ES2104861T3 - Electrodos solidos ioniselectivos a base de grafito de membrana polimera. - Google Patents
Electrodos solidos ioniselectivos a base de grafito de membrana polimera.Info
- Publication number
- ES2104861T3 ES2104861T3 ES92311834T ES92311834T ES2104861T3 ES 2104861 T3 ES2104861 T3 ES 2104861T3 ES 92311834 T ES92311834 T ES 92311834T ES 92311834 T ES92311834 T ES 92311834T ES 2104861 T3 ES2104861 T3 ES 2104861T3
- Authority
- ES
- Spain
- Prior art keywords
- oxidant
- solid
- ioniselective
- selective
- polymer membrane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract 2
- 229910002804 graphite Inorganic materials 0.000 title abstract 2
- 239000010439 graphite Substances 0.000 title abstract 2
- 229920005597 polymer membrane Polymers 0.000 title 1
- 239000007787 solid Substances 0.000 title 1
- 239000007800 oxidant agent Substances 0.000 abstract 3
- 230000001590 oxidative effect Effects 0.000 abstract 3
- 150000001768 cations Chemical class 0.000 abstract 2
- 239000003638 chemical reducing agent Substances 0.000 abstract 2
- 150000002500 ions Chemical class 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- 239000002555 ionophore Substances 0.000 abstract 1
- 230000000236 ionophoric effect Effects 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 230000035945 sensitivity Effects 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/333—Ion-selective electrodes or membranes
- G01N27/3335—Ion-selective electrodes or membranes the membrane containing at least one organic component
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Physics & Mathematics (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Biological Materials (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Carbon And Carbon Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
LA INVENCION SE REFIERE A UN ELECTRODO IONSELECTIVO DE ESTADO SOLIDO MEJORADO QUE TIENE MAYOR UNIFORMIDAD DE POTENCIAL ASIMETRICO Y ALTA SENSIBILIDAD Y SELECTIVIDAD PARA EL CATION DE INTERES. EL ELECTRODO COMPRENDE: (1) UN ELEMENTO POROSO (10) QUE CONTIENE GRAFITO; (2) UNA REFERENCIA ELECTROQUIMICA (20) EN UNA FORMA PRACTICAMENTE SECA EN AL MENOS UNA PARTE DEL ELEMENTO, COMPRENDIENDO LA REFERENCIA: (A) UN OXIDANTE Y (B) UN REDUCTOR QUE ES EL CONJUGADO DEL OXIDANTE, ESTANDO EL OXIDANTE Y EL REDUCTOR PRESENTES EN CANTIDADES APROXIMADAMENTE EQUIMOLARES; Y (3) UNA MEMBRANA POLIMERICA (30) QUE COMPRENDE UN IONOFORO IONSELECTIVO EN CONTACTO ELECTROQUIMICO CON LA REFERENCIA ELECTROQUIMICA. EL ELECTRODO SE PUEDE PREPARAR PARA SER SELECTIVO DE UNO DE VARIOS CATIONES, INCLUYENDO LITIO Y AMONIO. ASIMISMO, LA INVENCION SE REFIERE A METODOS PARA PREPARAR ESTOS ELECTRODOS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/821,158 US5286365A (en) | 1992-01-15 | 1992-01-15 | Graphite-based solid state polymeric membrane ion-selective electrodes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2104861T3 true ES2104861T3 (es) | 1997-10-16 |
Family
ID=25232670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92311834T Expired - Lifetime ES2104861T3 (es) | 1992-01-15 | 1992-12-29 | Electrodos solidos ioniselectivos a base de grafito de membrana polimera. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5286365A (es) |
| EP (1) | EP0551769B1 (es) |
| JP (1) | JP2546786Y2 (es) |
| AT (1) | ATE155580T1 (es) |
| CA (1) | CA2085322C (es) |
| DE (1) | DE69220915T2 (es) |
| ES (1) | ES2104861T3 (es) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9123083D0 (en) * | 1991-10-31 | 1991-12-18 | Band David M | Ion-selective polymeric electrodes |
| US5552032A (en) * | 1995-04-24 | 1996-09-03 | Beckman Instruments, Inc. | Solid state ion selective electrode and method of using the same |
| US5879878A (en) * | 1995-06-20 | 1999-03-09 | Australian Membrane And Biotechnology Research Institute | Method of producing a first layer electrode membrane for a biosensor |
| AUPN366995A0 (en) * | 1995-06-20 | 1995-07-13 | Australian Membrane And Biotechnology Research Institute | Self-assembly of bilayer membrane sensors |
| EP0879412A4 (en) * | 1996-02-08 | 2004-08-11 | Ambri Ltd | BIOSENSOR TO DETECT ENZYMS |
| EP1003850B1 (en) * | 1997-06-06 | 2009-05-27 | The Regents of the University of California | Inhibitors of dna immunostimulatory sequence activity |
| KR100289469B1 (ko) * | 1999-01-13 | 2001-05-02 | 차근식 | 친수성 폴리우레탄을 보호막으로 사용한 염화이온 선택성 전극 |
| JP3635263B2 (ja) | 2000-03-01 | 2005-04-06 | ラジオメーター・メディカル・アクティーゼルスカブ | 固体状態参照系を持つ電極デバイス |
| US6508921B1 (en) * | 2000-03-24 | 2003-01-21 | Beckman Coulter, Inc. | Lithium ion-selective electrode for clinical applications |
| US7842234B2 (en) | 2002-12-02 | 2010-11-30 | Epocal Inc. | Diagnostic devices incorporating fluidics and methods of manufacture |
| US7094330B2 (en) * | 2002-12-02 | 2006-08-22 | Epocal Inc. | Heterogeneous membrane electrodes |
| US7767068B2 (en) | 2002-12-02 | 2010-08-03 | Epocal Inc. | Heterogeneous membrane electrodes |
| GB0423025D0 (en) * | 2004-10-15 | 2004-11-17 | Oxford Biosensors Ltd | Voltammetric ion sensor |
| FR2900064B1 (fr) * | 2006-04-24 | 2008-12-12 | Electricite De France | Membrane selective des ions lithium pour la mesure de la concentration en lithium dans un fluide tel que la fluide du circuit primaire de refroidissement d'un reacteur d'une centrale nucleaire a eau pressurisee |
| CN101308113B (zh) * | 2008-01-23 | 2011-09-14 | 同济大学 | 以聚1-氨基蒽醌为载体的铅离子选择电极用膜、其制备方法及其用途 |
| ES2334748B1 (es) * | 2008-09-12 | 2011-01-10 | Consejo Superior De Investigaciones Cientificas(Csic) | Sensores potenciometricos basados en clusters de boro anionicos. |
| US20120118762A1 (en) * | 2009-02-13 | 2012-05-17 | Curtin University Of Technology | Sensing device and method |
| JP5254123B2 (ja) * | 2009-04-30 | 2013-08-07 | オルガノ株式会社 | リチウムイオン選択性電極 |
| EP2992319A1 (en) | 2013-05-02 | 2016-03-09 | Biochem Technology Inc. | Low drift ion selective electrode sensors |
| WO2016156941A1 (en) * | 2015-04-03 | 2016-10-06 | Diasys Diagnostics India Private Limited | Solid state electrolyte biosensor |
| CN105116036A (zh) * | 2015-08-13 | 2015-12-02 | 东北大学 | 一种铈(ⅳ)离子选择性电极的制备和使用方法 |
| EP3351931B1 (en) * | 2015-09-14 | 2025-10-08 | Hitachi High-Tech Corporation | Ion-selective electrode and method of manufacture thereof |
| JP6634805B2 (ja) * | 2015-12-10 | 2020-01-22 | 東亜ディーケーケー株式会社 | 塩素イオン選択性電極 |
| US10557814B2 (en) | 2016-06-24 | 2020-02-11 | City University Of Hong Kong | Electrochemical detector |
| US11923545B2 (en) * | 2020-01-22 | 2024-03-05 | Enevate Corporation | Crown ethers as additives for silicon-based Li-ion batteries |
| CN108732217A (zh) * | 2018-04-28 | 2018-11-02 | 深圳市西尔曼科技有限公司 | 铵离子微电极及其制作方法 |
| JP7146189B2 (ja) * | 2018-09-20 | 2022-10-04 | Koa株式会社 | 全固体型イオン選択性電極の製造方法 |
| JP2022537280A (ja) * | 2019-06-14 | 2022-08-25 | ローベルト ボツシユ ゲゼルシヤフト ミツト ベシユレンクテル ハフツング | イオン選択性電極用トランスデューサとしての金属フェロシアン化物ドープ炭素 |
| EP4090957A1 (en) * | 2020-01-13 | 2022-11-23 | Beckman Coulter, Inc. | Solid state ion selective electrodes |
| CN112285185A (zh) * | 2020-10-26 | 2021-01-29 | 河南城建学院 | 5-二茂铁异酞酰-l-色氨酸甲酯作为磷酸氢根离子选择性电极活性载体的应用 |
| IT202100000341A1 (it) * | 2021-01-11 | 2022-07-11 | Redoak S R L | Dispositivo di analisi di urine non trattate |
| JP7813428B2 (ja) * | 2021-08-30 | 2026-02-13 | シスメックス株式会社 | イオンセンサおよびイオンの測定方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3314864A (en) * | 1964-06-11 | 1967-04-18 | Beckman Instruments Inc | Gas analysis |
| US3662745A (en) * | 1969-06-30 | 1972-05-16 | Hoffmann La Roche | Metal-metal salt electrode and method for making the same |
| CH589096A5 (es) * | 1972-04-24 | 1977-06-30 | Moeller W Glasblaeserei | |
| US3856649A (en) * | 1973-03-16 | 1974-12-24 | Miles Lab | Solid state electrode |
| US4115209A (en) * | 1974-10-30 | 1978-09-19 | Research Corporation | Method of determining ion activity using coated ion selective electrodes |
| US4276141A (en) * | 1978-02-24 | 1981-06-30 | Beckman Instruments, Inc. | Solid state ion selective electrodes |
| US4271002A (en) * | 1979-06-27 | 1981-06-02 | Beckman Instruments, Inc. | Calcium ion-selective electrodes and membrane for use therein |
| IL59148A (en) * | 1980-01-17 | 1984-01-31 | Yeda Res & Dev | Lipophilic aliphatic amide lithium ionophores,their preparation and pharmaceutical compositions comprising them |
| US4303408A (en) * | 1980-02-05 | 1981-12-01 | Eastman Kodak Company | Removal of interferents in analytical assays in a two phase interferent-removal zone |
| SU920499A1 (ru) * | 1980-03-26 | 1982-04-15 | Ленинградский Ордена Ленина И Ордена Трудового Красного Знамени Государственный Университет Им.А.А.Жданова | Ионоселективный электрод дл определени концентрации тетрафенилборат-анионов |
| SU935776A1 (ru) * | 1980-10-02 | 1982-06-15 | Научно-производственное объединение "Квант" | Способ изготовлени твердофазного ионоселективного электрода |
| DE3146066A1 (de) * | 1980-11-28 | 1982-06-09 | Orion Research Puerto Rico, Inc., 00924 Rio Piedras, P.R. | Potentiometrische elektrode |
| JPS58156848A (ja) * | 1982-03-15 | 1983-09-17 | Fuji Photo Film Co Ltd | イオン選択電極及びその製造法 |
| US4431508A (en) * | 1982-12-10 | 1984-02-14 | Brown Jr Harold M | Solid state graphite electrode |
| US4454007A (en) * | 1983-01-27 | 1984-06-12 | E. I. Du Pont De Nemours And Company | Ion-selective layered sensor and methods of making and using the same |
| US4504368A (en) * | 1983-07-18 | 1985-03-12 | Eastman Kodak Company | Alkali metal ion-selective compositions and elements and a method of using same |
| JPS60243555A (ja) * | 1984-05-18 | 1985-12-03 | Fuji Photo Film Co Ltd | イオン選択電極及びその製造方法 |
| US4549951A (en) * | 1984-09-11 | 1985-10-29 | Sentech Medical Corporation | Ion selective electrode |
| CH660481A5 (de) * | 1984-09-13 | 1987-04-30 | Moeller Willi Fa | Cyclohexancarbonsaeurediamide und diese enthaltende ionenselektive membran. |
| EP0231476A1 (en) * | 1985-12-23 | 1987-08-12 | Siddiqi, Iqbal W., Dr. | Selectively ion-permeable electrodes for analyzing selected ions in aqueous solution |
| ES2004487T3 (es) * | 1986-10-01 | 1993-06-01 | Willi Moller Ag | Procedimineto para determinar la relacion entre las concentraciones de iones litio e iones sodio y dispositivo para la realizacion de este procedimiento. |
| CA1315927C (en) * | 1986-12-10 | 1993-04-13 | Terumo Kabushiki Kaisha | Ion carrier membrane, and ion sensor having same |
-
1992
- 1992-01-15 US US07/821,158 patent/US5286365A/en not_active Expired - Fee Related
- 1992-12-14 CA CA002085322A patent/CA2085322C/en not_active Expired - Fee Related
- 1992-12-29 DE DE69220915T patent/DE69220915T2/de not_active Expired - Fee Related
- 1992-12-29 EP EP92311834A patent/EP0551769B1/en not_active Expired - Lifetime
- 1992-12-29 ES ES92311834T patent/ES2104861T3/es not_active Expired - Lifetime
- 1992-12-29 AT AT92311834T patent/ATE155580T1/de active
-
1993
- 1993-01-14 JP JP1993003499U patent/JP2546786Y2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0551769A1 (en) | 1993-07-21 |
| JP2546786Y2 (ja) | 1997-09-03 |
| DE69220915D1 (de) | 1997-08-21 |
| EP0551769B1 (en) | 1997-07-16 |
| CA2085322C (en) | 2000-04-25 |
| CA2085322A1 (en) | 1993-07-16 |
| JPH0633063U (ja) | 1994-04-28 |
| ATE155580T1 (de) | 1997-08-15 |
| DE69220915T2 (de) | 1997-12-11 |
| US5286365A (en) | 1994-02-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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