ES2055723T3 - Polimeros de injerto con base de injerto de poliuretano, proceso de obtencion y usos de los mismos. - Google Patents

Polimeros de injerto con base de injerto de poliuretano, proceso de obtencion y usos de los mismos.

Info

Publication number
ES2055723T3
ES2055723T3 ES88115261T ES88115261T ES2055723T3 ES 2055723 T3 ES2055723 T3 ES 2055723T3 ES 88115261 T ES88115261 T ES 88115261T ES 88115261 T ES88115261 T ES 88115261T ES 2055723 T3 ES2055723 T3 ES 2055723T3
Authority
ES
Spain
Prior art keywords
graft polymers
vinyl
grafting
graft
grafted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES88115261T
Other languages
English (en)
Inventor
Matthias Dr Kroggel
Karl Josef Dr Rauterkus
Detlev Dr Seip
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Application granted granted Critical
Publication of ES2055723T3 publication Critical patent/ES2055723T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/08—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Graft Or Block Polymers (AREA)
  • Laminated Bodies (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Materials For Medical Uses (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

LOS POLIMERIZADOS DE INJERTO, EN LOS QUE SE INJERTA POLIMERAMENTE ESTER VINILICO DE ACIDOS CARBOXILICOS Y, DADO EL CASO, OTROS MONOMEROS ETILENICOS NO SATURADOS MEDIANTE POLIMERIZACION DE INJERTO INICIADA RADICALMENTE SOBRE BASES DE INJERTO DE POLIURETANO, ASI COMO LOS PRODUCTOS DE SAPONIFICACION DE LOS POLIMERIZADOS DE INJERTO, SE PUEDEN OBTENER INJERTANDO, MEDIANTE POLIMERIZACION DE INJERTO INICIADA RADICALMENTE, ESTER VINIOLICO DE ACIDO CARBOXILICO CON ENTRE 3 Y 20 ATOMOS DE CARBONO Y, EN SU CASO, OTROS MONOMEROS ETILENICOS POLIMERIZABLES NO SATURADOS, QUE SON A SU VEZ COPOLIMERIZABLES, EN CANTIDADES DE 10 A 99 % DEL PESO DEL POLIMERIZADO DE INJERTO SOBRE UNA BASE DE INJERTO DE POLIURETANO. EN SU CASO, SE PROCEDE A CONTINUACION A SAPONIFICAR EN LOS RESTOS DE POLIMERIZADOS INJERTADOS, TOTALMENTE O SOLO EN PARTE, MEDIANTE HIDROLISIS O ALCOHOLISIS, LAS UNIDADES DE ESTER VINILICO Y DE LOS DEMAS MONOMEROS SAPONIFICABLES. LOS ESTERES VINILICOS PREFERIDOS SON ACETATO DE VINILO Y/O PROPIONATODE VINILO, Y EN SU CASO, ESTER VINILICO DEL ACIDO VERSATICO. LA POLIMERIZACION DE INJERTO TIENE LUGAR EN SOLUCION O EN SUSTANCIA, PUDIENDOSE REALIZAR TAMBIEN EN EMULSION O EN SUSPENSION. LOS POLIMERIZADOS DE INJERTO NO SAPONIFICADOS SIRVEN COMO ADHESIVOS, ESPECIALMENTE COMO ADHESIVO POR FUSION. LOS POLIMERIZADOS DE INJERTO TOTAL O PARCIALMENTE SAPONIFICADOS SIRVEN -ENTRE OTRAS COSAS- PARA LA FABRICACION DE LAMINAS. INDEPENDIENTEMENTE DE LA BASE DE INJERTO DE POLIURETANO, DEL GRADO DE INJERTO, DEL GRADO DE HIDROLISIS Y DE LA CLASE DE MONOMEROS INJERTADOS, LOS POLIMERIZADOS DE INJERTO PUEDEN MOSTRAR, COMPARADOS CON POLIVINILALCOHOLES, PUNTOS DE FUSION SENSIBLEMENTE MAS BAJOS, DE FORMA QUE SU USO RESULTA VENTAJOSO A LA HORA DE FABRICAR LAMINAS POR MODELADO O EXTRUSION A TEMPERATURAS SUAVES SIN UTILIZAR ABLANDADORES ORGANICOS. LOS POLIMERIZADOS DE INJERTO SAPONIFICADOS SIRVEN ADEMAS COMO ADHESIVOS, ENTRE OTRAS COSAS.
ES88115261T 1987-09-24 1988-09-17 Polimeros de injerto con base de injerto de poliuretano, proceso de obtencion y usos de los mismos. Expired - Lifetime ES2055723T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19873732089 DE3732089A1 (de) 1987-09-24 1987-09-24 Propfpolymerisate mit polyurethan-pfropfgrundlage, verfahren zu ihrer herstellung und ihre verwendung

Publications (1)

Publication Number Publication Date
ES2055723T3 true ES2055723T3 (es) 1994-09-01

Family

ID=6336715

Family Applications (1)

Application Number Title Priority Date Filing Date
ES88115261T Expired - Lifetime ES2055723T3 (es) 1987-09-24 1988-09-17 Polimeros de injerto con base de injerto de poliuretano, proceso de obtencion y usos de los mismos.

Country Status (5)

Country Link
EP (1) EP0308832B1 (es)
JP (1) JPH01108208A (es)
AT (1) ATE107320T1 (es)
DE (2) DE3732089A1 (es)
ES (1) ES2055723T3 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3832877A1 (de) * 1988-09-28 1990-04-12 Hoechst Ag Organische dispersionspolymerisate auf der basis von ethylenisch ungesaettigten monameren, die wasserloesliche und vinylalkoholeinheiten mit einer polyurethanpfropfgrundlage enthaltende pfropfpolymerisate enthalten, verfahren zu ihrer herstellung und ihre verwendung
DE3835840A1 (de) * 1988-10-21 1990-05-31 Hoechst Ag Polyvinylacetalgruppen enthaltende pfropfpolymerisate auf polyurethanpfropfgrundlagen, verfahren zu ihrer herstellung und ihre verwendung
DE3843505A1 (de) * 1988-12-23 1990-07-05 Hoechst Ag Carbonsaeureester von hydroxylgruppenhaltigen pfropfpolymerisaten und verfahren zu ihrer herstellung
DE3920229A1 (de) * 1989-06-21 1991-01-03 Hoechst Ag Photopolymerisierbares gemisch und daraus hergestelltes aufzeichnungsmaterial
DE3920230A1 (de) * 1989-06-21 1991-01-24 Hoechst Ag Lichtempfindliches gemisch und daraus hergestelltes lichtempfindliches aufzeichnungsmaterial
DE3924811A1 (de) * 1989-07-27 1991-01-31 Hoechst Ag Pfropfpolymerisat mit ungesaettigten seitenketten, dieses enthaltendes lichtempfindliches gemisch sowie daraus hergestelltes aufzeichnungsmaterial
DE3928825A1 (de) * 1989-08-31 1991-03-07 Hoechst Ag Pfropfpolymerisat mit ungesaettigten seitenketten, dieses enthaltendes lichtempfindliches gemisch sowie daraus hergestelltes aufzeichnungsmaterial
DE4032908A1 (de) * 1990-10-17 1992-04-23 Hoechst Ag Pfropfpolymerisate auf carboxylgruppenhaltigen polyurethanpfropfgrundlagen, verfahren zu ihrer herstellung und ihre verwendung
JP3076011B2 (ja) * 1998-03-16 2000-08-14 三洋化成工業株式会社 エマルション型感圧接着剤組成物

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3968089A (en) * 1974-11-18 1976-07-06 Jefferson Chemical Company, Inc. Polymer-prepolymer composition prepared by polymerizing an ethylenically unsaturated monomer in the presence of an isocyanate-terminated prepolymer
DE3712069A1 (de) * 1987-04-09 1988-10-20 Basf Ag Verwendung von pfropfpolymerisaten auf basis von polyestern, polyesterurethanen und polyesteramiden als vergrauungsinhibitoren in waschmitteln

Also Published As

Publication number Publication date
DE3732089A1 (de) 1989-04-06
EP0308832A2 (de) 1989-03-29
ATE107320T1 (de) 1994-07-15
EP0308832B1 (de) 1994-06-15
JPH01108208A (ja) 1989-04-25
EP0308832A3 (en) 1990-08-29
DE3850199D1 (de) 1994-07-21

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