ES2104454T3 - Procedimiento para la preparacion de sistemas de catalizadores del tipo de metalocenos sobre materiales de soporte inertes. - Google Patents

Procedimiento para la preparacion de sistemas de catalizadores del tipo de metalocenos sobre materiales de soporte inertes.

Info

Publication number
ES2104454T3
ES2104454T3 ES95114344T ES95114344T ES2104454T3 ES 2104454 T3 ES2104454 T3 ES 2104454T3 ES 95114344 T ES95114344 T ES 95114344T ES 95114344 T ES95114344 T ES 95114344T ES 2104454 T3 ES2104454 T3 ES 2104454T3
Authority
ES
Spain
Prior art keywords
procedure
preparation
catalyst systems
support materials
type catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95114344T
Other languages
English (en)
Inventor
Dirk Kutschera
Rainer Rieger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanxess Organometallics GmbH
Original Assignee
Witco GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Witco GmbH filed Critical Witco GmbH
Application granted granted Critical
Publication of ES2104454T3 publication Critical patent/ES2104454T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
    • Y10S502/523—Miscellaneous specific techniques of general applicability
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

LA INVENCION TRATA DE UN PROCEDIMIENTO PARA LA OBTENCION DE SISTEMAS CATALITICOS DE METALOCENO INMOVILLIZADOS SOBRE MATERIALES SOPORTES INERTES HECHOS DE COMPUESTOS DE ALUMINIO, AGUA, METALOCENOS Y OPCIONALMENTE OLEFINAS, QUE SE CARACTERIZA PORQUE LOS REACTANTES SE INTRODUCEN EN REACTORES DE LECHO FLUIDIZADO JUNTO CON LA CORRIENTE DE GAS, Y DESPUES DE LA REACCION SE FIJAN DIRECTAMENTE SOBRE EL SOPORTE A PARTIR DE LA FASE GASEOSA
ES95114344T 1995-09-13 1995-09-13 Procedimiento para la preparacion de sistemas de catalizadores del tipo de metalocenos sobre materiales de soporte inertes. Expired - Lifetime ES2104454T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP95114344A EP0763545B1 (de) 1995-09-13 1995-09-13 Verfahren zur Herstellung von Metallocen-Katalysatorsystemen auf inerten Trägermaterialien

Publications (1)

Publication Number Publication Date
ES2104454T3 true ES2104454T3 (es) 1997-10-01

Family

ID=8219607

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95114344T Expired - Lifetime ES2104454T3 (es) 1995-09-13 1995-09-13 Procedimiento para la preparacion de sistemas de catalizadores del tipo de metalocenos sobre materiales de soporte inertes.

Country Status (7)

Country Link
US (1) US5789332A (es)
EP (1) EP0763545B1 (es)
JP (1) JPH09118710A (es)
AT (1) ATE152136T1 (es)
CA (1) CA2178121A1 (es)
DE (1) DE59500197D1 (es)
ES (1) ES2104454T3 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI95276C (fi) * 1993-12-03 1996-01-10 Borealis As Olefiinien polymerointikatalyytti ja menetelmä sen valmistamiseksi
EP0766700B1 (en) * 1994-06-24 2000-01-19 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US6043180A (en) * 1994-11-17 2000-03-28 The Dow Chemical Company Supported catalyst component, supported catalyst, their preparation, and addition polymerization process
EP0763546B1 (de) * 1995-09-13 1997-05-28 Witco GmbH Verfahren zur Herstellung von Metallocen-Katalysatorsystemen auf inerten Trägermaterialien unter Verwendung von Gasphasenreaktoren
US5990035A (en) * 1997-10-21 1999-11-23 Koeppl; Alexander Polymerization catalyst systems, their preparation, and use
US6242545B1 (en) * 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US8497330B2 (en) * 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
DE69927234T2 (de) * 1998-07-02 2006-06-29 Basell Polyolefine Gmbh Verfahren zur herstellung von amorphen alpha-olefinpolymeren, diese enthaltende zusammensetzungen und verfahren zur herstellung von verbrückten liganden
DE19833170A1 (de) * 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
GB9822123D0 (en) * 1998-10-09 1998-12-02 Borealis As Catalyst
CN102803280A (zh) 2009-06-11 2012-11-28 格雷斯公司 制造铝氧烷的方法和包括由此制备的铝氧烷的催化剂
KR101310592B1 (ko) * 2010-02-04 2013-09-23 주식회사 엘지화학 올레핀 중합용 담지 메탈로센 촉매의 제조방법
CN102815857A (zh) * 2012-09-07 2012-12-12 广东富睿实业集团有限公司 一种新型特种玻璃的制备方法
CN119549071B (zh) * 2023-09-04 2026-02-06 中国石油天然气股份有限公司 一种均相茂金属催化剂制备系统及方法

Family Cites Families (22)

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Publication number Priority date Publication date Assignee Title
US2477019A (en) * 1944-11-01 1949-07-26 Socony Vacuum Oil Co Inc Method for heat-treating solid inorganic adsorbents
BE603978A (es) * 1960-05-20
US3300458A (en) * 1963-08-19 1967-01-24 Union Carbide Corp Continuous processes for the production of ethylene polymers and catalysts suitable therefor
JPS5015475A (es) * 1973-06-08 1975-02-18
US3884832A (en) * 1974-02-04 1975-05-20 Chemplex Co Organotin chromate polymerization catalyst
GB1553197A (en) * 1975-08-21 1979-09-26 British Petroleum Co Polymersiation catalyst
US4427573A (en) * 1981-09-16 1984-01-24 Union Carbide Corporation Polymerization catalyst, process for preparing, and use for ethylene polymerization
EP0295312B1 (en) * 1986-12-30 1994-04-20 Mitsui Petrochemical Industries, Ltd. Solid catalyst for olefin polymerization and process for its preparation
US5026797A (en) * 1987-10-22 1991-06-25 Mitsubishi Petrochemical Co., Ltd. Process for producing ethylene copolymers
US5086025A (en) * 1988-03-29 1992-02-04 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US4904631A (en) * 1988-11-08 1990-02-27 Exxon Chemical Patents, Inc. Supported vanadium catalyst for polymerization of olefins and a process of preparing and using the same
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
US5206401A (en) * 1990-06-08 1993-04-27 Akzo Chemicals Inc. Method of making alkylaluminoxane
DE4032266A1 (de) * 1990-10-11 1992-04-16 Hoechst Ag Verfahren zur herstellung eines polyolefins
US5308815A (en) * 1991-07-26 1994-05-03 Ethyl Corporation Heterogeneous methylaluminoxane catalyst system
US5157008A (en) * 1991-08-01 1992-10-20 Ethyl Corporation Hydrocarbon solutions of alkylaluminoxane compounds
US5378672A (en) * 1992-03-04 1995-01-03 Fina Technology, Inc. Methods and systems for multi-component catalyst formulation
DE4207899A1 (de) * 1992-03-12 1993-09-16 Basf Ag Feststoff, enthaltend chemisch gebundene metallalkylgruppen, und seine verwendung
FI95276C (fi) * 1993-12-03 1996-01-10 Borealis As Olefiinien polymerointikatalyytti ja menetelmä sen valmistamiseksi
MX9500982A (es) * 1994-02-17 1997-02-28 Union Carbide Chem Plastic Composicion catalizadora cargada con metaloceno, secada por rociadura para usarse en la fabricacion de poliolefina.
DE4409249A1 (de) * 1994-03-18 1995-09-21 Witco Gmbh Verfahren zur Herstellung von Alkylaluminoxan auf inerten Trägermaterialien
US5721184A (en) * 1995-11-17 1998-02-24 Hoechst Method for making supported catalyst systems and catalyst systems therefrom

Also Published As

Publication number Publication date
DE59500197D1 (de) 1997-05-28
US5789332A (en) 1998-08-04
JPH09118710A (ja) 1997-05-06
EP0763545B1 (de) 1997-04-23
ATE152136T1 (de) 1997-05-15
CA2178121A1 (en) 1997-03-14
EP0763545A1 (de) 1997-03-19

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