ES2040141T3 - Procedimiento para preparar 1,3-propanodiol. - Google Patents

Procedimiento para preparar 1,3-propanodiol.

Info

Publication number
ES2040141T3
ES2040141T3 ES199191118212T ES91118212T ES2040141T3 ES 2040141 T3 ES2040141 T3 ES 2040141T3 ES 199191118212 T ES199191118212 T ES 199191118212T ES 91118212 T ES91118212 T ES 91118212T ES 2040141 T3 ES2040141 T3 ES 2040141T3
Authority
ES
Spain
Prior art keywords
chelate
earth metal
hydration
acrolein
anchor groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES199191118212T
Other languages
English (en)
Inventor
Dietrich Dr. Arntz
Norbert Dr. Wiegand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH filed Critical Degussa GmbH
Application granted granted Critical
Publication of ES2040141T3 publication Critical patent/ES2040141T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/64—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of functional groups containing oxygen only in singly bound form

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Saccharide Compounds (AREA)
  • Steroid Compounds (AREA)

Abstract

EL PROCEDIMIENTO SE BASA EN LA HIDRATIZACION DE ACROLEINA EN PRESENCIA DE UNA RESINA INTERCAMBIADORA DE IONES FORMANDO GELATINA EN BASE A POLIESTEROL /BENCENO DIVINILO COMO CATALIZADOR Y DE LA HIDRATIZACION RESULTANTE DE LA MEZCLA REACCIONANTE QUE CONTIENE 3-ALDEHIDOHIDROXIPROPIONICO LIBERADO DE LA ACROLEINA NO TRANSFORMADA. A TRAVES DE LA UTILIZACION DE INTERCAMBIOS DE IONES FORMANDO GELATINA CON GRUPOS DE ANCLAJE CON LA FORMULA GENERAL DONDE Z = H, C SUB 1-C SUB 6-ALQUILO, -CH SUB 2-CH(CH SUB 3)-Y'' O -(CH SUB 2) SUB 0-Y" Y Y Y/O Y'' = -COOH, -OH, PIRIDILO O -P-(O) (CH SUB 2 OH) OH, TRANSCURRE LA HIDRATIZACION CON TEMPERATURAS BAJAS CON MAS ALTO RENDIMIENTO DE TIEMPO Y ESPACIO Y ESPECIALMENTE UNA MAS ALTA SELECTIVIDAD, COMO EN LA UTILIZACION DE INTERCAMBIADORES DE IONES YA CONOCIDOS. PARTICULARMENTE SON APROPIADAS RESINAS CON GRUPOS DE ANCLAJE DE ACIDO AMINO ACETICO DE METILENO EN LA FORMA DE H O PARCIALMENTE DOTADAS CON IONES DE ALCALI-, ALCALINOTERREO
ES199191118212T 1990-11-30 1991-10-25 Procedimiento para preparar 1,3-propanodiol. Expired - Lifetime ES2040141T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4038192A DE4038192A1 (de) 1990-11-30 1990-11-30 Verfahren zur herstellung von 1,3-propandiol

Publications (1)

Publication Number Publication Date
ES2040141T3 true ES2040141T3 (es) 1993-10-01

Family

ID=6419276

Family Applications (1)

Application Number Title Priority Date Filing Date
ES199191118212T Expired - Lifetime ES2040141T3 (es) 1990-11-30 1991-10-25 Procedimiento para preparar 1,3-propanodiol.

Country Status (12)

Country Link
US (1) US5171898A (es)
EP (1) EP0487903B1 (es)
JP (1) JP2735717B2 (es)
KR (1) KR0174744B1 (es)
AT (1) ATE88171T1 (es)
AU (1) AU636805B2 (es)
BR (1) BR9105175A (es)
CA (1) CA2056681C (es)
DE (2) DE4038192A1 (es)
DK (1) DK0487903T3 (es)
ES (1) ES2040141T3 (es)
TW (1) TW311133B (es)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4138982A1 (de) * 1991-11-27 1993-06-03 Degussa Verfahren zur herstellung von 3-hydroxyalkanalen
DE4218282A1 (de) * 1992-06-03 1993-12-09 Degussa Verfahren zur Herstellung von 1,3-Propandiol
DE4222708A1 (de) * 1992-07-10 1994-01-13 Degussa Verfahren zur Herstellung von 1,3-Propandiol
DE4238492C2 (de) * 1992-11-14 1995-06-14 Degussa Verfahren zur Herstellung von 1,2- und 1,3-Propandiol
JP3342973B2 (ja) * 1994-11-22 2002-11-11 株式会社日本触媒 ヒドロキシアルカナールの製造方法
JP3274301B2 (ja) 1994-11-22 2002-04-15 株式会社日本触媒 ヒドロキシアルカナールの製造方法
US5811591A (en) * 1994-11-22 1998-09-22 Nippon Shokubai Co., Ltd. Process of producing hydroxyalkanal
DE19703383A1 (de) * 1997-01-30 1998-08-06 Degussa Verfahren zur Herstellung von 1,3-Propandiol
US5962745A (en) * 1997-02-14 1999-10-05 E. I. Du Pont De Nemours And Company Process for preparing 3-hydroxyalkanals
US6342646B1 (en) * 1999-07-30 2002-01-29 E. I. Du Pont De Nemours And Company Catalytic hydrogenation of 3-hydroxypropanal to 1,3-propanediol
US6284930B1 (en) * 1999-07-30 2001-09-04 E.I. Du Pont De Nemours And Company Process for the preparation of 3-hydroxypropanal
KR100337447B1 (ko) * 1999-08-27 2002-05-23 정몽혁 코발트 촉매 하에서 다치환된 구아니딘 화합물을 촉진제로 사용하는 1,3-프로판디올의 제조 방법
WO2001053573A1 (en) * 2000-01-20 2001-07-26 E.I. Du Pont De Nemours And Company Method for high-speed spinning of bicomponent fibers
US6692687B2 (en) 2000-01-20 2004-02-17 E. I. Du Pont De Nemours And Company Method for high-speed spinning of bicomponent fibers
TWI266760B (en) 2000-03-20 2006-11-21 Kvaerner Process Tech Ltd Process for the preparation of propane-1,3-diol
TWI224591B (en) * 2001-03-02 2004-12-01 Asahi Kasei Corp Process for the production of 1,3-propanediol
ATE340642T1 (de) * 2002-08-15 2006-10-15 Velocys Inc Verfahren in mikrokanalreaktoren mit gebundenem katalysator und einen gebundenen katalysator oder gebundene chirale hilfsmittel enthaltende systeme
US7276634B2 (en) 2002-10-03 2007-10-02 Shell Oil Company Reduction of the viscosity of reactive heavy byproducts during the production of 1,3-propanediol
US7342142B2 (en) * 2003-05-06 2008-03-11 E.I. Du Pont De Nemours And Company Hydrogenation of polytrimethylene ether glycol
US7084311B2 (en) * 2003-05-06 2006-08-01 E. I. Du Pont De Nemours And Company Hydrogenation of chemically derived 1,3-propanediol
US7323539B2 (en) * 2003-05-06 2008-01-29 E. I. Du Pont De Nemours And Company Polytrimethylene ether glycol and polytrimethylene ether ester with excellent quality
US7358211B2 (en) * 2004-11-24 2008-04-15 E.I. Du Pont De Nemours And Company Catalyst for the production of 1,3-propanediol by catalytic hydrogenation of 3-hydroxypropanal
CN100417443C (zh) * 2006-03-29 2008-09-10 上海华谊丙烯酸有限公司 一种丙烯醛水合制3-羟基丙醛的新型树脂催化剂及其应用
JP5755995B2 (ja) * 2011-10-26 2015-07-29 株式会社日立製作所 超臨界水を用いた反応プロセス
CN112062663B (zh) * 2019-06-11 2022-04-22 万华化学集团股份有限公司 一种丙烯醛水合制备3-羟基丙醛的方法
CN110204422B (zh) * 2019-07-01 2022-06-10 宁波环洋新材料股份有限公司 一种由丙烯醛制备1,3-丙二醇的方法
CN113105315B (zh) * 2021-04-14 2023-09-22 上海师范大学 一种连续催化反应合成高浓度3-羟基丙醛的方法
CN114392768B (zh) * 2022-01-13 2023-11-10 江苏扬农化工集团有限公司 一种烯醛水合制备羟基醛的催化剂及其方法
CN116573987B (zh) * 2023-04-23 2025-04-11 中国科学院宁波材料技术与工程研究所 一种制备1,3-二羟基丙烷的方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3536763A (en) * 1967-08-30 1970-10-27 Du Pont Hydration of acrolein to hydracrylaldehyde
US3518310A (en) * 1968-02-09 1970-06-30 Shell Oil Co Preparation of beta-hydroxypropionaldehyde and beta-alkoxypropionaldehydes
DE2054601C3 (de) * 1970-11-06 1980-02-14 Ruhrchemie Ag, 4200 Oberhausen- Holten Verfahren zur Herstellung von zweiwertigen Alkoholen
DE2057399B2 (de) * 1970-11-21 1978-12-21 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Acetaten des 13-Propandiols
US4031038A (en) * 1975-06-16 1977-06-21 The Dow Chemical Company Water insoluble chelate exchange resins having a crosslinked polymer matrix and pendant thereto a plurality of methyleneaminopyridine groups
DE3130610A1 (de) * 1981-08-01 1983-02-10 Skf Kugellagerfabriken Gmbh, 8720 Schweinfurt Verfahren zur herstellung von waelzlagerkaefigen aus blech
GB8817051D0 (en) * 1988-07-18 1988-08-24 Dow Stade Gmbh Ion exchange resins beads & processes for preparing them
DE3926136A1 (de) * 1989-08-08 1991-02-14 Degussa Verfahren zur herstellung von 1,3-propandiol

Also Published As

Publication number Publication date
DE4038192A1 (de) 1992-06-04
DK0487903T3 (da) 1993-05-17
US5171898A (en) 1992-12-15
EP0487903B1 (de) 1993-04-14
TW311133B (es) 1997-07-21
AU8829791A (en) 1992-06-04
BR9105175A (pt) 1992-07-21
JPH04300844A (ja) 1992-10-23
EP0487903A2 (de) 1992-06-03
ATE88171T1 (de) 1993-04-15
CA2056681A1 (en) 1992-05-31
AU636805B2 (en) 1993-05-06
CA2056681C (en) 2000-10-24
KR0174744B1 (ko) 1999-04-01
DE59100082D1 (de) 1993-05-19
EP0487903A3 (en) 1992-07-15
JP2735717B2 (ja) 1998-04-02
KR920009750A (ko) 1992-06-25

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