ES2086164T3 - Regeneracion de un catalizador de alquilacion. - Google Patents

Regeneracion de un catalizador de alquilacion.

Info

Publication number
ES2086164T3
ES2086164T3 ES93113424T ES93113424T ES2086164T3 ES 2086164 T3 ES2086164 T3 ES 2086164T3 ES 93113424 T ES93113424 T ES 93113424T ES 93113424 T ES93113424 T ES 93113424T ES 2086164 T3 ES2086164 T3 ES 2086164T3
Authority
ES
Spain
Prior art keywords
catalyst
rental
regeneration
water
alkylization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93113424T
Other languages
English (en)
Inventor
Alan Dan Eastman
Robert Bruce Eldridge
Richard Lee Anderson
David Paul Mann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of ES2086164T3 publication Critical patent/ES2086164T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0222—Sulfur-containing compounds comprising sulfonyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C07C2527/1206—Hydrogen fluoride
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/901—Catalyst and recycle considerations with recycle, rehabilitation, or preservation of solvent, diluent, or mass action agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

SE DESCRIBE UN PROCESO PARA REGENERAR UN CATALIZADOR DE ALQUILIZACION HX USADO, EN EL QUE X ES UN HALOGENO, MEDIANTE LA EXTRACCION DE ACEITE SOLUBLE EN ACIDO COMO UN SUBPRODUCTO NO DESEABLE DE LA REACCION DE ALQUILIZACION, DESDE UN LIQUIDO QUE CONTIENE UN COMPUESTO DE SULFONA. EL PROCESO INCLUYE EL USO DE AGUA PARA IMPULSAR LA FORMACION DE DOS FASES LIQUIDAS INMISCIBLES DE ASO Y SULFONA CON AGUA. LAS DOS FASES INMISCIBLES PUEDEN POSTERIORMENTE SEPARARSE LA UNA DE LA OTRA.
ES93113424T 1992-08-24 1993-08-23 Regeneracion de un catalizador de alquilacion. Expired - Lifetime ES2086164T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/935,089 US5237122A (en) 1992-08-24 1992-08-24 Alkylation catalyst regeneration

Publications (1)

Publication Number Publication Date
ES2086164T3 true ES2086164T3 (es) 1996-06-16

Family

ID=25466577

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93113424T Expired - Lifetime ES2086164T3 (es) 1992-08-24 1993-08-23 Regeneracion de un catalizador de alquilacion.

Country Status (17)

Country Link
US (1) US5237122A (es)
EP (1) EP0584760B1 (es)
JP (1) JP3258145B2 (es)
KR (1) KR100240382B1 (es)
CN (1) CN1039704C (es)
AU (1) AU652515B2 (es)
BR (1) BR9303228A (es)
CA (1) CA2099350C (es)
DE (1) DE69302245T2 (es)
DK (1) DK0584760T3 (es)
ES (1) ES2086164T3 (es)
FI (1) FI933698A7 (es)
GR (1) GR3019669T3 (es)
MX (1) MX9305013A (es)
NO (1) NO301261B1 (es)
SG (1) SG43228A1 (es)
ZA (1) ZA935656B (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5386076A (en) * 1992-02-11 1995-01-31 Mobil Oil Corporation Regeneration of HF-based alkylation catalyst
US5382746A (en) * 1992-02-11 1995-01-17 Mobil Oil Corporation Removal of light ASO in HF alkylation process
US5347065A (en) * 1993-04-26 1994-09-13 Phillips Petroleum Company Alkylation catalyst regeneration
US5304522A (en) * 1993-06-01 1994-04-19 Mobil Oil Corporation Liquid acid regeneration method
DE69421284T2 (de) * 1993-08-23 2000-02-17 Phillips Petroleum Co., Bartlesville Isoparrafin-olefin-alkylierung
US5763728A (en) * 1993-12-29 1998-06-09 Uop Recovery and recycle of HF-amine complex in HF alkylation
US5463162A (en) * 1994-01-21 1995-10-31 Phillips Petroleum Company Alkylation catalyst regeneration
DK171409B1 (da) * 1994-03-10 1996-10-21 Topsoe Haldor As Fremgangsmåde til genvinding af alkyleringskatalysatorer
US6245956B1 (en) * 1995-02-14 2001-06-12 Phillips Petroleum Company Method for separating sulfone from a hydrocarbon stream having a small concentration of sulfone
US5648587A (en) * 1995-12-04 1997-07-15 Phillips Petroleum Company Method for separating sulfone from a hydrocarbon stream having a concentration of sulfone producing a dry sulfone product
DK172906B1 (da) * 1996-06-17 1999-09-27 Topsoe Haldor As Fremgangsmåde til fjernelse af korrosive bestanddele fra en fluidastrøm
US6451173B1 (en) 1999-12-30 2002-09-17 Phillips Petroleum Company Separator system
US9290702B2 (en) * 2011-05-16 2016-03-22 Chevron U.S.A. Inc. Methods for monitoring ionic liquids using vibrational spectroscopy

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2081989A5 (es) * 1969-11-24 1971-12-10 Inst Francais Du Petrole
US4024203A (en) * 1969-11-24 1977-05-17 Institut Francais Du Petrole Oligomerization of unsaturated hydrocarbons with acid catalysts
US4014953A (en) * 1975-02-05 1977-03-29 Phillips Petroleum Company Method for purifying HF catalyst in an isoparaffin-olefin alkylation
US4199409A (en) * 1977-02-22 1980-04-22 Phillips Petroleum Company Recovery of HF from an alkylation unit acid stream containing acid soluble oil
US4189616A (en) * 1978-02-02 1980-02-19 Phillips Petroleum Company Maximum utilization of energy in isoparaffin recycle in alkylation
US4507506A (en) * 1983-04-21 1985-03-26 Phillips Petroleum Company Alpha-olefin conversion
US4663026A (en) * 1984-11-28 1987-05-05 Mobil Oil Corporation Solvent extraction and purification of acid soluble oil from an HF alkylation unit
US4861447A (en) * 1988-05-27 1989-08-29 Shell Oil Company Process for reducing corrosive impurities in sulfolane used for extracting aromatic hydrocarbons
US4897182A (en) * 1988-10-03 1990-01-30 Uop Aromatic extraction process having improved water stripper
US5122236A (en) * 1990-05-21 1992-06-16 Smith Jr Lawrence A Method for removal of dimethyl ether and methanol from c4 hydrocarbon streams

Also Published As

Publication number Publication date
CA2099350C (en) 1998-05-05
EP0584760A1 (en) 1994-03-02
DE69302245D1 (de) 1996-05-23
US5237122A (en) 1993-08-17
BR9303228A (pt) 1994-03-01
FI933698A0 (fi) 1993-08-23
JP3258145B2 (ja) 2002-02-18
NO932985D0 (no) 1993-08-20
NO301261B1 (no) 1997-10-06
ZA935656B (en) 1994-03-07
AU652515B2 (en) 1994-08-25
EP0584760B1 (en) 1996-04-17
GR3019669T3 (en) 1996-07-31
SG43228A1 (en) 1997-10-17
FI933698L (fi) 1994-02-25
DE69302245T2 (de) 1996-09-19
NO932985L (no) 1994-02-25
CN1083416A (zh) 1994-03-09
AU4429293A (en) 1994-03-03
KR940003613A (ko) 1994-03-12
CN1039704C (zh) 1998-09-09
MX9305013A (es) 1994-03-31
CA2099350A1 (en) 1994-02-25
KR100240382B1 (ko) 2000-01-15
JPH06182230A (ja) 1994-07-05
FI933698A7 (fi) 1994-02-25
DK0584760T3 (da) 1996-05-13

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