ES2062471T3 - Procedimiento para la preparacion de derivados de estilbeno. - Google Patents
Procedimiento para la preparacion de derivados de estilbeno.Info
- Publication number
- ES2062471T3 ES2062471T3 ES90420101T ES90420101T ES2062471T3 ES 2062471 T3 ES2062471 T3 ES 2062471T3 ES 90420101 T ES90420101 T ES 90420101T ES 90420101 T ES90420101 T ES 90420101T ES 2062471 T3 ES2062471 T3 ES 2062471T3
- Authority
- ES
- Spain
- Prior art keywords
- preparation
- procedure
- stilbenedicarboxylate
- stylben
- derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 abstract 2
- -1 2-benzoxazolyl Chemical group 0.000 abstract 2
- JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 abstract 1
- OONPLQJHBJXVBP-UHFFFAOYSA-N 3-(2-phenylethenyl)phthalic acid Chemical compound OC(=O)C1=CC=CC(C=CC=2C=CC=CC=2)=C1C(O)=O OONPLQJHBJXVBP-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001629 stilbenes Chemical class 0.000 abstract 1
- 235000021286 stilbenes Nutrition 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
- C07D263/62—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings
- C07D263/64—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings linked in positions 2 and 2' by chains containing six-membered aromatic rings or ring systems containing such rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
SE PRESENTA UN PROCESO PARA LA PREPARACION DE COMPUESTOS DE ESTILBENO TALES COMO BIS(2-BENZOXAZOLIL) ESTILBENOS, MEDIANTE LA REACCION DE UN ESTILBENODICARBOXILATO TAL COMO EL DIMETIL-4,4''-ESTILBENEDICARBOXILATO CON UN O-AMINOFENOL EN UN SOLVENTE ORGANICO TAL COMO EL CLORONAFTALENO EN LA PRESENCIA DE UNA CANTIDAD CATALITICA DE UN COMPUESTO DE ESTAÑO O TITANIO. LA REACCION SE LLEVA A CABO TIPICAMENTE A UNA TEMPERATURA ENTRE 200 Y 250 (GRADOS) C Y UN CATALIZADOR ADECUADO ES TANTO EL OXIDO DE ESTAÑO DIBULTIL COMO EL TETRAALCOXIDO DE TITANIO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/317,383 US4921964A (en) | 1989-03-01 | 1989-03-01 | Process for the preparation of stilbene derivatives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2062471T3 true ES2062471T3 (es) | 1994-12-16 |
Family
ID=23233402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90420101T Expired - Lifetime ES2062471T3 (es) | 1989-03-01 | 1990-02-26 | Procedimiento para la preparacion de derivados de estilbeno. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4921964A (es) |
| EP (2) | EP0472525A1 (es) |
| AT (1) | ATE113039T1 (es) |
| CA (1) | CA2050351A1 (es) |
| DE (1) | DE69013376T2 (es) |
| ES (1) | ES2062471T3 (es) |
| WO (1) | WO1990010001A1 (es) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5332828A (en) * | 1993-02-22 | 1994-07-26 | Eastman Kodak Company | Process for the preparation of bis (2-benzoxazolyl) stilbenes |
| US6177574B1 (en) * | 2000-03-02 | 2001-01-23 | Eastman Chemical Company | Preparation of mixtures of benzoxazolyl-stilbene compounds |
| ES2252320T3 (es) * | 2000-10-18 | 2006-05-16 | Ciba Specialty Chemicals Holding Inc. | Un procedimiento para la preparacion de compuestos de bis-benzacolilo. |
| CN103483328B (zh) * | 2013-08-30 | 2016-01-06 | 华南理工大学 | 一种二苯乙烯荧光增白剂及其制备方法和应用 |
| CN114591316B (zh) * | 2022-03-14 | 2024-09-20 | 黄石市利福达医药化工有限公司 | 一种2,5-双(苯并噁唑-2-)呋喃的制备方法 |
| CN115260115A (zh) * | 2022-08-09 | 2022-11-01 | 河南瑞奇特化工有限公司 | 一种室内外无色差的荧光增白剂及其制备方法 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL301930A (es) * | 1962-12-17 | |||
| GB1072918A (en) * | 1963-05-29 | 1967-06-21 | Eastman Kodak Co | Preparation of bis-benzoxazolyl stilbenes |
| BE648674A (es) * | 1963-06-07 | 1964-12-01 | ||
| GB1016219A (en) * | 1963-06-26 | 1966-01-05 | Ciba Ltd | Epoxide resins |
| BE651310A (es) * | 1963-08-01 | 1964-11-16 | ||
| GB1084136A (es) * | 1963-08-22 | |||
| GB1062257A (en) * | 1963-09-18 | 1967-03-22 | Sumitomo Chemical Co | Method for producing dioxazolyl stilbene optical brightening agents |
| CH469782A (de) * | 1963-11-14 | 1969-03-15 | Ciba Geigy | Verwendung von neuen Bis-oxazolyl-stilbenverbindungen als optische Aufhellmittel ausserhalb der Textilindustrie |
| US3366575A (en) * | 1964-03-13 | 1968-01-30 | Nippon Kayaku Kk | Enhancement of optical brightening effects by using two or more species of brightening agent |
| CH476793A (de) * | 1964-09-01 | 1969-08-15 | Ciba Geigy | Verwendung von neuen Bis-azolen als optische Aufhellmittel ausserhalb der Textilindustrie |
| CA967959A (en) * | 1965-03-12 | 1975-05-20 | Nathan N. Crounse | 4,4'-bis(benzoxazol-2-y1) stilbene |
| US3476747A (en) * | 1965-10-20 | 1969-11-04 | Eastman Kodak Co | Manufacture of 1,2-bis(aryl)ethylenes |
| CH477469A (de) * | 1965-12-02 | 1969-08-31 | Ciba Geigy | Verfahren zur Herstellung heterocyclischer Stilbenverbindungen |
| CH484930A (de) * | 1967-08-25 | 1970-01-31 | Ciba Geigy | Verfahren zur Herstellung von Aryloxazolen |
| US3586673A (en) * | 1968-02-05 | 1971-06-22 | Eastman Kodak Co | Preparation of symmetrically and unsymmetrically substituted stilbenebisbenzoxazoles |
| US3585208A (en) * | 1968-08-01 | 1971-06-15 | Eastman Kodak Co | Manufacture of benzoxazoles |
| CH514616A (de) * | 1968-10-07 | 1971-10-31 | Ciba Geigy Ag | Verfahren zur Herstellung von Arylenoxazolen |
| CH519006A (de) * | 1969-03-06 | 1972-02-15 | Ciba Geigy Ag | Verwendung von neuen Azol-Derivaten als optische Aufhellmittel für organische Materialien ausserhalb der Textilindustrie |
| GB1277793A (en) * | 1969-09-05 | 1972-06-14 | Kodak Ltd | Manufacture of stilbene derivatives |
| FR2157370A5 (es) * | 1971-10-21 | 1973-06-01 | Ciba Geigy Ag | |
| CH559741A5 (es) * | 1971-11-22 | 1975-03-14 | Ciba Geigy Ag | |
| US4282253A (en) * | 1979-11-14 | 1981-08-04 | The United States Of America As Represented By The Secretary Of The Army | Topical prophylaxis against schistosomiasis |
| US4282355A (en) * | 1980-02-14 | 1981-08-04 | Hoechst Aktiengesellschaft | Process for the manufacture of bis-benzoxazolyl-stilbene compounds |
| US4789755A (en) * | 1987-10-07 | 1988-12-06 | Eastman Kodak Company | Process for the preparation of stilbenedicarboxylate derivatives |
-
1989
- 1989-03-01 US US07/317,383 patent/US4921964A/en not_active Expired - Lifetime
-
1990
- 1990-02-26 CA CA002050351A patent/CA2050351A1/en not_active Abandoned
- 1990-02-26 EP EP90904494A patent/EP0472525A1/en active Pending
- 1990-02-26 AT AT90420101T patent/ATE113039T1/de not_active IP Right Cessation
- 1990-02-26 DE DE69013376T patent/DE69013376T2/de not_active Expired - Fee Related
- 1990-02-26 EP EP90420101A patent/EP0385890B1/en not_active Expired - Lifetime
- 1990-02-26 WO PCT/US1990/001089 patent/WO1990010001A1/en not_active Ceased
- 1990-02-26 ES ES90420101T patent/ES2062471T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| WO1990010001A1 (en) | 1990-09-07 |
| EP0472525A1 (en) | 1992-03-04 |
| EP0385890B1 (en) | 1994-10-19 |
| DE69013376T2 (de) | 1995-03-30 |
| ATE113039T1 (de) | 1994-11-15 |
| EP0385890A1 (en) | 1990-09-05 |
| US4921964A (en) | 1990-05-01 |
| CA2050351A1 (en) | 1990-09-02 |
| DE69013376D1 (de) | 1994-11-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2079040T3 (es) | Oxidacion de la celulosa por una solucion de dioxido de nitrogeno en un hidrocarburo perfluorado. | |
| DE69015587D1 (de) | Hypoglykämische Oxazolidindion-Derivate. | |
| DK341483D0 (da) | Fremgangsmade til epoxidation af olefiniske forbindelser | |
| ES2084438T3 (es) | Catalizadores para reacciones de hidrosililacion. | |
| DK344488D0 (da) | Hexacycliske forbindelser | |
| DE68920355D1 (de) | Herstellungsverfahren von aromatischen Karbonatverbindungen. | |
| ES2062471T3 (es) | Procedimiento para la preparacion de derivados de estilbeno. | |
| EP0643155A3 (en) | Process for the production of fluorochemicals. | |
| IT1230873B (it) | Processo per la preparazione di peraloeteri da peraloolefine e nuovi peraloeteri ottenuti. | |
| ES8604126A1 (es) | Un procedimiento para preparar un p-isononanoiloxibenceno- sulfonato | |
| NO169073C (no) | Analogifremgangsmaate for fremstilling av substituerte 4-benzylpiperazinyl-forbindelser | |
| ATE84039T1 (de) | Zinnverbindungen, verwendbar als latente katalysatoren fuer die herstellung von polyurethanen. | |
| ATE66479T1 (de) | 3-methyl-substituierte phenylnaphthyridine und diese enthaltende arzneimittel. | |
| ES436033A1 (es) | Procedimiento para la obtencion de nuevas 1-aril-5-alquili- den-2, 4-dioxoimidazolidinas. | |
| FI103788B1 (fi) | Menetelmä 5-(2,4-difluorifenyyli)salisyylihapon valmistamiseksi | |
| ES2054231T3 (es) | Procedimiento para preparar oxido de estireno. | |
| AU591320B2 (en) | Bimetallic catalyst | |
| ATE88471T1 (de) | Azolylmethylcyloalkyloxirane, ihre herstellung und verwendung als pflanzenschutzmittel. | |
| ES483249A1 (es) | Procedimiento para la obtencion de diciclopentilen(2,2'-bis (4-alquil-6-t-butilfenoles). | |
| DK0684946T3 (es) | ||
| FI890798A0 (fi) | Foerfarande foer diacylering av foereningar som innehaoller tvao aromatiska kaernor. | |
| DK0410343T3 (da) | Anvendelse af bisphenolderivater til behandling af diabetes mellitus | |
| ATE59374T1 (de) | Verfahren zur herstellung von halogenalkoholen. | |
| TR23149A (tr) | Zararli bitki oeldueruecue bilesim | |
| FI933928A0 (fi) | Heteroarenylpiperaziner, foerfarande foer framstaellning av dessa och anvaendning som laekemedel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
Ref document number: 385890 Country of ref document: ES |