ES2055556T3 - Catalizador y procedimiento para la sintesis de esteres carboxilicos saturados. - Google Patents
Catalizador y procedimiento para la sintesis de esteres carboxilicos saturados.Info
- Publication number
- ES2055556T3 ES2055556T3 ES91400683T ES91400683T ES2055556T3 ES 2055556 T3 ES2055556 T3 ES 2055556T3 ES 91400683 T ES91400683 T ES 91400683T ES 91400683 T ES91400683 T ES 91400683T ES 2055556 T3 ES2055556 T3 ES 2055556T3
- Authority
- ES
- Spain
- Prior art keywords
- chosen
- catalysts
- catalyst
- stabiliser
- synthesis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- -1 CARBOXYL ESTERS Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 229920006395 saturated elastomer Polymers 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- 239000003381 stabilizer Substances 0.000 abstract 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 229910021603 Ruthenium iodide Inorganic materials 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- SUWCFTLKWQKEFZ-UHFFFAOYSA-M azane;ruthenium(3+);chloride Chemical compound N.N.N.N.N.[Cl-].[Ru+3] SUWCFTLKWQKEFZ-UHFFFAOYSA-M 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- JYHHJVKGDCZCCL-UHFFFAOYSA-J carbon monoxide;dichlororuthenium Chemical compound [O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].Cl[Ru]Cl.Cl[Ru]Cl JYHHJVKGDCZCCL-UHFFFAOYSA-J 0.000 abstract 1
- NQZFAUXPNWSLBI-UHFFFAOYSA-N carbon monoxide;ruthenium Chemical compound [Ru].[Ru].[Ru].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] NQZFAUXPNWSLBI-UHFFFAOYSA-N 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 150000004694 iodide salts Chemical class 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
- C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
LA INVENCION SE REFIERE A UN PROCESO DE SINTESIS DE ESTERES CARBOXILICOS SATURADOS A PARTIR DE FORMIATO DE ALQUILO Y DE UNA OLEFINA, SIN PRESENCIA SUSTANCIAL DE MONOXIDO DE CARBONO, A UNA TEMPERATURA DE 120 BARES, EN PRESENCIA DE UN CATALIZADOR DE RUTENIO COORDINADO POR LIGANDOS ELEGIDOS ENTRE EL MONOXIDO DE CARBONO, LOS ATOMOS DE HALOGENO Y LAS AMINAS, Y EN PRESENCIA DE UNA AMIDA COMO SOLVENTE. DICHO CATALIZADOR ES ELEGIDO ENTRE LOS CATALIZADORES CONSTITUIDOS ESENCIALMENTE DE RUCL SUB 3, 3H SUB 2 O, LOS CATALIZADORES CONSTITUIDOS ESENCIALMENTE DE LA COMBINACION DE UN RUCL SUB 3,3H SUB 2 O ASOCIADO A POR LO MENOS UN ESTABILIZANTE ELEGIDO ENTRE EL YODO, LOS YODUROS COVALENTES Y LOS HALOGENUROS DE AMONIO CUATERNARIO; LOS CATALIZADORES QUE COMPRENDEN RU SUB 3 (CO)SUB 12 ASOCIADO A POR LO MENOS UN ESTABILIZANTE TAL COMO EL ANTES CITADO; Y LOS CATALIZADORES ELEGIDOS ENTRE RUL SUB 3, [RUCL SUB 2 (CO) SUB 3 ]2, RU(NH SUB 3)CL SUB 3 Y [RU(NH SUB 3)SUB 5 CL]CL SUB 2, QUE PUEDE COMPRENDER ADEMAS PORLO MENOS UN ESTABILIZANTE COMO EL ANTES CITADO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9003805A FR2659965B1 (fr) | 1990-03-26 | 1990-03-26 | Catalyseur et procede pour la synthese d'esters carboxyliques satures. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2055556T3 true ES2055556T3 (es) | 1994-08-16 |
Family
ID=9395091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES91400683T Expired - Lifetime ES2055556T3 (es) | 1990-03-26 | 1991-03-13 | Catalizador y procedimiento para la sintesis de esteres carboxilicos saturados. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5194676A (es) |
| EP (1) | EP0449693B1 (es) |
| JP (1) | JP2532005B2 (es) |
| AT (1) | ATE106381T1 (es) |
| CA (1) | CA2038973A1 (es) |
| DE (1) | DE69102182T2 (es) |
| DK (1) | DK0449693T3 (es) |
| ES (1) | ES2055556T3 (es) |
| FR (1) | FR2659965B1 (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102471219B (zh) * | 2009-07-31 | 2016-05-25 | 日立化成株式会社 | 酯化合物的制造方法 |
| KR20120036369A (ko) | 2009-09-03 | 2012-04-17 | 히다치 가세고교 가부시끼가이샤 | 트리시클로데칸 모노메탄올 모노카르복실산 및 그 유도체 |
| CN102596888A (zh) * | 2009-10-22 | 2012-07-18 | 日立化成工业株式会社 | 三环癸烷单甲醇单羧酸衍生物的制造方法 |
| JP5556301B2 (ja) * | 2010-03-29 | 2014-07-23 | 日立化成株式会社 | ノルボルナン骨格を有するポリアミド及びその製造方法 |
| DE102011089008B4 (de) * | 2011-12-19 | 2017-08-24 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Estern aus Formiaten und olefinisch ungesättigten Verbindungen |
| JP6528191B2 (ja) * | 2014-12-22 | 2019-06-12 | 日立化成株式会社 | エステル化合物の製造方法 |
| CN109574097B (zh) * | 2019-02-01 | 2021-11-16 | 江苏欣诺科催化剂有限公司 | 三氯六氨合钌的制备方法 |
| CN115870007B (zh) * | 2022-11-30 | 2024-03-15 | 东南大学 | 一种用于乙烯羰基化合成丙酸酯的复合催化剂及其使用方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3213155A (en) * | 1961-05-19 | 1965-10-19 | Exxon Research Engineering Co | Monoolefin isomerization process |
| US4664851A (en) * | 1981-12-30 | 1987-05-12 | Shell Oil Company | Process for the co-production of carboxylic acids and carboxylic acid esters |
| DE3366317D1 (en) * | 1982-10-20 | 1986-10-23 | Bp Chem Int Ltd | Preparation of carboxylic acids and esters thereof |
| GB8521547D0 (en) * | 1985-08-29 | 1985-10-02 | British Petroleum Co Plc | Production of esters |
| JPS6377846A (ja) * | 1986-09-19 | 1988-04-08 | Nkk Corp | Ｎ−置換脂肪族カルボン酸アミドの製造方法 |
| GB8722743D0 (en) * | 1987-09-28 | 1987-11-04 | Shell Int Research | Preparation of esters of carboxylic acids |
-
1990
- 1990-03-26 FR FR9003805A patent/FR2659965B1/fr not_active Expired - Fee Related
-
1991
- 1991-03-13 DK DK91400683.8T patent/DK0449693T3/da active
- 1991-03-13 AT AT91400683T patent/ATE106381T1/de active
- 1991-03-13 DE DE69102182T patent/DE69102182T2/de not_active Expired - Fee Related
- 1991-03-13 EP EP91400683A patent/EP0449693B1/fr not_active Expired - Lifetime
- 1991-03-13 ES ES91400683T patent/ES2055556T3/es not_active Expired - Lifetime
- 1991-03-25 CA CA002038973A patent/CA2038973A1/fr not_active Abandoned
- 1991-03-26 US US07/674,745 patent/US5194676A/en not_active Expired - Fee Related
- 1991-03-26 JP JP3132430A patent/JP2532005B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69102182T2 (de) | 1994-09-29 |
| ATE106381T1 (de) | 1994-06-15 |
| US5194676A (en) | 1993-03-16 |
| JPH0820557A (ja) | 1996-01-23 |
| CA2038973A1 (fr) | 1991-09-27 |
| DK0449693T3 (da) | 1994-06-20 |
| DE69102182D1 (de) | 1994-07-07 |
| FR2659965B1 (fr) | 1992-06-05 |
| FR2659965A1 (fr) | 1991-09-27 |
| EP0449693A1 (fr) | 1991-10-02 |
| EP0449693B1 (fr) | 1994-06-01 |
| JP2532005B2 (ja) | 1996-09-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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