ES2079236T3 - Procedimiento de epoxidacion que emplea catalizadores de silicalita ricos en titanio. - Google Patents

Procedimiento de epoxidacion que emplea catalizadores de silicalita ricos en titanio.

Info

Publication number
ES2079236T3
ES2079236T3 ES93303310T ES93303310T ES2079236T3 ES 2079236 T3 ES2079236 T3 ES 2079236T3 ES 93303310 T ES93303310 T ES 93303310T ES 93303310 T ES93303310 T ES 93303310T ES 2079236 T3 ES2079236 T3 ES 2079236T3
Authority
ES
Spain
Prior art keywords
rich
titanium
silicalite catalysts
epoxidation procedure
hydrogen peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93303310T
Other languages
English (en)
Inventor
Guy L Crocco
John G Zajacek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lyondell Chemical Technology LP
Original Assignee
Arco Chemical Technology LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25368548&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2079236(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Arco Chemical Technology LP filed Critical Arco Chemical Technology LP
Application granted granted Critical
Publication of ES2079236T3 publication Critical patent/ES2079236T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

LAS OLEFINAS SE EXPOXIDAN MEDIANTE PEROXIDO DE HIDROGENO EN LA PRESENCIA DE UN CATALIZADOR DE ZEOLITO DE SILICATO DE TITANIO EN FORMA CRISTALINA QUE TIENE UNA RELACION MOLAR SI:TI EN LA BANDA DE 8:1 Y 23:1. SE OBTIENE UNA ALTA PRODUCCION DE EPOXIDOS CON UNA MINIMA PERDIDA NO SELECTIVA TANTO DE PEROXIDO DE HIDROGENO COMO DE OLEFINA.
ES93303310T 1992-04-30 1993-04-28 Procedimiento de epoxidacion que emplea catalizadores de silicalita ricos en titanio. Expired - Lifetime ES2079236T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/876,772 US5262550A (en) 1992-04-30 1992-04-30 Epoxidation process using titanium-rich silicalite catalysts

Publications (1)

Publication Number Publication Date
ES2079236T3 true ES2079236T3 (es) 1996-01-01

Family

ID=25368548

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93303310T Expired - Lifetime ES2079236T3 (es) 1992-04-30 1993-04-28 Procedimiento de epoxidacion que emplea catalizadores de silicalita ricos en titanio.

Country Status (6)

Country Link
US (1) US5262550A (es)
EP (1) EP0568336B1 (es)
JP (1) JPH069592A (es)
AT (1) ATE129708T1 (es)
DE (1) DE69300720T2 (es)
ES (1) ES2079236T3 (es)

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US5468885A (en) * 1993-12-20 1995-11-21 Arco Chemical Technology, L.P. Epoxidizer oxygen recovery
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US5384418A (en) * 1994-01-25 1995-01-24 Arco Chemical Technology, L.P. Integrated process for epoxide production
US5474754A (en) * 1994-08-15 1995-12-12 Arco Chemical Technology, L.P. Preparation of an aluminosilicotitanate isomorphous with zeolite beta
US5463090A (en) * 1994-10-27 1995-10-31 Arco Chemical Technology, L.P. Integrated process for epoxide production
US5646314A (en) * 1994-11-16 1997-07-08 Arco Chemical Technology, L.P. Process for titanium silicalite-catalyzed epoxidation
US5523426A (en) * 1995-01-04 1996-06-04 Arco Chemical Technology, L.P. Integrated process for epoxidation
US5693834A (en) * 1995-03-15 1997-12-02 Arco Chemical Technology, L.P. Integrated process for epoxidation
US5591875A (en) * 1995-08-02 1997-01-07 Chang; Te Epoxidation Process
EP0771793B1 (en) * 1995-10-31 2001-04-04 Nippon Shokubai Co., Ltd. Method for the production of an epoxy compound
US5723637A (en) * 1995-12-06 1998-03-03 Sumitomo Chemical Company, Limited Process for producing propylene oxide
DE19600708A1 (de) * 1996-01-11 1997-07-17 Basf Ag Oxidationskatalysator mit einem Gehalt an Lanthanoidmetallen, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators
US5741749A (en) 1996-02-13 1998-04-21 Arco Chemical Technology, L.P. Regeneration of a titanium-containing molecular sieve
DE19607577A1 (de) * 1996-02-29 1997-09-04 Basf Ag Netzkatalysator auf Basis von Titan- oder Vanadiumzeolithen und inerten Netzgeweben zur Beschleunigung von Oxidationsreaktionen
ES2126485B1 (es) * 1996-05-16 1999-12-01 Univ Valencia Politecnica Procedimiento y catalizadores para la obtencion de epoxidos y derivados hidroxilados de acidos y esteres de acidos grasos.
DE19623608A1 (de) * 1996-06-13 1997-12-18 Basf Ag Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid oder Hydroperoxiden
DE19623611A1 (de) * 1996-06-13 1997-12-18 Basf Ag Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid
BE1010716A3 (fr) * 1996-10-25 1998-12-01 Solvay Procede de regeneration de catalyseurs de type silicalite au titane.
GB9707981D0 (en) * 1997-04-21 1997-06-11 Exxon Chemical Patents Inc Molecular sieve
DE19723751A1 (de) * 1997-06-06 1998-12-10 Basf Ag Formkörper und Verfahren zu dessen Herstellung
FR2764301B1 (fr) * 1997-06-09 1999-07-30 Elf Antar France Composition de carburant comprenant des composes oxygenes pour moteurs diesel
WO1998056780A1 (es) * 1997-06-10 1998-12-17 Universidad Politecnica De Valencia Procedimiento y catalizadores para la obtencion de epoxidos y derivados hidroxilados de acidos y esteres de acidos grasos
US5849938A (en) 1997-09-02 1998-12-15 Arco Chemical Technology, L.P. Separation of methanol and propylene oxide from a reaction mixture
BE1011456A3 (fr) * 1997-09-18 1999-09-07 Solvay Procede de fabrication d'un oxiranne.
BE1011576A3 (fr) * 1997-11-27 1999-11-09 Solvay Produit a base d'epichlorhydrine et procede de fabrication de ce produit.
BE1011578A3 (fr) * 1997-11-27 1999-11-09 Solvay Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de ce catalyseur.
BE1011577A3 (fr) * 1997-11-27 1999-11-09 Solvay Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de catalyseur.
KR100429675B1 (ko) * 1998-03-26 2004-05-03 렙솔 퀴미카 에스.에이. 올레핀계 화합물을 과산화수소로 에폭시화시키는 방법
DE19835907A1 (de) * 1998-08-07 2000-02-17 Basf Ag Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid
DE19839792A1 (de) * 1998-09-01 2000-03-02 Basf Ag Verfahren zur Herstellung eines Titansilikates mit RUT-Struktur
RU2234369C2 (ru) 1999-04-08 2004-08-20 Дау Глобал Текнолоджиз Инк. Способ гидроокисления олефинов до оксидов олефинов с использованием катализатора на основе окисленного золота
KR20000071797A (ko) * 1999-04-28 2000-11-25 나까니시 히로유끼 하이드록실화용 촉매 및 방향족 하이드록시 화합물의 제조방법
JP4325045B2 (ja) * 1999-11-09 2009-09-02 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法、該触媒及び該触媒を用いたオキシラン化合物の製造方法
DE19954322A1 (de) 1999-11-10 2001-05-17 Basf Ag Oxid und Verfahren zu dessen Herstellung
EP1122246A1 (de) 2000-02-07 2001-08-08 Degussa AG Verfahren zur Epoxidierung von Olefinen
EP1122247A1 (de) 2000-02-07 2001-08-08 Degussa AG Verfahren zur Epoxidierung von Olefinen
EP1122248A1 (de) 2000-02-07 2001-08-08 Degussa AG Verfahren zur Epoxidierung von Olefinen
FR2806084A1 (fr) * 2000-03-10 2001-09-14 Solvay Procede de fabrication d'un oxiranne
DE10015246A1 (de) * 2000-03-28 2001-10-04 Basf Ag Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid
IT1318680B1 (it) 2000-08-11 2003-08-27 Enichem Spa Processo per la produzione in continuo di ossidi olefinici.
DE50115570D1 (de) 2001-01-08 2010-09-09 Evonik Degussa Gmbh Verfahren zur Epoxidierung von Olefinen
US6596881B2 (en) 2001-06-13 2003-07-22 Degussa Ag Process for the epoxidation of olefins
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US6749668B2 (en) 2001-06-18 2004-06-15 Degussa Ag Process for the recovery of combustible components of a gas stream
JP2004525073A (ja) * 2001-08-13 2004-08-19 ダウ グローバル テクノロジーズ インコーポレイティド オレフィンオキシドの連続製造方法
US6610865B2 (en) 2001-08-15 2003-08-26 Degussa Ag Process for the epoxidation of olefins
US6596883B2 (en) 2001-08-23 2003-07-22 Degussa Ag Process for the epoxidation of olefins
US6720436B2 (en) 2002-03-18 2004-04-13 Degussa Ag Process for the epoxidation of olefins
US7141683B2 (en) 2002-05-02 2006-11-28 Degussa Ag Process for the epoxidation of olefins
US6838572B2 (en) 2002-09-30 2005-01-04 Degussa Ag Process for the epoxidation of olefins
US7722847B2 (en) 2002-09-30 2010-05-25 Evonik Degussa Gmbh Aqueous hydrogen peroxide solutions and method of making same
FR2846964B1 (fr) 2002-11-12 2006-07-21 Procede de fabrication de 1,2-epoxy-3-chloropropane
US7169945B2 (en) 2002-11-26 2007-01-30 Degussa Ag Process for the epoxidation of olefins
AU2002357507A1 (en) * 2002-12-24 2004-07-22 Showa Denko K. K. Method of oxidizing carbon-carbon double bond and process for producing oxidized compound
KR100762862B1 (ko) 2005-06-24 2007-10-04 쇼와 덴코 가부시키가이샤 탄소-탄소 이중결합의 산화방법 및 산화 화합물의 제조방법
US8048402B2 (en) * 2005-08-18 2011-11-01 Exxonmobil Chemical Patents Inc. Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins
CN101570523B (zh) * 2008-04-29 2011-11-02 中国石油化工股份有限公司 一种催化氧化烯丙醇生产环氧丙醇的方法
EP2403887A1 (en) * 2009-03-05 2012-01-11 Dow Global Technologies LLC (formerly Known As Dow Global Technologies Inc.) Polyols from hppo and polyurethane products made therefrom
CN102471298B (zh) * 2009-08-05 2014-12-31 陶氏环球技术有限责任公司 用于制备环氧烷的方法
TWI549946B (zh) * 2009-08-05 2016-09-21 陶氏全球科技公司 製備環氧丙烷的方法
RU2434859C1 (ru) * 2010-03-09 2011-11-27 Государственное образовательное учреждение высшего профессионального образования Нижегородский государственный технический университет им. Р.Е. Алексеева (НГТУ) Способ получения глицидола
EP2670741B8 (en) * 2011-02-04 2016-01-27 Blue Cube IP LLC Process for separating phases of a mixture containing an oxirane
TWI589567B (zh) * 2012-12-24 2017-07-01 China Petrochemical Development Corporation Taipei (Taiwan) Method of making epoxides
CN103172597B (zh) * 2013-04-03 2017-12-22 北京石油化工学院 钛硅分子筛催化合成环氧脂肪酸甲酯的方法
WO2016153969A1 (en) * 2015-03-20 2016-09-29 Northwestern University Catalysts and related methods for photocatalytc production of h2o2 and thermocatalytic reactant oxidation
CN114426551B (zh) * 2020-10-15 2024-02-02 中国石油化工股份有限公司 一种制备二氧化双环戊二烯dcpddo的方法
CN119430216B (zh) * 2023-07-31 2025-11-14 中国石油化工股份有限公司 一种钛硅分子筛及其制备方法和应用
CN119911992A (zh) * 2023-10-30 2025-05-02 中国石油化工股份有限公司 一种催化分解甲醇水溶液中过氧化氢的方法

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Also Published As

Publication number Publication date
EP0568336A3 (es) 1994-03-16
DE69300720D1 (de) 1995-12-07
EP0568336B1 (en) 1995-11-02
JPH069592A (ja) 1994-01-18
ATE129708T1 (de) 1995-11-15
US5262550A (en) 1993-11-16
DE69300720T2 (de) 1996-04-11
EP0568336A2 (en) 1993-11-03

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