ES2019123B3 - Procedimiento para la obtencion de un polimero de 1-olefina. - Google Patents

Procedimiento para la obtencion de un polimero de 1-olefina.

Info

Publication number
ES2019123B3
ES2019123B3 ES88108658T ES88108658T ES2019123B3 ES 2019123 B3 ES2019123 B3 ES 2019123B3 ES 88108658 T ES88108658 T ES 88108658T ES 88108658 T ES88108658 T ES 88108658T ES 2019123 B3 ES2019123 B3 ES 2019123B3
Authority
ES
Spain
Prior art keywords
procedure
obtaining
olephine
polymer
olephine polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES88108658T
Other languages
English (en)
Inventor
Martin Antberg
Hartmut Luker
Ludwig Bohm
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Application granted granted Critical
Publication of ES2019123B3 publication Critical patent/ES2019123B3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
ES88108658T 1987-06-05 1988-05-31 Procedimiento para la obtencion de un polimero de 1-olefina. Expired - Lifetime ES2019123B3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19873718888 DE3718888A1 (de) 1987-06-05 1987-06-05 Verfahren zur herstellung eines 1-olefinpolymers

Publications (1)

Publication Number Publication Date
ES2019123B3 true ES2019123B3 (es) 1991-06-01

Family

ID=6329146

Family Applications (1)

Application Number Title Priority Date Filing Date
ES88108658T Expired - Lifetime ES2019123B3 (es) 1987-06-05 1988-05-31 Procedimiento para la obtencion de un polimero de 1-olefina.

Country Status (7)

Country Link
EP (1) EP0293815B1 (es)
JP (1) JP2609287B2 (es)
AU (1) AU600831B2 (es)
CA (1) CA1312992C (es)
DE (2) DE3718888A1 (es)
ES (1) ES2019123B3 (es)
ZA (1) ZA883948B (es)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0279863B1 (en) * 1986-08-26 1992-10-14 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing alpha-olefin and polymerization process
DE3640948A1 (de) * 1986-11-29 1988-06-01 Hoechst Ag Verfahren zur herstellung eines 1-olefin-stereoblockpolymers
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
US5262498A (en) * 1991-01-12 1993-11-16 Hoechst Aktiengesellschaft Metallocene (co)polymers, process for their preparation and their use as catalysts
US5169818A (en) * 1991-01-12 1992-12-08 Hoechst Aktiengesellschaft Metallocene (co)polymers, process for their preparation and their use as catalysts
TW218884B (es) * 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5399636A (en) * 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
JP3273944B2 (ja) * 1991-11-25 2002-04-15 エクソンモービル・ケミカル・パテンツ・インク ポリアニオン性遷移金属触媒組成物
FR2725993B1 (fr) * 1994-10-21 1996-11-29 Atochem Elf Sa Composante catalytique solide contenant du zirconium et des groupements cycloalcadienyles, son procede d'obtention et procede de polymerisation des olefines en sa presence
CN1047388C (zh) * 1995-07-14 1999-12-15 中国石油化工总公司 负载型金属茂类化合物／铝氧烷催化剂的制备
DE19527652A1 (de) * 1995-07-28 1997-01-30 Hoechst Ag Metallocenverbindung
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
US6313239B1 (en) * 1996-03-05 2001-11-06 Bayer Corporation Olefin polymerization with group 4 metal-containing organosilicon dendrimers
WO1997032918A2 (en) * 1996-03-05 1997-09-12 Massachusetts Institute Of Technology Group 4 metal-containing organosilicon dendrimers and method for synthesizing organosilicon dendrimers
FI961511L (fi) * 1996-04-03 1997-10-04 Mikrokemia Oy Menetelmä olefiinien polymerointikatalyyttien valmistamiseksi
ES2129323B1 (es) * 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
IT1283010B1 (it) * 1996-05-15 1998-04-03 Enichem Spa Complesso metallocenico supportato e procedimento per la sua prepa- razione
KR100205738B1 (ko) * 1996-07-26 1999-07-01 이정국 담지체 계류 담지 촉매 및 그 제조 방법
DE69726821T2 (de) * 1996-10-30 2004-10-21 Repsol Quimica Sa Katalysatorsysteme für die Polymerisation und die Copolymerisation von Alpha-Olefinen
DE69705186T2 (de) 1996-10-30 2002-03-14 Repsol Quimica S.A., Madrid Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen
US20030195109A1 (en) 1996-10-31 2003-10-16 Jose Sancho Royo Catalytic systems for the polimerisation and copolimerisation of alpha-olefins
EP0856524A1 (en) 1997-02-01 1998-08-05 Repsol Quimica S.A. Heterogeneous catalyst components for olefins polymerization, preparation process and use thereof
US6177375B1 (en) * 1998-03-09 2001-01-23 Pq Corporation High activity olefin polymerization catalysts
KR100358225B1 (ko) 1998-04-09 2003-01-24 주식회사 엘지화학 조촉매의 재순환이 가능한 메탈로센 촉매 중합 방법
KR100380018B1 (ko) * 1998-04-09 2003-10-04 주식회사 엘지화학 메탈로센담지촉매및이를이용한올레핀중합방법
DE69914012T2 (de) * 1998-04-27 2004-12-09 Repsol Quimica S.A. Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
DE69904982T2 (de) * 1998-04-29 2004-01-08 Repsol Quimica S.A. Funktionalisierte Metallocene, deren Herstellung und deren Verwendung
KR100367463B1 (ko) * 1999-03-03 2003-01-14 주식회사 엘지화학 메탈로센 화합물 및 이를 이용한 올레핀 중합
US6194343B1 (en) * 1999-03-11 2001-02-27 University Of Waterloo Bridged “tethered” metallocenes
JP4622045B2 (ja) * 1999-06-03 2011-02-02 株式会社豊田中央研究所 重合触媒及び樹脂複合材の合成方法
US7041618B2 (en) * 1999-06-22 2006-05-09 Lg Chemical Ltd. Supported metallocene catalyst and olefin polymerization using the same
KR100354290B1 (ko) * 1999-06-22 2002-09-28 주식회사 엘지화학 담지 메탈로센 촉매 및 이를 이용한 올레핀 중합
US7247595B2 (en) 1999-06-22 2007-07-24 Lg Chem, Ltd. Supported metallocene catalyst and olefin polymerization using the same
TW548283B (en) * 2000-01-11 2003-08-21 Dow Chemical Co Chemically-modified supports and supported catalyst systems prepared therefrom
DE60102789T2 (de) 2001-01-18 2005-05-12 Repsol Quimica S.A. Olefinpolymerisationskatalysatoren
KR100690345B1 (ko) * 2004-09-03 2007-03-09 주식회사 엘지화학 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법
EP2070953A1 (en) 2007-12-11 2009-06-17 Total Petrochemicals Research Feluy Activating supports based on phosphonium complexes
EP2274341B1 (en) * 2008-04-28 2012-02-15 Univation Technologies, LLC Methods for preparing catalyst systems

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst

Also Published As

Publication number Publication date
DE3860988D1 (de) 1990-12-13
EP0293815A1 (de) 1988-12-07
ZA883948B (en) 1989-02-22
JP2609287B2 (ja) 1997-05-14
DE3718888A1 (de) 1988-12-22
JPS63312303A (ja) 1988-12-20
AU1732088A (en) 1988-12-08
CA1312992C (en) 1993-01-19
AU600831B2 (en) 1990-08-23
EP0293815B1 (de) 1990-11-07

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