ES2038419T3 - Polvo de silice y metodo para su produccion. - Google Patents
Polvo de silice y metodo para su produccion.Info
- Publication number
- ES2038419T3 ES2038419T3 ES198989312694T ES89312694T ES2038419T3 ES 2038419 T3 ES2038419 T3 ES 2038419T3 ES 198989312694 T ES198989312694 T ES 198989312694T ES 89312694 T ES89312694 T ES 89312694T ES 2038419 T3 ES2038419 T3 ES 2038419T3
- Authority
- ES
- Spain
- Prior art keywords
- silicon
- inert gas
- pressure
- melted
- atomized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 13
- 229910052710 silicon Inorganic materials 0.000 abstract 8
- 239000010703 silicon Substances 0.000 abstract 8
- 239000011261 inert gas Substances 0.000 abstract 5
- 239000011863 silicon-based powder Substances 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 238000000889 atomisation Methods 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 230000006835 compression Effects 0.000 abstract 1
- 238000007906 compression Methods 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000007670 refining Methods 0.000 abstract 1
- 238000012216 screening Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/02—Silicon
- C01B33/021—Preparation
- C01B33/023—Preparation by reduction of silica or free silica-containing material
- C01B33/025—Preparation by reduction of silica or free silica-containing material with carbon or a solid carbonaceous material, i.e. carbo-thermal process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/02—Silicon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/16—Preparation thereof from silicon and halogenated hydrocarbons direct synthesis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicon Compounds (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Medicinal Preparation (AREA)
- Powder Metallurgy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A UN POLVO DE SILICIO, PRODUCIDO MEDIANTE LA ATOMIZACION GASEOSA DE SILICIO FUNDIDO, CUYAS PARTICULAS TIENEN UN TAMAÑO QUE OSCILA ENTRE 0,1 Y 1.000 (MU)M, UN AREA ESPECIFICA ENTRE 0,001 Y 1 M (AL CUADRADO) /G, Y LA SIGUIENTE COMPOSICION QUIMICA CON LOS SIGUIENTES PORCENTAJES DE PESO: 0,1 1% DE HIERRO, 0,01 - 1% DE ALUMINIO, 0 - 8% DE COBRE, 0 - 1% DE CALCIO, 0 - 1% DE ZINC, 0 - 1% DE ESTAÑO, 0 - 5% DE BORO, 0 - 0,5% DE FOSFORO, 0 - 0,5% DE SODIO, 0 - 0,5% DE LITIO, 0 - 0,5 DE POTASIO, 0 - 0,5% DE MAGNESIO, 0 - 0,5% DE ESTRONCIO, 0, - 0,5% DE BARIO, 0 - 0,5% DE BERILIO, SIENDO EL RESTO DE SILICIO Y MENOS DE UN 0,3% DE IMPUREZAS COMO TI, V, CR, MO, W Y ZR. EL POLVO DE SILICIO SE PRODUCE CONTINUAMENTE MEDIANTE UN METODO QUE CONSTA DE LOS SIGUIENTES PASOS: A) PRODUCCION CONTINUA DE SILICIO EN UN HORNO ELECTRICO DE FUNDICION B) REFINO Y ALEACION DEL SILICIO FUNDIDO EN UN RECIPIENTE PARA TRATAMIENTO DE METALES C) SUMINISTRO CONTINUO A UN HORNO DE CONSERVACION DELSILICIO FUNDIDO DEL RECIPIENTE PARA TRATAMIENTO DE METALES D) SUMINISTRO CONTINUO DEL SILICIO FUNDIDO A UN APARATO ATOMIZADOR CERRADO EN DONDE EL SILICIO FUNDIDO SE ATOMIZA MEDIANTE UN GAS INERTE SUMINISTRADO DESDE EL RECIPIENTE DE PRESION O UNA UNIDAD COMPRESORA E) ELIMINACION CONTINUA DEL POLVO DE SILICIO ATOMIZADO DEL APARATO ATOMIZADOR F) SEPARACION DEL POLVO DE SILICIO ATOMIZADO Y GAS INERTE EN UN SEPARADOR SOLIDO/GASEOSO G) CRIBADO DEL POLVO DE SILICIO EN FRACCIONES PRE-ESTABLECIDAS DEL TAMAÑO DE LAS PARTICULAS H) SUMINISTRO A SILOS CERRADOS DE LAS DISTINTAS FRACCIONES DEL TAMAÑO DE LAS PARTICULAS DE POLVO DE SILICIO I) FILTRACION DEL GAS INERTE DEL PASO F) PARA LA ELIMINACION DE CUALQUIER PARTICULA SOLIDA DEL GAS INERTE J) ENFRIAMIENTO Y COMPRESION DEL GAS INERTE DEL PASO I) Y RECICLAJE DEL GAS INERTE COMPRIMIDO AL RECIPIENTE DE PRESION O DIRECTAMENTE AL APARATO ATOMIZADOR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO885453A NO165288C (no) | 1988-12-08 | 1988-12-08 | Silisiumpulver og fremgangsmaate for fremstilling av silisiumpulver. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2038419T3 true ES2038419T3 (es) | 1993-07-16 |
Family
ID=19891499
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES198989312694T Expired - Lifetime ES2038419T3 (es) | 1988-12-08 | 1989-12-06 | Polvo de silice y metodo para su produccion. |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US5128116A (es) |
| EP (1) | EP0372918B1 (es) |
| JP (1) | JPH02204320A (es) |
| CN (1) | CN1024412C (es) |
| AR (1) | AR242760A1 (es) |
| AT (1) | ATE86947T1 (es) |
| AU (1) | AU622247B2 (es) |
| BR (1) | BR8906362A (es) |
| CA (1) | CA2003167C (es) |
| DE (1) | DE68905448T2 (es) |
| ES (1) | ES2038419T3 (es) |
| NO (1) | NO165288C (es) |
| RU (1) | RU2055812C1 (es) |
| YU (1) | YU47501B (es) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4115183A1 (de) * | 1991-05-09 | 1992-11-12 | Bayer Ag | Feinteiliges silicium mit oberflaechlich gebundenem halogen, verfahren zu dessen herstellung und dessen verwendung |
| US5177234A (en) * | 1991-06-03 | 1993-01-05 | Dow Corning Corporation | Preparation of alkoxysilanes by contacting a solution of hydrogen fluoride in an alcohol with silicon |
| NO174165C (no) * | 1992-01-08 | 1994-03-23 | Elkem Aluminium | Fremgangsmåte ved kornforfining av aluminium samt kornforfiningslegering for utförelse av fremgangsmåten |
| US5833772A (en) * | 1992-11-18 | 1998-11-10 | Elkem Asa | Silicon alloy, method for producing the alloy and method for production of consolidated products from silicon |
| DE4303766A1 (de) * | 1993-02-09 | 1994-08-11 | Wacker Chemie Gmbh | Verfahren zur Herstellung von Methylchlorsilanen |
| FR2707619B1 (fr) * | 1993-07-01 | 1995-09-01 | Pechiney Electrometallurgie | Silicium métallurgique contenant du phosphore et destiné à la préparation des alkyl ou aryl halogénosilanes. |
| FR2716675B1 (fr) * | 1994-02-25 | 1996-04-12 | Pechiney Electrometallurgie | Silicium métallurgique à microstructure contrôlée pour la préparation des halogénosilanes. |
| FR2720385B1 (fr) * | 1994-05-31 | 1996-07-05 | Pechiney Electrometallurgie | Alliage de silicium pour la synthèse des alkyl ou aryl halogénosilanes contenant de l'aluminium, du calcium et du cuivre. |
| FR2723325B1 (fr) | 1994-08-04 | 1996-09-06 | Pechiney Electrometallurgie | Procede de preparation de granules de silicium a partir de metal fondu |
| FR2729131B1 (fr) * | 1995-01-09 | 1997-02-14 | Pechiney Electrometallurgie | Silicium et ferrosilicium metallurgique a basse teneur en oxygene |
| CN1089724C (zh) * | 1997-01-14 | 2002-08-28 | 武汉大学 | 高纯球形无定形硅微粉 |
| JP3346222B2 (ja) * | 1997-05-13 | 2002-11-18 | 信越化学工業株式会社 | アルキルハロシラン製造用触体の製造方法及びアルキルハロシランの製造方法 |
| US6025513A (en) * | 1997-06-27 | 2000-02-15 | Shin-Etsu Chemical Co., Ltd. | Preparation of alkylhalosilanes |
| US6638491B2 (en) | 2001-09-21 | 2003-10-28 | Neptec Optical Solutions, Inc. | Method of producing silicon metal particulates of reduced average particle size |
| US7175685B1 (en) * | 2002-04-15 | 2007-02-13 | Gt Solar Incorporated | Dry conversion of high purity ultrafine silicon powder to densified pellet form for silicon melting applications |
| US20070148034A1 (en) * | 2002-04-15 | 2007-06-28 | Gt Solar Incorporated | Dry conversion of high purity ultrafine silicon powder to densified pellet form for silicon melting applications |
| NO20022881L (no) * | 2002-06-17 | 2003-12-18 | Elkem Materials | Fremgangsmåte og apparatur for granulering av metallsmelter |
| US6780219B2 (en) * | 2002-07-03 | 2004-08-24 | Osram Sylvania Inc. | Method of spheridizing silicon metal powders |
| DE10353995A1 (de) | 2003-11-19 | 2005-06-09 | Degussa Ag | Nanoskaliges, kristallines Siliciumpulver |
| GB2409924A (en) * | 2004-01-06 | 2005-07-13 | Psimedica Ltd | Method of making a silicon-phosphorus composite |
| US20060105105A1 (en) * | 2004-11-12 | 2006-05-18 | Memc Electronic Materials, Inc. | High purity granular silicon and method of manufacturing the same |
| CN100357696C (zh) * | 2005-10-21 | 2007-12-26 | 刘继清 | 竖式热管冷却机 |
| US7429672B2 (en) * | 2006-06-09 | 2008-09-30 | Momentive Performance Materials Inc. | Process for the direct synthesis of trialkoxysilane |
| US7820126B2 (en) * | 2006-08-18 | 2010-10-26 | Iosil Energy Corporation | Method and apparatus for improving the efficiency of purification and deposition of polycrystalline silicon |
| GB0708385D0 (en) * | 2007-05-01 | 2007-06-06 | Atomising Systems Ltd | Method and apparatus for the gas atomisation of molten metal |
| US20080308970A1 (en) * | 2007-06-15 | 2008-12-18 | General Electric Company | Process for melting silicon powders |
| US20110059002A1 (en) * | 2008-04-11 | 2011-03-10 | John Allan Fallavollita | Methods and apparatus for recovery of silicon and silicon carbide from spent wafer-sawing slurry |
| CN103058194B (zh) | 2008-09-16 | 2015-02-25 | 储晞 | 生产高纯颗粒硅的反应器 |
| CN101857231A (zh) * | 2010-05-14 | 2010-10-13 | 长沙康晶硅业有限公司 | 一种超反应活性金属硅粉 |
| NO334216B1 (no) * | 2010-08-13 | 2014-01-13 | Elkem As | Fremgangsmåte for fremstilling av triklorsilan og silisium for bruk ved fremstilling av triklorsilan |
| JP2012081385A (ja) * | 2010-10-07 | 2012-04-26 | Disco Corp | 分離装置 |
| DE102011100884B4 (de) * | 2011-05-08 | 2015-03-05 | Centrotherm Photovoltaics Ag | Verfahren und vorrichtung zum entfernen von verunreinigungen aus metallurgischem silizium |
| DE102011112662B4 (de) * | 2011-05-08 | 2015-04-09 | Centrotherm Photovoltaics Ag | Verfahren zum Behandeln von metallurgischem Silizium |
| JP5148784B1 (ja) * | 2012-02-13 | 2013-02-20 | シャープ株式会社 | シリコン精製装置 |
| CN103043665B (zh) * | 2013-01-24 | 2014-11-26 | 厦门大学 | 一种硅粉的制备方法 |
| CN104151343B (zh) * | 2014-07-21 | 2016-09-07 | 鲁西化工集团股份有限公司硅化工分公司 | 一种提高甲基氯硅烷合成中硅粉利用率的添加剂 |
| CN104841213A (zh) * | 2015-05-25 | 2015-08-19 | 云南省龙陵县龙山硅有限责任公司 | 一种硅微粉回收再利用系统 |
| RU2592629C1 (ru) * | 2015-07-23 | 2016-07-27 | Борис Павлович Чесноков | Способ получения кремния |
| KR20190112809A (ko) | 2017-02-09 | 2019-10-07 | 와커 헤미 아게 | 리튬 이온 배터리의 애노드 재료를 위한 규소 입자 |
| CN107285319A (zh) * | 2017-06-27 | 2017-10-24 | 亚洲硅业（青海）有限公司 | 一种颗粒硅籽晶及其制备方法 |
| FR3083465B1 (fr) | 2018-07-03 | 2020-07-17 | Institut Polytechnique De Grenoble | Procede et dispositif de granulation |
| NL2021507B1 (en) * | 2018-08-28 | 2020-03-09 | Space Xyz B V | Assembly and method for producing metal powder |
| CN109482892B (zh) * | 2018-12-28 | 2024-01-23 | 山东重山光电材料股份有限公司 | 一种锂硅合金的生产方法及生产装置 |
| CN111634915A (zh) * | 2020-06-12 | 2020-09-08 | 将乐三晶新材料有限公司 | 熔融金属硅雾化制粉工艺 |
| CN114247892A (zh) * | 2021-12-24 | 2022-03-29 | 江苏永炬锻造有限公司 | 一种基于粉末冶金的模具钢的制备方法 |
| US20240309024A1 (en) | 2023-03-14 | 2024-09-19 | Momentive Performance Materials Inc. | Direct synthesis of alkenylhalosilanes |
| KR20260002708A (ko) | 2023-04-19 | 2026-01-06 | 모멘티브 퍼포먼스 머티리얼즈 인크. | 구리-알루미늄 합금 촉매를 이용한 알콕시실란의 직접 합성 |
| KR20260046213A (ko) | 2023-09-07 | 2026-04-06 | 와커 헤미 아게 | 하류 공정을 위한 실리콘의 연속 용융 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3592391A (en) * | 1969-01-27 | 1971-07-13 | Knapsack Ag | Nozzle for atomizing molten material |
| US4298423A (en) * | 1976-12-16 | 1981-11-03 | Semix Incorporated | Method of purifying silicon |
| SE412712B (sv) * | 1978-07-21 | 1980-03-17 | Asea Ab | Forfarande och anleggning for framstellning av pulver genom granulering av smelta |
| US4347199A (en) * | 1981-03-02 | 1982-08-31 | Dow Corning Corporation | Method and apparatus for rapidly freezing molten metals and metalloids in particulate form |
| US4374633A (en) * | 1981-03-16 | 1983-02-22 | Hart Robert J | Apparatus for the continuous manufacture of finely divided metals, particularly magnesium |
| DE3129009A1 (de) * | 1981-07-22 | 1983-02-10 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zum herstellen von fuer solarzellen verwendbarem silizium |
| DE3223821A1 (de) * | 1982-06-25 | 1983-12-29 | Siemens AG, 1000 Berlin und 8000 München | Verfahren und vorrichtung zum herstellen von hochreinnem siliciumgranulat |
| US4419060A (en) * | 1983-03-14 | 1983-12-06 | Dow Corning Corporation | Apparatus for rapidly freezing molten metals and metalloids in particulate form |
| DE3311343C2 (de) * | 1983-03-29 | 1987-04-23 | Alfred Prof. Dipl.-Ing.Dr.-Ing. 7830 Emmendingen Walz | Verfahren zur Herstellung von feinen Metallpulvern sowie Vorrichtung zur Durchführung des Verfahrens |
| US4564401A (en) * | 1983-09-29 | 1986-01-14 | Crucible Materials Corporation | Method for producing iron-silicon alloy articles |
| US4612179A (en) * | 1985-03-13 | 1986-09-16 | Sri International | Process for purification of solid silicon |
| GB8527852D0 (en) * | 1985-11-12 | 1985-12-18 | Osprey Metals Ltd | Atomization of metals |
| US4680096A (en) * | 1985-12-26 | 1987-07-14 | Dow Corning Corporation | Plasma smelting process for silicon |
-
1988
- 1988-12-08 NO NO885453A patent/NO165288C/no not_active IP Right Cessation
-
1989
- 1989-11-16 CA CA002003167A patent/CA2003167C/en not_active Expired - Fee Related
- 1989-12-04 AR AR89315599A patent/AR242760A1/es active
- 1989-12-05 JP JP1314471A patent/JPH02204320A/ja active Granted
- 1989-12-06 EP EP89312694A patent/EP0372918B1/en not_active Expired - Lifetime
- 1989-12-06 ES ES198989312694T patent/ES2038419T3/es not_active Expired - Lifetime
- 1989-12-06 AT AT89312694T patent/ATE86947T1/de not_active IP Right Cessation
- 1989-12-06 DE DE89312694T patent/DE68905448T2/de not_active Expired - Fee Related
- 1989-12-07 YU YU231089A patent/YU47501B/sh unknown
- 1989-12-07 RU SU894742789A patent/RU2055812C1/ru active
- 1989-12-07 AU AU46048/89A patent/AU622247B2/en not_active Ceased
- 1989-12-08 BR BR898906362A patent/BR8906362A/pt not_active IP Right Cessation
- 1989-12-08 CN CN89109112A patent/CN1024412C/zh not_active Expired - Fee Related
-
1990
- 1990-01-11 US US07/450,674 patent/US5128116A/en not_active Expired - Fee Related
- 1990-12-10 US US07/627,543 patent/US5094832A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| NO885453L (no) | 1990-06-11 |
| EP0372918A2 (en) | 1990-06-13 |
| US5128116A (en) | 1992-07-07 |
| AU622247B2 (en) | 1992-04-02 |
| AR242760A1 (es) | 1993-05-31 |
| NO885453D0 (no) | 1988-12-08 |
| DE68905448D1 (de) | 1993-04-22 |
| NO165288C (no) | 1991-01-23 |
| NO165288B (no) | 1990-10-15 |
| RU2055812C1 (ru) | 1996-03-10 |
| JPH02204320A (ja) | 1990-08-14 |
| YU231089A (en) | 1991-02-28 |
| CA2003167A1 (en) | 1990-06-08 |
| JPH05333B2 (es) | 1993-01-05 |
| CA2003167C (en) | 1996-12-10 |
| US5094832A (en) | 1992-03-10 |
| YU47501B (sh) | 1995-10-03 |
| EP0372918A3 (en) | 1991-07-24 |
| BR8906362A (pt) | 1990-08-21 |
| CN1024412C (zh) | 1994-05-04 |
| AU4604889A (en) | 1990-06-14 |
| EP0372918B1 (en) | 1993-03-17 |
| CN1043112A (zh) | 1990-06-20 |
| DE68905448T2 (de) | 1993-10-14 |
| ATE86947T1 (de) | 1993-04-15 |
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