ES2075914T3 - Un metodo para fabricar catodos para pilas de carbonato fundido. - Google Patents

Un metodo para fabricar catodos para pilas de carbonato fundido.

Info

Publication number
ES2075914T3
ES2075914T3 ES91108138T ES91108138T ES2075914T3 ES 2075914 T3 ES2075914 T3 ES 2075914T3 ES 91108138 T ES91108138 T ES 91108138T ES 91108138 T ES91108138 T ES 91108138T ES 2075914 T3 ES2075914 T3 ES 2075914T3
Authority
ES
Spain
Prior art keywords
carbonate
cast
manufacturing
casodes
batteries
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91108138T
Other languages
English (en)
Inventor
Ermete Antolini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Leonardo SpA
Original Assignee
Finmeccanica SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Finmeccanica SpA filed Critical Finmeccanica SpA
Application granted granted Critical
Publication of ES2075914T3 publication Critical patent/ES2075914T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8825Methods for deposition of the catalytic active composition
    • H01M4/8857Casting, e.g. tape casting, vacuum slip casting
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • H01M4/8621Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H01M4/8668Binders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8878Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882Heat treatment, e.g. drying, baking
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9016Oxides, hydroxides or oxygenated metallic salts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/14Fuel cells with fused electrolytes
    • H01M8/141Fuel cells with fused electrolytes the anode and the cathode being gas-permeable electrodes or electrode layers
    • H01M8/142Fuel cells with fused electrolytes the anode and the cathode being gas-permeable electrodes or electrode layers with matrix-supported or semi-solid matrix-reinforced electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8689Positive electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/14Fuel cells with fused electrolytes
    • H01M2008/147Fuel cells with molten carbonates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0048Molten electrolytes used at high temperature
    • H01M2300/0051Carbonates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/14Fuel cells with fused electrolytes
    • H01M8/148Measures, other than selecting a specific electrode material, to reduce electrode dissolution
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Thermal Sciences (AREA)
  • Fuel Cell (AREA)
  • Inert Electrodes (AREA)
  • Processing Of Solid Wastes (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Measurement Of Radiation (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

LA INVENCION SE REFIERE A UN METODO PARA FABRICAR CATODOS DE OXIDO DE NIQUEL DE LITIO PARA CELULAS DE CARBONATO FUNDIDO. DE ACUERDO CON LA INVENCION, EN UN PRIMER PASO, SE PREPARA UN MATERIAL VERDE, DE NIQUEL EN POLVO Y DE CARBONATO DE LITIO MEZCLADOS INTIMAMENTE, Y EN UN SEGUNDO PASO, ESTE MATERIAL VERDE SE INTRODUCE LA CELULA Y SE CALIENTA A UNA TEMPERATURA DE OPERACION DE LA CELULA. DURANTE ESTA OPERACION, TIENE LUGAR LO SIGUIENTE: LA OXIDACION DEL NIQUEL, LA LITIACION DEL NIQUEL Y LA UNION DE LA PLACA.
ES91108138T 1990-06-01 1991-05-21 Un metodo para fabricar catodos para pilas de carbonato fundido. Expired - Lifetime ES2075914T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT12469A IT1241857B (it) 1990-06-01 1990-06-01 Procedimento per la fabbricazione di catodi per celle a carbonati fusi

Publications (1)

Publication Number Publication Date
ES2075914T3 true ES2075914T3 (es) 1995-10-16

Family

ID=11140533

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91108138T Expired - Lifetime ES2075914T3 (es) 1990-06-01 1991-05-21 Un metodo para fabricar catodos para pilas de carbonato fundido.

Country Status (8)

Country Link
EP (1) EP0473882B1 (es)
AT (1) ATE124172T1 (es)
DE (1) DE69110581T2 (es)
DK (1) DK0473882T3 (es)
ES (1) ES2075914T3 (es)
FI (1) FI912633L (es)
HU (1) HUT59184A (es)
IT (1) IT1241857B (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4235514C2 (de) * 1992-10-21 1995-12-07 Fraunhofer Ges Forschung Poröse sauerstoffverzehrende Elektrode, Verfahren zu deren Herstellung und deren Verwendung
DE4241266C1 (de) * 1992-12-08 1994-07-21 Mtu Friedrichshafen Gmbh Verfahren zur Herstellung der Kathode einer Schmelzcarbonat-Brennstoffzelle
IT1269173B (it) * 1994-01-04 1997-03-21 Finmeccanica Spa Metodo per la fabbricazione di catodi per celle a combustibile
IT1269334B (it) * 1994-04-19 1997-03-26 Finmeccanica Spa Azienda Ansal Metodo per la fabbricazione di catodi per celle a combustibile
DE19609313C1 (de) * 1996-03-09 1997-09-25 Mtu Friedrichshafen Gmbh Verfahren zur Herstellung einer Kathode für eine Schmelzkarbonat-Brennstoffzelle und eine nach dem Verfahren hergestellte Kathode
DE102006047823A1 (de) * 2006-08-07 2008-02-14 Mtu Cfc Solutions Gmbh Elektrode für eine Schmelzkarbonat-Brennstollzelle und Verfahren zu ihrer Herstellung
CN113363511B (zh) * 2021-05-28 2022-12-16 华能国际电力股份有限公司 一种熔融碳酸盐燃料电池阴极材料及制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4386040A (en) * 1981-08-31 1983-05-31 General Electric Company Method of producing lithium nickel oxide cathode for molten carbonate fuel cell
US4891280A (en) * 1986-04-25 1990-01-02 The United States Of America As Represented By The United States Department Of Energy Cathode for molten carbonate fuel cell

Also Published As

Publication number Publication date
DK0473882T3 (da) 1995-10-30
FI912633A7 (fi) 1991-12-02
ATE124172T1 (de) 1995-07-15
IT9012469A1 (it) 1991-12-01
HUT59184A (en) 1992-04-28
EP0473882B1 (en) 1995-06-21
FI912633A0 (fi) 1991-05-31
EP0473882A1 (en) 1992-03-11
HU911825D0 (en) 1991-12-30
IT9012469A0 (it) 1990-06-01
DE69110581T2 (de) 1996-02-01
DE69110581D1 (de) 1995-07-27
FI912633L (fi) 1991-12-02
IT1241857B (it) 1994-02-01

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