ES2080300T3 - Copolimeros de monoepoxido de butadieno/anhidrido maleico. - Google Patents

Copolimeros de monoepoxido de butadieno/anhidrido maleico.

Info

Publication number
ES2080300T3
ES2080300T3 ES91905731T ES91905731T ES2080300T3 ES 2080300 T3 ES2080300 T3 ES 2080300T3 ES 91905731 T ES91905731 T ES 91905731T ES 91905731 T ES91905731 T ES 91905731T ES 2080300 T3 ES2080300 T3 ES 2080300T3
Authority
ES
Spain
Prior art keywords
epb
dioxolane
reaction
solvent
maleic anhydride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91905731T
Other languages
English (en)
Inventor
Richard W Blevins
S Richard Turner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Chemical Co
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Application granted granted Critical
Publication of ES2080300T3 publication Critical patent/ES2080300T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/04—Anhydrides, e.g. cyclic anhydrides
    • C08F222/06—Maleic anhydride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyethers (AREA)
  • Epoxy Resins (AREA)

Abstract

LOS COPOLIMEROS SE PRODUCEN CUANDO SE COPOLIMERIZA 3,4-EPOXI-1BUTENO (EPB) CON ANHIDRIDO MALEICO. LA COPOLIMERIZACION LA INICIAL RADICALES LIBRES Y CONSISTE EN LA 1,2-PROPAGACION Y LA 1,5-PROPAGACION DEL EPB. CUANDO SE UTILIZA UN ETER COMO EL SOLVENTE DE REACCION, EL PRODUCTO ES SOLUBLE Y SE COMPONE ESENCIALMENTE DE (A) UN MONOMERO DERIVADO DEL ANHIDRIDO MALEICO Y (B) DOS MONOMEROS DERIVADOS DEL EPB. CUANDO EL SOLVENTE DE REACCION ES UNA CETONA, EL PRODUCTO DE POLIMERO TAMBIEN ES SOLUBLE Y CONTIENE ADICIONALMENTE (C) UNA UNIDAD DERIVADA DE UN DIOXOLANO FORMADO IN SITU. CUANDO LA REACCION SE LLEVA A CABO ANTE LA PRESENCIA DE UN SOLVENTE NO POLAR (EJ. UN HIDROCARBURO O UN HALOCARBURO), O PURO (EJ. EN AUSENCIA DE UN SOLVENTE), EL PRODUCTO DE POLIMERO ES INDISOLUBLE EN SOLVENTES ORGANICOS COMUNES Y CONTIENE (D) UN DIMERO DE EPB SIMETRICO. EL DIMERO NO SE FORMA APARENTEMENTE, O SE FORMA SOLO HASTA UN PUNTO MUY LIMITADO, CUANDO SE LLEVA A CABO LA POLIMERIZACION EN SOLVENTES DE REACCION POLARES. LOS PRODUCTOS DE POLIMERO CON UNA UNIDAD DE DIOXOLANO SE PUEDE PREPARA UTILIZANDO EL DIOXOLANO PREVIAMENTE FORMADO EN LA MEZCLA DE POLIMERIZACION. ASI, ESTA INVENCION NO QUEDA LIMITADA A LA PREPARACION IN SITU DEL DIOXOLANO A PARTIR DE UNA MEZCLA DE REACCION QUE CONTENGA CETONA. LOS PRODUCTOS DE ESTA INVENCION SE PUEDEN MOLDEAR A MODO DE PELICULAS CLARAS Y SE PUEDEN UTILIZAR TAMBIEN COMO POLIMEROS REACTIVOS.
ES91905731T 1990-03-23 1991-03-14 Copolimeros de monoepoxido de butadieno/anhidrido maleico. Expired - Lifetime ES2080300T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/498,183 US5013806A (en) 1990-03-23 1990-03-23 Butadiene monoepoxide/maleic anhydride copolymers

Publications (1)

Publication Number Publication Date
ES2080300T3 true ES2080300T3 (es) 1996-02-01

Family

ID=23979929

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91905731T Expired - Lifetime ES2080300T3 (es) 1990-03-23 1991-03-14 Copolimeros de monoepoxido de butadieno/anhidrido maleico.

Country Status (10)

Country Link
US (1) US5013806A (es)
EP (1) EP0524198B1 (es)
JP (1) JP3155274B2 (es)
AT (1) ATE131180T1 (es)
CA (1) CA2078552C (es)
DE (1) DE69115266T2 (es)
DK (1) DK0524198T3 (es)
ES (1) ES2080300T3 (es)
GR (1) GR3018461T3 (es)
WO (1) WO1991014720A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5304611A (en) * 1992-12-30 1994-04-19 Eastman Kodak Company Copolymers of vinyl dioxolanes and imidized derivatives of maleic anhydride
US5302680A (en) * 1992-12-30 1994-04-12 Eastman Kodak Company Copolymers of epoxybutadiene and maleimides
US5310839A (en) * 1992-12-30 1994-05-10 Eastman Chemical Company Copolymers of vinyl dioxolanes and maleimides
WO1994015975A1 (en) * 1992-12-30 1994-07-21 Eastman Chemical Company Copolymers of epoxybutadiene and imidized derivatives of maleic anhydride
WO1995019382A1 (en) * 1994-01-18 1995-07-20 Eastman Chemical Company Polyether polymers derived from 3,4-epoxy-1-butene
US6107425A (en) * 1998-02-06 2000-08-22 Shipley Company, L.L.C. Narrow molecular weight distribution polymers and use of same as resin binders for negative-acting photoresists
US6146495A (en) 1998-08-31 2000-11-14 Nalco Chemical Company Kraft process for the production of wood pulp by adding a copolymer of 1,2-dihydroxy-3-butene antiscalant
US20090112888A1 (en) * 2007-10-25 2009-04-30 Rand Warsaw Method of providing database access to non-programmers

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2540072A (en) * 1948-08-19 1951-01-30 Hercules Powder Co Ltd Preparation of copolymer of chloromaleic anhydride and butadiene
US2582708A (en) * 1948-10-01 1952-01-15 Standard Oil Dev Co Lubricating oil additives
US2570601A (en) * 1950-11-13 1951-10-09 Universal Oil Prod Co Production of resins from butadiene monoxide and from mixtures of butadiene monoxide and vinyl compounds
US3230207A (en) * 1961-03-01 1966-01-18 Nippon Carbide Kogyo Kk Process for polymerizing olefin oxides with a catalyst consisting of a zinc alkyl and an oxide or hydroxide of a group iia metal
DE1173658B (de) * 1962-05-11 1964-07-09 Huels Chemische Werke Ag Verfahren zur Herstellung von fluessigen Epoxypolydiolefinen
US3398126A (en) * 1965-03-24 1968-08-20 Allied Chem Propylene oxide-butadiene monoxide copolymers cross-linked with maleic anhydride
US3530103A (en) * 1965-06-03 1970-09-22 Stauffer Chemical Co Copolymers of carbon bisulfide and certain monoolefinic monomers
US3851015A (en) * 1972-02-17 1974-11-26 Aquitaine Petrole Method for copolymerizing monomers of different types
USRE29028E (en) * 1973-06-26 1976-11-02 Hoechst Aktiengesellschaft Heat-curable pulverulent coating agent consisting of a mixture of copolymers containing glycidyl groups, dicarboxylic acid anhydrides and curing anhydrides
US3944533A (en) * 1973-08-25 1976-03-16 Bayer Aktiengesellschaft Polyalkenamers of wide molecular-weight distribution
US3998126A (en) 1974-09-03 1976-12-21 Ross Rudd Delayed bolt action for firearm
DE3712265A1 (de) * 1987-04-10 1988-10-20 Giulini Chemie Verfahren zur herstellung von copolymerisaten mit hohem polymerisationsgrad

Also Published As

Publication number Publication date
WO1991014720A1 (en) 1991-10-03
EP0524198B1 (en) 1995-12-06
DK0524198T3 (da) 1996-01-08
EP0524198A1 (en) 1993-01-27
ATE131180T1 (de) 1995-12-15
DE69115266T2 (de) 1996-05-02
JP3155274B2 (ja) 2001-04-09
US5013806A (en) 1991-05-07
GR3018461T3 (en) 1996-03-31
DE69115266D1 (en) 1996-01-18
JPH06504798A (ja) 1994-06-02
CA2078552C (en) 1997-07-08

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