ES2045855T3 - Composicion catalitica que comprende titanio y fosforo, su preparacion y su utilizacion para la condensacion de un epoxido sobre un anhidrido de acido carboxilico. - Google Patents
Composicion catalitica que comprende titanio y fosforo, su preparacion y su utilizacion para la condensacion de un epoxido sobre un anhidrido de acido carboxilico.Info
- Publication number
- ES2045855T3 ES2045855T3 ES90402909T ES90402909T ES2045855T3 ES 2045855 T3 ES2045855 T3 ES 2045855T3 ES 90402909 T ES90402909 T ES 90402909T ES 90402909 T ES90402909 T ES 90402909T ES 2045855 T3 ES2045855 T3 ES 2045855T3
- Authority
- ES
- Spain
- Prior art keywords
- catalytic composition
- phosphorus
- anhydride
- condensation
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title abstract 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 2
- 150000002118 epoxides Chemical class 0.000 title abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 title abstract 2
- 239000011574 phosphorus Substances 0.000 title abstract 2
- 229910052719 titanium Inorganic materials 0.000 title abstract 2
- 239000010936 titanium Substances 0.000 title abstract 2
- 150000008064 anhydrides Chemical class 0.000 title 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title 1
- 238000009833 condensation Methods 0.000 title 1
- 230000005494 condensation Effects 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 150000002430 hydrocarbons Chemical group 0.000 abstract 2
- -1 CARBOXYL ACIDS Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/56—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds other than from esters thereof
- C08G63/58—Cyclic ethers; Cyclic carbonates; Cyclic sulfites ; Cyclic orthoesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0239—Quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0255—Phosphorus containing compounds
- B01J31/0257—Phosphorus acids or phosphorus acid esters
- B01J31/0258—Phosphoric acid mono-, di- or triesters ((RO)(R'O)2P=O), i.e. R= C, R'= C, H
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0255—Phosphorus containing compounds
- B01J31/0257—Phosphorus acids or phosphorus acid esters
- B01J31/0259—Phosphorus acids or phosphorus acid esters comprising phosphorous acid (-ester) groups ((RO)P(OR')2) or the isomeric phosphonic acid (-ester) groups (R(R'O)2P=O), i.e. R= C, R'= C, H
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/40—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
- C08G63/42—Cyclic ethers; Cyclic carbonates; Cyclic sulfites; Cyclic orthoesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/48—Ring-opening reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Resins (AREA)
Abstract
EL INVENTO TIENE POR OBJETO UNA COMPOSICION CATALITICA QUE COMPRENDE TITANIO Y FOSFORO Y QUE RESULTA DE LA PUESTA EN CONTACTO DE AL MENOS UN TITANATO CON AL MENOS UNA SAL DE "ONIUM" CATERNARIA DE UN ACIDO ESCOGIDO EN EL GRUPO FORMADO POR ACIDO FOSFORICO Y ACIDOS FOSFONICOS DE FORMULA R7H2PO3 EN LA CUAL R7 ES UN GRUPO HIDROCARBONADO QUE TIENE DE 1 A 38 ATOMOS DE CARBONO Y EL RESTO "ONIUM" ES UN RESTO DE FORMULA (R8R8R10R11M)+ EN LA CUAL M ES UN ELEMENTO DEL GRUPO VA DE LA CLASIFICACION PERIODICA DE LOS ELEMENTOS, PREFERENTEMENTE NITROGENO O UN GRUPO HIDROCARBONADO QUE TIENE DE 1 A 38 ATOMOS DE CARBONO. ESTA COMPOSICION CATALITICA ES UTILIZABLE PARA LA APLICACION DE ESTERES Y DE POLIESTERES A PARTIR DE EPOXIDOS Y ANHIDRIDOS DE ACIDOS CARBOXILICOS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8913658A FR2653036B1 (fr) | 1989-10-17 | 1989-10-17 | Composition catalytique comprenant du titane et du phosphore, sa preparation et son utilisation pour la condensation d'un epoxyde sur un anhydride d'acide carboxylique. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2045855T3 true ES2045855T3 (es) | 1994-01-16 |
Family
ID=9386543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90402909T Expired - Lifetime ES2045855T3 (es) | 1989-10-17 | 1990-10-16 | Composicion catalitica que comprende titanio y fosforo, su preparacion y su utilizacion para la condensacion de un epoxido sobre un anhidrido de acido carboxilico. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5104842A (es) |
| EP (1) | EP0424252B1 (es) |
| JP (1) | JPH03229642A (es) |
| AT (1) | ATE80566T1 (es) |
| CA (1) | CA2027887A1 (es) |
| DE (1) | DE69000318T2 (es) |
| ES (1) | ES2045855T3 (es) |
| FR (1) | FR2653036B1 (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0622390B1 (en) * | 1993-04-27 | 1999-12-01 | Nippon Shokubai Co., Ltd. | Process for producing polyester by ring-opening copolymerization |
| US6353061B1 (en) | 1993-05-26 | 2002-03-05 | Dentsply Gmbh | α, ω-methacrylate terminated macromonomer compounds |
| US5998499A (en) | 1994-03-25 | 1999-12-07 | Dentsply G.M.B.H. | Liquid crystalline (meth)acrylate compounds, composition and method |
| US6369164B1 (en) | 1993-05-26 | 2002-04-09 | Dentsply G.M.B.H. | Polymerizable compounds and compositions |
| CA2146816A1 (en) | 1994-04-22 | 1995-10-23 | Joachim E. Klee | Process and composition for preparing a dental polymer product |
| ID26040A (id) * | 1998-04-17 | 2000-11-16 | Du Pont | Komposisi katalitik yang terdiri dari senyawa titanium, senyawa amina fosfor; pembuatan dan penggunaannya |
| WO1999054039A1 (en) * | 1998-04-17 | 1999-10-28 | E.I. Du Pont De Nemours And Company | Catalyst composition comprising a titanium compound, a phosphorus compound and a solubility promoter; preparation and use thereof |
| TW548291B (en) | 1999-06-24 | 2003-08-21 | Teijin Ltd | Catalyst for producing a polyester and process for producing the polyester by using same |
| US6914107B2 (en) | 2001-01-24 | 2005-07-05 | E. I. Du Pont De Nemours And Company | Catalyst composition and process therewith |
| US6489433B2 (en) | 2001-02-23 | 2002-12-03 | E. I. Du Pont De Nemours And Company | Metal-containing composition and process therewith |
| US6506853B2 (en) | 2001-02-28 | 2003-01-14 | E. I. Du Pont De Nemours And Company | Copolymer comprising isophthalic acid |
| JP5204459B2 (ja) * | 2007-10-17 | 2013-06-05 | 共栄社化学株式会社 | 硬化性樹脂成分の製造方法 |
| AU2019321043A1 (en) * | 2018-08-16 | 2021-04-08 | Evonik Operations Gmbh | Preparation of diesters of (meth)acrylic acid from epoxides |
| WO2020264244A1 (en) | 2019-06-28 | 2020-12-30 | Eastman Chemical Company | Process for making novel polycondensation pre-polyesters, other polyester precursors and copolyesters |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3056818A (en) * | 1955-10-13 | 1962-10-02 | Goodrich Co B F | Titanium and zirconium esterification catalysts |
| US3664966A (en) * | 1970-02-09 | 1972-05-23 | Continental Oil Co | Dehydrohalogenation catalyst |
| US4506091A (en) * | 1981-11-06 | 1985-03-19 | Deardorff Donald L | Removal of catalyst residues from polyesters |
| US4436838A (en) * | 1982-09-29 | 1984-03-13 | Texaco Inc. | Process for preparing alkanols and esters from synthesis gas |
| CA1270002A (en) * | 1986-01-27 | 1990-06-05 | Max P. Mcdaniel | Ethylene dimerization and polymerization |
-
1989
- 1989-10-17 FR FR8913658A patent/FR2653036B1/fr not_active Expired - Lifetime
-
1990
- 1990-10-16 ES ES90402909T patent/ES2045855T3/es not_active Expired - Lifetime
- 1990-10-16 US US07/598,285 patent/US5104842A/en not_active Expired - Fee Related
- 1990-10-16 DE DE9090402909T patent/DE69000318T2/de not_active Expired - Fee Related
- 1990-10-16 EP EP90402909A patent/EP0424252B1/fr not_active Expired - Lifetime
- 1990-10-16 AT AT90402909T patent/ATE80566T1/de not_active IP Right Cessation
- 1990-10-17 JP JP2280563A patent/JPH03229642A/ja active Pending
- 1990-10-17 CA CA002027887A patent/CA2027887A1/fr not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US5104842A (en) | 1992-04-14 |
| DE69000318T2 (de) | 1993-02-25 |
| CA2027887A1 (fr) | 1991-04-18 |
| EP0424252A1 (fr) | 1991-04-24 |
| EP0424252B1 (fr) | 1992-09-16 |
| DE69000318D1 (de) | 1992-10-22 |
| FR2653036A1 (fr) | 1991-04-19 |
| FR2653036B1 (fr) | 1992-01-10 |
| ATE80566T1 (de) | 1992-10-15 |
| JPH03229642A (ja) | 1991-10-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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