ES2075865T3 - Procedimiento para la hidroformilacion de una olefina. - Google Patents

Procedimiento para la hidroformilacion de una olefina.

Info

Publication number
ES2075865T3
ES2075865T3 ES90119931T ES90119931T ES2075865T3 ES 2075865 T3 ES2075865 T3 ES 2075865T3 ES 90119931 T ES90119931 T ES 90119931T ES 90119931 T ES90119931 T ES 90119931T ES 2075865 T3 ES2075865 T3 ES 2075865T3
Authority
ES
Spain
Prior art keywords
reactor
stage
liquid phase
olephine
type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90119931T
Other languages
English (en)
Inventor
Chihiro Miyazawa
Hiroshi Mikami
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Application granted granted Critical
Publication of ES2075865T3 publication Critical patent/ES2075865T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

UN PROCESO PARA HIDROMORFILACION DE UNA OLEFINA, EL CUAL COMPRENDE REACCIONAR UNA OLEFINA CON MONOXIDO DE CARBONO E HIDROGENO EN PRESENCIA DE UN CATALIZADOR DE RODIO QUE TIENE UN COMPUESTO DE FOSFORO ORGANICO TRIVALENTE COMO LIGANTE, EN DONDE LA REACCION DE HIDROMORFILACION SE REALIZA MEDIANTE DOS SISTEMAS DE REACTOR DE ETAPA, P.EJ., UN PRIMER SISTEMA DE REACTOR DE ETAPA QUE COMPRENDE UN REACTOR O REACTORES TENIENDO UNA MEZCLA CARACTERISTICA DE LA FASE LIQUIDA QUE SUSTANCIALMENTE ES DEL TIPO DE MEZCLADO COMPLETO, Y UN SEGUNDO SISTEMA DE REACTOR DE ETAPA QUE ES UN SISTEMA DE REACCION DEL TIPO DE SOLUCION CATALIZADORA CIRCULANTE Y CONTENIENDO UN REACTOR O REACTORES QUE TIENEN UNA CARACTERISTICA DE MEZCLADO DEL TIPO DE FLUJO POR PISTON, EN DONDE, CUANDO LA CARACTERISTICA DE MEZCLADO DE LA FASE LIQUIDA ESTA REPRESENTADA POR UN MODELO DE DIFUSION Y UN NUMERO NO DIMENSIONAL U (REFERENCIADO A PARTIR DE AQUI COMO UN "PARAMETRO DE FLUJO DE MEZCLADO") DEFINIDO POR LA FORMULA (I): EN DONDE U ES UNA VELOCIDAD MEDIA DE FLUJO (CM/SEG), L ES LA LONGITUD (CM) DE LA CAPA DE REACCION, Y E ES UN COEFICIENTE MEDIO DE DIFUSION (CM2/SEG), VALE AL MENOS 0,4 , ENTONCES UN PRODUCTO GASEOSO O UNA MEZCLA DE GAS-LIQUIDO DESCARGADOS DEL PRIMER SISTEMA DE ETAPA DE REACTOR, SE SEPARA HACIA UNA CORRIENTE QUE CONTIENE LA OLEFINA NO REACCIONADA Y OTRA CORRIENTE, Y UNA PARTE O LA TOTALIDAD DE LA CORRIENTE QUE CONTIENE LA OLEFINA NO REACCIONADA SE SUMINISTRA AL SEGUNDO SISTEMA DE ETAPA DE REACTOR.
ES90119931T 1989-10-19 1990-10-17 Procedimiento para la hidroformilacion de una olefina. Expired - Lifetime ES2075865T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27227589 1989-10-19

Publications (1)

Publication Number Publication Date
ES2075865T3 true ES2075865T3 (es) 1995-10-16

Family

ID=17511582

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90119931T Expired - Lifetime ES2075865T3 (es) 1989-10-19 1990-10-17 Procedimiento para la hidroformilacion de una olefina.

Country Status (8)

Country Link
US (1) US5105018A (es)
EP (1) EP0423769B1 (es)
JP (1) JP2893902B2 (es)
KR (1) KR0152655B1 (es)
BR (1) BR9005296A (es)
CA (1) CA2027991C (es)
DE (1) DE69017346T2 (es)
ES (1) ES2075865T3 (es)

Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN117120946A (zh) * 2021-04-26 2023-11-24 三菱电机株式会社 数控装置、学习装置及颤振的抑制方法

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US5410091A (en) * 1994-06-02 1995-04-25 Quimica Oxal C.A. Rhodium catalyzed oxo process in tubular reactor
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DE19530698A1 (de) * 1995-08-21 1997-02-27 Basf Ag Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags
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FR2763938B1 (fr) * 1997-05-27 1999-10-22 Inst Francais Du Petrole Procede pour l'hydroformylation d'olefines
DE19836807A1 (de) 1998-08-14 2000-02-17 Basf Ag Verfahren zur Herstellung von Aldehyden und/oder Alkoholen oder Aminen
US7217321B2 (en) * 2001-04-06 2007-05-15 California Institute Of Technology Microfluidic protein crystallography techniques
DE19954665B4 (de) * 1999-11-13 2004-02-12 Celanese Chemicals Europe Gmbh Verfahren zur Hydroformylierung olefinisch ungesättigter Verbindungen
US6906164B2 (en) * 2000-12-07 2005-06-14 Eastman Chemical Company Polyester process using a pipe reactor
CN1225444C (zh) * 2001-03-08 2005-11-02 三菱化学株式会社 醛类的制备方法
DE10160368B4 (de) * 2001-12-08 2004-04-08 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von Aldehyden
JP2006503086A (ja) * 2002-10-15 2006-01-26 ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション ビス−キレート化配位子及びカルボニル化方法におけるその使用
KR20060096433A (ko) 2003-10-21 2006-09-11 바스프 악티엔게젤샤프트 알데히드의 연속식 제조 방법
DE10357718A1 (de) 2003-12-09 2005-07-21 Basf Ag Verfahren zur Herstellung von Tricyclodecandialdehyd
KR100547587B1 (ko) * 2004-06-12 2006-01-31 주식회사 엘지화학 인을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
US7943094B2 (en) * 2006-12-07 2011-05-17 Grupo Petrotemex, S.A. De C.V. Polyester production system employing horizontally elongated esterification vessel
WO2008147129A1 (en) * 2007-05-29 2008-12-04 Lg Chem, Ltd. Method for the hydroformylation of olefins and apparatus using the same
US8739145B2 (en) * 2008-03-26 2014-05-27 Avaya Inc. Super nested block method to minimize coverage testing overhead
KR101229195B1 (ko) * 2009-10-07 2013-02-01 주식회사 엘지화학 올레핀으로부터 고 수율의 알데히드 제조 방법 및 이에 사용되는 반응 장치
CN102115433B (zh) * 2010-12-06 2013-09-11 淄博诺奥化工有限公司 一种乙烯低压羰基合成生产丙醛的方法
CN102826972B (zh) * 2011-06-17 2015-05-13 中国石油化工股份有限公司 一种烯烃氢甲酰化反应制备醛的方法
CA2858351C (en) 2011-12-20 2016-11-22 Dow Technology Investments Llc A hydroformylation process
SG11201404813WA (en) 2012-03-07 2014-10-30 Basf Se METHOD FOR THERMAL INTEGRATION IN THE HYDROGENATION AND DISTILLATION OF C<sb>3</sb>-C<sb>20</sb> ALDEHYDES
WO2013144735A1 (en) 2012-03-26 2013-10-03 Sasol Technology (Proprietary) Limited Conversion of a mixture of c2 - and c3 -olefins to butanol
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
MY172695A (en) 2012-04-12 2019-12-10 Basf Se Method for replenishing the catalyst in continuous hydroformylation
US9340480B2 (en) 2013-04-30 2016-05-17 Oxea Corporation Aldehyde production process with multi-stage condensation
JP2016540780A (ja) 2013-12-19 2016-12-28 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
PL3319951T3 (pl) 2015-07-10 2022-02-28 Basf Se Sposób hydroformylowania 2-podstawionych butadienów oraz wytwarzania ich produktów pochodnych, w szczególności ambroksu
WO2017064064A1 (en) 2015-10-12 2017-04-20 Basf Se Hydroformylation process for producing 1,6-disubstituted hexane derivatives
EP3429984A1 (en) * 2016-03-18 2019-01-23 Dow Technology Investments LLC Hydroformylation process
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
JP2020523297A (ja) 2017-06-13 2020-08-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ １，６−ヘキサンジオール誘導体を製造するためのヒドロホルミル化方法
SE1930249A1 (en) * 2019-07-18 2020-11-17 Perstorp Ab USE OF A METHOD FOR REDUCTION OF HEAVY END FORMATION AND CATALYST LOSS IN A HYDROFORMYLATION PROCESS COMPRISING A BIDENTATE PHOSPHITE LIGAND
EP4010309A1 (en) 2019-08-09 2022-06-15 OQ Chemicals Corporation Hydroformylation system with vent reactor recycle to primary reactor
US12281063B2 (en) 2020-02-11 2025-04-22 Basf Se Low-pressure hydroformylation of diisobutene
US20230406802A1 (en) 2020-12-22 2023-12-21 Dow Technology Investments Llc Hydroformylation reaction processes
CN117942895A (zh) * 2024-01-23 2024-04-30 兖矿鲁南化工有限公司 一种丁醇装置反应器气液混合反应系统

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DE2965157D1 (en) * 1979-03-21 1983-05-11 Davy Mckee London Process for the production of aldehydes by hydroformylation of alkenes
US4528404A (en) * 1983-03-16 1985-07-09 Exxon Research And Engineering Co. High temperature hydroformylation in the presence of triarylphosphine rhodium carbonyl hydride complex catalyst systems
CA1259331A (en) * 1984-03-30 1989-09-12 Gregory J. Dembowski Process for recovery of phosphorus ligand from vaporized aldehyde
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117120946A (zh) * 2021-04-26 2023-11-24 三菱电机株式会社 数控装置、学习装置及颤振的抑制方法

Also Published As

Publication number Publication date
EP0423769A2 (en) 1991-04-24
JPH03204831A (ja) 1991-09-06
KR910007852A (ko) 1991-05-30
EP0423769A3 (en) 1991-07-24
KR0152655B1 (ko) 1998-10-15
BR9005296A (pt) 1991-09-17
CA2027991C (en) 2001-04-24
US5105018A (en) 1992-04-14
CA2027991A1 (en) 1991-04-20
JP2893902B2 (ja) 1999-05-24
DE69017346D1 (de) 1995-04-06
DE69017346T2 (de) 1995-10-12
EP0423769B1 (en) 1995-03-01

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