ES2086597T3 - Procedimiento para la obtencion de homo- y copolimeros del propeno mediante un sistema catalizador de ziegler-natta. - Google Patents

Procedimiento para la obtencion de homo- y copolimeros del propeno mediante un sistema catalizador de ziegler-natta.

Info

Publication number
ES2086597T3
ES2086597T3 ES92114197T ES92114197T ES2086597T3 ES 2086597 T3 ES2086597 T3 ES 2086597T3 ES 92114197 T ES92114197 T ES 92114197T ES 92114197 T ES92114197 T ES 92114197T ES 2086597 T3 ES2086597 T3 ES 2086597T3
Authority
ES
Spain
Prior art keywords
titanium
component
solid phase
ziegler
propene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92114197T
Other languages
English (en)
Inventor
Juergen Dr Kerth
Rainer Dr Hemmerich
Peter Dr Koelle
Patrik Dr Mueller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2086597T3 publication Critical patent/ES2086597T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

PROCEDIMIENTO PARA LA OBTENCION DE POLIMERIZADOS DEL PROPENO MEDIANTE UN SISTEMA DE CATALIZADORES ZIEGLER-NATTA DE (1) UN COMPONENTE DE TITANIO, QUE SE BASA EN UN GEL DE SILICE CONFORMADOR, FINAMENTE DISTRIBUIDO Y QUE CONTIENE TITANIO, MAGNESIO, CLORO ASI COMO UN DERIVADO DEL ACIDO BENZOLCARBOXILICO, (2) UN COMPONENTE DE ALUMINIO ASI COMO (3) UN COMPONENTE DE SILANO. ES CARACTERISTICA LA APLICACION DE UN COMPONENTE DE TITANIO (1), QUE SE OBTIENE PRODUCIENDO (1.1) EN PRIMER LUGAR (I) UNA SUSTANCIA DE SOPORTE A PARTIR DE (IA) UN GEL DE SILICE QUE PRESENTA UN CONTENIDO DE HUMEDAD RELATIVAMENTE ELEVADO, (IB) UN COMPUESTO ORGANICO DE MAGNESIO Y (IC) UN AGENTE DE CLORACION GASEOSO, DE TAL MANERA QUE PRIMERO (1.1.1) SE TRANSFORMA (IA) CON (IB), (1.1.2) DESPUES SE INTRODUCE EN LO OBTENIDO (IC) DE (1.1.1), (1.2) A CONTINUACION SE PRODUCE UN PRODUCTO INTERMEDIO DE FASE SOLIDA A PARTIR DE (I), (II) UN ALCANOL, (III) TETRACLORURO DE TITANIO ASI COMO (IV) UN DERIVADO DEL ACIDO FTALICO, DE TAL MODO, QUE(1.2.1) PRIMERO SE TRANSFORMA (I) CON (II), (1.2.2) A CONTINUACION SE AÑADE A LOS RESULTANTE (III) DE (1.2.1), CON LA MEDIDA DE QUE TAMBIEN EN (1.2.1) O (1.2.2) SE AÑADA (IV), (1.3) DESPUES LA RESULTANTE DE FASE SOLIDA DE (1.2) SE EXTRAIGA CON TETRACLORURO DE TITANIO O UNA MEZCLA DE TETRACLORURO DE TITANIO/HIDROCARBURO Y (1.4) FINALMENTE SE LAVA LOS RESULTANTE DE FASE SOLIDA DE (1.3) CON UN HIDROCARBURO LIQUIDO.
ES92114197T 1991-08-30 1992-08-20 Procedimiento para la obtencion de homo- y copolimeros del propeno mediante un sistema catalizador de ziegler-natta. Expired - Lifetime ES2086597T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4128829A DE4128829A1 (de) 1991-08-30 1991-08-30 Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-nata-katalysatorsystems

Publications (1)

Publication Number Publication Date
ES2086597T3 true ES2086597T3 (es) 1996-07-01

Family

ID=6439491

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92114197T Expired - Lifetime ES2086597T3 (es) 1991-08-30 1992-08-20 Procedimiento para la obtencion de homo- y copolimeros del propeno mediante un sistema catalizador de ziegler-natta.

Country Status (10)

Country Link
US (1) US5288824A (es)
EP (1) EP0530599B1 (es)
JP (1) JPH05194649A (es)
BR (1) BR9202981A (es)
DE (2) DE4128829A1 (es)
ES (1) ES2086597T3 (es)
RU (1) RU2090571C1 (es)
TR (1) TR26220A (es)
TW (1) TW215925B (es)
ZA (1) ZA926519B (es)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5773537A (en) * 1992-05-19 1998-06-30 Basf Aktiengesellschaft Ziegler-natta catalyst systems containing specific organosilicon compounds
DE19543292A1 (de) 1995-11-21 1997-05-22 Basf Ag Copolymerisate des Propylens mit anderen C¶2¶-C¶1¶¶0¶-Alk-1-enen
DE19543293A1 (de) 1995-11-21 1997-05-22 Basf Ag Copolymerisate des Propylens
US5773516A (en) * 1995-12-06 1998-06-30 Basf Aktiengesellschaft Propylene polymers
DE19545499A1 (de) 1995-12-06 1997-06-12 Basf Ag Verbesserte statistische Propylencopolymerisate
DE19545498A1 (de) 1995-12-06 1997-06-12 Basf Ag Verbesserte Propylenpolymerisate
DE19623226A1 (de) 1996-06-11 1997-12-18 Basf Ag Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren
DE19635503A1 (de) 1996-09-02 1998-03-05 Basf Ag Weißbrucharme, zähmodifizierte Propylenpolymerisate
DE19637367A1 (de) * 1996-09-13 1998-03-19 Basf Ag Bei ihrer Herstellung modifizierte Ziegler-Natta-Katalysatorsysteme
DE19637370A1 (de) * 1996-09-13 1998-03-19 Basf Ag Bei ihrer Herstellung modifizierte Ziegler-Natta-Katalysatorsysteme
DE19646118A1 (de) * 1996-11-08 1998-05-14 Basf Ag Mit ungesättigten Estern teilvernetzte Kunststoffmassen
DE19653079A1 (de) * 1996-12-19 1998-06-25 Basf Ag Verfahren zur Gasphasenpolymerisation von C¶2¶-C¶8¶-Alk-1-enen mittels Ziegler -Natta- oder Metallocen-Katalysatorsystemen
DE19722569A1 (de) 1997-05-28 1998-12-03 Basf Ag Statistische Propylencopolymerisate
DE19726796A1 (de) 1997-06-24 1999-01-07 Basf Ag Propylenpolymerisate
DE19728141A1 (de) 1997-07-02 1999-01-07 Basf Ag Verfahren zur Polymerisation von C2-C8-Alk-1-enen mittels eines Ziegler-Natta-Katalysatorsystems
US7022795B1 (en) 1998-03-13 2006-04-04 Novolen Technology Holdings, C.V. Highly crystalline propylene homopolymers
DE19857292A1 (de) 1998-12-11 2000-06-15 Targor Gmbh Talkumverstärkte Polypropylen-Formmasse mit hoher Schlagzähigkeit
DE19912011A1 (de) 1999-03-17 2000-09-21 Targor Gmbh Verfahren zur Gasphasenpolymerisation von C2-C8-Alk-1-enen
DE19961890A1 (de) 1999-12-20 2001-06-21 Targor Gmbh Frontteil enthaltend ein Dekorteil
DE10046877A1 (de) * 2000-09-22 2002-04-11 Basell Polypropylen Gmbh Schichtverbundmaterial mit verschiedenen Harzschichten
DE10105276A1 (de) * 2001-02-02 2002-08-08 Basell Polypropylen Gmbh Verfahren zum Dosieren von Katalysatoren
DE10110551A1 (de) * 2001-03-05 2002-09-12 Basell Polypropylen Gmbh Verfahren zur Dosierung von Katalysatoren
EP1517954B1 (en) * 2002-06-26 2014-05-28 Basell Poliolefine Italia S.r.l. Impact-resistant polyolefin compositions
MXPA04012699A (es) * 2002-06-26 2005-03-23 Basell Poliolefine Spa Composiciones de poliolefina resistentes a impactos.
US7816452B2 (en) * 2002-07-24 2010-10-19 Basell Poliolifine Italia s.r.l. At least two-stage process for preparing propylene polymer compositions
US6831032B2 (en) 2002-08-19 2004-12-14 Novolen Technology Holdings C.V. Ziegler-Natta catalyst and methods of making and using same
DE10261107A1 (de) * 2002-12-20 2004-07-01 Basell Polyolefine Gmbh Formmassen aus einem hochmolekularen Propylenpolymerisat
WO2004074329A1 (en) * 2003-02-24 2004-09-02 China Petroleum & Chemical Corporation Complex support suitable for propylene polymerization catalyst, a catalyst component and catalyst containing the same
EP1680468B1 (en) * 2003-11-06 2011-08-17 Basell Poliolefine Italia S.r.l. Polypropylene composition
KR101256036B1 (ko) * 2004-06-08 2013-04-19 바셀 폴리올레핀 이탈리아 에스.알.엘 강성, 충격 강도 및 파단점 신율의 높은 균형 및 낮은 열수축율을 갖는 폴리올레핀 조성물
US8378028B2 (en) * 2008-02-29 2013-02-19 Basell Poliolefine Italia, s.r.l. Polyolefin compositions
DE102009020090A1 (de) 2009-05-06 2010-11-11 Lanxess Deutschland Gmbh Reduktion des Einflusses der Wasseraufnahme auf die elektrische Leitfähigkeit von elektrisch leitfähigen Polyamid-Formmassen

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3730022A1 (de) * 1987-09-08 1989-03-16 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems
DE3932553A1 (de) * 1989-09-29 1991-04-11 Basf Ag Katalysatorsysteme vom typ der ziegler-natta-katalysatoren
DE3936857A1 (de) * 1989-11-06 1991-05-08 Basf Ag Katalysatorsysteme vom typ der ziegler-natta-katalysatoren
US5126302A (en) * 1990-04-30 1992-06-30 Quantum Chemical Corporation Olefin polymerization catalyst and methods

Also Published As

Publication number Publication date
US5288824A (en) 1994-02-22
EP0530599A1 (de) 1993-03-10
JPH05194649A (ja) 1993-08-03
BR9202981A (pt) 1993-04-06
DE59206219D1 (de) 1996-06-13
DE4128829A1 (de) 1993-03-04
ZA926519B (en) 1994-02-28
TR26220A (tr) 1995-02-15
RU2090571C1 (ru) 1997-09-20
EP0530599B1 (de) 1996-05-08
TW215925B (es) 1993-11-11

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