ES2104122T3 - Sistema catalitico modificado de monociclopentadienil-metal de transicion/alumoxano para la polimerizacion de olefinas. - Google Patents

Sistema catalitico modificado de monociclopentadienil-metal de transicion/alumoxano para la polimerizacion de olefinas.

Info

Publication number
ES2104122T3
ES2104122T3 ES93902669T ES93902669T ES2104122T3 ES 2104122 T3 ES2104122 T3 ES 2104122T3 ES 93902669 T ES93902669 T ES 93902669T ES 93902669 T ES93902669 T ES 93902669T ES 2104122 T3 ES2104122 T3 ES 2104122T3
Authority
ES
Spain
Prior art keywords
metal
catalyst system
alumoxane
transitional
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93902669T
Other languages
English (en)
Other versions
ES2104122T5 (es
Inventor
Jo Ann Marie Henderson Canich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25209551&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2104122(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2104122T3 publication Critical patent/ES2104122T3/es
Publication of ES2104122T5 publication Critical patent/ES2104122T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

ESTE INVENTO COMPRENDE UN SISTEMA CATALIZADOR Y UN PROCESO QUE USA TAL SISTEMA CATALIZADOR PARA LA PRODUCCION DE POLIOLEFINAS DE PESO MOLECULAR ALTO, PARTICULARMENTE POLIETILENO Y POLI-A-OLEFINA MAS ALTA, Y COPOLIMEROS DE ETILENO Y/O A-OLEFINAS CON OTROS MONOMEROS INSATURADOS, INCLUYENDO DIOLEFINAS, MONOMEROS INSATURADOS ACETILENICAMENTE Y OLEFINAS CICLICAS. EL SISTEMA CATALIZADOR COMPRENDE TRES COMPONENTES, UN COMPONENTE METAL DE TRANSICION DEL GRUPO IV B MONOCICLOPENTADIENIL, UN ALUMOXANO, Y UN MODIFICADOR. EL SISTEMA CATALIZADOR ES ALTAMENTE ACTIVO, A PROPORCIONES BAJAS DE ALUMINIO AL METAL DE TRANSICION DEL GRUPO IV B, INCREMENTA CATALIZAR LA PRODUCCION DE UN PRODUCTO DE POLIOLEFINA CONTENIENDO NIVELES BAJOS DE RESIDUO DE METAL CATALIZADOR.
ES93902669T 1991-12-23 1992-12-21 Sistema catalitico modificado de monociclopentadienil-metal de transicion/alumoxano para la polimerizacion de olefinas. Expired - Lifetime ES2104122T5 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US81243291A 1991-12-23 1991-12-23

Publications (2)

Publication Number Publication Date
ES2104122T3 true ES2104122T3 (es) 1997-10-01
ES2104122T5 ES2104122T5 (es) 2001-03-01

Family

ID=25209551

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93902669T Expired - Lifetime ES2104122T5 (es) 1991-12-23 1992-12-21 Sistema catalitico modificado de monociclopentadienil-metal de transicion/alumoxano para la polimerizacion de olefinas.

Country Status (6)

Country Link
EP (1) EP0618931B2 (es)
JP (1) JP2816766B2 (es)
CA (1) CA2126317C (es)
DE (1) DE69220676T3 (es)
ES (1) ES2104122T5 (es)
WO (1) WO1993013140A1 (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5264405A (en) * 1989-09-13 1993-11-23 Exxon Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US5621126A (en) * 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
USRE37788E1 (en) * 1987-01-30 2002-07-09 Exxon Chemical Patents, Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
CA2164968A1 (en) * 1993-06-15 1994-12-22 Syoji Naganuma Process for preparing olefin polymer and catalyst for polymerization of olefin
JP3216748B2 (ja) 1993-07-23 2001-10-09 出光興産株式会社 芳香族ビニル化合物重合体組成物の製造触媒及びそれを用いた芳香族ビニル化合物重合体組成物の製造方法
JP3180523B2 (ja) 1993-09-13 2001-06-25 出光興産株式会社 スチレン系重合体製造用触媒の選択方法
EP0664304B1 (en) * 1993-12-27 1999-08-04 Mitsui Chemicals, Inc. Olefin polymerization catalyst and process for olefin polymerization
US5464906A (en) * 1994-11-21 1995-11-07 The Dow Chemical Company Ethylene homopolymerization using group 3 metal complexes
JP3847783B2 (ja) * 1995-01-24 2006-11-22 イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー オレフィンの重合方法
US5880241A (en) * 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
US6897272B1 (en) 1995-01-24 2005-05-24 E.I. Du Pont De Nemours And Company α-olefins and olefin polymers and processes therefor
JPH08253522A (ja) * 1995-03-14 1996-10-01 Idemitsu Kosan Co Ltd オレフィン重合用触媒及びそれを用いたオレフィン系重合体の製造方法
US6759499B1 (en) 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
JPH1112289A (ja) * 1997-06-19 1999-01-19 Sumitomo Chem Co Ltd 架橋型遷移金属錯体の製造方法
DE19804970A1 (de) * 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
US6281320B1 (en) 1999-02-04 2001-08-28 Union Carbide Chemicals & Plastics Technology Corporation Use of chelatable phenols with metallocene- aluminoxane catalyst systems
JP2000351813A (ja) 1999-04-09 2000-12-19 Mitsui Chemicals Inc エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
CA2393793C (en) * 1999-12-10 2009-09-29 Jerzy Klosin Substituted group 4 metal complexes, catalysts and olefin polymerization process
GB0220681D0 (en) * 2002-09-05 2002-10-16 Borealis Tech Oy Process
WO2008052673A1 (en) * 2006-10-30 2008-05-08 Basell Polyolefine Gmbh Process for the polymerization of olefins using catalyst systems based on an organic transition metal complex

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0780930B2 (ja) * 1985-12-26 1995-08-30 三井石油化学工業株式会社 α−オレフインの重合方法
DE3782243T2 (de) † 1986-08-26 1993-03-04 Mitsui Petrochemical Ind Katalysator zur polymerisierung von alpha-olefin und verfahren.
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
JP2573613B2 (ja) * 1987-08-14 1997-01-22 三菱化学株式会社 エチレンの重合法
MY103812A (en) † 1988-02-12 1993-09-30 Mitsui Chemicals Inc Olefin polymerization catalyst and process for the polymerization of olefins.
US5057475A (en) † 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
GB9103527D0 (en) † 1991-02-20 1991-04-10 Exxon Chemical Patents Inc Hp catalyst killer

Also Published As

Publication number Publication date
WO1993013140A1 (en) 1993-07-08
ES2104122T5 (es) 2001-03-01
EP0618931A1 (en) 1994-10-12
JP2816766B2 (ja) 1998-10-27
DE69220676D1 (de) 1997-08-07
JPH07501846A (ja) 1995-02-23
EP0618931B2 (en) 2000-11-02
DE69220676T3 (de) 2001-05-17
CA2126317C (en) 2000-03-14
EP0618931B1 (en) 1997-07-02
DE69220676T2 (de) 1997-12-11
CA2126317A1 (en) 1993-07-08

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