ES2037637T3 - Polimero reticulado, absorbente de agua, y su utilizacion para la fabricacion de articulos higienicos. - Google Patents
Polimero reticulado, absorbente de agua, y su utilizacion para la fabricacion de articulos higienicos.Info
- Publication number
- ES2037637T3 ES2037637T3 ES91909230T ES91909230T ES2037637T3 ES 2037637 T3 ES2037637 T3 ES 2037637T3 ES 91909230 T ES91909230 T ES 91909230T ES 91909230 T ES91909230 T ES 91909230T ES 2037637 T3 ES2037637 T3 ES 2037637T3
- Authority
- ES
- Spain
- Prior art keywords
- polymer
- manufacture
- water absorbent
- polymerisation
- ppm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title abstract 6
- 239000002250 absorbent Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 230000002745 absorbent Effects 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 4
- 239000000178 monomer Substances 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- 239000011780 sodium chloride Substances 0.000 abstract 2
- PNKUSGQVOMIXLU-UHFFFAOYSA-N Formamidine Chemical compound NC=N PNKUSGQVOMIXLU-UHFFFAOYSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920003169 water-soluble polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Hematology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Graft Or Block Polymers (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Television Receiver Circuits (AREA)
Abstract
LA INVENCION SE REFIERE A UN POLIMERO RETICULADO, ABSORBENTE DE AGUA QUE SE PUEDE OBTENER POR LA POLIMERIZACION DE UNA MEZCLA COMPUESTA DE A) 60 A 99 % EN PESO DE MONOMEROS POLIMERIZABLES CON GRUPOS ACIDOS, NO SATURADOS QUE SE PRESENTAN AL MENOS NEUTRALIZADOS HASTA EL 30 %, B) 0 A 37 % EN PESO DE MONOMERO COPOLIMERIZABLE CON A), C) 0,1 A 3,0 % EN PESO DE UN AGENTE RETICULADO Y D) 0 A 10 % EN PESO DE UN POLIMERO SOLUBLE EN AGUA, REALIZANDOSE LA POLIMERIZACION CON UN SISTEMA CATALIZADOR REDOX, QUE CONTIENE COMO COMPONENTE REDUCTOR ACIDO SULFINICO FORMAMIDINA. EL POLIMERO ESTA CARACTERIZADO POR UNA RETENCION DE MAS DE 28 G DE SOLUCION ACUOSA AL 0,9 % DE NACL POR 1 G DE POLIMERO, UNA ABSORCION DE MAS DE 26 G DE SOLUCION ACUOSA AL 0,9 % DE NACL POR 1 G DE POLIMERO CON UNA CARGA DE 20 G/CM (AL CUADRADO) Y UN CONTENIDO DE MONOMERO RESIDUAL MENOR DE 700 PPM, CON PREFERENCIA MENOR DE 500 PPM. LA INVENCION SE REFIERE ADEMAS AL EMPLEO DE ESTE POLIMERO PARA LA PRODUCCION DE ARTICULOS HIGIENICOS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4015085A DE4015085C2 (de) | 1990-05-11 | 1990-05-11 | Vernetztes, wasserabsorbierendes Polymer und Verwendung zur Herstellung von Hygieneartikeln, zur Bodenverbesserung und in Kabelummantelungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2037637T1 ES2037637T1 (es) | 1993-07-01 |
| ES2037637T3 true ES2037637T3 (es) | 1994-12-01 |
Family
ID=6406153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES91909230T Expired - Lifetime ES2037637T3 (es) | 1990-05-11 | 1991-05-10 | Polimero reticulado, absorbente de agua, y su utilizacion para la fabricacion de articulos higienicos. |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0527867B1 (es) |
| JP (1) | JP3076853B2 (es) |
| AT (1) | ATE111924T1 (es) |
| AU (1) | AU648559B2 (es) |
| CA (1) | CA2082506A1 (es) |
| DE (2) | DE4015085C2 (es) |
| ES (1) | ES2037637T3 (es) |
| GR (1) | GR930300039T1 (es) |
| WO (1) | WO1991018031A1 (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4206850C2 (de) * | 1992-03-05 | 1996-08-29 | Stockhausen Chem Fab Gmbh | Polymerzusammensetzungen, Herstellgung von Polymerzusammensetzungen, insbesondere Absorptionsmaterialien und deren Verwendung |
| US5416160A (en) * | 1992-06-19 | 1995-05-16 | The Dow Chemical Company | Water-swellable polymers having improved color |
| DE4435422A1 (de) * | 1994-10-04 | 1996-04-18 | Basf Ag | Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion |
| DE19529348C2 (de) * | 1995-08-09 | 1997-11-20 | Stockhausen Chem Fab Gmbh | Absorptionsmittel für Wasser und wäßrige Flüssigkeiten auf Polyacrylatbasis sowie Verfahren zu ihrer Herstellung und Verwendung |
| ES2410372T3 (es) * | 1996-12-13 | 2013-07-01 | Dsg International Limited | Composiciones de material compuesto sumamente absorbente, láminas absorbentes provistas de las composiciones y proceso para la producción de las mismas |
| DE19854573A1 (de) | 1998-11-26 | 2000-05-31 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit 2-Oxo-tetrahydro-1,3-oxazinen |
| AU4690201A (en) | 2000-04-13 | 2001-10-30 | Sanyo Chemical Ind Ltd | Crosslinked polymer, process for producing the same, absorbent structure, and absorbent article |
| WO2002032975A1 (de) * | 2000-10-18 | 2002-04-25 | Basf Aktiengesellschaft | Hydrogel-bildende polymerisate |
| DE10225943A1 (de) | 2002-06-11 | 2004-01-08 | Basf Ag | Verfahren zur Herstellung von Estern von Polyalkoholen |
| WO2004037900A1 (de) * | 2002-10-25 | 2004-05-06 | Stockhausen Gmbh | Zweistufiges mischverfahren zur herstellung eines absorbierenden polymers |
| EP1736508A1 (en) | 2005-06-22 | 2006-12-27 | Basf Aktiengesellschaft | Hydrogel-forming polymers with increased permeability and high absorption capacity |
| JP2019094444A (ja) * | 2017-11-24 | 2019-06-20 | Sdpグローバル株式会社 | 吸水性樹脂粒子及びその製造方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE861155C (de) * | 1941-02-22 | 1952-12-29 | Hoechst Ag | Verfahren zur Emulsionspolymerisation bei gleichzeitiger Gegenwart von Oxydationsmitteln und Reduktionsmitteln |
| DE926091C (de) * | 1942-07-21 | 1955-04-07 | Hoechst Ag | Verfahren zur Herstellung von Polymerisaten oder Mischpolymerisaten einfach ungesaettigter Verbindungen |
| US4115339A (en) * | 1971-11-18 | 1978-09-19 | Hercules Incorporated | High molecular-weight, water-soluble vinyl polymers |
| JPS51125468A (en) * | 1975-03-27 | 1976-11-01 | Sanyo Chem Ind Ltd | Method of preparing resins of high water absorbency |
| US4286082A (en) * | 1979-04-06 | 1981-08-25 | Nippon Shokubai Kagaku Kogyo & Co., Ltd. | Absorbent resin composition and process for producing same |
| CA1178744A (en) * | 1979-07-11 | 1984-11-27 | Daniel F. Herman | Polymeric electrolytes |
| DE3124008A1 (de) * | 1981-06-19 | 1983-01-27 | Chemische Fabrik Stockhausen & Cie, 4150 Krefeld | Vernetzte, in wasser quellbare copolymerisate und ihre verwendung als absorptionsmittel fuer waessrige koerperfluessigkeiten wie urin |
| US4677174A (en) * | 1986-04-21 | 1987-06-30 | American Colloid Company | Water absorbent styrene-acrylic acid copolymers |
| DE3312424A1 (de) * | 1983-04-07 | 1984-10-11 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von perlfoermigen polymerisaten |
| US4666975A (en) * | 1984-03-05 | 1987-05-19 | Kao Corporation | Absorptive material |
| FR2575479B1 (fr) * | 1984-12-27 | 1987-02-27 | Charbonnages Ste Chimique | Copolymeres amphoteres, leur procede de fabrication et leur application a la retention d'eau |
| DE3505920A1 (de) * | 1985-02-21 | 1986-08-21 | Röhm GmbH, 6100 Darmstadt | Schwach vernetzte, in wasser schnell quellende, teilchenfoermige, feste polymerisate oder mischpolymerisate, verfahren zu ihrer herstellung und ihre verwendung in hygieneartikeln |
| US4616063A (en) * | 1985-03-06 | 1986-10-07 | Atlantic Richfield Company | Water absorbent polymer composition |
| JPS61271303A (ja) * | 1985-05-24 | 1986-12-01 | Lion Corp | 吸水性樹脂の製造方法 |
| US4654039A (en) * | 1985-06-18 | 1987-03-31 | The Proctor & Gamble Company | Hydrogel-forming polymer compositions for use in absorbent structures |
| CA1284543C (en) * | 1985-06-22 | 1991-05-28 | Kazuo Saotome | Aqueous composition, method of producing a water absorbent polymer, water absorbent polymer-coated article and method of producing the same |
| DE3605332A1 (de) * | 1986-02-19 | 1987-08-20 | Bayer Ag | Chloropren-polymerisation |
| CS263644B1 (en) * | 1986-10-16 | 1989-04-14 | Hudecek Slavko | Copolymers of acrylic or methacrylic acid or alkalic metal salts thereof |
| DE3713601A1 (de) * | 1987-04-23 | 1988-11-10 | Stockhausen Chem Fab Gmbh | Verfahren zur herstellung eines stark wasserabsorbierenden polymerisats |
| KR0130652B1 (ko) * | 1987-08-14 | 1998-04-07 | 존 휴즈 | 수분 흡수성 수지의 제조 방법 |
| US4833222A (en) * | 1987-10-22 | 1989-05-23 | The Dow Chemical Company | Crosslinker stabilizer for preparing absorbent polymers |
| DE3741158A1 (de) * | 1987-12-04 | 1989-06-15 | Stockhausen Chem Fab Gmbh | Polymerisate mit hoher aufnahmegeschwindigkeit fuer wasser und waessrige fluessigkeiten, verfahren zu ihrer herstellung und verwendung als absorptionsmittel |
| KR970009239B1 (ko) * | 1988-06-16 | 1997-06-09 | 미츠비시유카 가부시키가이샤 | 고흡수성 폴리머의 제조방법 |
-
1990
- 1990-05-11 DE DE4015085A patent/DE4015085C2/de not_active Expired - Fee Related
-
1991
- 1991-05-10 JP JP03508473A patent/JP3076853B2/ja not_active Expired - Fee Related
- 1991-05-10 EP EP91909230A patent/EP0527867B1/de not_active Expired - Lifetime
- 1991-05-10 AU AU77897/91A patent/AU648559B2/en not_active Ceased
- 1991-05-10 ES ES91909230T patent/ES2037637T3/es not_active Expired - Lifetime
- 1991-05-10 DE DE59103054T patent/DE59103054D1/de not_active Expired - Lifetime
- 1991-05-10 WO PCT/EP1991/000878 patent/WO1991018031A1/de not_active Ceased
- 1991-05-10 AT AT91909230T patent/ATE111924T1/de not_active IP Right Cessation
- 1991-05-10 CA CA002082506A patent/CA2082506A1/en not_active Abandoned
-
1993
- 1993-06-07 GR GR930300039T patent/GR930300039T1/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2037637T1 (es) | 1993-07-01 |
| WO1991018031A1 (de) | 1991-11-28 |
| EP0527867B1 (de) | 1994-09-21 |
| JPH05507508A (ja) | 1993-10-28 |
| DE4015085A1 (de) | 1991-12-12 |
| CA2082506A1 (en) | 1991-11-12 |
| DE59103054D1 (de) | 1994-10-27 |
| EP0527867A1 (de) | 1993-02-24 |
| DE4015085C2 (de) | 1995-06-08 |
| ATE111924T1 (de) | 1994-10-15 |
| AU648559B2 (en) | 1994-04-28 |
| JP3076853B2 (ja) | 2000-08-14 |
| GR930300039T1 (en) | 1993-06-07 |
| AU7789791A (en) | 1991-12-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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