ES2102068T3 - Empleo de copolimeros de vinilpirrolidona y vinilimidazol como aditivo de detergentes, asi como su procedimiento de obtencion. - Google Patents
Empleo de copolimeros de vinilpirrolidona y vinilimidazol como aditivo de detergentes, asi como su procedimiento de obtencion.Info
- Publication number
- ES2102068T3 ES2102068T3 ES93923472T ES93923472T ES2102068T3 ES 2102068 T3 ES2102068 T3 ES 2102068T3 ES 93923472 T ES93923472 T ES 93923472T ES 93923472 T ES93923472 T ES 93923472T ES 2102068 T3 ES2102068 T3 ES 2102068T3
- Authority
- ES
- Spain
- Prior art keywords
- weight
- pct
- unsaturated monomers
- polymers
- optionally
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title abstract 3
- 239000000654 additive Substances 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000000996 additive effect Effects 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 7
- 239000000203 mixture Substances 0.000 abstract 3
- 229920000642 polymer Polymers 0.000 abstract 3
- 102000004169 proteins and genes Human genes 0.000 abstract 3
- 108090000623 proteins and genes Proteins 0.000 abstract 3
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 abstract 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 abstract 2
- 239000012736 aqueous medium Substances 0.000 abstract 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- OSSNTDFYBPYIEC-UHFFFAOYSA-O 1-ethenylimidazole;hydron Chemical class C=CN1C=C[NH+]=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-O 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3788—Graft polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Detergent Compositions (AREA)
Abstract
UTILIZACION DE COPOLIMEROS QUE PUEDEN SER PRODUCIDOS MEDIANTE COPOLIMERIZACION INICIADA RADICALMENTE DE MEZCLA DE MONOMEROS COMPUESTAS DE (A) 60 HASTA 99 % EN PESO DE 1 - VINILPIRROLIDON, 1 - VINILIMIDAZOL O SUS MEZCLAS; (B) 1 HASTA 40 % EN PESO DE MONOMEROS NITROGENADOS, BASICOS, NO SATURADOS ETILENICAMENTE COMO BASES LIBRES, SALES, O EN FORMA CUATERNARIA, Y SI SE REQUIERE (C) HASTA 20 % EN PESO DE OTROS MONOMEROS NO SATURADOS MONOETILENICAMENTE. ESTOS COPOLIMEROS SON UTILIZADOS COMO ADITIVOS PARA AGENTES DE LAVADO A FIN DE INHIBIR LA TRANSMISION DE COLORACION DURANTE EL PROCESO DE LAVADO. SE DESCRIBEN TAMBIEN AGENTES DE LAVADO CONTENIENDO TALES POLIMEROS, ASI COMO POLIMEROS QUE PUEDEN SER PRODUCIDOS MEDIANTE POLIMERIZACION INICIADA RADIALMENTE DE (A) 1 - VINILPIRROLIDONA, 1 - VINILIMIDAZOL, 1 VINILIMIDAZOLIO O SUS MEZCLAS Y SI SE REQUIERE (B) OTROS MONOMEROS NITROGENADOS, BASICOS, NO SATURADOS ETILENICAMENTE, COMO BASES LIBRES, SALES O EN FORMA CUATERNARIA, Y/O (C) OTROS MONOMEROS NO SATURADOS MONOETILENICAMENTE, EN UN MEDIO ACUOSO EN PRESENCIA DE PROTEINAS SOLUBLES EN AGUA. SE DESCRIBE UN PROCESO PARA LA PREPARACION DE ESTOS POLIMEROS MEDIANTE POLIMERIZACION DE MONOMEROS (A) Y SI SE REQUIERE (B) Y/O (C) EN UN MEDIO ACUOSO EN PRESENCIA DE PROTEINAS SOLUBLES EN AGUA. POR 100 PARTES EN PESO DE MONOMERO UTILIZADO PARA LA POLIMERIZACION SE UTILIZA 0,5 HASTA 400 PARTES EN PESO DE PROTEINAS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4235798A DE4235798A1 (de) | 1992-10-23 | 1992-10-23 | Verwendung von Vinylpyrrolidon- und Vinylimidazol-Copolymerisaten als Waschmitteladditiv, neue Polymerisate des Vinylpyrrolidons und des Vinylimidazols und Verfahren zu ihrer Herstellung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2102068T3 true ES2102068T3 (es) | 1997-07-16 |
Family
ID=6471172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93923472T Expired - Lifetime ES2102068T3 (es) | 1992-10-23 | 1993-10-15 | Empleo de copolimeros de vinilpirrolidona y vinilimidazol como aditivo de detergentes, asi como su procedimiento de obtencion. |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US5627151A (es) |
| EP (1) | EP0665875B1 (es) |
| JP (1) | JP3272359B2 (es) |
| AT (1) | ATE154385T1 (es) |
| CA (1) | CA2146853A1 (es) |
| DE (2) | DE4235798A1 (es) |
| ES (1) | ES2102068T3 (es) |
| WO (1) | WO1994010281A1 (es) |
Families Citing this family (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07502141A (ja) * | 1991-09-30 | 1995-03-02 | ゼネラル・ダイナミックス・インフォメーション・システムズ・インコーポレーテッド | めっきしたしなやかなリード線 |
| DE4329065A1 (de) * | 1993-08-28 | 1995-03-02 | Henkel Kgaa | Flüssigwaschmittel |
| ATE227333T1 (de) * | 1994-04-14 | 2002-11-15 | Procter & Gamble | Waschmittelzusammensetzungen mit zusätzen zur verhinderung der farbstoffübertragung sowie verfahren zur deren herstellung |
| DE4421179A1 (de) * | 1994-06-17 | 1995-12-21 | Basf Ag | Farbstoffübertragungsinhibitoren für Wasch- und Reinigungsmittel |
| DE19655045C2 (de) * | 1995-01-31 | 2000-08-31 | Tokyo Ohka Kogyo Co Ltd | Wasserlösliches Copolymer auf Basis von Vinylpyrrolidon und Vinylimidazol |
| US5725978A (en) * | 1995-01-31 | 1998-03-10 | Basf Aktiengesellschaft | Water-soluble photosensitive resin composition and a method of forming black matrix patterns using the same |
| PT754748E (pt) * | 1995-07-20 | 2002-02-28 | Procter & Gamble | Composicoes detergentes que inibem a transferencia de corantes |
| DE19532718A1 (de) * | 1995-09-05 | 1997-03-06 | Basf Ag | Pulverförmige, poröse, N-Vinylimidazol-Einheiten enthaltende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19621509A1 (de) | 1996-05-29 | 1997-12-04 | Basf Ag | Verwendung von wasserlöslichen, N-Vinylimidazol-Einheiten enthaltenden Copolymerisaten als Farbübertragungsinhibitoren in Waschmitteln |
| DE19646437A1 (de) * | 1996-11-11 | 1998-05-14 | Basf Ag | Verwendung von quaternierten Vinylimidazol-Einheiten enthaltenden Polymerisaten als farbfixierenden und farbübertragungsinhibierenden Zusatz zu Wäschenachbehandlungsmitteln und zu Waschmitteln |
| US5880081A (en) * | 1997-04-07 | 1999-03-09 | Gopalkrishnan; Sridhar | Concentrated built liquid detergents containing a dye-transfer inhibiting additive |
| DE19745637A1 (de) * | 1997-10-16 | 1999-04-22 | Basf Ag | Verwendung von kationischen Copolymerisaten aus ungesättigten Säuren und N-Vinylimidazoliumsalzen in haarkosmetischen Zubereitungen |
| US5990198A (en) * | 1998-03-24 | 1999-11-23 | Xerox Corporation | Ink compositions containing vinyl pyrrolidinone/vinyl imidazolium copolymers |
| USRE39450E1 (en) * | 1999-04-28 | 2006-12-26 | National Starch And Chemical Investment Holding Co | Polyvinylpyrridinium derivatives as anti-dye transfer agents |
| US6191098B1 (en) | 1999-04-28 | 2001-02-20 | National Starch And Chemical Investment Holding Corporation | Polyvinylpyridinium derivatives as anti-dye transfer agents |
| US6207778B1 (en) * | 1999-05-07 | 2001-03-27 | Isp Investments Inc. | Conditioning/styling terpolymers |
| US6306815B1 (en) | 1999-09-10 | 2001-10-23 | National Starch And Chemical Investment Holding Corporation | Quaternary polyvinylpyrridinium derivatives as anti-dye transfer agents |
| ATE264141T1 (de) | 1999-11-05 | 2004-04-15 | Johnson Matthey Plc | Immobilisierte ionische flüssigkeiten |
| US6391995B2 (en) | 2000-02-09 | 2002-05-21 | Reilly Industries, Inc. | Polymer compositions useful as dye complexing agents, and processes for preparing same |
| DE10029696A1 (de) * | 2000-06-16 | 2001-12-20 | Basf Ag | Waschaktive Zubereitung |
| US6887524B2 (en) | 2000-10-13 | 2005-05-03 | The Procter & Gamble Company | Method for manufacturing laundry additive article |
| US20020119721A1 (en) * | 2000-10-13 | 2002-08-29 | The Procter & Gamble Company | Multi-layer dye-scavenging article |
| US6833336B2 (en) * | 2000-10-13 | 2004-12-21 | The Procter & Gamble Company | Laundering aid for preventing dye transfer |
| US6482790B2 (en) * | 2000-12-05 | 2002-11-19 | Isp Investments Inc. | Laundry detergent compositions containing water soluble dye complexing polymers |
| US7256166B2 (en) * | 2002-01-18 | 2007-08-14 | The Procter & Gamble Company | Laundry articles |
| US20050119151A1 (en) * | 2002-04-10 | 2005-06-02 | Konstanze Mayer | Textile cleaning agent which is gentle on textiles |
| US7115254B1 (en) * | 2002-10-25 | 2006-10-03 | Nalco Company | Personal care compositions containing N,N-diallyldialkylammonium halide/N-vinylpyrrolidone polymers |
| US20050215449A1 (en) * | 2002-11-20 | 2005-09-29 | Josef Penninger | Textile care product |
| US8592361B2 (en) | 2002-11-25 | 2013-11-26 | Colgate-Palmolive Company | Functional fragrance precursor |
| ATE434076T1 (de) * | 2002-12-03 | 2009-07-15 | Basf Se | Pfropfpolymerisaten als hilfsmittel für die textilfärberei und den textildruck |
| DE10257389A1 (de) | 2002-12-06 | 2004-06-24 | Henkel Kgaa | Flüssiges saures Waschmittel |
| DE102004020015A1 (de) * | 2004-04-21 | 2005-11-10 | Henkel Kgaa | Textilpflegemittel |
| DE102004020544A1 (de) | 2004-04-27 | 2005-11-24 | Basf Ag | Copolymere mit N-heterocyclischen Gruppen und deren Verwendung als Additiv in Waschmitteln |
| DE102004021732A1 (de) * | 2004-04-30 | 2005-11-24 | Henkel Kgaa | Textilplegemittel mit amingruppenhaltigem Celluloseether |
| US20060264346A1 (en) * | 2005-05-19 | 2006-11-23 | Sullivan Mary K | Timed-release cleansing and/or treatment formulation and method for making and using the same |
| DE102005039580A1 (de) | 2005-08-19 | 2007-02-22 | Henkel Kgaa | Farbschützendes Waschmittel |
| WO2007023862A1 (ja) | 2005-08-26 | 2007-03-01 | Nippon Shokubai Co., Ltd. | 染料移行防止剤、洗濯用洗剤組成物 |
| DE102006012018B3 (de) | 2006-03-14 | 2007-11-15 | Henkel Kgaa | Farbschützendes Waschmittel |
| EP2021451A1 (de) * | 2006-05-18 | 2009-02-11 | Henkel AG & Co. KGaA | Farbschützendes waschmittel |
| EP2106413A1 (de) * | 2006-12-21 | 2009-10-07 | Basf Se | Thermosensitiver polymerer farbübertragungsinhibitor |
| JP5041469B2 (ja) | 2007-02-01 | 2012-10-03 | 花王株式会社 | 洗剤組成物 |
| US20100189664A1 (en) * | 2007-07-09 | 2010-07-29 | Basf Se | Cosmetic agents based on vinylimidazole polymers |
| US8623343B2 (en) * | 2007-07-17 | 2014-01-07 | Basf Se | Highly cationic copolymers based on quaternized nitrogen-containing monomers |
| US9096817B2 (en) * | 2007-11-06 | 2015-08-04 | Rhodia Operations | Copolymer for processing or modifying surfaces |
| RU2570529C2 (ru) | 2010-08-06 | 2015-12-10 | Басф Се | Применение сополимера n-виниллактам/винилимидазол в качестве диспергирующего агента, водная пестицидная композиция, содержащая этот сополимер, способ получения указанной композиции, а также способ борьбы с фитопатогенными грибками, и/или ростом нежелательных растений, и/или нежелательной атакой насекомых или клещей, и/или регулирования роста растений |
| KR20140114076A (ko) | 2012-02-13 | 2014-09-25 | 헨켈 아게 운트 코 카게아아 | 색-보호 세척제 또는 세정제 |
| EP2814928B1 (de) | 2012-02-13 | 2018-04-04 | Henkel AG & Co. KGaA | Farbschützendes wasch- oder reinigungsmittel |
| JP6147860B2 (ja) * | 2012-09-27 | 2017-06-14 | ロディア オペレーションズRhodia Operations | 銀ナノ構造を作製するための方法及び同方法に有用なコポリマー |
| DE102012219403A1 (de) | 2012-10-24 | 2014-04-24 | Henkel Ag & Co. Kgaa | Farbschützende Waschmittel |
| DE102012024442A1 (de) | 2012-12-14 | 2014-06-18 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Die Primärwaschkraft verbessernde polymere Wirkstoffe |
| DE102013203484A1 (de) | 2013-03-01 | 2014-09-04 | Henkel Ag & Co. Kgaa | Farbschützende Waschmittel |
| EP3119863A4 (en) * | 2014-03-19 | 2017-08-30 | Rhodia Opérations S.A.S. | New copolymers useful in liquid detergent compositions |
| US10017716B2 (en) | 2014-08-22 | 2018-07-10 | Rohm And Haas Company | Imidazole-modified carbohydrate polymers as laundry dye transfer inhibitors |
| DE102014220663A1 (de) | 2014-10-13 | 2016-04-14 | Henkel Ag & Co. Kgaa | Farbschützende Waschmittel |
| DE102014220662A1 (de) | 2014-10-13 | 2016-04-14 | Henkel Ag & Co. Kgaa | Farbschützende Waschmittel |
| EP3241889B1 (en) * | 2016-05-03 | 2019-03-20 | The Procter and Gamble Company | Cleaning composition |
| DE102017004698A1 (de) | 2017-05-17 | 2018-11-22 | Henkel Ag & Co. Kgaa | Farbschützende Waschmittel |
| EP3421583A1 (en) | 2017-06-26 | 2019-01-02 | Basf Se | Use of cationic vinylcarboxamide/vinylamine copolymers as a color care agent for laundering formulations |
| CN110684144A (zh) * | 2019-10-28 | 2020-01-14 | 浙江理工大学上虞工业技术研究院有限公司 | 一种防沾色皂洗剂的制备方法 |
| CN116515040B (zh) * | 2023-05-25 | 2025-06-06 | 上海宇昂水性新材料科技股份有限公司 | 一种n-乙烯吡咯烷酮/1-乙烯基咪唑共聚物及其制备方法和防沾色剂 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE785653A (es) * | 1971-07-02 | 1973-01-02 | Procter & Gamble Europ | |
| DE2814287A1 (de) * | 1978-04-03 | 1979-10-11 | Henkel Kgaa | Waschmittel mit einem gehalt an verfaerbungsinhibierenden zusaetzen |
| NZ192549A (en) * | 1979-01-12 | 1981-11-19 | Unilever Ltd | Liquid detergent comprising a copolymer of n-vinylpyrrolidone |
| DE2926568A1 (de) * | 1979-06-30 | 1981-01-22 | Hoechst Ag | Verfahren zur herstellung von hydrophilierten pfropfpolymerisaten aus proteinen und deren verwendung |
| MY105119A (en) * | 1988-04-12 | 1994-08-30 | Kao Corp | Low irritation detergent composition. |
| US4923694A (en) * | 1988-08-25 | 1990-05-08 | Gaf Chemicals Corporation | Hydrolysis resistant vinyl lactam amino acrylamide polymers |
| DE4016002A1 (de) * | 1990-05-18 | 1991-11-21 | Basf Ag | Verwendung von wasserloeslichen oder wasserdispergierbaren gepfropften proteinen als zusatz zu wasch- und reinigungsmitteln |
-
1992
- 1992-10-23 DE DE4235798A patent/DE4235798A1/de not_active Withdrawn
-
1993
- 1993-10-15 WO PCT/EP1993/002851 patent/WO1994010281A1/de not_active Ceased
- 1993-10-15 ES ES93923472T patent/ES2102068T3/es not_active Expired - Lifetime
- 1993-10-15 JP JP51062594A patent/JP3272359B2/ja not_active Expired - Fee Related
- 1993-10-15 US US08/325,177 patent/US5627151A/en not_active Expired - Lifetime
- 1993-10-15 AT AT93923472T patent/ATE154385T1/de not_active IP Right Cessation
- 1993-10-15 DE DE59306750T patent/DE59306750D1/de not_active Expired - Lifetime
- 1993-10-15 EP EP93923472A patent/EP0665875B1/de not_active Expired - Lifetime
- 1993-10-15 CA CA002146853A patent/CA2146853A1/en not_active Abandoned
-
1996
- 1996-08-08 US US08/694,023 patent/US5846924A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE4235798A1 (de) | 1994-04-28 |
| EP0665875A1 (de) | 1995-08-09 |
| JPH08502773A (ja) | 1996-03-26 |
| US5846924A (en) | 1998-12-08 |
| JP3272359B2 (ja) | 2002-04-08 |
| CA2146853A1 (en) | 1994-05-11 |
| WO1994010281A1 (de) | 1994-05-11 |
| ATE154385T1 (de) | 1997-06-15 |
| US5627151A (en) | 1997-05-06 |
| EP0665875B1 (de) | 1997-06-11 |
| DE59306750D1 (de) | 1997-07-17 |
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| Date | Code | Title | Description |
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| FG2A | Definitive protection |
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