ES2064063T3 - Procedimiento de preparacion de una masa solida de captacion de mercurio. - Google Patents

Procedimiento de preparacion de una masa solida de captacion de mercurio.

Info

Publication number
ES2064063T3
ES2064063T3 ES91402902T ES91402902T ES2064063T3 ES 2064063 T3 ES2064063 T3 ES 2064063T3 ES 91402902 T ES91402902 T ES 91402902T ES 91402902 T ES91402902 T ES 91402902T ES 2064063 T3 ES2064063 T3 ES 2064063T3
Authority
ES
Spain
Prior art keywords
stage
copper
sulfide
mercury
solid mass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91402902T
Other languages
English (en)
Inventor
Charles Cameron
Philippe Courty
Georges Berrebi
Raymond Roumieu
Hans Rabehasaina
Francois Eschard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Europeene de Retraitement de Catalysateurs EURECAT
IFP Energies Nouvelles IFPEN
Original Assignee
Europeene de Retraitement de Catalysateurs EURECAT
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Europeene de Retraitement de Catalysateurs EURECAT, IFP Energies Nouvelles IFPEN filed Critical Europeene de Retraitement de Catalysateurs EURECAT
Application granted granted Critical
Publication of ES2064063T3 publication Critical patent/ES2064063T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0233—Compounds of Cu, Ag, Au
    • B01J20/0237—Compounds of Cu
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0285—Sulfides of compounds other than those provided for in B01J20/045
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Treating Waste Gases (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Gas Separation By Absorption (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UNA MASA SOLIDA DE CAPTACION DEL MERCURIO QUE COMPRENDE UN SOPORTE O DISPERSANTE MINERAL SOLIDO, ESENCIALMENTE COBRE Y AZUFRE AL MENOS EN PARTE EN FORMA DE SULFURO DE COBRE. LA INVENCION SE CARACTERIZA EN QUE ES EL PRODUCTO RESULTANTE DE LAS SIGUIENTES ETAPAS: A)SE INCORPORA AL MENOS UN COMPUESTO DE COBRE, DISTINTO DEL SULFURO, A UN SOPORTE O DISPERSANTE MINERAL SOLIDO. B)SE CALCINA EL PRODUCTO OBTENIDO EN LA ETAPA (A) DE MANERA A TRANSFORMAR AL MENOS EN PARTE EL O LOS COMPUESTOS DE COBRE QUE CONTIENE DE OXIDO DE COBRE (CUO Y/O CU SUB 2O), C)SE PONE EN CONTACTO EL PRODUCTO OBTENIDO EN LA ETAPA (B) O EN LA ETAPA (A) SI NO HA HABIDO ETAPA (B), CON AZUFRE ELEMENTAL, D)SE SOMETE EL PRODUCTO RESULTANTE DE LA ETAPA (C), LLAMADO PRECURSOR, A UN TRATAMIENTO TERMICO, EN ATMOSFERA NO OXIDANTE, BAJO BARRIDO DE GAS, A UNA TEMPERATURA Y DURANTE UN TIEMPO SUFICIENTES PARA PERMITIR LA FORMACION DE SULFURO DEL O DE LOS METALES PRESENTES.
ES91402902T 1990-10-30 1991-10-29 Procedimiento de preparacion de una masa solida de captacion de mercurio. Expired - Lifetime ES2064063T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR909013597A FR2668388B1 (fr) 1990-10-30 1990-10-30 Procede de preparation d'une masse solide de captation de mercure.

Publications (1)

Publication Number Publication Date
ES2064063T3 true ES2064063T3 (es) 1995-01-16

Family

ID=9401789

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91402902T Expired - Lifetime ES2064063T3 (es) 1990-10-30 1991-10-29 Procedimiento de preparacion de una masa solida de captacion de mercurio.

Country Status (11)

Country Link
US (1) US5350728A (es)
EP (1) EP0484233B1 (es)
JP (1) JP3198345B2 (es)
CN (1) CN1053597C (es)
AU (1) AU648120B2 (es)
DE (1) DE69101899T2 (es)
DZ (1) DZ1536A1 (es)
ES (1) ES2064063T3 (es)
FI (1) FI103871B1 (es)
FR (1) FR2668388B1 (es)
NO (1) NO176556C (es)

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RU2153395C1 (ru) * 1999-02-15 2000-07-27 Открытое акционерное общество "Органический синтез" Способ изготовления сорбента с металлосульфидным поглощающим слоем
DE19939382A1 (de) * 1999-08-05 2001-04-19 Ftu Gmbh Forschung Und Tech En Verfahren und Vorrichtung zur Abtrennung von Quecksilber aus heißen Pyrolysegasden
US6537443B1 (en) * 2000-02-24 2003-03-25 Union Oil Company Of California Process for removing mercury from liquid hydrocarbons
US8124036B1 (en) 2005-10-27 2012-02-28 ADA-ES, Inc. Additives for mercury oxidation in coal-fired power plants
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CA2601239C (en) 2005-03-17 2013-07-16 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US8150776B2 (en) 2006-01-18 2012-04-03 Nox Ii, Ltd. Methods of operating a coal burning facility
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GB0616343D0 (en) 2006-08-17 2006-09-27 Johnson Matthey Plc Mercury removal
US20080207443A1 (en) * 2007-02-28 2008-08-28 Kishor Purushottam Gadkaree Sorbent comprising activated carbon, process for making same and use thereof
US8741243B2 (en) 2007-05-14 2014-06-03 Corning Incorporated Sorbent bodies comprising activated carbon, processes for making them, and their use
US7998898B2 (en) * 2007-10-26 2011-08-16 Corning Incorporated Sorbent comprising activated carbon, process for making same and use thereof
JP2010537805A (ja) * 2007-08-29 2010-12-09 コーニング インコーポレイテッド 流体流から毒性金属を除去するプロセス
GB0802828D0 (en) * 2008-02-15 2008-03-26 Johnson Matthey Plc Absorbents
US8124213B2 (en) * 2008-05-30 2012-02-28 Corning Incorporated Flow-through sorbent comprising a metal sulfide
US20090297885A1 (en) * 2008-05-30 2009-12-03 Kishor Purushottam Gadkaree Composite Comprising An Inorganic Substrate With A Coating Comprising Activated Carbon And Metal Sulfide
US8691722B2 (en) * 2008-07-03 2014-04-08 Corning Incorporated Sorbent comprising activated carbon particles, sulfur and metal catalyst
GB0900965D0 (en) * 2009-01-21 2009-03-04 Johnson Matthey Plc Sorbents
US8268744B2 (en) * 2009-06-16 2012-09-18 Amcol International Corporation High shear method for manufacturing a synthetic smectite mineral
GB0914272D0 (en) * 2009-08-17 2009-09-30 Johnson Matthey Plc Sorbent
US8951487B2 (en) 2010-10-25 2015-02-10 ADA-ES, Inc. Hot-side method and system
US11298657B2 (en) 2010-10-25 2022-04-12 ADA-ES, Inc. Hot-side method and system
US8524179B2 (en) 2010-10-25 2013-09-03 ADA-ES, Inc. Hot-side method and system
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
AU2011212805B2 (en) 2010-02-04 2016-03-24 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
CA2792732C (en) 2010-03-10 2018-07-31 Martin A. Dillon Process for dilute phase injection of dry alkaline materials
US8784757B2 (en) 2010-03-10 2014-07-22 ADA-ES, Inc. Air treatment process for dilute phase injection of dry alkaline materials
US8025726B1 (en) * 2010-04-08 2011-09-27 Nalco Company Sulfur containing silica particle
WO2012044420A1 (en) * 2010-09-27 2012-04-05 Conocophillips Company In situ process for mercury removal
US8845986B2 (en) 2011-05-13 2014-09-30 ADA-ES, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US9017452B2 (en) 2011-11-14 2015-04-28 ADA-ES, Inc. System and method for dense phase sorbent injection
US20130202511A1 (en) * 2012-02-06 2013-08-08 Uop Llc Method for Removal of Heterocyclic Sulfur using Metallic Copper
GB201204650D0 (en) 2012-03-16 2012-05-02 Johnson Matthey Plc A method for producing a sulphided copper sorbent
US8992868B2 (en) * 2012-05-01 2015-03-31 Fuel Tech, Inc. Dry processes, apparatus compositions and systems for reducing mercury, sulfur oxides and HCl
US8883099B2 (en) 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
CN102698753B (zh) * 2012-05-15 2014-09-24 中国科学院过程工程研究所 一种用于汞氧化的催化剂、其制备方法及其用途
US8974756B2 (en) 2012-07-25 2015-03-10 ADA-ES, Inc. Process to enhance mixing of dry sorbents and flue gas for air pollution control
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GB201322461D0 (en) * 2013-12-18 2014-02-05 Johnson Matthey Plc Method for preparing a sorbent
CN105126557B (zh) * 2014-05-30 2017-03-01 北京三聚环保新材料股份有限公司 一种硫化铜脱汞剂的制备方法
US10350545B2 (en) 2014-11-25 2019-07-16 ADA-ES, Inc. Low pressure drop static mixing system
CN105170118B (zh) * 2015-09-30 2017-12-29 太仓碧奇新材料研发有限公司 一种去除印染废水中酸性橙ⅱ的钛白粉复合材料的制备方法
CN105498469B (zh) * 2015-11-27 2017-10-03 北京三聚环保新材料股份有限公司 一种硫化铜脱汞剂的制备方法
CN105854544A (zh) * 2016-05-24 2016-08-17 南京华电节能环保设备有限公司 一种烟气的除汞净化方法
FR3053260B1 (fr) * 2016-06-30 2020-12-11 Ifp Energies Now Masse de captation constitue d'une phase active sous forme cristalline
CN106179234B (zh) * 2016-08-05 2018-11-16 浙江品客智能科技股份有限公司 一种水过滤材料及其制备方法和应用及其水处理装置
CN108456574A (zh) * 2018-04-12 2018-08-28 西南石油大学 一种用于湿气脱汞的脱汞剂及其制备方法
CN108439642B (zh) * 2018-04-16 2022-03-11 中国石油工程建设有限公司 一种气田水高浓度汞高效脱除系统及方法
KR102248568B1 (ko) * 2018-07-26 2021-05-06 한국원자력연구원 방사성 핵종 흡착제, 이의 제조방법 및 이를 이용한 방사성 핵종의 제거 방법

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Also Published As

Publication number Publication date
FR2668388B1 (fr) 1994-09-09
FI103871B (fi) 1999-10-15
FI103871B1 (fi) 1999-10-15
FR2668388A1 (fr) 1992-04-30
NO176556B (no) 1995-01-16
FI915108A0 (fi) 1991-10-30
DZ1536A1 (fr) 2002-02-17
JP3198345B2 (ja) 2001-08-13
NO914221L (no) 1992-05-04
AU648120B2 (en) 1994-04-14
NO176556C (no) 1995-04-26
JPH05168912A (ja) 1993-07-02
NO914221D0 (no) 1991-10-28
EP0484233B1 (fr) 1994-05-04
CN1063239A (zh) 1992-08-05
US5350728A (en) 1994-09-27
EP0484233A1 (fr) 1992-05-06
CN1053597C (zh) 2000-06-21
FI915108A7 (fi) 1992-05-01
DE69101899D1 (de) 1994-06-09
AU8683891A (en) 1993-01-28
DE69101899T2 (de) 1994-08-25

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