ES2000867A6 - Procedimiento y aparato para la eliminacion de los oxidos de azufre de un gas que los contiene - Google Patents
Procedimiento y aparato para la eliminacion de los oxidos de azufre de un gas que los contieneInfo
- Publication number
- ES2000867A6 ES2000867A6 ES8601060A ES8601060A ES2000867A6 ES 2000867 A6 ES2000867 A6 ES 2000867A6 ES 8601060 A ES8601060 A ES 8601060A ES 8601060 A ES8601060 A ES 8601060A ES 2000867 A6 ES2000867 A6 ES 2000867A6
- Authority
- ES
- Spain
- Prior art keywords
- ammonium sulfate
- zone
- sulfur oxide
- liquor
- containing gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 title abstract 12
- 229910052921 ammonium sulfate Inorganic materials 0.000 title abstract 12
- 235000011130 ammonium sulphate Nutrition 0.000 title abstract 12
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 title abstract 9
- 238000000034 method Methods 0.000 title abstract 3
- 229910052815 sulfur oxide Inorganic materials 0.000 title abstract 2
- 238000010521 absorption reaction Methods 0.000 title 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 abstract 7
- 239000007789 gas Substances 0.000 abstract 4
- 238000005201 scrubbing Methods 0.000 abstract 4
- 238000006386 neutralization reaction Methods 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/24—Sulfates of ammonium
- C01C1/245—Preparation from compounds containing nitrogen and sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Abstract
PROCEDIMIENTO Y APARATO PARA ELIMINAR LOS OXIDOS DE AZUFRE DE UN GAS CONTENIENDO OXIDOS DE AZUFRE CON PRODUCCION SIMULTANEA DE SULFATO DE AMONIO. EL GAS CONTENIENDO OXIDOS DE AZUFRE SE INTRODUCE EN LA ZONA DE DEPURACION DE SULFATO DE AMONIO Y PASA A CONTRACORRIENTE RESPECTO A LAS GOTAS O A LA PULVERIZACION DE LICOR DE SULFATO DE AMONIO. EL LICOR DE SULFATO DE AMONIO ABSORBE EL OXIDO DE AZUFRE EN LAS ZONAS DE DEPURACION, Y EL LICOR QUE CONTIENE EL OXIDO DE AZUFRE ABSORBIDO SE ACUMULA EN EL DEPOSITO DE LICOR DE SULFATO DE AMONIO DONDE SE INTRODUCEN AMONIO ACUOSO EN LA ZONA DE NEUTRALIZACION Y UN GAS CONTENIENDO OXIGENO EN LA ZONA DE OXIDACION DE OXIDO DE AZUFRE. EL OXIDO DE AZUFRE SE SEPARA DEL SULFATO DE AMONIO QUE SE LLEVA A LA ZONA DE DEPURACION DE SULFATO DE AMONIO. EL SULFATO DE AMONIO PRODUCIDO SE RETIRA DE LA ZONA DE EXTRACCION DE PRODUCTO.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US76577485A | 1985-08-15 | 1985-08-15 | |
| US06/831,381 US4690807A (en) | 1985-08-15 | 1986-02-20 | Process for the simultaneous absorption of sulfur oxides and production of ammonium sulfate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2000867A6 true ES2000867A6 (es) | 1988-03-16 |
Family
ID=27117649
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES8601060A Expired ES2000867A6 (es) | 1985-08-15 | 1986-08-13 | Procedimiento y aparato para la eliminacion de los oxidos de azufre de un gas que los contiene |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4690807A (es) |
| EP (1) | EP0212523B1 (es) |
| CN (1) | CN86106161A (es) |
| DE (1) | DE3684835D1 (es) |
| DK (1) | DK390686A (es) |
| ES (1) | ES2000867A6 (es) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1091995A (zh) * | 1993-03-08 | 1994-09-14 | 巴布考克及威尔考克斯公司 | 使用氨-石灰石洗涤副产物并应用于农业 |
| US5362458A (en) * | 1993-03-22 | 1994-11-08 | General Electric Environmental Services, Incorporated | Process for the simultaneous absorption of sulfur oxides and production of ammonium sulfate |
| GEP20002319B (en) * | 1994-06-09 | 2000-12-25 | Abb Env Systems | Method and Apparatus for Purifying Gas |
| US5512072A (en) * | 1994-12-05 | 1996-04-30 | General Electric Environmental Services, Inc. | Flue gas scrubbing apparatus |
| US6652817B1 (en) * | 1995-06-14 | 2003-11-25 | Hitachi, Ltd. | Apparatus for processing organohalogen compounds |
| US6991771B2 (en) * | 1996-10-09 | 2006-01-31 | Powerspan Corp. | NOx, Hg, and SO2 removal using ammonia |
| DE19727038C1 (de) * | 1997-06-25 | 1999-02-04 | Metallgesellschaft Ag | Vorrichtung zur Durchführung von Gasreaktionen, Verwendung der Vorrichtung und Verfahren zum Betreiben der Vorrichtung |
| DE19731062C2 (de) * | 1997-07-19 | 2001-07-12 | Lurgi Lentjes Bischoff Gmbh | Verfahren zur Entfernung von sauren Gasen aus Rauchgasen, insbesondere aus Kraftwerksabgasen und Abgasen von Müllverbrennungsanlagen |
| US6066304A (en) * | 1998-08-06 | 2000-05-23 | Delores Pircon | Process for removing sulfur dioxide out of a gas |
| US6221325B1 (en) * | 1998-09-08 | 2001-04-24 | Marsulex Environmental Technologies, Llc | Process for controlling ammonia slip in the reduction of sulfur dioxide emission |
| US6187278B1 (en) * | 1998-09-08 | 2001-02-13 | Marsulex Environmental Technologies, Llc | Process for controlling ammonia slip in the reduction of sulfur dioxide emission |
| US6277343B1 (en) * | 1999-09-23 | 2001-08-21 | Marsulex Environmental Technologies, Llc | Flue gas scrubbing method and apparatus therefor |
| US6531104B1 (en) | 2000-11-21 | 2003-03-11 | Alstom (Schweiz) Ag | Process for the absorption of sulfur oxides and the production of ammonium sulfate |
| US6638342B2 (en) * | 2001-11-28 | 2003-10-28 | Marsulex Environmental Technologies | Process and facility for removing metal contaminants from fertilizer streams |
| US6936231B2 (en) * | 2001-12-06 | 2005-08-30 | Powerspan Corp. | NOx, Hg, and SO2 removal using ammonia |
| CN100364647C (zh) * | 2004-09-22 | 2008-01-30 | 上海弗卡斯环保工程有限公司 | 氨法烟气脱硫装置及其工艺 |
| US20070154374A1 (en) * | 2006-01-05 | 2007-07-05 | Envirosolv Energy Llc | Method for removing sulfur dioxide and other acid gases, mercury, and nitrogen oxides from a gas stream with the optional production of ammonia based fertilizers |
| CN100460045C (zh) * | 2006-05-31 | 2009-02-11 | 中国石油化工股份有限公司 | 一种处理废气中SOx的方法 |
| US7771685B2 (en) * | 2007-04-26 | 2010-08-10 | Marsulex Environmental Technologies, Corp | Process and system for removing hydrogen sulfide and mercaptans in ammonia-based desulfurization systems |
| DE102007039926B4 (de) | 2007-08-23 | 2012-03-22 | Götaverken Miljö AB | Verfahren und Vorrichtung zur Abgasreinigung |
| US7947168B2 (en) * | 2008-03-05 | 2011-05-24 | Syncrude Canada Ltd. | Segregation of streams for the production of ammonia |
| US8353980B2 (en) * | 2008-12-05 | 2013-01-15 | Marsulex Environmental Technologies Corporation | Flue gas scrubbing apparatus and process |
| US8859831B2 (en) * | 2011-08-02 | 2014-10-14 | Gas Technology Institute | Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors |
| EP2928828B1 (en) * | 2012-12-06 | 2016-10-05 | Cap Iii B.V. | Process and apparatus for producing ammonium sulfate crystals |
| DE102013003001A1 (de) * | 2013-02-22 | 2014-08-28 | Man Diesel & Turbo Se | Brennkraftmaschine, Abgasrückführungsvorrichtung und Verfahren zur Abgasrückführung |
| WO2014172860A1 (zh) * | 2013-04-24 | 2014-10-30 | 江苏新世纪江南环保股份有限公司 | 酸性尾气氨法烟气治理方法及装置 |
| DE102013008756A1 (de) * | 2013-05-23 | 2014-11-27 | Messer Austria Gmbh | Verfahren und Vorrichtung zum Behandeln eines mit Schwefeldioxid beladenen Gasstroms |
| CA2971059C (en) * | 2013-09-17 | 2018-06-26 | Ihi Corporation | Exhaust gas processing system and processing method |
| CN104649298B (zh) * | 2014-04-21 | 2017-01-04 | 柳州钢铁股份有限公司 | 硫酸铵的生产方法 |
| CN105271305A (zh) * | 2015-09-29 | 2016-01-27 | 山东钢铁股份有限公司 | 一种剩余氨水蒸氨所得氨水的处理方法 |
| CN108144428A (zh) | 2017-03-15 | 2018-06-12 | 江苏新世纪江南环保股份有限公司 | 一种氨法高效脱除气体中硫氧化物和尘的方法及装置 |
| CN107213785B (zh) | 2017-05-25 | 2020-08-07 | 江苏新世纪江南环保股份有限公司 | 一种fcc尾气氨法脱硝脱硫除尘的方法及装置 |
| CN107213769B (zh) | 2017-05-25 | 2019-09-20 | 江苏新世纪江南环保股份有限公司 | 一种分室加氨的氨法脱硫方法及装置 |
| EP3842125B1 (en) | 2017-06-14 | 2025-12-10 | Jiangnan Environmental Protection Group Inc. | Automatic ammonia-adding system and method for ammonia-based desulfurization device |
| US10603624B2 (en) | 2017-07-03 | 2020-03-31 | Marsulex Environmental Technologies Corporation | Wet flue gas desulfurization process and apparatus |
| CN107213770B (zh) | 2017-07-03 | 2023-03-17 | 江苏新世纪江南环保股份有限公司 | 氨法脱硫吸收塔及其建立方法和运行方法 |
| CN108722163B (zh) | 2017-09-07 | 2019-06-07 | 江苏新世纪江南环保股份有限公司 | 一种氨法脱硫控制吸收过程气溶胶产生的方法 |
| US11202983B2 (en) * | 2017-11-08 | 2021-12-21 | Btu International, Inc. | Devices, systems and methods for flux removal from furnace process gas |
| CN110368816A (zh) * | 2018-04-13 | 2019-10-25 | 江苏新世纪江南环保股份有限公司 | 一种氨法脱硫溶液的氧化方法及装置 |
| CN110732227B (zh) | 2018-07-20 | 2023-02-21 | 江南环保集团股份有限公司 | 一种酸性气处理的方法和装置 |
| CN109005854B (zh) * | 2018-10-26 | 2021-03-19 | 重庆开凡农业科技有限公司 | 一体化滴灌系统 |
| CN114870579A (zh) | 2022-05-16 | 2022-08-09 | 江苏新世纪江南环保股份有限公司 | 一种氨法脱硫脱碳系统余热回收的方法及装置 |
| CN110975546B (zh) | 2019-12-26 | 2021-08-17 | 江苏新世纪江南环保股份有限公司 | 一种改进的氨法脱硫控制吸收过程气溶胶产生的方法 |
| CN111573695A (zh) * | 2020-04-09 | 2020-08-25 | 浙江省天正设计工程有限公司 | 一种含磷硫高浓度有机废水资源化处理工艺 |
| CN115253360B (zh) * | 2022-06-27 | 2023-10-27 | 国能龙源环保有限公司 | 一种氨法脱硫浓缩塔结晶、出料、溶料控制方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US909017A (en) * | 1906-05-18 | 1909-01-05 | David E Parker | Apparatus for preparing oxone. |
| US1986889A (en) * | 1931-09-05 | 1935-01-08 | Koppers Co Delaware | Preparation of ammonium sulphate |
| US3186802A (en) * | 1961-03-02 | 1965-06-01 | Carves Simon Ltd | Apparatus for the production of ammonium sulphate |
| FR1388690A (fr) * | 1963-04-29 | 1965-02-12 | Azote Office Nat Ind | Fixation et valorisation de l'anhydride sulfureux rejeté dans l'atmosphère par leseffluents industriels |
| US3676059A (en) * | 1970-06-01 | 1972-07-11 | Albert B Welty Jr | Sulfate control in ammonia flue gas desulfurization |
| UST909017I4 (en) | 1972-04-13 | 1973-04-17 | Sulfur dioxide removal prom stack gases | |
| US3843789A (en) * | 1973-02-26 | 1974-10-22 | Air Prod & Chem | Removal of sulfur oxides from stack gas |
| JPS5513770B2 (es) * | 1973-09-26 | 1980-04-11 | ||
| DE2431130C3 (de) * | 1974-06-28 | 1979-07-26 | Maschinenfabrik Burkau R. Wolf Kg, 4048 Grevenbroich | Verfahren zur Entfernung von sauren Komponenten aus Abgasen |
| DE2708919C2 (de) * | 1977-03-02 | 1982-05-27 | Dr. C. Otto & Comp. Gmbh, 4630 Bochum | Verfahren zur Reinigung von SO↓2↓-haltigen Industrieabgasen |
| US4250160A (en) * | 1977-08-15 | 1981-02-10 | Exxon Research & Engineering Co. | Production of ammonium sulfate |
| DE2741116C2 (de) * | 1977-09-13 | 1984-11-22 | Dr. C. Otto & Co Gmbh, 4630 Bochum | Verfahren zur Entfernung von Schwefeldioxid aus Gasen, insbesondere Industrieabgasen |
| DE2819994A1 (de) * | 1978-05-08 | 1979-11-22 | Basf Ag | Verfahren zur entfernung von schwefeldioxid aus abwaessern und gegebenenfalls abgasen |
| JPS57121387A (en) * | 1981-01-21 | 1982-07-28 | Sony Corp | Charge transfer type image pickup element |
| DE3128753A1 (de) * | 1981-07-21 | 1983-04-07 | Hans Gotthard Dr. Dipl.-Chem. 4230 Wesel Remstedt | Rauchgasentschwefelung |
| DE3227187C1 (de) * | 1982-07-21 | 1988-12-01 | Gottfried Bischoff Bau kompl. Gasreinigungs- und Wasserrückkühlanlagen GmbH & Co KG, 4300 Essen | Waschturm fuer eine Anlage zur Entschwefelung von Rauchgas |
| US4430303A (en) * | 1982-09-30 | 1984-02-07 | Linde Aktiengesellschaft | Removal of undesirable gaseous components from a hot waste gas |
| JPS60172335A (ja) * | 1984-02-20 | 1985-09-05 | Babcock Hitachi Kk | 湿式排煙脱硫方法 |
-
1986
- 1986-02-20 US US06/831,381 patent/US4690807A/en not_active Expired - Lifetime
- 1986-08-11 DE DE8686111065T patent/DE3684835D1/de not_active Expired - Lifetime
- 1986-08-11 EP EP86111065A patent/EP0212523B1/en not_active Expired - Lifetime
- 1986-08-13 ES ES8601060A patent/ES2000867A6/es not_active Expired
- 1986-08-15 CN CN198686106161A patent/CN86106161A/zh active Pending
- 1986-08-15 DK DK390686A patent/DK390686A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DK390686D0 (da) | 1986-08-15 |
| DK390686A (da) | 1987-02-16 |
| EP0212523A2 (en) | 1987-03-04 |
| EP0212523B1 (en) | 1992-04-15 |
| CN86106161A (zh) | 1987-02-18 |
| US4690807A (en) | 1987-09-01 |
| EP0212523A3 (en) | 1987-10-07 |
| DE3684835D1 (de) | 1992-05-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2000867A6 (es) | Procedimiento y aparato para la eliminacion de los oxidos de azufre de un gas que los contiene | |
| CA2116949A1 (en) | Process for the simultaneous absorption of sulfur oxides and production of ammonium sulfate | |
| GB1445232A (en) | Process for removing sulphur dioxide from dust-laden waste gases | |
| MY8600489A (en) | Process for the removal of urea ammonia and carbon dioxide from dilute aqueous solutions | |
| YU118980A (en) | Process for the purification of waste water containing carbamides | |
| ATE73005T1 (de) | Verfahren zur gleichzeitigen entstickung und entschwefelung eines sauerstoffhaltigen abgases. | |
| DE3264299D1 (en) | Process and apparatus to regulate the nh3 content of the wash liquor whilst washing gases | |
| IN158998B (es) | ||
| DE2625005B2 (de) | Verfahren zur Entfernung von Stickstoffdioxid aus Abgasen | |
| ES437246A1 (es) | Procedimiento para el tratamiento de vapor de agua generado al concentrar una solucion acuosa de urea. | |
| IN169678B (es) | ||
| EP0172972A3 (en) | Process for removing ammonia from a gas containing sulphurous acid anhydride | |
| EP0205976A3 (en) | A process for the removal of sulfur oxides from gaseous and/or liquid waste products | |
| GB1401325A (en) | Process for scrubbing so2 from a gas stream | |
| JPS5314678A (en) | Simultaneous treating method for desulfurization and denitration of lue gas | |
| JPS5573329A (en) | Treatment of exhaust gas which contains nitrogen oxide | |
| GR3005249T3 (es) | ||
| JPS52150381A (en) | Treatment of hydrogen sulfide | |
| GB1513493A (en) | Treatment of gas mixtures containing oxides of nitrogen | |
| DE3261381D1 (en) | Process for scrubbing acid gases from gas mixtures | |
| JPS52114593A (en) | Treatment of tail gas from claus process sulfur recovery unit | |
| ES8604427A1 (es) | Procedimiento para eliminar por lavado fosfaminas u otras impurezas que reaccionan de modo alcalino, por ejemplo nh3, a partir de gases | |
| JPS52150380A (en) | Removal of nitrogen oxides | |
| JPS51151257A (en) | An exhaust gas desulfurization and denitration process | |
| Iwai et al. | Oxidation of Arsenic (III) With Oxygen in Alkaline Solutions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 20060814 |