ES2062025T3 - Componente catalizador para polimerizacion de olefinas. - Google Patents

Componente catalizador para polimerizacion de olefinas.

Info

Publication number
ES2062025T3
ES2062025T3 ES89309303T ES89309303T ES2062025T3 ES 2062025 T3 ES2062025 T3 ES 2062025T3 ES 89309303 T ES89309303 T ES 89309303T ES 89309303 T ES89309303 T ES 89309303T ES 2062025 T3 ES2062025 T3 ES 2062025T3
Authority
ES
Spain
Prior art keywords
catalyst
component
alpha
titanium
olephine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89309303T
Other languages
English (en)
Inventor
Mamoru Mitsui Petrochemi Kioka
Masao Mitsui Petrochemi Nakano
Akinori Mitsui Petroche Toyota
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP63228955A external-priority patent/JP2677395B2/ja
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Application granted granted Critical
Publication of ES2062025T3 publication Critical patent/ES2062025T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

UN COMPONENTE CATALIZADOR ((ALFA)") OBTENIDO EN EL TRATAMIENTO CATALIZADOR DE POLIMERIZACION DE OLEFINA ((ALFA)) FORMADO DE (A) UN COMPONENTE CATALIZADOR DE TITANIO SOLIDO MQUE COMPRENDE MAGNESIO, TITANIO, HALOGENO Y UN DONANTE DE ELECTRON COMO INGREDIENTES ESENCIALES, (B) UN COMPONENTE CATALIZADOR DE COMPUESTO ORGANOALUMINICO, Y REQUERIDO (C) UN DONANTE DE ELECTRON CON UNA ALFA-OLEFINA QUE POR POLIMERIZACION PRELIMINAR MEN UNA CANTIDAD DE 0,7 A 500 G. POR GRAMO DEL COMPONENTE CATALIZADOR DE TITANIO (A) EN LA PRESENCIA DE DICHO CALATALIZADOR (X), Y CONTACTANDO EL CATALIZADOR TRATADO ((ALFA)) CON AL MENOS 0.7 MOL POR GRAMO DE ATOMO DE TITANIO EN EL CATALIZADOR TRATADO ((ALFA)) DE HIDROGENO. UN PROCESO PARA PRODUCIR DICHO COMPONENTE. UN CATALIZADOR (Y) PARA POLIMERIZADION DE OLEFINA FORMADO DE (I) EL COMPONENTE YA MENCIONADO (X"). (II) UN COMPUESTO ORGANOALUMIONICO Y ES REQUERIDO (III) UN DONANTE DE ELECTRON. TAMBIEN ES PROVISTO UN PROCESO PARA POLIMERIZAR OLEFINAS CON LA PRESENCIA DEL CATALIZADOR (Y).
ES89309303T 1988-09-13 1989-09-13 Componente catalizador para polimerizacion de olefinas. Expired - Lifetime ES2062025T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP63228955A JP2677395B2 (ja) 1988-09-13 1988-09-13 オレフィン重合用触媒成分の製造方法
JP22895688 1988-09-13

Publications (1)

Publication Number Publication Date
ES2062025T3 true ES2062025T3 (es) 1994-12-16

Family

ID=26528559

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89309303T Expired - Lifetime ES2062025T3 (es) 1988-09-13 1989-09-13 Componente catalizador para polimerizacion de olefinas.

Country Status (7)

Country Link
US (1) US4990477A (es)
EP (1) EP0360491B1 (es)
KR (1) KR930001064B1 (es)
CN (1) CN1021229C (es)
CA (1) CA1334841C (es)
DE (1) DE68911812T2 (es)
ES (1) ES2062025T3 (es)

Families Citing this family (53)

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WO1991002758A1 (fr) * 1989-08-18 1991-03-07 Tonen Corporation COMPOSANT CATALYTIQUE POUR LA POLYMERISATION D'α-OLEFINE
US5556820A (en) * 1989-12-28 1996-09-17 Idemitsu Petrochemical Co., Ltd. Catalyst component for olefin polymerization and process for producing polyolefins
JP2509767B2 (ja) * 1991-06-28 1996-06-26 出光石油化学株式会社 オレフィン重合体の製造法
CA2040598A1 (en) * 1990-04-20 1991-10-21 Masatoshi Toda Process for producing polyolefins
JPH0441496A (ja) * 1990-06-05 1992-02-12 Shin Etsu Chem Co Ltd ジシクロペンチルジメトキシシラン
FI90083C (fi) * 1990-12-20 1993-12-27 Neste Oy Foer olefinpolymerisation avsett stereospecifikt katalysatorsystem
IT1246614B (it) * 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
JP3193110B2 (ja) * 1992-04-15 2001-07-30 三菱化学株式会社 プロピレン重合体の製造法
US6410663B2 (en) 1992-06-08 2002-06-25 Fina Technology, Inc. Electron donors in a Ziegler-Natta catalyst for the production of high melt flow copolymers
CA2098664A1 (en) † 1992-06-30 1993-12-31 Hajime Sadatoshi Polypropylene random copolymer and film thereof
JP3284319B2 (ja) * 1992-07-06 2002-05-20 昭和電工株式会社 オレフィン重合用触媒およびオレフィン重合体の製造法
DE69333773T2 (de) 1992-11-13 2006-04-06 Cryovac, Inc. Wärmeschrumpfbare, durch Single-site-Katalyse hergestellte Copolymere enthaltende Folien.
EP0622382B1 (en) * 1993-03-31 2001-12-12 Fina Technology, Inc. A process for increased randomness in co-polymerization of olefins
US5424263A (en) * 1993-04-23 1995-06-13 Quantum Chemical Corporation Supported polymerization catalyst
US5536773A (en) * 1993-07-16 1996-07-16 Mitsui Petrochemical Industries, Ltd. Polypropylene resin composition and the use of the same
US6284857B1 (en) 1993-07-22 2001-09-04 Mitsui Chemical, Inc. Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition
TW354792B (en) 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
US5518973A (en) * 1993-10-15 1996-05-21 Exxon Chemical Patents Inc. Titanium trichloride catalyst system for polymerizing olefins
ATE166074T1 (de) * 1994-02-04 1998-05-15 Exxon Chemical Patents Inc Zweidonokatalysatorsystem zur olefinpolymerisation
US6686433B1 (en) 1994-02-04 2004-02-03 Exxonmobil Chemical Patents Inc. Dual donor catalyst system for the polymerization of olefins
JP3472935B2 (ja) * 1994-02-18 2003-12-02 三井化学株式会社 エチレン系重合体およびその製造方法、エチレン重合用固体状チタン触媒成分ならびにエチレン重合用触媒
US6133385A (en) * 1994-04-06 2000-10-17 Fina Technology, Inc. Catalyst systems for improved stereoselectivity and broader molecular weight distribution in polymerization of olefins
FR2728181B1 (fr) 1994-12-16 1997-01-31 Appryl Snc Composante catalytique pour la polymerisation des olefines, son procede de fabrication, et procede de polymerisation des olefines en presence de ladite composante catalytique
FI102070B1 (fi) * 1996-03-29 1998-10-15 Borealis As Uusi kompleksiyhdiste, sen valmistus ja käyttö
US5849655A (en) * 1996-12-20 1998-12-15 Fina Technology, Inc. Polyolefin catalyst for polymerization of propylene and a method of making and using thereof
US5948720A (en) * 1997-01-07 1999-09-07 Huntsman Polymers Corporation Catalyst for the production of flexible polyolefin compositions, methods for making and using same, and products thereof
US6100351A (en) * 1997-01-07 2000-08-08 Huntsman Polymers Corporation Olefin polymerization process and products thereof
US6080818A (en) * 1997-03-24 2000-06-27 Huntsman Polymers Corporation Polyolefin blends used for non-woven applications
IT1292109B1 (it) * 1997-06-09 1999-01-25 Montell North America Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1292108B1 (it) * 1997-06-09 1999-01-25 Montell North America Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1292107B1 (it) * 1997-06-09 1999-01-25 Montell North America Inc Componenti e catalizzatori per la polimerizzazione di olefine
KR100528310B1 (ko) * 1998-03-23 2005-11-15 바셀 테크놀로지 캄파니 비이브이 올레핀 중합용 예비중합된 촉매 성분
US6087459A (en) * 1998-05-14 2000-07-11 Exxon Chemical Patents Inc. Polymeric materials formed using blends of electron donors
KR100700957B1 (ko) * 1999-04-15 2007-03-28 바셀 테크놀로지 컴퍼니 비.브이. 올레핀 중합반응을 위한 성분 및 촉매
KR100607538B1 (ko) * 1999-04-20 2006-08-02 삼성토탈 주식회사 열접착성 필름용 프로필렌-에틸렌-부텐-1 공중합체 및 이를 포함하는 수지조성물
KR100549106B1 (ko) * 1999-04-20 2006-02-06 삼성토탈 주식회사 증착용 폴리프로필렌 수지 조성물
US6586543B1 (en) * 1999-09-01 2003-07-01 Degussa Ag Process for the preparation of substantially amorphous poly-α-olefins
SG124236A1 (en) * 2000-03-30 2006-08-30 Sumitomo Chemical Co Prepolymerization catalyst for use in gas phase polymerization of olefins and process for producing the same
US6399707B1 (en) 2000-09-29 2002-06-04 Exxonmobil Chemical Patents Inc. Impact copolymer and plastomer blend
WO2002044220A1 (en) * 2000-11-29 2002-06-06 Reliance Industries Limited A lower a-alkene polymerisation heterogeneous solid catalyst
US6566294B2 (en) 2000-12-21 2003-05-20 Exxonmobil Chemical Patents Inc. Multi-donor catalyst system for the polymerization of olefins
US6562132B2 (en) * 2001-04-04 2003-05-13 Ase Americas, Inc. EFG crystal growth apparatus and method
KR100702435B1 (ko) * 2004-11-03 2007-04-03 주식회사 엘지화학 고활성 마그네슘 담지 촉매 및 이를 이용한 폴리올레핀의제조방법
US8507628B2 (en) 2007-10-02 2013-08-13 Fina Technology, Inc. Propylene based polymers for injection stretch blow molding
US9090000B2 (en) * 2009-03-26 2015-07-28 Fina Technology, Inc. Injection stretch blow molded articles and random copolymers for use therein
US10294312B2 (en) 2014-12-12 2019-05-21 Exxonmobil Research And Engineering Company Olefin polymerization catalyst system comprising mesoporous organosilica support
WO2016195832A1 (en) 2015-05-29 2016-12-08 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates comprising broad molecular weight distribution polypropylene
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
WO2020231526A1 (en) 2019-05-15 2020-11-19 Exxonmobil Chemical Patents Inc. Polypropylene-based compositions
CN110144022B (zh) * 2019-05-28 2020-02-21 国家能源集团宁夏煤业有限责任公司 Ziegler-Natta催化剂的工业制备方法
EP4107196A1 (en) 2020-02-17 2022-12-28 ExxonMobil Chemical Patents Inc. Propylene-based polymer compositions having a high molecular weight tail
JP7526587B2 (ja) * 2020-04-28 2024-08-01 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分の製造方法
US20260015443A1 (en) 2022-07-27 2026-01-15 Exxonmobil Chemical Patents Inc. Polyproplyene compositions with enhanced strain hardening and methods of producing the same

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4922315B1 (es) * 1970-12-28 1974-06-07
US4295991A (en) * 1978-09-26 1981-10-20 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof
JPS6042806B2 (ja) * 1979-12-26 1985-09-25 日石三菱株式会社 共重合体の製造方法
FR2591602B1 (fr) * 1985-12-18 1988-02-26 Atochem Procede de traitement de catalyseurs spheriques de polymerisation des olefines. application du catalyseur obtenu a la polymerisation des olefines.
JPH0735410B2 (ja) * 1986-01-31 1995-04-19 三菱油化株式会社 オレフィンの立体規則性重合用触媒
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst

Also Published As

Publication number Publication date
US4990477A (en) 1991-02-05
DE68911812T2 (de) 1994-04-14
CN1021229C (zh) 1993-06-16
CA1334841C (en) 1995-03-21
DE68911812D1 (de) 1994-02-10
EP0360491A2 (en) 1990-03-28
EP0360491B1 (en) 1993-12-29
KR900004404A (ko) 1990-04-12
KR930001064B1 (ko) 1993-02-15
CN1042156A (zh) 1990-05-16
EP0360491A3 (en) 1991-06-05

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