A (es) 2025-05-02
CN120019169A (zh) 2025-05-16
CA3265496A1 (fr) 2024-05-02
TW202417145A (zh) 2024-05-01

Similar Documents

Publication Publication Date Title
CN104087759A (zh) 复合脱气管
KR100917700B1 (ko) 신뢰성 있는 가스 주입용 스토퍼
US4899992A (en) Devices and apparatus for injecting gas into high temperature liquids, e.g. molten metals
AU610697B2 (en) Gas-permeable block for metallurgical operations
JPH07227B2 (ja) 浸漬ノズル及びその製造方法
WO2024089097A1 (fr) Bouchon de purge de gaz réfractaire et procédé de production d'un bouchon de purge de gaz réfractaire
WO2024089098A1 (fr) Bouchon de purge de gaz réfractaire et procédé de régulation de la conduction de gaz vers un bouchon de purge de gaz réfractaire
WO2024089095A1 (fr) Bouchon de purge de gaz réfractaire
EP2773474A1 (fr) Dispositifs de purge réfractaire
AU2005263118B2 (en) Stopper rod for delivering gas into a molten metal
EP0771601B1 (fr) Busette de coulée réfractaire
US5855843A (en) Gas sink in the form of an interstitial flushing device
EP2111938B1 (fr) Bouchon de purge par gaz de soufflage dans un récipient de traitement métallique
US5820816A (en) Purging device and method of making same
KR19990082319A (ko) 야금용기를 위한 가스 제거 바닥
JP7824512B2 (ja) ガス吹込みプラグおよびガス吹込みプラグの製造方法
LU500076B1 (en) Gas purging plug for a metallurgical container
JPS5919716Y2 (ja) ガス吹込用成形体
TW202041301A (zh) 塞棒等之製造方法
JPH0229958B2 (fr)
JPH08246032A (ja) 底吹ポーラスプラグの補修方法
HUP9701550A2 (hu) Berendezés és eljárás rétegelt üvegfolyam formálására
ES2210838T3 (es) Tubo de vertido sumergido con manguito resistente a la erosion y procedimiento de fabricacion del mismo.
JPS62203663A (ja) ガス吹込み用網状細孔を備えた溶融金属注入用ノズル
JPH04218611A (ja) 製鋼炉用ガス吹込耐火物成形体の製造法

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: UNKNOWN

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20250422

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC ME MK MT NL NO PL PT RO RS SE SI SK SM TR

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)