ES2081536T3 - Copolimeros de dispersion en disolventes alifaticos. - Google Patents

Copolimeros de dispersion en disolventes alifaticos.

Info

Publication number
ES2081536T3
ES2081536T3 ES92115067T ES92115067T ES2081536T3 ES 2081536 T3 ES2081536 T3 ES 2081536T3 ES 92115067 T ES92115067 T ES 92115067T ES 92115067 T ES92115067 T ES 92115067T ES 2081536 T3 ES2081536 T3 ES 2081536T3
Authority
ES
Spain
Prior art keywords
polymer
blocks
dispersion
weight
dispersing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92115067T
Other languages
English (en)
Inventor
James E Hall
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Application granted granted Critical
Publication of ES2081536T3 publication Critical patent/ES2081536T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

ESTE INVENTO MUESTRA UN PROCESO PARA LA COPOLIMERIZACION DE DISPERSION DE ENTRE 35% Y 70% EN PESO DE MONOMERO AROMATICO SUSTITUIDO DE VINILO Y ENTRE 30% Y 65% EN PESO DE UN MONOMERO DE DIENO CONJUGADO QUE COMPRENDE LLEVAR A CABO LA POLIMERIZACION EN UNA MEZCLA DE REACCION QUE CONTIENE UN MEDIO DISPERSOR DE HIDROCARBURO LINEAL ALIFATICO LIQUIDO, UN SISTEMA CATALIZADOR ANIONICO, Y UN AGENTE DISPERSOR DE COPOLIMERO EN BLOQUE QUE COMPRENDE AL MENOS DOS BLOQUES DE POLIMERO DONDE AL MENOS UNO DE LOS BLOQUES DE POLIMERO ES SOLUBLE EN EL MEDIO DE DISPERSION Y AL MENOS EL OTRO DE LOS BLOQUES DE POLIMERO ES INSOLUBLE EN EL MEDIO DE DISPERSION Y EL MEDIO DE DISPERSION ACTUA PARA DISPERSAR UN COPOLIMERO ALEATORIO DE DIENOS CONJUGADOS Y AROMATIZADOS SUSTITUIDOS DE VINILO FORMADOS EN PRESENCIA DEL AGENTE DISPERSOR.
ES92115067T 1991-09-03 1992-09-03 Copolimeros de dispersion en disolventes alifaticos. Expired - Lifetime ES2081536T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US75449291A 1991-09-03 1991-09-03

Publications (1)

Publication Number Publication Date
ES2081536T3 true ES2081536T3 (es) 1996-03-16

Family

ID=25035045

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92115067T Expired - Lifetime ES2081536T3 (es) 1991-09-03 1992-09-03 Copolimeros de dispersion en disolventes alifaticos.

Country Status (10)

Country Link
US (1) US5395902A (es)
EP (1) EP0530796B1 (es)
JP (1) JPH07108930B2 (es)
KR (1) KR100237193B1 (es)
BR (1) BR9203445A (es)
CA (1) CA2077370C (es)
DE (1) DE69205931T2 (es)
ES (1) ES2081536T3 (es)
MX (1) MX9205059A (es)
ZA (1) ZA926695B (es)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
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DE4416478A1 (de) * 1994-05-10 1995-11-16 Basf Ag Plastisole, enthaltend anionische Polymerisate
DE4444016A1 (de) * 1994-12-10 1996-06-13 Basf Ag Verfahren zur Herstellung von Polystyrol durch anionische Polymerisation
DE19507777A1 (de) * 1995-03-06 1996-09-12 Basf Ag Filtrierbare Polystyrol-Dispersionen
DE19509785A1 (de) * 1995-03-17 1996-09-19 Basf Ag Verfahren zur Herstellung von Polymerisaten von vinylaromatischen Verbindungen unter Druck in Gegenwart von leicht flüchtigen Kohlenwasserstoffen
US6008295A (en) * 1997-07-11 1999-12-28 Bridgestone Corporation Diene polymers and copolymers incorporating partial coupling and terminals formed from hydrocarboxysilane compounds
DE19733535A1 (de) * 1997-08-02 1999-02-04 Basf Ag Schaumstoff-Formteile für die Lebensmittelverpackung
US6605680B1 (en) 2000-04-07 2003-08-12 Eastman Chemical Resins, Inc. Low color, aromatic modified C5 hydrocarbon resins
US6881795B2 (en) * 2001-03-28 2005-04-19 Firestone Polymers, Llc CO2 terminated rubber for plastics
US6437050B1 (en) 2001-10-04 2002-08-20 Bridgestone Corporation Nano-particle preparation and applications
US6956084B2 (en) * 2001-10-04 2005-10-18 Bridgestone Corporation Nano-particle preparation and applications
US6706823B2 (en) 2001-12-31 2004-03-16 Bridgestone Corporation Conductive gels
EP1583780B1 (en) * 2002-12-18 2013-09-04 Bridgestone Corporation Method for clay exfoliation, compositions therefore, and modified rubber contaiing same
US6875818B2 (en) * 2003-01-16 2005-04-05 Bridgestone Corporation Polymer nano-strings
US7205370B2 (en) * 2004-01-12 2007-04-17 Bridgestone Corporation Polymeric nano-particles of flower-like structure and applications
US7718737B2 (en) * 2004-03-02 2010-05-18 Bridgestone Corporation Rubber composition containing functionalized polymer nanoparticles
US7112369B2 (en) * 2004-03-02 2006-09-26 Bridgestone Corporation Nano-sized polymer-metal composites
US8063142B2 (en) 2004-03-02 2011-11-22 Bridgestone Corporation Method of making nano-particles of selected size distribution
US20050215693A1 (en) * 2004-03-29 2005-09-29 Xiaorong Wang Clay modified rubber composition and a method for manufacturing same
US20050228074A1 (en) * 2004-04-05 2005-10-13 Bridgestone Corporation Amphiphilic polymer micelles and use thereof
US20050282956A1 (en) * 2004-06-21 2005-12-22 Xiaorong Wang Reversible polymer/metal nano-composites and method for manufacturing same
US7998554B2 (en) * 2004-07-06 2011-08-16 Bridgestone Corporation Hydrophobic surfaces with nanoparticles
US7572855B2 (en) 2005-01-28 2009-08-11 Bridgestone Corporation Nano-composite and compositions manufactured thereof
US7579398B2 (en) * 2005-02-02 2009-08-25 Bridgestone Corporation Nano-composite and compositions therefrom
US7659342B2 (en) * 2005-02-03 2010-02-09 Bridgestone Corporation Polymer nano-particle with polar core and method for manufacturing same
US7538159B2 (en) 2005-12-16 2009-05-26 Bridgestone Corporation Nanoparticles with controlled architecture and method thereof
US9061900B2 (en) * 2005-12-16 2015-06-23 Bridgestone Corporation Combined use of liquid polymer and polymeric nanoparticles for rubber applications
US7884160B2 (en) 2005-12-19 2011-02-08 Bridgestone Corporation Non-spherical nanoparticles made from living triblock polymer chains
US8288473B2 (en) 2005-12-19 2012-10-16 Bridgestone Corporation Disk-like nanoparticles
US7601772B2 (en) * 2005-12-20 2009-10-13 Bridgestone Corporation Nano-composite and method thereof
US8877250B2 (en) 2005-12-20 2014-11-04 Bridgestone Corporation Hollow nano-particles and method thereof
US8697775B2 (en) * 2005-12-20 2014-04-15 Bridgestone Corporation Vulcanizable nanoparticles having a core with a high glass transition temperature
US7560510B2 (en) 2005-12-20 2009-07-14 Bridgestone Corporation Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties
US7935184B2 (en) 2006-06-19 2011-05-03 Bridgestone Corporation Method of preparing imidazolium surfactants
KR101445405B1 (ko) 2006-07-28 2014-09-26 가부시키가이샤 브리지스톤 상간 영역을 갖는 중합체성 코어-쉘 나노입자
US7597959B2 (en) * 2006-12-19 2009-10-06 Bridgestone Corporation Core-shell fluorescent nanoparticles
US7649049B2 (en) * 2006-12-20 2010-01-19 Bridgestone Corporation Rubber composition containing a polymer nanoparticle
US8716409B2 (en) * 2006-12-29 2014-05-06 Firestone Polymers, Llc Carboxylate terminated polymers and their use in impact-modified plastics
US7829624B2 (en) * 2007-06-29 2010-11-09 Bridgestone Corporation One-pot synthesis of nanoparticles and liquid polymer for rubber applications
RU2501816C2 (ru) * 2008-04-30 2013-12-20 Стирон Юроп Гмбх Стирол-бутадиеновые полимеры со стирольным градиентом и способы изготовления таковых
CN102341342B (zh) 2008-12-31 2014-07-16 株式会社普利司通 核起始的纳米颗粒形成方法、纳米颗粒和组合物
US9062144B2 (en) 2009-04-03 2015-06-23 Bridgestone Corporation Hairy polymeric nanoparticles with first and second shell block polymer arms
EP2488556B1 (en) 2009-10-14 2013-09-11 Bridgestone Corporation Processes for preparation of cyclic acyclic diene copolymer and rubber composition
US9115222B2 (en) * 2009-12-29 2015-08-25 Bridgestone Corporation Well defined, highly crosslinked nanoparticles and method for making same
US20110172364A1 (en) * 2009-12-29 2011-07-14 Chen Yaohong Charged Nanoparticles And Method Of Controlling Charge
US9428604B1 (en) 2011-12-30 2016-08-30 Bridgestone Corporation Nanoparticle fillers and methods of mixing into elastomers

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3402160A (en) * 1967-02-16 1968-09-17 Firestone Tire & Rubber Co Styrene resins
US4098980A (en) * 1976-06-24 1978-07-04 The Goodyear Tire & Rubber Company Non-aqueous dispersion polymerization of conjugated diolefins
US4452960A (en) * 1982-09-20 1984-06-05 The Goodyear Tire & Rubber Company Process for nonaqueous dispersion polymerization of butadiene in the presence of polymeric dispersing agents
US5270395A (en) * 1987-05-01 1993-12-14 Basf Corporation Process of dispersion polymerization of butadiene in propane or butane
US4942209A (en) * 1987-12-18 1990-07-17 Mobil Oil Corporation Anionic polymerization in high viscosity dispersing medium to form microparticles with narrow size distribution

Also Published As

Publication number Publication date
CA2077370A1 (en) 1993-03-04
JPH07108930B2 (ja) 1995-11-22
MX9205059A (es) 1993-03-01
EP0530796B1 (en) 1995-11-08
US5395902A (en) 1995-03-07
DE69205931D1 (de) 1995-12-14
BR9203445A (pt) 1993-04-06
CA2077370C (en) 1998-12-15
EP0530796A1 (en) 1993-03-10
DE69205931T2 (de) 1996-04-04
JPH05214005A (ja) 1993-08-24
KR100237193B1 (ko) 2000-01-15
ZA926695B (en) 1993-12-23
KR930006067A (ko) 1993-04-20

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