ES2060195T3 - Perfeccionamiento a la preparacion de catalizadores con quiralidad a base de complejos de rutenio y fosforo. - Google Patents

Perfeccionamiento a la preparacion de catalizadores con quiralidad a base de complejos de rutenio y fosforo.

Info

Publication number
ES2060195T3
ES2060195T3 ES90912758T ES90912758T ES2060195T3 ES 2060195 T3 ES2060195 T3 ES 2060195T3 ES 90912758 T ES90912758 T ES 90912758T ES 90912758 T ES90912758 T ES 90912758T ES 2060195 T3 ES2060195 T3 ES 2060195T3
Authority
ES
Spain
Prior art keywords
ruthenium
catalyzers
computes
phosphorus
improvement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90912758T
Other languages
English (en)
Inventor
Sylvain Juge
Jean-Pierre Genet
Sergio Mallari
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe National Elf Aquitaine
Original Assignee
Societe National Elf Aquitaine
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe National Elf Aquitaine filed Critical Societe National Elf Aquitaine
Application granted granted Critical
Publication of ES2060195T3 publication Critical patent/ES2060195T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/30—Preparation of optical isomers
    • C07C227/32—Preparation of optical isomers by stereospecific synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/16—Preparation of optical isomers
    • C07C231/18—Preparation of optical isomers by stereospecific synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

PROCESO DE PREPARACION DE UN CATALIZADOR QUIRAL, CONSTITUIDO POR UN COMPLEJO ORGANICO DE RUTENIO Y DE FOSFORO, QUE COMPRENDE EL CALENTAMIENTO DE UN COMPLEJO DE RUTENIO CON UNA FOSFINA, EN EL SENO DE UN LIQUIDO ORGANICO, INERTE RESPECTO DE LAS SUSTANCIAS EN PRESENCIA, CALENTANDOSE EL COMPLEJO A BASE DE UN DIENO Y DE UN COMPUESTO ALILICO; EL PRODUCTO OBTENIDO TRAS ESTE CALENTAMIENTO SE SOMETE A LA ACCION DE UN ACIDO EN UN SOLVENTE ORGANICO.
ES90912758T 1989-08-23 1990-08-10 Perfeccionamiento a la preparacion de catalizadores con quiralidad a base de complejos de rutenio y fosforo. Expired - Lifetime ES2060195T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8911159A FR2651152B1 (fr) 1989-08-23 1989-08-23 Perfectionnement a la preparation de catalyseurs chiraux a base de complexes du ruthenium et du phosphore.

Publications (1)

Publication Number Publication Date
ES2060195T3 true ES2060195T3 (es) 1994-11-16

Family

ID=9384870

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90912758T Expired - Lifetime ES2060195T3 (es) 1989-08-23 1990-08-10 Perfeccionamiento a la preparacion de catalizadores con quiralidad a base de complejos de rutenio y fosforo.

Country Status (8)

Country Link
US (1) US5324850A (es)
EP (1) EP0489071B1 (es)
JP (1) JPH05500023A (es)
CA (1) CA2064870A1 (es)
DE (1) DE69004575T2 (es)
ES (1) ES2060195T3 (es)
FR (1) FR2651152B1 (es)
WO (1) WO1991002588A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5559262A (en) * 1995-01-31 1996-09-24 E. I. Du Pont De Nemours And Company Process for the preparation of ruthenium complexes and their in situ use as hydrogenation catalysts
DE69602586T2 (de) * 1995-11-22 2000-03-02 Firmenich S.A., Genf/Geneve Rutheniumkatalysatoren und deren verwendung zur asymmetrischen cyclopentenonhydrierung
US6159890A (en) * 1996-04-30 2000-12-12 Bp Amoco Corporation Ruthenium-containing catalyst system for olefin metathesis
US6156692A (en) * 1996-04-30 2000-12-05 Bp Amoco Corporation Ruthenium-containing catalyst composition for olefin metathesis
DE69820205T2 (de) * 1997-05-20 2004-09-30 Firmenich S.A. Ruthenium-katalysatoren und ihre verwendung zur asymmetrischen hydrierung von substraten mit schwacher koordination
US6214763B1 (en) 1997-05-20 2001-04-10 Firmenich Sa Ruthenium catalysts and their use in the asymmetric hydrogenation of weakly coordinating substrates
IT1308629B1 (it) * 1999-02-23 2002-01-09 Recordati Chem Pharm Processo per la produzione di paroxetina.
US8975414B2 (en) 2011-10-13 2015-03-10 Elevance Renewable Sciences, Inc. Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes
US8779152B2 (en) 2011-10-13 2014-07-15 Elevance Renewable Sciences, Inc. Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2396735A1 (fr) * 1977-07-04 1979-02-02 Rhone Poulenc Ind Procede de preparation de citronellal optiquement actif
US4331818A (en) * 1980-03-19 1982-05-25 The Procter & Gamble Company Chiral phospine ligand
ATE77383T1 (de) * 1985-10-18 1992-07-15 Hoffmann La Roche Chirale rhodium-diphosphinkomplexe fuer asymmetrische hydrierungen.
JPS63145291A (ja) * 1986-12-09 1988-06-17 Takasago Corp ルテニウム−ホスフイン錯体
DE3773882D1 (de) * 1987-01-21 1991-11-21 Sumitomo Chemical Co Verfahren zur herstellung von optisch aktiven arylessigsaeurederivaten.
JPH0667947B2 (ja) * 1987-09-08 1994-08-31 高砂香料工業株式会社 ルテニウム−ホスフイン錯体
JPH0692427B2 (ja) * 1989-07-11 1994-11-16 高砂香料工業株式会社 ２，２’―ビス（ジシクロヘキシルホスフィノ）―６，６’―ジメチル―１，１’―ビフェニルを配位子とする錯体，およびその錯体を用いた有機カルボン酸とそのエステルの製造方法
US5118825A (en) * 1990-12-10 1992-06-02 Ethyl Corporation Ruthenium phosphine complex

Also Published As

Publication number Publication date
JPH05500023A (ja) 1993-01-14
FR2651152A1 (fr) 1991-03-01
WO1991002588A1 (fr) 1991-03-07
EP0489071A1 (fr) 1992-06-10
DE69004575T2 (de) 1994-05-19
EP0489071B1 (fr) 1993-11-10
DE69004575D1 (de) 1993-12-16
FR2651152B1 (fr) 1991-11-29
CA2064870A1 (en) 1991-02-24
US5324850A (en) 1994-06-28

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