ES2013197A6 - Procedimiento de preparacion de aldoximas aromaticas. - Google Patents
Procedimiento de preparacion de aldoximas aromaticas.Info
- Publication number
- ES2013197A6 ES2013197A6 ES8902099A ES8902099A ES2013197A6 ES 2013197 A6 ES2013197 A6 ES 2013197A6 ES 8902099 A ES8902099 A ES 8902099A ES 8902099 A ES8902099 A ES 8902099A ES 2013197 A6 ES2013197 A6 ES 2013197A6
- Authority
- ES
- Spain
- Prior art keywords
- oxime
- alpha
- production
- aromatic
- phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 125000003118 aryl group Chemical group 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000002923 oximes Chemical class 0.000 abstract 3
- FZENGILVLUJGJX-NSCUHMNNSA-N (E)-acetaldehyde oxime Chemical compound C\C=N\O FZENGILVLUJGJX-NSCUHMNNSA-N 0.000 abstract 1
- VTWKXBJHBHYJBI-VURMDHGXSA-N (nz)-n-benzylidenehydroxylamine Chemical compound O\N=C/C1=CC=CC=C1 VTWKXBJHBHYJBI-VURMDHGXSA-N 0.000 abstract 1
- CAHQGWAXKLQREW-UHFFFAOYSA-N Benzal chloride Chemical compound ClC(Cl)C1=CC=CC=C1 CAHQGWAXKLQREW-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- -1 benzaldehyde oxime Chemical compound 0.000 abstract 1
- 150000002443 hydroxylamines Chemical class 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 238000000638 solvent extraction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/32—Oximes
- C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
- C07C251/48—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
- C07C249/14—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PROCEDIMIENTO DE PREPARACION DE ALDOXIMAS AROMATICAS, TALES COMO BENZALDOXIMA, HACIENDO REACCIONAR EL ALFA, ALFA-DIHALURO CORRESPONDIENTE, TAL COMO CLOROBENZAL, CON UNA SAL DE HIDROXILAMINA EN PRESENCIA DE UN EXCESO DE UNA BASE ACUOSA SUFICIENTE PARA MANTENER EL PRODUCTO OXIMICO EN SOLUCION. LAS IMPUREZAS ORGANICAS PUEDEN SEPARARSE POR FASES DE LA MEZCLA DE REACCION. A CONTINUACION, SE NEUTRALIZA LA SOLUCION ACUOSA QUE CONTIENE EL PRODUCTO OXIMICO PARA SEPARAR UNA FASE OXIMICA, QUE PUEDE RECUPERARSE POR DECANTACION O EXTRACCION EN DISOLVENTE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/208,438 US4922017A (en) | 1988-06-20 | 1988-06-20 | Process for production of aromatic aldoximes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2013197A6 true ES2013197A6 (es) | 1990-04-16 |
Family
ID=22774610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES8902099A Expired - Lifetime ES2013197A6 (es) | 1988-06-20 | 1989-06-15 | Procedimiento de preparacion de aldoximas aromaticas. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4922017A (es) |
| EP (1) | EP0420941B1 (es) |
| JP (1) | JPH0676362B2 (es) |
| KR (1) | KR0152056B1 (es) |
| DE (1) | DE68912329T2 (es) |
| ES (1) | ES2013197A6 (es) |
| WO (1) | WO1989012623A1 (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021117053A1 (en) * | 2019-12-12 | 2021-06-17 | Dr. Silviu Pharmachem Pvt. Ltd. | An improved process for preparation of pure aldoxime |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3081347A (en) * | 1958-12-29 | 1963-03-12 | Exxon Research Engineering Co | Preparation of polyaminomethyl aromatic compounds |
| US3129260A (en) * | 1961-01-30 | 1964-04-14 | Shell Oil Co | Preparation of a benzaldoxime |
| NL301053A (es) * | 1963-11-27 | |||
| US3624157A (en) * | 1969-12-17 | 1971-11-30 | Velsicol Chemical Corp | Process for preparing ortho-chlorobenzaldehyde |
| US4323706A (en) * | 1978-02-23 | 1982-04-06 | Allied Corporation | Production of acetaldehyde oxime |
| JPS56166131A (en) * | 1980-05-26 | 1981-12-21 | Nippon Oil & Fats Co Ltd | Preparation of mixture of m-phenoxybenzyl alcohol with m-phenoxybenzaldehyde |
-
1988
- 1988-06-20 US US07/208,438 patent/US4922017A/en not_active Expired - Lifetime
-
1989
- 1989-05-31 WO PCT/US1989/002377 patent/WO1989012623A1/en not_active Ceased
- 1989-05-31 JP JP1507979A patent/JPH0676362B2/ja not_active Expired - Fee Related
- 1989-05-31 EP EP89908346A patent/EP0420941B1/en not_active Expired - Lifetime
- 1989-05-31 KR KR1019900700305A patent/KR0152056B1/ko not_active Expired - Fee Related
- 1989-05-31 DE DE89908346T patent/DE68912329T2/de not_active Expired - Fee Related
- 1989-06-15 ES ES8902099A patent/ES2013197A6/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0420941A1 (en) | 1991-04-10 |
| JPH0676362B2 (ja) | 1994-09-28 |
| WO1989012623A1 (en) | 1989-12-28 |
| JPH03501977A (ja) | 1991-05-09 |
| DE68912329D1 (de) | 1994-02-24 |
| US4922017A (en) | 1990-05-01 |
| KR900701739A (ko) | 1990-12-04 |
| DE68912329T2 (de) | 1994-04-28 |
| EP0420941B1 (en) | 1994-01-12 |
| KR0152056B1 (ko) | 1998-10-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 20100528 |