ES2070858T3 - Procedimiento de preparacion de dispersiones coloidales de dioxido cerico en medio alcoholico. - Google Patents
Procedimiento de preparacion de dispersiones coloidales de dioxido cerico en medio alcoholico.Info
- Publication number
- ES2070858T3 ES2070858T3 ES88402049T ES88402049T ES2070858T3 ES 2070858 T3 ES2070858 T3 ES 2070858T3 ES 88402049 T ES88402049 T ES 88402049T ES 88402049 T ES88402049 T ES 88402049T ES 2070858 T3 ES2070858 T3 ES 2070858T3
- Authority
- ES
- Spain
- Prior art keywords
- ceric dioxide
- ceric
- dioxide
- procedure
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 title abstract 7
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 title abstract 7
- 239000006185 dispersion Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000001476 alcoholic effect Effects 0.000 title 1
- 239000000084 colloidal system Substances 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 abstract 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 abstract 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 abstract 1
- 229940093475 2-ethoxyethanol Drugs 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 238000001246 colloidal dispersion Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- -1 nitrate ions Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0004—Preparation of sols
- B01J13/0026—Preparation of sols containing a liquid organic phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0004—Preparation of sols
- B01J13/0047—Preparation of sols containing a metal oxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/224—Oxides or hydroxides of lanthanides
- C01F17/235—Cerium oxides or hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/30—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6
- C01F17/32—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6 oxide or hydroxide being the only anion, e.g. NaCeO2 or MgxCayEuO
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/42—Unsaturated compounds containing hydroxy or O-metal groups
- C07C59/52—Unsaturated compounds containing hydroxy or O-metal groups a hydroxy or O-metal group being bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C65/01—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups
- C07C65/03—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Colloid Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Catalysts (AREA)
- Paints Or Removers (AREA)
Abstract
LA INVENCION TIENE POR OBJETO UN PROCEDIMIENTO DE PREPARACION DE DISPERSIONES COLOIDALES DE DIOXIDO DE CERIO EN MEDIO ALCOHOLICO CARACTERIZADO PORQUE CONSISTE EN MEZZCLAR (A) OXIDO CERICO QUE COMPRENDE NITRATO DE AMONIO Y UN MIEMBRO ELEGIDO EN EL GRUPO FORMADO POR EL AGUA, EL METANOL, EL ACIDO ACETICO Y SUS MEZCLAS, (B) UN ACIDO HIDROXIFENILCARBOXILICO CON 7 A 20 ATOMOS DE CARBONO Y (C) UN ALCOHOL EVENTUALMENTE PORTADOR DE UN AGRUPAMIENTO ETER O CETONA, DESPUES ELIMINAR EL AGUA, EL METANOL, EL ACIDO ACETICO LIBERADO DURANTE EL CALENTAMIENTO Y EN SEPARAR LAS PARTICULAS SOLIDAS NO DISUELTAS. LA INVENCION PROPORCIONA COMPLEJOS ASOCIATIVOS DISPERSABLES EN EL ALCOHOL QUE COMPRENDEN DIOXIDO CERICO Y UN ACIDO HIDROXIFENILCARBOXILICO CON APROXIMADAMENTE 7 A 20 ATOMOS DE CARBONO EN LA RELACION MOLAR ACIDO ORGANICO/CEO2 DE AL MENOS 1/6.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/087,076 US4886624A (en) | 1987-08-19 | 1987-08-19 | Colloidal alcohol-dispersible association complexes of ceric dioxide and a hydroxyphenyl carboxylic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2070858T3 true ES2070858T3 (es) | 1995-06-16 |
Family
ID=22202978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES88402049T Expired - Lifetime ES2070858T3 (es) | 1987-08-19 | 1988-08-05 | Procedimiento de preparacion de dispersiones coloidales de dioxido cerico en medio alcoholico. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4886624A (es) |
| EP (1) | EP0304369B1 (es) |
| JP (1) | JP2785018B2 (es) |
| AT (1) | ATE121094T1 (es) |
| AU (2) | AU2141388A (es) |
| BR (1) | BR8804203A (es) |
| CA (1) | CA1316176C (es) |
| DE (1) | DE3853562T2 (es) |
| ES (1) | ES2070858T3 (es) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2583737B1 (fr) * | 1985-06-20 | 1987-08-14 | Rhone Poulenc Spec Chim | Nouveau compose de cerium iv et son procede de preparation. |
| US5308548A (en) * | 1985-06-20 | 1994-05-03 | Rhone-Poulenc Specialities Chimiques | Preparing a dispersible, sol-forming cerium (IV) composition |
| US4850009A (en) * | 1986-05-12 | 1989-07-18 | Clinicom Incorporated | Portable handheld terminal including optical bar code reader and electromagnetic transceiver means for interactive wireless communication with a base communications station |
| US5279789A (en) * | 1988-12-23 | 1994-01-18 | Rhone-Poulenc Chimie | Ceric oxide particulates having improved morphology |
| US5449387A (en) * | 1992-06-17 | 1995-09-12 | Rhone-Poulenc Chemicals Limited | Cerium (IV) catalyst compounds and promoting combustion of hydrocarbon fuels therewith |
| US6210451B1 (en) | 1995-02-21 | 2001-04-03 | Rhone-Poulenc Chimie | Colloidal organic sols comprising tetravalent metal oxide/organic acid complexes |
| FR2736042B1 (fr) * | 1995-06-30 | 1997-09-12 | Rhone Poulenc Chimie | Dispersion colloidale et composition redispersible sous forme d'une dispersion colloidale a base d'oxyde de cerium |
| FR2797199B1 (fr) * | 1999-08-04 | 2001-10-05 | Rhodia Terres Rares | Dispersion colloidale organique de particules essentiellement monocristallines d'au moins un compose a base d'au moins une terre rare, son procede de preparation et son utilisation |
| US6387981B1 (en) | 1999-10-28 | 2002-05-14 | 3M Innovative Properties Company | Radiopaque dental materials with nano-sized particles |
| US6730156B1 (en) | 1999-10-28 | 2004-05-04 | 3M Innovative Properties Company | Clustered particle dental fillers |
| US6376590B2 (en) | 1999-10-28 | 2002-04-23 | 3M Innovative Properties Company | Zirconia sol, process of making and composite material |
| AU3505400A (en) | 1999-10-28 | 2001-05-08 | 3M Innovative Properties Company | Dental materials with nano-sized silica particles |
| US6572693B1 (en) | 1999-10-28 | 2003-06-03 | 3M Innovative Properties Company | Aesthetic dental materials |
| FR2801299B1 (fr) * | 1999-11-23 | 2002-06-07 | Rhodia Terres Rares | Dispersion colloidale aqueuse a base d'au moins un compose d'un lanthanide et d'un complexant, procede de preparation et utilisation |
| US7393882B2 (en) | 2002-01-31 | 2008-07-01 | 3M Innovative Properties Company | Dental pastes, dental articles, and methods |
| FR2836479B1 (fr) * | 2002-02-27 | 2005-09-09 | Rhodia Elect & Catalysis | Utilisation d'un sol organique de cerium dans les peintures, notamment les lasures ou les vernis |
| FR2853261B1 (fr) * | 2003-04-04 | 2006-06-30 | Rhodia Elect & Catalysis | Dispersion colloidale d'un compose d'une terre rare comprenant un agent anti-oxydant et son utilisation comme adjuvant de gazole pour moteurs a combustion interne |
| JP5512280B2 (ja) | 2006-12-28 | 2014-06-04 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科充填剤及び方法 |
| CN106315657B (zh) * | 2016-08-08 | 2018-07-13 | 徐志祥 | 一种纳米金属氧化物的制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3231592A (en) * | 1961-05-08 | 1966-01-25 | Carborundum Co | Oil-dispersible metal oxide-fatty acid complexes and their manufacture |
| US4599201A (en) * | 1982-04-12 | 1986-07-08 | Rhone-Poulenc, Inc. | Process for preparing ceric carboxylates |
| US4545923A (en) * | 1982-06-11 | 1985-10-08 | Rhone-Poulenc Inc. | Process for preparing colloidal ceric oxide and complexes thereof with free organic acids |
| US4647401A (en) * | 1983-01-24 | 1987-03-03 | Rhone Poulenc Inc. | Process for preparing colloidal ceric oxide and complexes thereof with free organic acids |
| US4663439A (en) * | 1984-11-26 | 1987-05-05 | Rhone-Poulenc, Inc. | Process for the preparation of ceric alkoxides |
| GB8430244D0 (en) * | 1984-11-30 | 1985-01-09 | Atomic Energy Authority Uk | Preparation of materials |
-
1987
- 1987-08-19 US US07/087,076 patent/US4886624A/en not_active Expired - Fee Related
-
1988
- 1988-08-05 DE DE3853562T patent/DE3853562T2/de not_active Expired - Fee Related
- 1988-08-05 EP EP88402049A patent/EP0304369B1/fr not_active Expired - Lifetime
- 1988-08-05 AT AT88402049T patent/ATE121094T1/de not_active IP Right Cessation
- 1988-08-05 ES ES88402049T patent/ES2070858T3/es not_active Expired - Lifetime
- 1988-08-18 BR BR8804203A patent/BR8804203A/pt not_active Application Discontinuation
- 1988-08-18 AU AU21413/88A patent/AU2141388A/en not_active Abandoned
- 1988-08-18 CA CA000575122A patent/CA1316176C/en not_active Expired - Fee Related
- 1988-08-19 JP JP63204895A patent/JP2785018B2/ja not_active Expired - Lifetime
-
1992
- 1992-03-16 AU AU12937/92A patent/AU660657B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| BR8804203A (pt) | 1989-03-14 |
| DE3853562T2 (de) | 1995-12-07 |
| DE3853562D1 (de) | 1995-05-18 |
| EP0304369A2 (fr) | 1989-02-22 |
| AU660657B2 (en) | 1995-07-06 |
| JPS6468384A (en) | 1989-03-14 |
| US4886624A (en) | 1989-12-12 |
| ATE121094T1 (de) | 1995-04-15 |
| AU2141388A (en) | 1989-02-23 |
| EP0304369A3 (en) | 1990-08-16 |
| JP2785018B2 (ja) | 1998-08-13 |
| EP0304369B1 (fr) | 1995-04-12 |
| AU1293792A (en) | 1992-05-28 |
| CA1316176C (en) | 1993-04-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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