ES2033248T3 - Metodo para preparar composiciones curables que contienen un poliepoxido y un bisfenol halogenado. - Google Patents
Metodo para preparar composiciones curables que contienen un poliepoxido y un bisfenol halogenado.Info
- Publication number
- ES2033248T3 ES2033248T3 ES198787102617T ES87102617T ES2033248T3 ES 2033248 T3 ES2033248 T3 ES 2033248T3 ES 198787102617 T ES198787102617 T ES 198787102617T ES 87102617 T ES87102617 T ES 87102617T ES 2033248 T3 ES2033248 T3 ES 2033248T3
- Authority
- ES
- Spain
- Prior art keywords
- radical
- formula
- carbon atoms
- value
- independently
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 3
- 229920000647 polyepoxide Polymers 0.000 title abstract 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 9
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 4
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 125000005843 halogen group Chemical group 0.000 abstract 3
- 125000003700 epoxy group Chemical group 0.000 abstract 2
- 239000003822 epoxy resin Substances 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
- C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
- C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/3218—Carbocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
- C08G59/621—Phenols
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/032—Organic insulating material consisting of one material
- H05K1/0326—Organic insulating material consisting of one material containing O
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/032—Organic insulating material consisting of one material
- H05K1/034—Organic insulating material consisting of one material containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Epoxy Resins (AREA)
Abstract
Un método parala preparación de una composición que comprende: (A) por lo menos uno de los siguientes ingredientes: (1) por lo menos una resina epoxi representada por las fórmulas I, II, III, IV, V o VI **fórmula**donde cada radical A'' is independientemente un grupo hidrocarbilo divalente de uno a doce átomos de carbono, - S - , - S - S - , - SO - , - SO2 - , - CO - u - O - ; cada radical B está representada por la fórmula **fórmula** cada radical B'' está representada por la fórmula **fórmula** cada radical B" está representada por la fórmula **fórmula** cada radical R es independientemente hidrógeno o un grupo alquilo de uno a cuatro átomos de carbono; cada radical Q es independientemente hidrógeno o un grupo hidrocarbilo de uno a diez átomos de carbono; cada radical R'' es independientemente hidrógeno, un grupo hidrocarbilo o hidrocarbiloxi de uno a diez átomos de carbono o un halogeno; m tiene un valor de n - 1; m'' tiene un valor de n'' - 1; m" tiene un valor de n" - 1; cada símbolo n, n''y n" tiene independientemente un valor de 0 a 3; q tiene un valor de a 4, preferiblemente de 0,1 a 2, más preferiblemente de 0,5 a 1,5; cada y tiene independientemente un valor medio de uno a cinco; y'' tiene un valor medio de 0 a 3 y cada z y z'' tiene independientemente un valor de 0 a 3; (2) el producto de reacción de (a) por lo menos una resina epoxi como la definida en el componente (A - 1) y (a) por lo menos un fenol dihídrico o polihídrico representado por las siguientes fórmulas VII,VIII o IX **fórmula** donde A es un grupo hidrocarbonado divalente de uno a doce átomos de carbono, - O - ,-S-,-S -S -,-SO-,-SO2 - o - CO - ; cada radical A" es independientemente un grupo hidrocarbonado divalente de uno a seis átomos de carbono; cada radical Y es independientemente hidrógeno, un halogeno o un grupo hidrocarbilo o hidrocarbiloxi de uno a diezátomos de carbono; cada radical Y'' es independientemente hidrogeno, un grupo hidrocarbilo o hidrocarbiloxi de uno a diez átomos de carbono, preferiblemente de uno a cuatro átomos de carbono, un átomo de halogeno o un grupo hidroxilo; n tiene un valor de o 1; y donde los componentes (A- 2 - a) y (A- 2 -b) están presentes en cantidades tales que la relación de grupos hidroxilo fenólicos a grupos epóxido está comprendida entre 0,01:1 y 0,5:1, preferiblemente entre 0,05:1 y 0,25:1 y lo más preferiblemente entre 0,1:1 y 0,2:1; o (3) sus mezclas y (B) por lo menos un fenol dihídrico o polihídrico halogenado representado por las fórmula X, XI o XII. **fórmula** donde A, A", Y, Y'' y n son los definidos anteriormente y cada radical X es un halogeno; método que consiste en mezclar los componentes (A) y (B) en cantidades tales que la relación de grupos hidroxilo fenólicos a grupos epóxido está comprendida entre 0,7:1 a 1,1:1, estando caracterizado el citado método por emplear como por lo menos una fracción del componente (B) un fenol dihídrico halogenado donde por lo menos el 5 por ciento en peso de los átomos de halogeno presentes en el componente (B) están en la posición meta con respecto a los grupos hidroxilo.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83242886A | 1986-02-24 | 1986-02-24 | |
| US91126786A | 1986-09-24 | 1986-09-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2033248T3 true ES2033248T3 (es) | 1993-03-16 |
Family
ID=27125524
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES198787102617T Expired - Lifetime ES2033248T3 (es) | 1986-02-24 | 1987-02-24 | Metodo para preparar composiciones curables que contienen un poliepoxido y un bisfenol halogenado. |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0239784B1 (es) |
| JP (1) | JP2603630B2 (es) |
| KR (1) | KR900008737B1 (es) |
| AU (1) | AU590392B2 (es) |
| CA (1) | CA1272345A (es) |
| DE (1) | DE3778747D1 (es) |
| ES (1) | ES2033248T3 (es) |
| IL (1) | IL81654A0 (es) |
| MY (1) | MY101879A (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5503937A (en) * | 1984-07-17 | 1996-04-02 | The Dow Chemical Company | Curable composition which comprises adducts of heterocyclic compounds |
| US4727119A (en) * | 1986-09-15 | 1988-02-23 | The Dow Chemical Company | Halogenated epoxy resins |
| EP0264705A3 (en) * | 1986-10-10 | 1990-10-31 | The Dow Chemical Company | Blends of relatively low molecular weight epoxy resins and relatively high molecular weight epoxy or phenoxy resins and cured products therefrom |
| US4847348A (en) * | 1987-07-17 | 1989-07-11 | The Dow Chemical Company | Imide Modified epoxy resins |
| AU608627B2 (en) * | 1987-08-10 | 1991-04-11 | Dow Chemical Company, The | Curing agent compositions, laminating varnishes containing same and laminates prepared therefrom |
| US4868059A (en) * | 1987-11-16 | 1989-09-19 | The Dow Chemical Company | Curable composition containing a difunctional epoxy resin, a polyfunctional epoxy resin, a difunctional phenol and a polyfunctional phenol |
| IL88389A (en) * | 1987-11-30 | 1992-02-16 | Dow Chemical Co | Curable compositions and electrical or electronic components or devices encapsulated therewith |
| EP0328020B1 (en) * | 1988-02-12 | 1996-10-09 | The Dow Chemical Company | Use of a catalyst in epoxy compositions |
| US4874669A (en) * | 1988-08-15 | 1989-10-17 | The Dow Chemical Company | Curable compositions containing an epoxy resin, a difunctional phenol and a polyfunctional phenol |
| JPH07103213B2 (ja) * | 1988-10-04 | 1995-11-08 | 日本化薬株式会社 | 不飽和基含有ポリカルボン酸樹脂を含む樹脂組成物及びソルダーレジスト樹脂組成物 |
| US4892925A (en) * | 1989-01-23 | 1990-01-09 | The Dow Chemical Company | Process for preparing phenolic hydroxyl-containing compounds from 2,6-dibromo-3,5-dialkyl-4-hydroxybenzyl ethers |
| MY106546A (en) * | 1990-05-15 | 1995-06-30 | Dow Chemical Co | Advanced and unadvanced compositions, nucleophilic derivatives thereof curable and coating compositions thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL283388A (es) * | 1961-10-03 | |||
| US4604317A (en) * | 1984-10-05 | 1986-08-05 | The Dow Chemical Company | Curable compositions containing a polyepoxide and a halogenated bisphenol |
| US4661644A (en) * | 1985-09-09 | 1987-04-28 | The Dow Chemical Company | Brominated epoxyaromatic compounds |
| US4684700A (en) * | 1986-02-14 | 1987-08-04 | The Dow Chemical Company | Advanced epoxy resins prepared from triglycidyl ethers and dihydri phenols |
| US4672103A (en) * | 1986-02-14 | 1987-06-09 | The Dow Chemical Company | Non-sintering epoxy resins prepared from triglycidyl ethers and epihalohydrins |
-
1987
- 1987-02-23 CA CA000530312A patent/CA1272345A/en not_active Expired - Fee Related
- 1987-02-24 ES ES198787102617T patent/ES2033248T3/es not_active Expired - Lifetime
- 1987-02-24 AU AU69171/87A patent/AU590392B2/en not_active Ceased
- 1987-02-24 IL IL81654A patent/IL81654A0/xx not_active IP Right Cessation
- 1987-02-24 KR KR1019870001550A patent/KR900008737B1/ko not_active Expired
- 1987-02-24 MY MYPI87000185A patent/MY101879A/en unknown
- 1987-02-24 DE DE8787102617T patent/DE3778747D1/de not_active Expired - Fee Related
- 1987-02-24 EP EP87102617A patent/EP0239784B1/en not_active Expired - Lifetime
- 1987-02-24 JP JP62039338A patent/JP2603630B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| IL81654A0 (en) | 1987-09-16 |
| EP0239784A2 (en) | 1987-10-07 |
| DE3778747D1 (de) | 1992-06-11 |
| AU590392B2 (en) | 1989-11-02 |
| AU6917187A (en) | 1987-08-27 |
| CA1272345A (en) | 1990-07-31 |
| EP0239784A3 (en) | 1988-08-31 |
| JP2603630B2 (ja) | 1997-04-23 |
| JPS62265322A (ja) | 1987-11-18 |
| MY101879A (en) | 1992-02-15 |
| EP0239784B1 (en) | 1992-05-06 |
| KR900008737B1 (ko) | 1990-11-29 |
| KR870007980A (ko) | 1987-09-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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