ES2101942T3 - Procedimiento de epoxidacion. - Google Patents
Procedimiento de epoxidacion.Info
- Publication number
- ES2101942T3 ES2101942T3 ES93300866T ES93300866T ES2101942T3 ES 2101942 T3 ES2101942 T3 ES 2101942T3 ES 93300866 T ES93300866 T ES 93300866T ES 93300866 T ES93300866 T ES 93300866T ES 2101942 T3 ES2101942 T3 ES 2101942T3
- Authority
- ES
- Spain
- Prior art keywords
- epoxidation
- peroxide
- hydrogen
- epoxidation procedure
- organorrenium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000006735 epoxidation reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
LAS OLEFINAS SE EPOXIDAN CON PEROXIDO DE HIDROGENO EN PRESENCIA DE UN CATALIZADOR DE OXIDO DE ORGANORRENIO Y UN SOLVENTE DE ALCOHOL SECUNDARIO DE ALQUILARILO. SE OBTIENE UNA ELEVADA PRODUCCION DE EPOXIDOS CON UNA PERDIDA MINIMA, NO SELECTIVA, DE PEROXIDO DE HIDROGENO U OLEFINA. LA EPOXIDACION PUEDE COMPRENDER TAMBIEN UN PASO DE UN PROCESO INTEGRADO EN QUE SE ORIGINA UNA MEZCLA OXIDANTE MEDIANTE UNA OXIDACION CON OXIGENO MOLECULAR DEL ALCOHOL SECUNDARIO DE ALQUILARILO Y SE UTILIZA DIRECTAMENTE EN LA EPOXIDACION SIN MAS PURIFICACION NI EXTRACION.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/832,568 US5166372A (en) | 1992-02-07 | 1992-02-07 | Epoxidation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2101942T3 true ES2101942T3 (es) | 1997-07-16 |
Family
ID=25262051
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93300866T Expired - Lifetime ES2101942T3 (es) | 1992-02-07 | 1993-02-05 | Procedimiento de epoxidacion. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5166372A (es) |
| EP (1) | EP0560488B1 (es) |
| JP (1) | JP3203583B2 (es) |
| DE (1) | DE69310962T2 (es) |
| ES (1) | ES2101942T3 (es) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE140454T1 (de) * | 1991-11-26 | 1996-08-15 | Eniricerche Spa | Verfahren zur oxidation von organischen verbindungen mit nach einem anthrachinon- redoxverfahren hergestellten wasserstoffperoxid |
| US5166372A (en) * | 1992-02-07 | 1992-11-24 | Arco Chemical Technology, L.P. | Epoxidation process |
| GB9309458D0 (en) * | 1993-05-07 | 1993-06-23 | Bp Chem Int Ltd | Process |
| US5384418A (en) * | 1994-01-25 | 1995-01-24 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
| DE59504369D1 (de) * | 1994-01-27 | 1999-01-14 | Hoechst Ag | Verfahren zur katalytischen Oxidation von aromatischen Verbindungen |
| DE4419800A1 (de) * | 1994-06-06 | 1995-12-07 | Hoechst Ag | Verfahren zur selektiven Oxidation aromatischer Verbindungen |
| US5463090A (en) * | 1994-10-27 | 1995-10-31 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
| US5523426A (en) * | 1995-01-04 | 1996-06-04 | Arco Chemical Technology, L.P. | Integrated process for epoxidation |
| EP0771793B1 (en) * | 1995-10-31 | 2001-04-04 | Nippon Shokubai Co., Ltd. | Method for the production of an epoxy compound |
| US5599956A (en) * | 1996-02-22 | 1997-02-04 | Uop | Integrated process for the production of propylene oxide |
| US5633391A (en) * | 1996-04-12 | 1997-05-27 | National Starch And Chemical Investment Holding Corporation | Methyltrioxorhenium-bis(trimethylsilyl)peroxide epoxidation of olefins |
| US5723636A (en) * | 1996-04-12 | 1998-03-03 | National Starch And Chemical Investment Holding Corporation | Methyltrioxorhenium-urea hydrogen peroxide epoxidation of olefins |
| US5811601A (en) * | 1996-08-09 | 1998-09-22 | The Dow Chemical Company | Isomerization of vinyl glycols to unsaturated diols |
| US5959163A (en) * | 1997-09-04 | 1999-09-28 | The Dow Chemical Company | Process for the preparation of 1,4-butenediol from epoxybutene |
| US6500968B2 (en) | 1998-08-26 | 2002-12-31 | Hydrocarbon Technologies, Inc. | Process for selective oxidation of organic feedstocks with hydrogen peroxide |
| US6576214B2 (en) * | 2000-12-08 | 2003-06-10 | Hydrocarbon Technologies, Inc. | Catalytic direct production of hydrogen peroxide from hydrogen and oxygen feeds |
| US6749668B2 (en) * | 2001-06-18 | 2004-06-15 | Degussa Ag | Process for the recovery of combustible components of a gas stream |
| ES2378875T3 (es) * | 2002-03-14 | 2012-04-18 | Repsol Qu�?Mica S.A. | Procedimiento de obtención de peróxido de hidrógeno |
| US7141683B2 (en) | 2002-05-02 | 2006-11-28 | Degussa Ag | Process for the epoxidation of olefins |
| EP1359148A1 (en) * | 2002-05-02 | 2003-11-05 | Degussa AG | Process for the epoxidation of olefins |
| ES2339110T3 (es) * | 2003-02-03 | 2010-05-17 | Repsol Quimica S.A. | Procedimiento integrado para la oxidacion selectiva de compuestos organicos. |
| US7067103B2 (en) | 2003-03-28 | 2006-06-27 | Headwaters Nanokinetix, Inc. | Direct hydrogen peroxide production using staged hydrogen addition |
| US7655137B2 (en) * | 2003-07-14 | 2010-02-02 | Headwaters Technology Innovation, Llc | Reforming catalysts having a controlled coordination structure and methods for preparing such compositions |
| US7569508B2 (en) | 2004-11-17 | 2009-08-04 | Headwaters Technology Innovation, Llc | Reforming nanocatalysts and method of making and using such catalysts |
| US7011807B2 (en) * | 2003-07-14 | 2006-03-14 | Headwaters Nanokinetix, Inc. | Supported catalysts having a controlled coordination structure and methods for preparing such catalysts |
| US7045479B2 (en) | 2003-07-14 | 2006-05-16 | Headwaters Nanokinetix, Inc. | Intermediate precursor compositions used to make supported catalysts having a controlled coordination structure and methods for preparing such compositions |
| US7144565B2 (en) | 2003-07-29 | 2006-12-05 | Headwaters Nanokinetix, Inc. | Process for direct catalytic hydrogen peroxide production |
| DE10342150A1 (de) * | 2003-09-12 | 2005-04-28 | Degussa | Verfahren zur Oxidation organischer Substrate und Katalysatorzusammensetzung zur Durchführung des Verfahrens |
| US7632775B2 (en) | 2004-11-17 | 2009-12-15 | Headwaters Technology Innovation, Llc | Multicomponent nanoparticles formed using a dispersing agent |
| US7396795B2 (en) | 2005-08-31 | 2008-07-08 | Headwaters Technology Innovation, Llc | Low temperature preparation of supported nanoparticle catalysts having increased dispersion |
| JP5491030B2 (ja) * | 2005-10-25 | 2014-05-14 | ユニバーシティ・オブ・カンザス | オレフィンのエポキシドへの選択的な酸化のための方法 |
| US8080677B2 (en) * | 2005-10-25 | 2011-12-20 | University Of Kansas | Process for selective oxidation of olefins to epoxides |
| US7718710B2 (en) | 2006-03-17 | 2010-05-18 | Headwaters Technology Innovation, Llc | Stable concentrated metal colloids and methods of making same |
| US7541309B2 (en) | 2006-05-16 | 2009-06-02 | Headwaters Technology Innovation, Llc | Reforming nanocatalysts and methods of making and using such catalysts |
| US7563742B2 (en) | 2006-09-22 | 2009-07-21 | Headwaters Technology Innovation, Llc | Supported nickel catalysts having high nickel loading and high metal dispersion and methods of making same |
| US8217191B2 (en) * | 2008-11-05 | 2012-07-10 | Aiken John E | Process for integrated co-production of hydrogen peroxide and epoxidized esters |
| DE102008062686A1 (de) | 2008-12-17 | 2010-07-01 | Süd-Chemie AG | Verfahren zur Herstellung von Methyltrioxorhenium (MTO) |
| DE102008062687A1 (de) | 2008-12-17 | 2010-07-01 | Süd-Chemie AG | Verfahren zur Herstellung von Alkyltrioxorhenium |
| CN102190634B (zh) * | 2011-03-10 | 2013-05-08 | 辽宁大学 | 一种温度控制相转移铼催化剂催化烯烃环氧化方法 |
| US9765182B2 (en) * | 2013-09-20 | 2017-09-19 | The United States Of America, As Represented By The Secretary Of Agriculture | Elastomer derived from epoxidized vegetable oil |
| CN104926606B (zh) * | 2014-03-21 | 2017-12-12 | 湖南长岭石化科技开发有限公司 | 一种对来自烯烃环氧化反应过程的回收醇溶剂进行纯化的方法和一种烯烃环氧化方法 |
| GB201608776D0 (en) | 2016-05-18 | 2016-06-29 | Dextra Lab Ltd | Methods and compounds |
| CN106349016A (zh) * | 2016-08-22 | 2017-01-25 | 江苏怡达化学股份有限公司 | 一种用于甲醇回收的前处理系统及工艺 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2871102A (en) * | 1951-08-18 | 1959-01-27 | Shell Dev | Process for the production of hydrogen peroxide |
| US2869989A (en) * | 1952-04-23 | 1959-01-20 | Shell Dev | Method for the recovery of hydrogen peroxide |
| US2819949A (en) * | 1953-01-19 | 1958-01-14 | Shell Dev | Purification of hydrogen peroxide |
| US2871103A (en) * | 1953-12-23 | 1959-01-27 | Shell Dev | Method for the production of hydrogen peroxide |
| GB758907A (en) * | 1953-12-23 | 1956-10-10 | Bataafsche Petroleum | Improvements in or relating to the production of hydrogen peroxide |
| GB758967A (en) * | 1954-04-27 | 1956-10-10 | Bataafsche Petroleum | Improvements in or relating to the production of hydrogen peroxide and the hydrogen peroxide thus produced |
| US2871104A (en) * | 1955-01-31 | 1959-01-27 | Shell Dev | Manufacture of hydrogen peroxide |
| US2949343A (en) * | 1955-09-06 | 1960-08-16 | Shell Oil Co | Purifying hydrogen peroxide |
| US3012860A (en) * | 1958-03-17 | 1961-12-12 | Shell Oil Co | Hydrogen peroxide purification |
| US3074782A (en) * | 1959-05-29 | 1963-01-22 | Shell Oil Co | Hydrogen peroxide purification |
| US3003853A (en) * | 1959-09-24 | 1961-10-10 | Shell Oil Co | Production of hydrogen peroxide |
| FR1505332A (fr) * | 1965-11-30 | 1967-12-15 | Inst Francais Du Petrole | Procédé de fabrication d'époxydes |
| FR1506459A (fr) * | 1966-11-02 | 1967-12-22 | Naphtachimie Sa | Procédé de préparation d'époxydes et produits préparés selon ce procédé |
| US4303632A (en) * | 1979-12-14 | 1981-12-01 | E. I. Du Pont De Nemours And Company | Preparation of hydrogen peroxide |
| US4864041A (en) * | 1987-02-04 | 1989-09-05 | Emory University | Transition metal-substituted polyoxometalates as catalysts for homogenous liquid-phase organic oxidation processes |
| DE3731690C1 (de) * | 1987-09-21 | 1989-01-19 | Degussa | Verfahren zur katalytischen Epoxidation von Olefinen mit Wasserstoffperoxid |
| DE3731689A1 (de) * | 1987-09-21 | 1989-03-30 | Degussa | Rhenium-oxo-porphyrin-komplexe |
| US4897252A (en) * | 1989-01-10 | 1990-01-30 | Arco Chemical Technology, Inc. | Production of hydrogen peroxide |
| US4975266A (en) * | 1989-01-10 | 1990-12-04 | Arco Chemical Technology, Inc. | Production of hydrogen peroxide |
| US5039508A (en) * | 1989-01-10 | 1991-08-13 | Arco Chemical Technology, Inc. | Production of hydrogen peroxide |
| DE3902357A1 (de) * | 1989-01-27 | 1990-08-02 | Hoechst Ag | Verwendung von rheniumorganischen verbindungen zur oxidation von c-c-mehrfachbindungen, darauf basierende oxidationsverfahren und neue rheniumorganische verbindungen |
| US5041680A (en) * | 1991-02-19 | 1991-08-20 | Arco Chemical Technology, Inc. | Production of hydrogen peroxide |
| US5166372A (en) | 1992-02-07 | 1992-11-24 | Arco Chemical Technology, L.P. | Epoxidation process |
-
1992
- 1992-02-07 US US07/832,568 patent/US5166372A/en not_active Expired - Fee Related
-
1993
- 1993-02-04 JP JP03923393A patent/JP3203583B2/ja not_active Expired - Fee Related
- 1993-02-05 ES ES93300866T patent/ES2101942T3/es not_active Expired - Lifetime
- 1993-02-05 EP EP93300866A patent/EP0560488B1/en not_active Expired - Lifetime
- 1993-02-05 DE DE69310962T patent/DE69310962T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0560488B1 (en) | 1997-05-28 |
| US5166372A (en) | 1992-11-24 |
| DE69310962D1 (de) | 1997-07-03 |
| JP3203583B2 (ja) | 2001-08-27 |
| EP0560488A1 (en) | 1993-09-15 |
| JPH061781A (ja) | 1994-01-11 |
| DE69310962T2 (de) | 1997-09-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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