ES2031984T3 - Procedimiento para la obtencion de dioxido de titanio. - Google Patents
Procedimiento para la obtencion de dioxido de titanio.Info
- Publication number
- ES2031984T3 ES2031984T3 ES88118917T ES88118917T ES2031984T3 ES 2031984 T3 ES2031984 T3 ES 2031984T3 ES 88118917 T ES88118917 T ES 88118917T ES 88118917 T ES88118917 T ES 88118917T ES 2031984 T3 ES2031984 T3 ES 2031984T3
- Authority
- ES
- Spain
- Prior art keywords
- sulfuric acid
- titanium
- titanium dioxide
- diluted
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 239000004408 titanium dioxide Substances 0.000 title abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 238000000354 decomposition reaction Methods 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000002893 slag Substances 0.000 abstract 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1236—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching
- C22B34/124—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching using acidic solutions or liquors
- C22B34/125—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching using acidic solutions or liquors containing a sulfur ion as active agent
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
- C01G23/0532—Producing by wet processes, e.g. hydrolysing titanium salts by hydrolysing sulfate-containing salts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
PARA LA PRODUCCION DE DIOXIDO DE TITANIO POR EL PROCESO DEL SULFATO SE USAN COMO MATERIALES DE PARTIDA ESCORIA DE TITANIO E ILMENITA OBTENIDOS DE FORMA PARALELA PERO SEPARADAMENTE, ESTO ES, SE DESCOMPONEN CON ACIDO SULFURICO AL 98,0% Y AL 85%, ESTANDO LAS TEMPERATURAS DE PARTIDA ALGO POR DEBAJO DE LA TEMPERATURA DE INICIACION, INICIANDOSE LAS REACCIONES DE DESCOMPOSICION MEDIANTE LA INYECCION DE UNA CANTIDAD MINIMA DE VAPOR CALIENTE. TRAS LA DESCOMPOSICION SE MEZCLAN AMBAS LEJIAS MADRE Y SE ELABORAN CONJUNTAMENTE HASTA SER TIO2, CONCENTRANDOSE HASTA UN 85% Y RECICLANDOSE EL ACIDO SULFURICO DILUIDO SL 23% QUE SALE DE LA REACCION SEPARANDO LAS SALES METALICAS. CON ESTO SE USA PARA LA OBTENCION DE ESCORIA DE TITANIO PREFERENTEMENTE ACIDO SULFURICO ALTAMENTE CONCENTRADO U OBTENIDO MEDIANTE CALCINACION DE LOS SULFATOS METALICOS RESULTANTES DEL PROCESO, MIENTRAS QUE EL EXCESO DE ACIDO SULFURICO CONCENTRADO AL 85% SIRVE PARA LA OBTENCION DE ILMENITA, DE FORMA QUE SE REUTILIZA ECONOMICAMENTE LA PRACTICA TOTALIDAD DEL ACIDO SULFURICO DILUIDO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH4548/87A CH672633A5 (es) | 1987-11-23 | 1987-11-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2031984T3 true ES2031984T3 (es) | 1993-01-01 |
Family
ID=4278134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES88118917T Expired - Lifetime ES2031984T3 (es) | 1987-11-23 | 1988-11-14 | Procedimiento para la obtencion de dioxido de titanio. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5068093A (es) |
| EP (1) | EP0317857B1 (es) |
| JP (1) | JPH01164733A (es) |
| KR (1) | KR940006034B1 (es) |
| AT (1) | ATE76627T1 (es) |
| AU (1) | AU616221B2 (es) |
| CA (1) | CA1327125C (es) |
| CH (1) | CH672633A5 (es) |
| DE (2) | DE3744575C1 (es) |
| ES (1) | ES2031984T3 (es) |
| FI (1) | FI90525C (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3912554C1 (es) * | 1989-04-17 | 1990-07-12 | Bayer Ag, 5090 Leverkusen, De | |
| US6440383B1 (en) | 1999-06-24 | 2002-08-27 | Altair Nanomaterials Inc. | Processing aqueous titanium chloride solutions to ultrafine titanium dioxide |
| US6548039B1 (en) | 1999-06-24 | 2003-04-15 | Altair Nanomaterials Inc. | Processing aqueous titanium solutions to titanium dioxide pigment |
| US6375923B1 (en) | 1999-06-24 | 2002-04-23 | Altair Nanomaterials Inc. | Processing titaniferous ore to titanium dioxide pigment |
| RU2255047C1 (ru) * | 2004-04-06 | 2005-06-27 | Томский политехнический университет | Способ получения диоксида титана |
| CN104030344A (zh) * | 2014-05-22 | 2014-09-10 | 昆明有色冶金设计研究院股份公司 | 一种四氯化钛收尘渣的综合处理方法 |
| CN113430391A (zh) * | 2021-07-16 | 2021-09-24 | 沈阳有色金属研究院有限公司 | 一种低温焙烧-水浸处理钛白酸解残渣的方法 |
| CN115924967B (zh) * | 2023-03-08 | 2023-05-16 | 国能龙源环保有限公司 | 利用钛渣制备钛白粉的方法及其钛白粉 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA609030A (en) * | 1960-11-22 | E.I. Du Pont De Nemours And Company | Preparation of hydrolyzable titanium sulfate solutions | |
| CA673236A (en) * | 1963-10-29 | W. Grose Robert | Extraction of titania from ores and slags | |
| US2531926A (en) * | 1949-02-15 | 1950-11-28 | American Cyanamid Co | Production of titanium dioxide pigment from high titanium dioxide content slags |
| GB710065A (en) * | 1951-11-23 | 1954-06-02 | Titan Co Inc | Improvements in or relating to a method for producing titanium concentrates |
| US2774650A (en) * | 1953-05-01 | 1956-12-18 | Nat Lead Co | Method for decomposition of titaniferous ores |
| US3218131A (en) * | 1961-01-27 | 1965-11-16 | Independence Foundation | Process for recovery of titania values |
| GB1037399A (en) * | 1963-10-28 | 1966-07-27 | Quebec Iron & Titanium Corp | Leaching tio-containing slags |
| FR1548343A (es) * | 1967-07-07 | 1968-12-06 | ||
| DE1592406B2 (de) * | 1967-09-25 | 1978-12-14 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Titandioxydpigmenten mit hohem Weißgrad |
| US3868441A (en) * | 1973-05-02 | 1975-02-25 | Ethyl Corp | Process for reducing trivalent titanium content in slag |
| DE2454220A1 (de) * | 1974-11-15 | 1976-05-20 | Bayer Antwerpen Nv | Verfahren zur filtration feststoffhaltiger aufschlussloesungen bei der titandioxidherstellung |
| US4038363A (en) * | 1975-10-21 | 1977-07-26 | Quebec Iron & Titanium Corporation-Fer Et Titane Due Quebec, Inc. | Upgrading sorelslag for production of synthetic rutile |
| US4119698A (en) * | 1976-11-26 | 1978-10-10 | Kernforschungsanlage Julich, Gesellschaft Mit Beschrankter Haftung | Reclamation treatment of red mud |
| DE2726418C3 (de) * | 1977-06-11 | 1986-03-27 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von konzentrierten Titanylsulfataufschlußlösungen |
| DE2729755C2 (de) * | 1977-07-01 | 1983-12-22 | Kronos Titan-Gesellschaft Mbh, 5090 Leverkusen | Verfahren zur Herstellung von Titandioxid durch diskontinuierliches Aufschließen von Ilmeniterzen mit Schwefelsäure |
| IT1086097B (it) * | 1977-09-21 | 1985-05-28 | Montedison Spa | Procedimento per preparare soluzioni acquose limpide di acido solforico |
| IT1086096B (it) * | 1977-09-21 | 1985-05-28 | Montedison Spa | Procedimento per la concentrazione di soluzioni acquose di acido solforico |
| IT1087257B (it) * | 1977-10-14 | 1985-06-04 | Montedison Spa | Procedimento per concentrare acido solforino inibendo i fenomeni di corrosione |
| US4107264A (en) * | 1977-11-14 | 1978-08-15 | Allied Chemical Corporation | Recovery of TiO2 from ilmenite-type ore by a membrane based electrodialysis process |
| US4288415A (en) * | 1979-08-10 | 1981-09-08 | Nl Industries, Inc. | Process for manufacturing titanium compounds using a reducing agent |
| US4288416A (en) * | 1979-08-10 | 1981-09-08 | Nl Industries, Inc. | Process for manufacturing titanium compounds |
| DE2951749A1 (de) * | 1979-12-21 | 1981-07-02 | Bayer Ag, 5090 Leverkusen | Verfahren zur aufarbeitung von aufschlussrueckstaenden bei der titandioxidherstellung |
| DE2951799A1 (de) * | 1979-12-21 | 1981-07-02 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung einer hydrolysierbaren titanylsulfatloesung |
| DE2951746A1 (de) * | 1979-12-21 | 1981-07-02 | Bayer Ag, 5090 Leverkusen | Aufschluss ternaerer rohstoffmischungen |
| DE3343256A1 (de) * | 1983-11-30 | 1985-06-05 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von titandioxid |
| DE3513121A1 (de) * | 1985-04-12 | 1986-10-23 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von titandioxid |
| DE3513120A1 (de) * | 1985-04-12 | 1986-10-23 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von titandioxid |
| DE3537941A1 (de) * | 1985-10-25 | 1987-04-30 | Bayer Ag | Aus duennsaeure gewonnene metallsulfatsuspension, verfahren zu ihrer herstellung sowie deren verwendung |
| DE3630220A1 (de) * | 1986-09-05 | 1988-03-10 | Bayer Ag | Verfahren zur herstellung von titandioxidpigmenten |
-
1987
- 1987-11-23 CH CH4548/87A patent/CH672633A5/de not_active IP Right Cessation
- 1987-12-30 DE DE19873744575 patent/DE3744575C1/de not_active Expired
-
1988
- 1988-11-11 KR KR1019880014790A patent/KR940006034B1/ko not_active Expired - Fee Related
- 1988-11-14 DE DE8888118917T patent/DE3871496D1/de not_active Expired - Lifetime
- 1988-11-14 AT AT88118917T patent/ATE76627T1/de not_active IP Right Cessation
- 1988-11-14 ES ES88118917T patent/ES2031984T3/es not_active Expired - Lifetime
- 1988-11-14 EP EP19880118917 patent/EP0317857B1/de not_active Expired - Lifetime
- 1988-11-14 FI FI885254A patent/FI90525C/fi not_active IP Right Cessation
- 1988-11-17 US US07/273,439 patent/US5068093A/en not_active Expired - Lifetime
- 1988-11-21 CA CA 583611 patent/CA1327125C/en not_active Expired - Fee Related
- 1988-11-22 JP JP63293766A patent/JPH01164733A/ja active Granted
- 1988-11-22 AU AU25772/88A patent/AU616221B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| AU616221B2 (en) | 1991-10-24 |
| ATE76627T1 (de) | 1992-06-15 |
| KR940006034B1 (ko) | 1994-07-02 |
| FI885254A7 (fi) | 1989-05-24 |
| EP0317857B1 (de) | 1992-05-27 |
| US5068093A (en) | 1991-11-26 |
| AU2577288A (en) | 1989-05-25 |
| JPH01164733A (ja) | 1989-06-28 |
| FI885254A0 (fi) | 1988-11-14 |
| CH672633A5 (es) | 1989-12-15 |
| FI90525C (fi) | 1994-02-25 |
| EP0317857A1 (de) | 1989-05-31 |
| DE3744575C1 (de) | 1989-06-08 |
| JPH0524867B2 (es) | 1993-04-09 |
| FI90525B (fi) | 1993-11-15 |
| DE3871496D1 (de) | 1992-07-02 |
| CA1327125C (en) | 1994-02-22 |
| KR890008030A (ko) | 1989-07-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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