ES2096185T3 - Isomerizacion de dimetilnaftaleno. - Google Patents

Isomerizacion de dimetilnaftaleno.

Info

Publication number
ES2096185T3
ES2096185T3 ES93118422T ES93118422T ES2096185T3 ES 2096185 T3 ES2096185 T3 ES 2096185T3 ES 93118422 T ES93118422 T ES 93118422T ES 93118422 T ES93118422 T ES 93118422T ES 2096185 T3 ES2096185 T3 ES 2096185T3
Authority
ES
Spain
Prior art keywords
isomerization
dimetilnaftaleno
zeolite
dimethylaphthalene
isomerizes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93118422T
Other languages
English (en)
Inventor
David Lee Sikkenga
Ian Clayton Zaenger
Gregory Scott Williams
Joyce Dale Lamb
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Corp North America Inc
Original Assignee
BP Corp North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Corp North America Inc filed Critical BP Corp North America Inc
Application granted granted Critical
Publication of ES2096185T3 publication Critical patent/ES2096185T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/20—Polycyclic condensed hydrocarbons
    • C07C15/24—Polycyclic condensed hydrocarbons containing two rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/31—Rearrangement of carbon atoms in the hydrocarbon skeleton changing the number of rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C07C2529/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • C07C2529/12—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/10—One of the condensed rings being a six-membered aromatic ring the other ring being six-membered, e.g. tetraline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

UN DIMETILNAFTALENO SE ISOMERIZA MEDIANTE CONTACTO EN FORMA LIQUIDA CON UN CATALIZADOR DE ISOMERIZACION SOLIDO QUE COMPRENDE BIEN UN ZEOLITO BETA O BIEN UN ZEOLITO CRISTALINO DE TIPO Y QUE TENGA UNA RELACION MOLAR SILICE/ALUMINIO DE ENTRE 4:1 Y 10:1 Y UNAS VENTANAS EN FORMA DE PORO SUMINISTRADAS POR ANILLOS DE 12 MIEMBROS QUE CONTIENEN OXIGENO Y UN TAMAÑO DE CELDA UNITARIA DE ENTRE 24.2 Y 24.7 ANGSTROM (10 ELEVADO A 10M). LA ISOMERIZACION SE REALIZA A UNA TEMPERATURA ELEVADA Y A UNA PRESION SUFICIENTEMENTE ALTA PARA MANTENER EL MATERIAL EN LA FASE LIQUIDA.
ES93118422T 1988-06-24 1989-06-20 Isomerizacion de dimetilnaftaleno. Expired - Lifetime ES2096185T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US21100088A 1988-06-24 1988-06-24
US07/316,308 US4950825A (en) 1988-06-24 1989-02-27 Preparation of a dimethyltetralin

Publications (1)

Publication Number Publication Date
ES2096185T3 true ES2096185T3 (es) 1997-03-01

Family

ID=26905713

Family Applications (2)

Application Number Title Priority Date Filing Date
ES93118422T Expired - Lifetime ES2096185T3 (es) 1988-06-24 1989-06-20 Isomerizacion de dimetilnaftaleno.
ES89306236T Expired - Lifetime ES2061995T3 (es) 1988-06-24 1989-06-20 Preparacion de una dimetiltetralina.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES89306236T Expired - Lifetime ES2061995T3 (es) 1988-06-24 1989-06-20 Preparacion de una dimetiltetralina.

Country Status (13)

Country Link
US (1) US4950825A (es)
EP (2) EP0589490B1 (es)
JP (1) JP2660078B2 (es)
KR (1) KR0145694B1 (es)
CN (1) CN1020716C (es)
BR (1) BR8907013A (es)
CA (1) CA1325434C (es)
DE (2) DE68927717T2 (es)
ES (2) ES2096185T3 (es)
NZ (1) NZ229664A (es)
RU (1) RU2126782C1 (es)
SG (1) SG52399A1 (es)
WO (1) WO1989012612A1 (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5401892A (en) * 1988-06-24 1995-03-28 Amoco Corporation Preparation of a dimethyltetralin by cyclizing an orthotolylpentene phenylhexene using an ultra-stable crystalline aluminosilicate molecular sieve y-zeolite
US5034561A (en) * 1990-06-15 1991-07-23 Amoco Corporation Catalytic alkenylbenzene cyclization
US5118892A (en) * 1988-06-24 1992-06-02 Amoco Corporation Preparation of a dimethylnaphthalene
US5073670A (en) * 1988-06-24 1991-12-17 Amoco Corporation Preparation of a dimethyltetralin
US5284987A (en) * 1990-06-15 1994-02-08 Amoco Corporation Preparation of a dimethyltetralin in a distillation reactor
US4999326A (en) * 1990-06-18 1991-03-12 Amoco Corporation Palladium catalyst reactivation
DE69110114T2 (de) * 1990-12-12 1995-10-26 Kawasaki Steel Co Verfahren zur Herstellung von 2-Methylnaphthalin und Verfahren zur Wiederherstellung der Aktivität von festen sauren Katalysatoren.
JPH05310611A (ja) * 1991-08-16 1993-11-22 Kawasaki Steel Corp ２−メチルナフタレンの製造方法
JP2891272B2 (ja) * 1992-08-03 1999-05-17 三菱瓦斯化学株式会社 ジメチルテトラリンの製造方法
DE60002513T2 (de) 1999-02-22 2004-04-08 Mitsubishi Gas Chemical Co., Inc. Verfahren zur Herstellung von Dimethyltetralin
MXPA02006832A (es) * 2000-01-14 2002-10-23 Bp Corp North America Inc Sintesis y uso de los 1,5-naftalenodicarboxilatos dimetilicos y sus intermediarios.
US6642407B2 (en) 2001-05-18 2003-11-04 Exxon Mobil Chemical Patents Inc. Production, purification and polymerization of aromatic dicarboxylic acids
US7247742B2 (en) * 2004-05-20 2007-07-24 Bp Corporation North America Inc. Recycling polyethylene naphthalate containing materials in a process to produce diesters
KR100621823B1 (ko) * 2004-07-21 2006-09-14 재단법인서울대학교산학협력재단 2,6-디알킬테트랄린의 제조 방법
KR100769021B1 (ko) * 2006-04-04 2007-10-23 주식회사 효성 탈알루미늄된 제올라이트 베타 촉매를 이용한1,5-디메틸테트랄린의 제조방법
KR100721442B1 (ko) * 2006-06-23 2007-05-23 주식회사 효성 이성화 반응 및 결정화 공정을 포함하는2,6-디메틸나프탈렌의 분리 및 정제 방법
KR100960050B1 (ko) * 2008-03-20 2010-05-31 주식회사 효성 이온교환된 제올라이트 촉매를 이용한1,5-디메틸테트랄린의 제조방법
WO2012005694A1 (en) * 2010-07-07 2012-01-12 Agency For Science, Technology And Research Dihydroindenes and related compounds
CN103319370B (zh) * 2012-03-21 2016-08-03 黑龙江福和华星制药集团股份有限公司 一种(7-甲氧基-1-萘基)乙腈的制备方法
CN115504849A (zh) 2021-06-07 2022-12-23 河北中化滏恒股份有限公司 1,4－二甲基四氢萘的制造方法
CN115504850B (zh) * 2021-06-07 2025-05-23 河北中化滏恒股份有限公司 1,4－二甲基萘的制造方法
CN119859085B (zh) * 2023-10-19 2026-03-03 帕潘纳(北京)科技有限公司 一种1,4-二甲基萘的制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3803253A (en) * 1971-12-14 1974-04-09 Sun Research Development Hydroisomerization of dimethylnaphthalenes using a calcium zeolite catalyst
US3855328A (en) * 1971-12-14 1974-12-17 Sun Research Development Isomerization and/or transalkylation and/or disproportionation of alkylnaphthalenes
US3775498A (en) * 1972-06-09 1973-11-27 Sun Research Development Preparation of 2,6-dimethylnaphthalene
US3775500A (en) * 1972-08-09 1973-11-27 Sun Research Development Preparation of 2,7-dimethylnaphthalene
US3775496A (en) * 1972-08-09 1973-11-27 Sun Research Development Preparation of 2,6-dimethylnaphthalene and 2,7-dimethylnaphthalene
US3775497A (en) * 1972-08-09 1973-11-27 Sun Research Development Preparation of 2,3-dimethylnaphthalene
JPS5724331B2 (es) * 1973-05-31 1982-05-24
JPS587613B2 (ja) * 1973-09-18 1983-02-10 帝人株式会社 アルキルテトラリン ノ セイゾウホウホウ
US3843737A (en) * 1973-10-31 1974-10-22 Sun Ventures Inc Adiabatic recycle design for exothermic heterogeneously catalyzed reactions
JPS5724767B2 (es) * 1973-11-01 1982-05-26
US3997616A (en) * 1975-06-27 1976-12-14 Teijin Limited Process for the preparation of alkylteralins

Also Published As

Publication number Publication date
EP0589490A1 (en) 1994-03-30
EP0351074B1 (en) 1994-09-07
CN1020716C (zh) 1993-05-19
CN1038805A (zh) 1990-01-17
KR0145694B1 (ko) 1998-08-17
ES2061995T3 (es) 1994-12-16
JP2660078B2 (ja) 1997-10-08
DE68927717T2 (de) 1997-07-03
DE68918016T2 (de) 1994-12-22
SG52399A1 (en) 1998-09-28
EP0351074A1 (en) 1990-01-17
JPH03500052A (ja) 1991-01-10
EP0589490B1 (en) 1997-01-22
NZ229664A (en) 1990-07-26
RU2126782C1 (ru) 1999-02-27
BR8907013A (pt) 1990-12-26
WO1989012612A1 (en) 1989-12-28
KR900701698A (ko) 1990-12-04
DE68918016D1 (de) 1994-10-13
US4950825A (en) 1990-08-21
CA1325434C (en) 1993-12-21
DE68927717D1 (de) 1997-03-06

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