ES2075132T3 - USE OF METAL-PORPHYRINS AS BLEACHING CATALYSTS. - Google Patents
USE OF METAL-PORPHYRINS AS BLEACHING CATALYSTS.Info
- Publication number
- ES2075132T3 ES2075132T3 ES90200228T ES90200228T ES2075132T3 ES 2075132 T3 ES2075132 T3 ES 2075132T3 ES 90200228 T ES90200228 T ES 90200228T ES 90200228 T ES90200228 T ES 90200228T ES 2075132 T3 ES2075132 T3 ES 2075132T3
- Authority
- ES
- Spain
- Prior art keywords
- metal
- porphyrins
- bleaching catalysts
- iii
- bleaching
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004061 bleaching Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 150000007942 carboxylates Chemical class 0.000 abstract 1
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 230000002087 whitening effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Catalysts (AREA)
Abstract
SE REVELA LAS METALO-PORFIRINAS CON UNA MEJORADA ESTABILIDAD FRENTE A LA OXIDACION, PARA USARLAS COMO CATALIZADORAS BLANQUEADORES PERACIDAS EN EL BLANQUEAMIENTO DE TEJIDOS. LAS METALO-PORFIRINAS SON PROFIRINAS MN(III) O FE(III) CON AR SUSTITUYENTES EN LA POSICION MESO, ELEGIDAS ENTRE: (FORMULAS A, B Y C); DONDE N Y M PUEDEN SER 0 O 1, A PUEDE SER UN GRUPO SULFATO, FOSFATO O CARBOXILATO: B ES UN ALQUIL C1-C10, POLIETOXIALQUIL O HIDROXIALQUIL Y X1 Y X2 SON CL, BR, CH3, C2H5 O CH3O.METAL-PORPHYRINES WITH AN IMPROVED STABILITY AGAINST OXIDATION ARE REVEALED FOR USE AS PERCIDENT BLEACHING CATALYZERS IN TISSUE WHITENING. THE METAL-PORPHYRINS ARE PROFIRINES MN (III) OR FAITH (III) WITH AR SUBSTITUTES IN THE MESO POSITION, CHOSEN BETWEEN: (FORMULAS A, B AND C); WHERE N AND M MAY BE 0 OR 1, A MAY BE A GROUP OF SULPHATE, PHOSPHATE OR CARBOXYLATE: B IS A C1-C10 ALKYL, POLYETOXIALKYL OR HYDROXIALKYL AND X1 AND X2 ARE CL, BR, CH3, C2H5 OR CH3O.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB898904062A GB8904062D0 (en) | 1989-02-22 | 1989-02-22 | Metall-porphyrins for use as bleach catalyst |
| GB898905993A GB8905993D0 (en) | 1989-03-15 | 1989-03-15 | Metallo-porphyrins for use as bleach catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2075132T3 true ES2075132T3 (en) | 1995-10-01 |
Family
ID=26294997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90200228T Expired - Lifetime ES2075132T3 (en) | 1989-02-22 | 1990-01-31 | USE OF METAL-PORPHYRINS AS BLEACHING CATALYSTS. |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0384503B1 (en) |
| JP (1) | JPH02261547A (en) |
| AU (1) | AU612538B2 (en) |
| BR (1) | BR9000786A (en) |
| CA (1) | CA2010271A1 (en) |
| DE (1) | DE69020380T2 (en) |
| ES (1) | ES2075132T3 (en) |
| NO (1) | NO900787L (en) |
Families Citing this family (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69129150T2 (en) * | 1991-10-14 | 1998-10-08 | The Procter & Gamble Co., Cincinnati, Ohio | Detergent compositions with additives to prevent dye transfer |
| TR26870A (en) * | 1991-10-14 | 1994-08-22 | Procter & Gamble | Detergent compositions to prevent dye transfer during washing |
| EP0553607B1 (en) * | 1992-01-31 | 1998-03-18 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer in washing |
| US5445651A (en) * | 1992-01-31 | 1995-08-29 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer in washing |
| EP0553608B1 (en) * | 1992-01-31 | 1998-06-17 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer in washing |
| EP0596184B1 (en) * | 1992-11-06 | 1998-04-15 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer |
| US5599924A (en) * | 1992-08-14 | 1997-02-04 | Trustees Of The University Of Pennsylvania | Electron-deficient porphyrins and processes and intermediates for preparing same |
| US5493017A (en) * | 1992-08-14 | 1996-02-20 | The Trustees Of The University Of Pennsylvania | Ring-metalated porphyrins |
| US5371199B1 (en) * | 1992-08-14 | 1995-12-26 | Univ Pennsylvania | Substituted porphyrins porphyrin-containing polymers and synthetic methods therefor |
| US5817830A (en) * | 1992-08-14 | 1998-10-06 | Trustees Of The University Of Pennsylvania | Pyrrolic compounds |
| EP0596186A1 (en) * | 1992-11-06 | 1994-05-11 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer in washing |
| EP0596187A1 (en) * | 1992-11-06 | 1994-05-11 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer in washing |
| US5288746A (en) * | 1992-12-21 | 1994-02-22 | The Procter & Gamble Company | Liquid laundry detergents containing stabilized glucose/glucose oxidase as H2 O2 generation system |
| ES2111924T3 (en) * | 1993-04-08 | 1998-03-16 | Procter & Gamble | COMPOSITION AND PROCEDURE TO INHIBIT THE DYE TRANSFER. |
| CA2160231C (en) * | 1993-04-09 | 1999-09-21 | Marnix Karel Christiane Moens | Machine dishwashing method employing a metallo catalyst and enzymatic source of hydrogen peroxide |
| EP0622447A1 (en) * | 1993-04-26 | 1994-11-02 | The Procter & Gamble Company | Enzymatic detergent compositions inhibiting dye transfer |
| US5686014A (en) * | 1994-04-07 | 1997-11-11 | The Procter & Gamble Company | Bleach compositions comprising manganese-containing bleach catalysts |
| JP3009471B2 (en) * | 1994-04-07 | 2000-02-14 | ザ、プロクター、エンド、ギャンブル、カンパニー | Bleaching composition comprising a metal-containing bleaching catalyst and an antioxidant |
| US5908821A (en) * | 1994-05-11 | 1999-06-01 | Procter & Gamble Company | Dye transfer inhibiting compositions with specifically selected metallo catalysts |
| GB2294268A (en) | 1994-07-07 | 1996-04-24 | Procter & Gamble | Bleaching composition for dishwasher use |
| US5578136A (en) | 1994-08-31 | 1996-11-26 | The Procter & Gamble Company | Automatic dishwashing compositions comprising quaternary substituted bleach activators |
| JPH10513214A (en) * | 1995-02-02 | 1998-12-15 | ザ、プロクター、エンド、ギャンブル、カンパニー | Automatic dishwashing composition containing cobalt chelation catalyst |
| ATE209245T1 (en) * | 1995-02-02 | 2001-12-15 | Procter & Gamble | METHOD FOR REMOVAL OF TEA STAINS IN DISHWASHERS HAVING COMPOSITIONS CONTAINING COBALT (III) CATALYST |
| US5968881A (en) * | 1995-02-02 | 1999-10-19 | The Procter & Gamble Company | Phosphate built automatic dishwashing compositions comprising catalysts |
| DE69614114T2 (en) * | 1995-06-16 | 2002-04-25 | The Procter & Gamble Company, Cincinnati | FIBER COMPOSITIONS CONTAINING COBALT CATALYSTS |
| TR199701633T1 (en) * | 1995-06-16 | 1998-04-21 | The Procter & Gamble Company | Automatic dishwasher detergent compounds containing cobalt catalyst. |
| US5703034A (en) * | 1995-10-30 | 1997-12-30 | The Procter & Gamble Company | Bleach catalyst particles |
| EP0778342A1 (en) | 1995-12-06 | 1997-06-11 | The Procter & Gamble Company | Detergent compositions |
| DE19620267A1 (en) * | 1996-05-20 | 1997-11-27 | Henkel Kgaa | Catalytically active activator complexes with N¶4¶ ligands for peroxygen compounds |
| EP0927241A1 (en) * | 1996-08-26 | 1999-07-07 | The Procter & Gamble Company | Cellulase activity control by a terminator |
| DE19721886A1 (en) | 1997-05-26 | 1998-12-03 | Henkel Kgaa | Bleaching system |
| AU1463799A (en) | 1997-11-21 | 1999-06-15 | Procter & Gamble Company, The | Product applicator |
| GB9725614D0 (en) | 1997-12-03 | 1998-02-04 | United States Borax Inc | Bleaching compositions |
| GB0114155D0 (en) * | 2001-06-11 | 2001-08-01 | Unilever Plc | Complex for catalytically bleaching a substrate |
| DE10163331A1 (en) | 2001-12-21 | 2003-07-10 | Henkel Kgaa | Support-fixed bleach catalyst complex compounds are suitable as catalysts for peroxygen compounds |
| EP1590426B1 (en) | 2003-02-03 | 2014-01-08 | Unilever PLC | Laundry cleansing and conditioning compositions |
| US20070138674A1 (en) | 2005-12-15 | 2007-06-21 | Theodore James Anastasiou | Encapsulated active material with reduced formaldehyde potential |
| JP5401034B2 (en) | 2007-12-19 | 2014-01-29 | ライオン株式会社 | Bleaching aid and bleaching aid particles containing the bleaching aid |
| CN101922111B (en) * | 2010-09-14 | 2012-05-09 | 东华大学 | A method of low temperature activation bleaching using water-soluble metalloporphyrins |
| EP4592449A3 (en) | 2012-01-04 | 2025-10-22 | The Procter & Gamble Company | Fibrous structures comprising particles and methods for making same |
| EP3075832B1 (en) | 2015-03-30 | 2021-04-14 | Dalli-Werke GmbH & Co. KG | Manganese-amino acid compounds in cleaning compositions |
| JP6790257B2 (en) | 2016-11-01 | 2020-11-25 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | Leuco colorants as bluish agents in laundry care compositions, their packaging, kits and methods |
| ES2827831T3 (en) | 2016-11-01 | 2021-05-24 | Procter & Gamble | Methods for using leuco dyes as blueing agents in laundry care compositions |
| US11697905B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
| US11697906B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles and product-shipping assemblies for containing the same |
| JP6886045B2 (en) | 2017-01-27 | 2021-06-16 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | Activator-containing articles that exhibit consumer-acceptable article usage characteristics |
| US11697904B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
| EP3444328A1 (en) | 2017-08-18 | 2019-02-20 | The Procter & Gamble Company | Cleaning agent |
| EP3894527A1 (en) | 2018-12-14 | 2021-10-20 | The Procter & Gamble Company | Foaming fibrous structures comprising particles and methods for making same |
| US11485934B2 (en) | 2019-08-02 | 2022-11-01 | The Procter & Gamble Company | Foaming compositions for producing a stable foam and methods for making same |
| US20210148044A1 (en) | 2019-11-15 | 2021-05-20 | The Procter & Gamble Company | Graphic-Containing Soluble Articles and Methods for Making Same |
| EP4347933A1 (en) | 2021-05-28 | 2024-04-10 | The Procter & Gamble Company | Natural polymer-based fibrous elements comprising a surfactant and methods for making same |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1541576A (en) * | 1975-06-20 | 1979-03-07 | Procter & Gamble Ltd | Inhibiting dye ltransfer in washing |
| ATE123749T1 (en) * | 1987-04-17 | 1995-06-15 | David H Dolphin | PORPHYRINS, PROCESS FOR THE PRODUCTION THEREOF AND USES. |
| US4892941A (en) * | 1987-04-17 | 1990-01-09 | Dolphin David H | Porphyrins |
| GB8720863D0 (en) * | 1987-09-04 | 1987-10-14 | Unilever Plc | Metalloporphyrins |
-
1990
- 1990-01-31 DE DE1990620380 patent/DE69020380T2/en not_active Expired - Fee Related
- 1990-01-31 ES ES90200228T patent/ES2075132T3/en not_active Expired - Lifetime
- 1990-01-31 EP EP19900200228 patent/EP0384503B1/en not_active Expired - Lifetime
- 1990-02-16 CA CA 2010271 patent/CA2010271A1/en not_active Abandoned
- 1990-02-19 NO NO90900787A patent/NO900787L/en unknown
- 1990-02-20 BR BR9000786A patent/BR9000786A/en not_active IP Right Cessation
- 1990-02-20 JP JP2039565A patent/JPH02261547A/en active Pending
- 1990-02-20 AU AU49927/90A patent/AU612538B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| AU612538B2 (en) | 1991-07-11 |
| AU4992790A (en) | 1990-08-30 |
| DE69020380T2 (en) | 1995-12-07 |
| BR9000786A (en) | 1991-01-22 |
| EP0384503B1 (en) | 1995-06-28 |
| EP0384503A1 (en) | 1990-08-29 |
| CA2010271A1 (en) | 1990-08-22 |
| JPH02261547A (en) | 1990-10-24 |
| DE69020380D1 (en) | 1995-08-03 |
| NO900787L (en) | 1990-08-23 |
| NO900787D0 (en) | 1990-02-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2075132T3 (en) | USE OF METAL-PORPHYRINS AS BLEACHING CATALYSTS. | |
| BR8707405A (en) | HAIR DYEING COMPOSITION WITH OXIDATION BASED ON A GEL FORM APPLICATION MASS AND PROCESS FOR HAIR DYEING | |
| ES2040261T3 (en) | PROCEDURE FOR PREPARING 6-FLUOR-4-OXO-1,4-DIHYDROKINOLINE-3-CARBOXYLIC ACIDS AND 9-FLUOR-3-METHYL-7-OXO-2,3-DIHYDRO-7H-PIRIDO (1,2, 3-DE) (1,4) BENZOXAZINA-6-CARBOXILICO SUBSTITUTED. | |
| DE69015650D1 (en) | Manufacture of diamond-coated cutting tools. | |
| ES2097291T3 (en) | MANGANESE BLEACHING CATALYST AND ITS USE. | |
| ES2107495T3 (en) | DISHWASHER COMPOSITION. | |
| ES2066991T3 (en) | HIPOGLUCEMIANT AGENTS OF OXAZOLIDINADIONA. | |
| ATE63110T1 (en) | COLORLESS KETIMINE, THEIR PRODUCTION AND USE AS CROSSLINKING AGENTS. | |
| ATE133663T1 (en) | ANTIGLANCOMA COMPOSITIONS CONTAINING 3-ARYLCARBONYL-1-AMINOALKYL-1H-INDOLE | |
| DE2962573D1 (en) | Fluorescent dyestuffs of the stilbene series, process for their preparation and their use in the whitening of organic materials and as laser dyestuffs | |
| PT77717A (en) | VINYLENE CARBONATE POLYMERISATES PROCESS FOR THEIR PREPARATION AND THEIR PREPARATION AND THEIR USE | |
| DE3770889D1 (en) | MANUFACTURE OF CUBIC BORNITRIDE. | |
| IE39646L (en) | Agents for bleaching or colouring hair | |
| FI920898A0 (en) | EGALISERANDE OXIDERANDE HAORFAERGNINGS- MEDEL. | |
| ATE74629T1 (en) | CONTINUOUS PRODUCTION OF DIALKAN SULFONYL PEROXIDES. | |
| NO863453D0 (en) | HOWEPOROEST ALUMINUM PHOSPHATE. | |
| GB1461062A (en) | Oxygenated tricyclic derivatives as perfuming and flavouring agents | |
| DE3762879D1 (en) | POLYSULFURED OLEFIN COMPOSITIONS, THEIR PRODUCTION AND THEIR USE AS LUBRICANT ADDITIVES. | |
| FR2531336B1 (en) | COMPOSITION CONTAINING IMIDAZOLIDINYLUREA AND PARABENATES, USEFUL AS A COSMETIC PRESERVATIVE, COMPATIBLE WITH AQUEOUS-BASED PRODUCTS | |
| IE45037L (en) | Heteroarylspiroisobenzofuran compounds | |
| MY104777A (en) | Benzoxazine dyes | |
| ATE120718T1 (en) | PREPARATION OF PEROXIDE COMPOSITIONS. | |
| DE69012882D1 (en) | Manufacture of nitrogen compositions. | |
| ATE61360T1 (en) | ANTIOXIDANT COMPOUNDS, THEIR PRODUCTION AND USE. | |
| ATE110320T1 (en) | MANUFACTURE OF CONTAINERS. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
Ref document number: 384503 Country of ref document: ES |