ES2103748T3 - Uso de dioxido de carbono liquido como agente soplante en la produccion de espuma de poliuretano flexible, de celula abierta. - Google Patents
Uso de dioxido de carbono liquido como agente soplante en la produccion de espuma de poliuretano flexible, de celula abierta.Info
- Publication number
- ES2103748T3 ES2103748T3 ES90916868T ES90916868T ES2103748T3 ES 2103748 T3 ES2103748 T3 ES 2103748T3 ES 90916868 T ES90916868 T ES 90916868T ES 90916868 T ES90916868 T ES 90916868T ES 2103748 T3 ES2103748 T3 ES 2103748T3
- Authority
- ES
- Spain
- Prior art keywords
- blowing agent
- polyurethane foam
- open cell
- mixture
- cell polyurethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004604 Blowing Agent Substances 0.000 title abstract 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title abstract 4
- 229920005830 Polyurethane Foam Polymers 0.000 title abstract 3
- 239000011496 polyurethane foam Substances 0.000 title abstract 3
- 229910002092 carbon dioxide Inorganic materials 0.000 title abstract 2
- 239000001569 carbon dioxide Substances 0.000 title abstract 2
- 239000007788 liquid Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 abstract 4
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000005442 diisocyanate group Chemical group 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000000852 hydrogen donor Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/127—Mixtures of organic and inorganic blowing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/05—Open cells, i.e. more than 50% of the pores are open
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
PROCESO PARA LA PRODUCCION DE UNA ESPUMA DE POLIURETANO DE CELULAS ABIERTAS QUE COMPRENDE EL MEZCLADO DE LOS SIGUIENTES COMPONENTES A TEMPERATURAS AMBIENTE EN LA ZONA DE MEZCLADO: UN DIISOCIANATO CON UNA FUNCIONALIDAD DE, AL MENOS, 2,0 APROXIMADAMENTE, AL MENOS UN DADOR DE HIDROGENO, AL MENOS UN SURFACTANTE EFECTIVO EN LA FORMACION DE ESPUMA DE POLIURETANO DE CELULAS ABIERTAS, AL MENOS UN CATALIZADOR Y UN AGENTE DE SOPLADO QUE COMPRENDA UN GAS QUE TENGA UN PUNTO DE EBULLICION INFERIOR APROXIMADAMENTE A -100 (GRADOS) F A TEMPERATURA Y PRESION ATMOSFERICAS QUE CONTENGA PREFERIBLEMENTE DIOXIDO DE CARBONO. ADEMAS, LA MEZCLA TAMBIEN PUEDE CONTENER, OPCIONALMENTE, AGUA. LA MEZCLA ESTA SUJETA A UNA PRESION, EN DICHA ZONA DE MEZCLADO, SUFICIENTE PARA MANTENER EL AGENTE DE SOPLADO EN ESTADO LIQUIDO A TEMPERATURAS AMBIENTE. TRAS EL MEZCLADO, LA MEZCLA SE EXPULSA DE LA ZONA DE MEZCLADO A PRESION ATMOSFERICA, DE ESTE MODO SE EVAPORA COMPLETA E INSTANTANEAMENTE EL AGENTE DE SOPLADO PARA FACILITAR LA EXPANSION DE LA MEZCLA. LA ESPUMA RESULTANTE SE CURA A CONTINUACION A TEMPERATURAS AMBIENTE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/442,645 US5120770A (en) | 1989-11-29 | 1989-11-29 | Use of liquid carbon dioxide as a blowing agent in the production of open-cell polyurethane foam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2103748T3 true ES2103748T3 (es) | 1997-10-01 |
Family
ID=23757592
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90916868T Expired - Lifetime ES2103748T3 (es) | 1989-11-29 | 1990-11-13 | Uso de dioxido de carbono liquido como agente soplante en la produccion de espuma de poliuretano flexible, de celula abierta. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5120770A (es) |
| EP (1) | EP0502871B1 (es) |
| AT (1) | ATE152751T1 (es) |
| CA (1) | CA2069878C (es) |
| DE (1) | DE69030670T2 (es) |
| DK (1) | DK0502871T3 (es) |
| ES (1) | ES2103748T3 (es) |
| WO (1) | WO1991008243A1 (es) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3903336A1 (de) * | 1989-02-04 | 1990-08-09 | Bayer Ag | Verwendung von c(pfeil abwaerts)3(pfeil abwaerts)- bis c(pfeil abwaerts)5(pfeil abwaerts)-polyfluoralkanen als treibgase |
| BR9106262A (pt) * | 1990-03-23 | 1993-04-06 | Du Pont | Espumas de polimeros contendo agentes bloqueadores |
| DE4212362A1 (de) * | 1992-04-13 | 1993-10-14 | Linde Ag | Herstellung aufgeschäumter Kunststoffe |
| NO309077B1 (no) | 1993-07-14 | 2000-12-11 | Foaming Techn Cardio Bv | FremgangsmÕte og system for kontinuerlig tilvirkning av polyuretanskumblokker |
| IT1270979B (it) * | 1993-09-30 | 1997-05-26 | Afros Spa | Procedimento e apparecchiatura per la produzione in continuo di schiume poliuretaniche in blocchi |
| US5340490A (en) * | 1993-07-14 | 1994-08-23 | Alliedsignal Inc. | Azeotrope-like compositions of trifluoromethane and carbon dioxide or hexafluoroethane and carbon dioxide |
| US5665287A (en) * | 1993-07-14 | 1997-09-09 | Foaming Technologies Cardio Bv | Froth process for continous manufacture of polyurethane foam slab-stocks |
| US5336696A (en) * | 1993-12-10 | 1994-08-09 | Nisshinbo Industries, Inc. | Halogen-free blowing agents that include cycloaliphatic hydrocarbons and are suitable for isocyanate-based polymeric foams |
| US5539008A (en) * | 1993-12-29 | 1996-07-23 | Minnesota Mining And Manufacturing Company | Foamable composition containing unsaturated perfluorochemical blowing agent |
| DE4422568C1 (de) * | 1994-06-28 | 1996-02-15 | Bayer Ag | Verfahren und Vorrichtung zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid |
| DE19502708C2 (de) * | 1995-01-28 | 2003-10-23 | Solvay Fluor & Derivate | Verfahren zur Herstellung von Ein- oder Mehrkomponenten-Polyurethanschaumstoffen |
| DE59501858D1 (de) * | 1994-11-02 | 1998-05-14 | Solvay Fluor & Derivate | Flüssiges kohlendioxid enthaltende treibmittel |
| DE4446876A1 (de) * | 1994-12-27 | 1996-07-04 | Bayer Ag | Verfahren und Vorrichtung zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid |
| US6005014A (en) * | 1995-07-11 | 1999-12-21 | Beamech Group Limited | Apparatus and process for producing polymeric foam |
| US5604267A (en) * | 1995-08-30 | 1997-02-18 | Arco Chemical Technology, L.P. | Process for producing froth polyurethane foam |
| US5525640A (en) * | 1995-09-13 | 1996-06-11 | Osi Specialties, Inc. | Silicone surfactants for use in inert gas blown polyurethane foams |
| DE19539072C1 (de) * | 1995-10-20 | 1997-06-12 | Hennecke Gmbh Maschf | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polyurethanblockschaum |
| DE19621305A1 (de) * | 1996-05-28 | 1997-12-04 | Bayer Ag | Verfahren zur Herstellung von elastischen Polyurethanblockschaumstoffen |
| US5789454A (en) * | 1996-08-12 | 1998-08-04 | Osi Specialties, Inc. | Silicone surfactant compositions useful in inert gas blown polyurethane foams |
| US6106473A (en) | 1996-11-06 | 2000-08-22 | Sts Biopolymers, Inc. | Echogenic coatings |
| US7229413B2 (en) * | 1996-11-06 | 2007-06-12 | Angiotech Biocoatings Corp. | Echogenic coatings with overcoat |
| EP0942819A2 (en) * | 1996-11-27 | 1999-09-22 | Foaming Technologies Cardio B.V. | Process and low-output plant for the continuous production of slab-stock foam |
| US5801210A (en) * | 1997-10-29 | 1998-09-01 | Bayer Corporation | Method and apparatus for the production of essentially void free foams |
| US5883143A (en) * | 1998-06-18 | 1999-03-16 | Bayer Aktiengesellschaft | Method and device for the production of foam using carbon dioxide dissolved under pressure |
| DE19803362A1 (de) * | 1998-01-29 | 1999-08-05 | Sartorius Gmbh | Geschäumte poröse Membranen aus thermoplastischen Polymeren sowie Verfahren und Vorrichtung zu ihrer Herstellung |
| US6290883B1 (en) * | 1999-08-31 | 2001-09-18 | Lucent Technologies Inc. | Method for making porous CMP article |
| US6403663B1 (en) | 1999-09-20 | 2002-06-11 | North Carolina State University | Method of making foamed materials using surfactants and carbon dioxide |
| DE19961417C1 (de) * | 1999-12-17 | 2001-07-19 | Bayer Ag | Verfahren zur Herstellung von Verbundmaterialien |
| IT1319643B1 (it) * | 2000-11-09 | 2003-10-23 | Enichem Spa | Procedimento per la produzione di schiume poliuretaniche rigide edarticoli finiti da esse ottenuti. |
| US6458861B1 (en) | 2001-01-18 | 2002-10-01 | Bayer Antwerp N.V. | Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components |
| KR101561890B1 (ko) * | 2014-08-22 | 2015-10-26 | 주식회사 덕성 | 원사 코팅용 수성 열경화성 우레탄 컴파운드 및 이를 코팅한 코팅 원사의 제조방법 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB904003A (en) * | 1958-02-06 | 1962-08-22 | Dunlop Rubber Co | Method and apparatus for the production of cellular synthetic rubber |
| US3882052A (en) * | 1973-12-17 | 1975-05-06 | Olin Corp | On-site generation of non-froth polyurethane foam |
| US4337318A (en) * | 1980-09-30 | 1982-06-29 | Doyle Earl N | Process for the total pre-expansion of polyurethane foam |
| GB2116574A (en) * | 1982-03-19 | 1983-09-28 | Ici Plc | Method of manufacturing polyurethane foams |
| GB8329628D0 (en) * | 1983-11-05 | 1983-12-07 | Rubber & Plastic Res Ass | Polyurethanes |
| DE3916873C2 (de) * | 1988-05-27 | 2003-01-09 | Elastogran Gmbh | Verfahren zur Herstellung von zellhaltigen Kunststoffen nach dem Polyisocyanat-polyadditionsverfahren und eine Katalysatorkombination hierfür |
| US4906672A (en) * | 1988-07-29 | 1990-03-06 | Pmc, Inc. | Blowing agents for polyurethane foam |
| US4945119A (en) * | 1989-05-10 | 1990-07-31 | The Dow Chemical Company | Foaming system for rigid urethane and isocyanurate foams |
-
1989
- 1989-11-29 US US07/442,645 patent/US5120770A/en not_active Expired - Lifetime
-
1990
- 1990-11-13 CA CA002069878A patent/CA2069878C/en not_active Expired - Lifetime
- 1990-11-13 DK DK90916868.4T patent/DK0502871T3/da active
- 1990-11-13 AT AT90916868T patent/ATE152751T1/de not_active IP Right Cessation
- 1990-11-13 ES ES90916868T patent/ES2103748T3/es not_active Expired - Lifetime
- 1990-11-13 EP EP90916868A patent/EP0502871B1/en not_active Expired - Lifetime
- 1990-11-13 WO PCT/US1990/006485 patent/WO1991008243A1/en not_active Ceased
- 1990-11-13 DE DE69030670T patent/DE69030670T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO1991008243A1 (en) | 1991-06-13 |
| DK0502871T3 (da) | 1997-12-15 |
| CA2069878A1 (en) | 1991-05-30 |
| CA2069878C (en) | 1997-07-01 |
| DE69030670D1 (de) | 1997-06-12 |
| DE69030670T2 (de) | 1998-01-02 |
| EP0502871A1 (en) | 1992-09-16 |
| ATE152751T1 (de) | 1997-05-15 |
| EP0502871B1 (en) | 1997-05-07 |
| US5120770A (en) | 1992-06-09 |
| EP0502871A4 (en) | 1992-11-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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