ES2062277T3 - Adhesivo de poliuretano de dos componentes. - Google Patents

Adhesivo de poliuretano de dos componentes.

Info

Publication number
ES2062277T3
ES2062277T3 ES90124094T ES90124094T ES2062277T3 ES 2062277 T3 ES2062277 T3 ES 2062277T3 ES 90124094 T ES90124094 T ES 90124094T ES 90124094 T ES90124094 T ES 90124094T ES 2062277 T3 ES2062277 T3 ES 2062277T3
Authority
ES
Spain
Prior art keywords
components
isocianate
equivalent
low viscosity
polyurethane adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90124094T
Other languages
English (en)
Inventor
Jeffrey F Dormish
Peter W Boerner
Randall C Rains
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Corp
Original Assignee
Miles Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Miles Inc filed Critical Miles Inc
Application granted granted Critical
Publication of ES2062277T3 publication Critical patent/ES2062277T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5036—Polyethers having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
    • C08G18/5048—Products of hydrolysis of polyether-urethane prepolymers containing isocyanate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/12—Polyurethanes from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/54—Inorganic substances

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

LA INVENCION SE REFIERE A UN ADHESIVO DE POLIURETANO DE DOS COMPONENTES DE BAJA VISCOSIDAD QUE COMPRENDE (A) UN COMPONENTE DE ISOCIANATO DE BAJA VISCOSIDAD EN UNA CANTIDAD SUFICIENTE PARA SUMINISTRAR UN INDICE DE ISOCIANATO DE ENTRE 100 Y 150 COMPRENDIENDO UN POLIISOCIANATO ORGANICO EN EL QUE HASTA EL 10 % EQUIVALENTE DE LOS GRUPOS DE ISOCIANATO DE DICHO POLIISOCIANATO HAN SIDO MODIFICADOS MEDIANTE UNA REACCION CON UNO O MAS COMPUESTOS REACTIVOS AL ISOCIANATO; Y (B) UN COMPONENTE SECATIVO DE BAJA VISCOSIDAD QUE COMPRENDE I) DESDE EL 5 AL 50 % DE PORCENTAJE EQUIVALENTE, EN RELACION CON LOS EQUIVALENTES TOTALES DE GRUPOS AMINOS E HIDROXIL DE COMPONENTES (B) (I) Y (B) (II), DE UN POLIOL POLIETER Y/O UN POLIETER TERMINADO MEDIANTE GRUPOS AMINO AROMATICOS QUE TENGAN UN PESO EQUIVALENTE MAYOR A 500, II) DESDE EL 50 AL 95 DEL PORCENTAJE EQUIVALENTE, EN RELACION CON LOS EQUIVALENTES TOTALES DE GRUPOS AMINO E HIDROXIL DE LOS COMPONENTES (B) I) Y (B) II), DE UNO O MAS EXTENDEDORES DE CADENA Y/O ENLAZADORES, EN LOS QUE AL MENOS UN EXTENDEDOR DE CADENA DIOL COMPRENDA ENTRE EL 5 Y 50 % DE EQUIVALENTES REACTIVOS AL ISOCIANATO DEL COMPUESTO (B) II), Y III) UNO O MAS DIAMINOS O TRIAMINOS REACTIVOS AL ISOCIANATO EN UNA CANTIDAD SUFICIENTE PARA PRODUCIR UNA RESISTENCIA ADECUADA AL FLUJO CUANDO LOS COMPONENTES (A) Y (B) SE MEZCLAN; EN EL PRESENTE COMPUESTO AL MENOS UNO DE LOS COMPONENTES (A) O (B) CONTIENE AL MENOS UN EXCIPIENTE EN UNA CANTIDAD TOTAL DE ENTRE EL 10 Y EL 40 % DEL PESO DEL ADHESIVO DE POLIURETANO.
ES90124094T 1990-01-16 1990-12-13 Adhesivo de poliuretano de dos componentes. Expired - Lifetime ES2062277T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/465,715 US5164473A (en) 1990-01-16 1990-01-16 Two-component polyurethane adhesive

Publications (1)

Publication Number Publication Date
ES2062277T3 true ES2062277T3 (es) 1994-12-16

Family

ID=23848882

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90124094T Expired - Lifetime ES2062277T3 (es) 1990-01-16 1990-12-13 Adhesivo de poliuretano de dos componentes.

Country Status (7)

Country Link
US (1) US5164473A (es)
EP (1) EP0442084B1 (es)
JP (1) JPH04211485A (es)
KR (1) KR0148382B1 (es)
CA (1) CA2033889C (es)
DE (1) DE69006711T2 (es)
ES (1) ES2062277T3 (es)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
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US5451629A (en) * 1985-05-31 1995-09-19 Jacobs; Richard Fast bonding electrically conductive composition and structures
CA2049912C (en) * 1991-03-13 1997-01-28 Arden E. Schmucker Adhesive composition
GB9125918D0 (en) * 1991-12-05 1992-02-05 Ici Plc Reaction system for preparing polyurethane/polyurea
US5175228A (en) * 1991-12-09 1992-12-29 Gencorp Inc. Two-component primerless urethane-isocyanurate adhesive compositions having high temperature resistance
US5340901A (en) * 1991-12-09 1994-08-23 Gencorp Inc. Two-component, primerless, organic phosphorus containing polyurethane adhesive
US5606003A (en) * 1994-09-01 1997-02-25 Gencorp Inc. Primerless urethane adhesive compositions
CA2163402A1 (en) * 1994-12-12 1996-06-13 Peter H. Markusch Thixotropic polyurea compositions
US5770673A (en) * 1996-04-10 1998-06-23 Bayer Corporation Non-sagging, light stable polyurethane compositions, a process for producing them, and their use as seam sealants
US5668211A (en) * 1996-12-18 1997-09-16 Bayer Corporation Two-component polyurethane adhesive
US5719252A (en) * 1996-12-18 1998-02-17 Bayer Corporation Unfilled two-component polyurethane adhesive
KR20030028282A (ko) * 2001-09-28 2003-04-08 유한회사 정우화인 이액형 폴리우레탄 접착제의 폴리올 혼합액 및 그 제조방법
US6582771B1 (en) 2002-05-03 2003-06-24 Bayer Corporation Method for producing a polyurethane/geofabric composite
KR101572276B1 (ko) * 2007-07-23 2015-11-26 다우 글로벌 테크놀로지스 엘엘씨 사용 온도 범위에 걸쳐 실질적으로 일정한 ｇ-계수를 갖는 2 부분 폴리우레탄 경화성 조성물
EP2199358B1 (en) * 2007-10-12 2013-06-12 Emulsion Technology Co. Ltd. Urethane adhesive composition
CN102131839B (zh) * 2008-08-22 2014-06-04 陶氏环球技术公司 适合于将大质量部件粘结到结构体上的粘合剂组合物
CN103261254B (zh) * 2010-12-20 2015-02-11 陶氏环球技术有限责任公司 在固化状态下具有改进的耐久性的含异氰酸酯官能组分的可固化组合物
DE102011002885A1 (de) * 2011-01-19 2012-07-19 Henkel Ag & Co. Kgaa Lagerstabiler NCO-freier Kaschierklebstoff
KR101903822B1 (ko) * 2011-05-16 2018-10-02 앳슈랜드 라이센싱 앤드 인텔렉츄얼 프라퍼티 엘엘씨 상승된 고온 저장 탄성률을 갖는 2액형 폴리우레아-우레탄 접착제
CN102408864B (zh) * 2011-08-05 2013-05-08 四川蜀龙富旺达科技有限公司 断桥隔热铝型材双组分聚氨酯浇注胶
CN102746816B (zh) * 2011-09-08 2014-08-13 湖北航天化学技术研究所 安全气囊气体发生器用聚氨酯密封胶及其制备方法和应用
CN102504749B (zh) * 2011-11-17 2016-04-27 上海埃菲东多胶粘技术有限公司 一种高弹性、导热、环保型聚氨酯密封胶
CN102533200B (zh) * 2012-02-29 2013-11-20 广州睿腾化工产品有限公司 双组份聚氨酯胶粘剂
BR112015000514A2 (pt) * 2012-08-24 2017-06-27 Sika Tech Ag adesivo de poliuretano estrutural.
EP2700666A1 (de) * 2012-08-24 2014-02-26 Sika Technology AG Struktureller Polyurethanklebstoff
EP2706075A1 (de) * 2012-09-11 2014-03-12 Sika Technology AG Struktureller Polyurethanklebstoff mit tiefer Glasübergangstemperatur
CN102863939B (zh) * 2012-10-17 2013-08-07 厦门大学 一种水性聚氨酯鞋用胶粘剂及其制备方法
CN103013420B (zh) * 2012-11-30 2016-04-06 三棵树涂料股份有限公司 环保型耐黄变水性聚氨酯通用胶
CN103131379B (zh) * 2013-03-19 2014-10-08 四川金来缘科技有限公司 一种高弹高拉伸性的无影胶及其制备方法
CN104277754B (zh) * 2013-07-29 2016-06-15 湖北航天化学技术研究所 一种适用于nepe推进剂的限燃层材料及其制备方法
CN103788913B (zh) * 2014-03-04 2015-08-26 大连怿文新材料科技发展有限公司 石油管道封头用聚天门冬氨酸酯型密封胶及其制备方法
CN103897649B (zh) * 2014-03-12 2015-11-11 南京艾布纳密封技术有限公司 一种单组份硅烷改性聚氨酯密封胶的制备方法
CN103897650B (zh) * 2014-03-17 2016-05-18 郑州大学 一种不易起泡的单组份聚氨酯密封胶
CN104497957B (zh) * 2014-12-18 2017-06-16 李东 一种用于覆膜铁生产的覆膜胶水及其生产方法
CN104629673A (zh) * 2015-02-03 2015-05-20 吉林辰龙生物质材料有限责任公司 一种水性聚氨酯胶粘剂的制备方法
CN104673176B (zh) * 2015-03-10 2016-10-05 济南伟传信息技术有限公司 一种电子灌封胶及其制备方法
CN104817994B (zh) * 2015-04-27 2017-04-19 武汉戴尔惠科技有限公司 一种快速固化复合胶粘剂及其制备方法
CN104804698B (zh) * 2015-04-27 2017-04-05 武汉戴尔惠科技有限公司 一种太阳能背板用双组分复合胶粘剂及其制备方法
CN104974705A (zh) * 2015-06-23 2015-10-14 苏州博利迈新材料科技有限公司 高固含量纳米聚氨酯胶黏剂及其制备方法
CN104974707B (zh) * 2015-07-07 2017-12-05 上海天洋热熔粘接材料股份有限公司 一种湿固化聚氨酯热熔胶及其制备方法
CN104974708A (zh) * 2015-07-09 2015-10-14 常州市金呈宇五金有限公司 一种改性聚氨酯胶黏剂及其制备方法
CN105153989A (zh) * 2015-07-09 2015-12-16 常州市金呈宇五金有限公司 一种改性双组份耐磨、耐油性聚氨酯胶黏剂及其制备方法
CN105602515B (zh) * 2016-01-18 2018-06-26 广东工业大学 一种紫外光固化转印胶及其制备方法与应用
TWI793073B (zh) 2016-05-10 2023-02-21 美商陶氏全球科技有限責任公司 包括胺引發的多元醇的雙組分無溶劑黏著劑組合物
TWI756219B (zh) * 2016-05-10 2022-03-01 美商陶氏全球科技有限責任公司 包括胺引發之多元醇之雙組分無溶劑黏著劑組合物
CN108138022A (zh) 2016-09-29 2018-06-08 Dic株式会社 粘接剂、使用其的层叠膜、以及粘接剂用多元醇组合物
WO2020227963A1 (en) * 2019-05-15 2020-11-19 Dow Global Technologies Llc Two-component adhesive compositions, articles prepared with same and preparation methods thereof
CN110204674A (zh) * 2019-06-10 2019-09-06 长安大学 一种路面疏水防冻复合剂的制备方法
CN110330627A (zh) * 2019-07-10 2019-10-15 福建元发树脂有限公司 无溶剂单组份聚氨酯注塑树脂
CN113583590B (zh) * 2020-04-30 2024-04-02 宁德时代新能源科技股份有限公司 一种双组分胶粘剂组合物、拆卸该胶粘剂的方法及包含该胶粘剂的电池
CN111621259B (zh) * 2020-06-22 2022-03-18 湖北博天体育设施有限公司 一种透气式塑胶跑道用的水性聚氨酯胶黏剂及其制备方法
CN112210336A (zh) * 2020-09-04 2021-01-12 上海吒吒新材料科技有限公司 一种耐低温聚氨酯胶粘剂及其制备方法
IT202100010037A1 (it) * 2021-04-21 2022-10-21 Tema Tech And Materials Srl Pannello rigido per edilizia con strato centrale schiumato e rivestimento in resina.

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US4336298A (en) * 1981-06-12 1982-06-22 The B. F. Goodrich Company Adhesive composition and composite made therewith
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US4743672A (en) * 1987-02-26 1988-05-10 Ashland Oil, Inc. Sag resistant, two component urethane adhesives
US4876308A (en) * 1988-02-18 1989-10-24 Gencorp Inc. Polyurethane adhesive for a surface treatment-free fiber reinforced plastic
US4994540A (en) * 1990-01-16 1991-02-19 Mobay Corporation Sag resistant, unfilled, low viscosity urethane structural adhesive

Also Published As

Publication number Publication date
EP0442084A1 (en) 1991-08-21
CA2033889C (en) 2001-10-16
US5164473A (en) 1992-11-17
DE69006711D1 (de) 1994-03-24
DE69006711T2 (de) 1994-06-01
EP0442084B1 (en) 1994-02-16
KR910014486A (ko) 1991-08-31
KR0148382B1 (ko) 1998-11-02
CA2033889A1 (en) 1991-07-17
JPH04211485A (ja) 1992-08-03

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