ES2053701T3 - Mezcla de norborneno con duracion prolongada de uso. - Google Patents
Mezcla de norborneno con duracion prolongada de uso.Info
- Publication number
- ES2053701T3 ES2053701T3 ES88121765T ES88121765T ES2053701T3 ES 2053701 T3 ES2053701 T3 ES 2053701T3 ES 88121765 T ES88121765 T ES 88121765T ES 88121765 T ES88121765 T ES 88121765T ES 2053701 T3 ES2053701 T3 ES 2053701T3
- Authority
- ES
- Spain
- Prior art keywords
- cocatalyst
- alcohols
- monomer
- halides
- optional
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 title 1
- 230000002035 prolonged effect Effects 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 4
- 239000012190 activator Substances 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000005234 alkyl aluminium group Chemical group 0.000 abstract 1
- -1 alkylaluminum halides Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 150000003138 primary alcohols Chemical class 0.000 abstract 1
- 238000007142 ring opening reaction Methods 0.000 abstract 1
- 150000003333 secondary alcohols Chemical class 0.000 abstract 1
- 150000003509 tertiary alcohols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Dental Preparations (AREA)
- Materials For Medical Uses (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
ESTE INVENTO PERTENECE A LA POLIMERIZACION DE UNA CARGA MONOMERA QUE CONTIENE AL MENOS UN MONOMERO TIPO NORBONENE, UN ACTIVADOR HALOMETALICO OPCIONAL, UN ANILLO ABIERTO CATALIZADO METATESICO Y COCATALIZADOR. EL COCATALIZADOR ES SELECCIONADO DE HALIDOS ALKOXIALKOLAUMINIO, ARILOXIALKILALUMINIO, ALKOXI - ALKIL - ALUMINIO, Y HALIDOS ARILOXIALKILALUMINIO QUE SON PREPARADOS PARA REACCIONAR UN COMPONENTE COCATALIZADOR SELECCIONADO DE HALIDOS ALKILALUMINIO O ALKILALUMNIO CON UN ALCOHOL DERIVADO DE ALCOHOLES TERCIARIOS, ALCOHOLES PRIMARIOS DIFICULTADOS, ALCOHOLES SECUNDARIOS DIFICULTADOS Y MEZCLAS DE ELLOS. DEL USO DE ESOS ALCOHOLES DERIVADOS RESULTA UNA VIDA DE CONSERVACION MAS GRANDE QUE EXCEDE SOBRE UNA MEDIA HORA, PREFERIBLEMENTE QUE EXCEDE DOS HORAS DE LA CARGA DE UN MONOMERO. ESTE INVENTO ES TAMBIEN DIRIGIDO A LA COMPOSICION QUE INCLUYE AL MENOS UN MONOMERO, ACTIVADOR OPCIONAL Y EL COCATALIZADOR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14006287A | 1987-12-31 | 1987-12-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2053701T3 true ES2053701T3 (es) | 1994-08-01 |
Family
ID=22489573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES88121765T Expired - Lifetime ES2053701T3 (es) | 1987-12-31 | 1988-12-28 | Mezcla de norborneno con duracion prolongada de uso. |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0324979B1 (es) |
| AT (1) | ATE103302T1 (es) |
| BR (1) | BR8806953A (es) |
| DE (1) | DE3888669T2 (es) |
| ES (1) | ES2053701T3 (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4943621A (en) * | 1988-08-04 | 1990-07-24 | The B. F. Goodrich Company | Storage stable components of reactive formulations for bulk polymerization of cycloolefin monomers |
| DE69022534T2 (de) * | 1989-11-01 | 1996-02-29 | Nippon Zeon Co | Verfahren zur Herstellung von Norbonenpolymeren durch Ringöffnung unter Verwendung von Lagerstabilitätsverlängerungsmitteln. |
| JPH04226124A (ja) * | 1990-06-08 | 1992-08-14 | B F Goodrich Co:The | 塊状重合用反応性配合液、共触媒組成物および大型成形品の製造法 |
| JP3082354B2 (ja) * | 1991-09-27 | 2000-08-28 | 日本ゼオン株式会社 | メタセシス共触媒、それを含む触媒系およびシクロオレフィンの重合方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2106301A1 (de) * | 1971-02-10 | 1972-08-17 | Bayer | Verfahren zur Polymerisation von Cycloalkenen |
| US4426502A (en) * | 1982-06-14 | 1984-01-17 | The B. F. Goodrich Company | Bulk polymerization of cycloolefins |
| US4418179A (en) * | 1982-09-29 | 1983-11-29 | The B. F. Goodrich Company | Impact modified polycycloolefins |
| US4727125A (en) * | 1986-11-03 | 1988-02-23 | Hercules Incorporated | Thermally activated two component metathesis catalyst system |
-
1988
- 1988-12-28 EP EP88121765A patent/EP0324979B1/en not_active Expired - Lifetime
- 1988-12-28 ES ES88121765T patent/ES2053701T3/es not_active Expired - Lifetime
- 1988-12-28 AT AT88121765T patent/ATE103302T1/de not_active IP Right Cessation
- 1988-12-28 DE DE3888669T patent/DE3888669T2/de not_active Expired - Fee Related
- 1988-12-29 BR BR888806953A patent/BR8806953A/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0324979A3 (en) | 1990-08-22 |
| ATE103302T1 (de) | 1994-04-15 |
| BR8806953A (pt) | 1989-08-29 |
| EP0324979A2 (en) | 1989-07-26 |
| DE3888669T2 (de) | 1994-07-28 |
| EP0324979B1 (en) | 1994-03-23 |
| DE3888669D1 (de) | 1994-04-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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