ES2041674T3 - Desactivacion de catalizadores de sal de fosfonio. - Google Patents
Desactivacion de catalizadores de sal de fosfonio.Info
- Publication number
- ES2041674T3 ES2041674T3 ES198787200731T ES87200731T ES2041674T3 ES 2041674 T3 ES2041674 T3 ES 2041674T3 ES 198787200731 T ES198787200731 T ES 198787200731T ES 87200731 T ES87200731 T ES 87200731T ES 2041674 T3 ES2041674 T3 ES 2041674T3
- Authority
- ES
- Spain
- Prior art keywords
- deactivation
- phosphony
- salt catalysts
- sulphonic acid
- phosphonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 230000009849 deactivation Effects 0.000 title abstract 2
- 150000003839 salts Chemical class 0.000 title 1
- -1 hydrocarbyl phosphonium salt Chemical class 0.000 abstract 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 abstract 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 150000004714 phosphonium salts Chemical class 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/688—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
PROCESO PARA DESACTIVAR UN CATALIZADOR DE SAL HIDROCARBIL FOSFONIO EN UNA REACCION DE FUSION DE RESINA EPOXI POR CONTACTO CON UN ACIDO SULFONICO, TAL COMO ACIDO P-TOLUENSULDONICO O ACIDO METANO SULFONICO. ELPROCESO ES ESPECIALMENTE CONVENIENTE PARA DESACTIVACION DE SALES DE FOSFONIO RESISTENTES A LA HUMEDAD TALES COMO METILEN BIS (HALUROS DE TRIMETILFOSFONIO).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/858,311 US4692504A (en) | 1986-04-30 | 1986-04-30 | Deactivation of phosphonium salt catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2041674T3 true ES2041674T3 (es) | 1993-12-01 |
Family
ID=25328000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES198787200731T Expired - Lifetime ES2041674T3 (es) | 1986-04-30 | 1987-04-15 | Desactivacion de catalizadores de sal de fosfonio. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4692504A (es) |
| EP (1) | EP0244015B1 (es) |
| JP (1) | JPS62262749A (es) |
| KR (1) | KR870010101A (es) |
| CN (1) | CN1009650B (es) |
| AT (1) | ATE78274T1 (es) |
| AU (1) | AU584796B2 (es) |
| BR (1) | BR8702060A (es) |
| CA (1) | CA1309548C (es) |
| DE (1) | DE3780349T2 (es) |
| ES (1) | ES2041674T3 (es) |
| GR (1) | GR3005295T3 (es) |
| ZA (1) | ZA873012B (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5503937A (en) * | 1984-07-17 | 1996-04-02 | The Dow Chemical Company | Curable composition which comprises adducts of heterocyclic compounds |
| US4946817A (en) * | 1984-07-17 | 1990-08-07 | The Dow Chemical Company | Latent catalysts for epoxy-containing compounds |
| US5202051A (en) * | 1987-04-29 | 1993-04-13 | Shell Oil Company | Stabilization of epoxy/nitroparaffin solutions |
| US4933420A (en) * | 1988-09-23 | 1990-06-12 | The Dow Chemical Company | Epoxy resins containing phosphonium catalysts |
| US4939112A (en) * | 1988-10-06 | 1990-07-03 | James River Paper Company, Inc. | Catalyst for synthesis of vesicular phenoxy resins |
| US5310854A (en) * | 1989-08-23 | 1994-05-10 | The Dow Chemical Company | Epoxy resin composition and process therefor |
| US5208317A (en) * | 1990-02-06 | 1993-05-04 | The Dow Chemical Company | Composition comprising epoxy resin and cationic amine phosphonium catalyst |
| US4981926A (en) * | 1990-02-06 | 1991-01-01 | The Dow Chemical Company | Composition of epoxy resin, amino group-containing phosphonium catalyst and curing agent |
| US5140079A (en) * | 1990-02-06 | 1992-08-18 | The Dow Chemical Company | Latent, curable, catalyzed mixtures of epoxy-containing and phenolic-hydroxyl-containing compounds containing compounds or complexes formed from contacting organic phosphines or arsines with weak nucleophilic acids |
| ZA913801B (en) * | 1990-05-21 | 1993-01-27 | Dow Chemical Co | Latent catalysts,cure-inhibited epoxy resin compositions and laminates prepared therefrom |
| US5169473A (en) * | 1990-05-21 | 1992-12-08 | The Dow Chemical Company | Latent catalysts, epoxy compositions incorporating same, and coating, impregnating and bonding methods employing the compositions |
| US5721323A (en) * | 1990-05-21 | 1998-02-24 | The Dow Chemical Company | Cure inhibited epoxy resin compositions and laminates prepared from the compositions |
| US5202407A (en) * | 1992-01-24 | 1993-04-13 | The Dow Chemical Company | Precatalyzed catalyst compositions, process for preparing epoxy resins curable compositions, articles resulting from curing the resultant compositions |
| DE19547786A1 (de) * | 1995-12-20 | 1997-06-26 | Basf Lacke & Farben | Aufbau von modifizierten Epoxidharzen für die kathodische Elektrotauchlackierung mit Katalysator-Desaktivierung und Diolmodifizierung |
| JP2004210672A (ja) * | 2002-12-27 | 2004-07-29 | Nippon Chem Ind Co Ltd | ビスホスホニウム塩化合物及びその製造方法 |
| CN1319446C (zh) * | 2004-09-27 | 2007-06-06 | 深圳市绿微康生物工程有限公司 | 新型生物农药-松刚霉素生产方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3477990A (en) * | 1967-12-07 | 1969-11-11 | Shell Oil Co | Process for reacting a phenol with an epoxy compound and resulting products |
| US3547885A (en) * | 1968-03-08 | 1970-12-15 | Sun Oil Co | Process for curing polyepoxides with anhydrides and phosphonium halide catalysts therefor |
| DE2416227C3 (de) * | 1974-04-03 | 1980-04-30 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Entfernung von Katalysatoren aus flüssigen Reaktionsgemischen |
| US3978027A (en) * | 1975-05-07 | 1976-08-31 | Shell Oil Company | Process for reacting a phenol with an epoxy compound |
| US4410596A (en) * | 1980-12-04 | 1983-10-18 | The Dow Chemical Co. | Process for preparing epoxy resins having improved physical properties when cured |
| US4352918A (en) * | 1980-12-04 | 1982-10-05 | The Dow Chemical Company | Process for preparing epoxy resins having improved physical properties when cured using quaternary phosphonium catalysts |
| US4370465A (en) * | 1980-12-04 | 1983-01-25 | The Dow Chemical Co. | Epoxy resins having improved physical properties when cured |
| US4366295A (en) * | 1981-06-01 | 1982-12-28 | The Dow Chemical Company | Stable precatalyzed epoxy resin compositions |
| US4496709A (en) * | 1982-06-23 | 1985-01-29 | The Dow Chemical Company | Process for preparing epoxy resins employing a phosphonium trifluoroacetate catalyst |
| US4438254A (en) * | 1983-02-28 | 1984-03-20 | The Dow Chemical Company | Process for producing epoxy resins |
| GB8420817D0 (en) * | 1984-08-16 | 1984-09-19 | Dow Chemical Rheinwerk Gmbh | Preparing epoxy resins |
-
1986
- 1986-04-30 US US06/858,311 patent/US4692504A/en not_active Expired - Fee Related
-
1987
- 1987-04-07 CA CA000533994A patent/CA1309548C/en not_active Expired - Fee Related
- 1987-04-15 AT AT87200731T patent/ATE78274T1/de active
- 1987-04-15 DE DE8787200731T patent/DE3780349T2/de not_active Expired - Lifetime
- 1987-04-15 EP EP87200731A patent/EP0244015B1/en not_active Expired - Lifetime
- 1987-04-15 ES ES198787200731T patent/ES2041674T3/es not_active Expired - Lifetime
- 1987-04-28 AU AU72149/87A patent/AU584796B2/en not_active Ceased
- 1987-04-28 KR KR870004122A patent/KR870010101A/ko not_active Withdrawn
- 1987-04-28 ZA ZA873012A patent/ZA873012B/xx unknown
- 1987-04-28 JP JP62103485A patent/JPS62262749A/ja active Pending
- 1987-04-28 CN CN87103127A patent/CN1009650B/zh not_active Expired
- 1987-04-28 BR BR8702060A patent/BR8702060A/pt not_active IP Right Cessation
-
1992
- 1992-07-29 GR GR920401626T patent/GR3005295T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN87103127A (zh) | 1987-12-30 |
| US4692504A (en) | 1987-09-08 |
| EP0244015A2 (en) | 1987-11-04 |
| EP0244015A3 (en) | 1989-02-01 |
| KR870010101A (ko) | 1987-11-30 |
| CA1309548C (en) | 1992-10-27 |
| EP0244015B1 (en) | 1992-07-15 |
| ATE78274T1 (de) | 1992-08-15 |
| CN1009650B (zh) | 1990-09-19 |
| JPS62262749A (ja) | 1987-11-14 |
| GR3005295T3 (es) | 1993-05-24 |
| AU584796B2 (en) | 1989-06-01 |
| BR8702060A (pt) | 1988-02-09 |
| ZA873012B (en) | 1987-11-25 |
| DE3780349D1 (de) | 1992-08-20 |
| DE3780349T2 (de) | 1992-12-17 |
| AU7214987A (en) | 1987-11-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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