ES2104927T3 - Procedimiento para la produccion de mezclas de 2-hidroxitetrahidrofurano y 4-hidroxibutanol. - Google Patents
Procedimiento para la produccion de mezclas de 2-hidroxitetrahidrofurano y 4-hidroxibutanol.Info
- Publication number
- ES2104927T3 ES2104927T3 ES92912218T ES92912218T ES2104927T3 ES 2104927 T3 ES2104927 T3 ES 2104927T3 ES 92912218 T ES92912218 T ES 92912218T ES 92912218 T ES92912218 T ES 92912218T ES 2104927 T3 ES2104927 T3 ES 2104927T3
- Authority
- ES
- Spain
- Prior art keywords
- dihydrofuran
- hydroxybutanal
- production
- hydroxytetrahydrofuran
- hydroxitetrahydrofuran
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- ARGCQEVBJHPOGB-UHFFFAOYSA-N 2,5-dihydrofuran Chemical compound C1OCC=C1 ARGCQEVBJHPOGB-UHFFFAOYSA-N 0.000 abstract 4
- JNODDICFTDYODH-UHFFFAOYSA-N 2-hydroxytetrahydrofuran Chemical compound OC1CCCO1 JNODDICFTDYODH-UHFFFAOYSA-N 0.000 abstract 4
- PIAOXUVIBAKVSP-UHFFFAOYSA-N γ-hydroxybutyraldehyde Chemical compound OCCCC=O PIAOXUVIBAKVSP-UHFFFAOYSA-N 0.000 abstract 4
- JKTCBAGSMQIFNL-UHFFFAOYSA-N 2,3-dihydrofuran Chemical compound C1CC=CO1 JKTCBAGSMQIFNL-UHFFFAOYSA-N 0.000 abstract 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D307/28—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
- C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
- C07C45/59—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/20—Oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
- Catalysts (AREA)
Abstract
SE DESCUBRE UN PROCESO PARA LA PRODUCCION DE UNA MEZCLA EQUILIBRADA DE 2 HIDROXITETRAHIDROFURANO Y UN 4 POR UN PROCESO DE DOS ETAPAS QUE COMPRENDE (1) CALENTAR 2,5IHIDROFURANO EN PRESENCIA DE UN SISTEMA CATALIZADOR QUE CONTIENE UN FOSFURO, RUTENIO O RODIO PARA CONVERTIR EL 2,5 URANO A 2,3 IDROFURANO CON AGUA EN PRESENCIA DE UN CATALIZADOR ACIDO PARA CONVERTIR EL 2,3 TRAHIDROFURANO Y 4 HIDROXIBUTANO. TAMBIEN SE DESCUBRE UN PROCESO PARA LA PRODUCCION CONTINUA DE UNA SOLUCION ACUOSA DE 2 IDROXYTETRAHIDROFURANO Y 4 ROXITETRAHIDROFURANO Y 4 CATALITICAMENTE PARA PRODUCIR 1,4 - BUTANODIOL.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/702,483 US5254701A (en) | 1991-05-20 | 1991-05-20 | Process for the production of mixtures of 2-hydroxytetrahydrofuran and 4-hydroxybutanal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2104927T3 true ES2104927T3 (es) | 1997-10-16 |
Family
ID=24821398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92912218T Expired - Lifetime ES2104927T3 (es) | 1991-05-20 | 1992-05-14 | Procedimiento para la produccion de mezclas de 2-hidroxitetrahidrofurano y 4-hidroxibutanol. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5254701A (es) |
| EP (1) | EP0586522B1 (es) |
| JP (1) | JPH06507898A (es) |
| AT (1) | ATE155781T1 (es) |
| CA (1) | CA2099115C (es) |
| DE (1) | DE69221146T2 (es) |
| ES (1) | ES2104927T3 (es) |
| WO (1) | WO1992020667A1 (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5254702A (en) * | 1992-04-13 | 1993-10-19 | Arco Chemical Technology, L.P. | Process for the preparation of 2-oxytetrahydrofurans |
| DE4325753A1 (de) * | 1993-07-31 | 1995-02-02 | Basf Ag | Verfahren zur Herstellung von 1,4-Butandiol |
| DE4422051A1 (de) * | 1994-06-27 | 1996-01-04 | Basf Ag | Verfahren zur Herstellung von 1,4-Butandiol |
| US5536851A (en) * | 1995-01-31 | 1996-07-16 | Eastman Chemical Company | Preparation of 2,3-dihydrofurans |
| US5670672A (en) * | 1995-01-31 | 1997-09-23 | Eastman Chemical Company | Process for the preparation of 2,3-dihydrofurans |
| US5681969A (en) * | 1996-05-03 | 1997-10-28 | Eastman Chemical Company | Continuous process for the conversion of 2,5-dihydrofuran to 2,3-dihydrofuran |
| KR100469944B1 (ko) * | 1998-03-10 | 2005-12-28 | 삼성정밀화학 주식회사 | 히드록시테트라히드로퓨란의제조방법 |
| US6222058B1 (en) | 1998-03-30 | 2001-04-24 | Eastman Chemical Company | Process for the manufacture of cyclopropanecarbonitrile |
| US5986141A (en) * | 1998-09-29 | 1999-11-16 | Eastman Chemical Company | Process for the production of cyclopropanemethylamine |
| US6610878B1 (en) | 1999-05-10 | 2003-08-26 | Eastman Chemical Company | Poly(3-cyclopropyl-3-hydroxypropionate) and processes for its preparation and derivatives thereof |
| US6353140B1 (en) | 2000-10-19 | 2002-03-05 | Eastman Chemical Company | Process for the purification of cyclopropanecarboxaldehyde |
| JP4483156B2 (ja) * | 2002-03-28 | 2010-06-16 | 三菱化学株式会社 | ガンマブチロラクトンの精製方法 |
| WO2009133950A1 (ja) | 2008-05-01 | 2009-11-05 | 株式会社クラレ | ビニルエーテル系化合物の製造方法 |
| CN102746203B (zh) * | 2012-07-12 | 2014-08-27 | 浙江医药股份有限公司新昌制药厂 | 一种高含量玉米黄素的制备方法 |
| JP6191213B2 (ja) * | 2013-04-19 | 2017-09-06 | 東レ株式会社 | テトラヒドロフラン含有物の精製方法 |
| CN114685404A (zh) * | 2020-12-25 | 2022-07-01 | 南通泰禾化工股份有限公司 | 一种用于环丙甲醛制备的2,3-二氢呋喃中间体制备方法 |
| CN114349616B (zh) * | 2022-01-10 | 2023-12-26 | 上海巽田科技股份有限公司 | 制备环丙烷甲醛的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2556325A (en) * | 1951-06-12 | Production of z | ||
| DE1248669B (de) * | 1965-01-07 | 1968-03-14 | Badische Anilin &. Soda-Fabrik Aktien gesellschaft, 6700 Ludwigshafen | Verfahren zur Herstellung von 2 3-Dihydrofuranen |
| IT1066754B (it) * | 1975-11-05 | 1985-03-12 | Firestone Tire & Rubber Co | Procedimento per la preparazione di gamma idrossitetraidrofurano e di tetraidrofurano mediante idroformilazione di alcool allilico |
| NL8002342A (nl) * | 1980-04-23 | 1981-11-16 | Stamicarbon | Bereiding van 2-hydroxytetrahydrofuraan. |
| DE3308931A1 (de) * | 1983-03-12 | 1984-09-20 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von 3-hydroxytetrahydrofuran |
| US4533742A (en) * | 1984-02-02 | 1985-08-06 | Texaco Inc. | Preparation of 2-hydroxytetrahydrofuran by hydroformylation of allyl alcohol using ketone solvents |
| US4529808A (en) * | 1984-02-02 | 1985-07-16 | Texaco Inc. | Bi-solvent system for the hydroformylation of allyl alcohol using a rhodium catalyst |
| DE3909485A1 (de) * | 1989-03-22 | 1990-09-27 | Basf Ag | Verfahren zur herstellung von butandiol-1,4 und tetrahydrofuran |
-
1991
- 1991-05-20 US US07/702,483 patent/US5254701A/en not_active Expired - Fee Related
-
1992
- 1992-05-14 DE DE69221146T patent/DE69221146T2/de not_active Expired - Fee Related
- 1992-05-14 JP JP5500156A patent/JPH06507898A/ja active Pending
- 1992-05-14 AT AT92912218T patent/ATE155781T1/de active
- 1992-05-14 EP EP92912218A patent/EP0586522B1/en not_active Revoked
- 1992-05-14 WO PCT/US1992/003978 patent/WO1992020667A1/en not_active Ceased
- 1992-05-14 ES ES92912218T patent/ES2104927T3/es not_active Expired - Lifetime
- 1992-05-14 CA CA002099115A patent/CA2099115C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5254701A (en) | 1993-10-19 |
| EP0586522A1 (en) | 1994-03-16 |
| WO1992020667A1 (en) | 1992-11-26 |
| JPH06507898A (ja) | 1994-09-08 |
| ATE155781T1 (de) | 1997-08-15 |
| DE69221146D1 (de) | 1997-09-04 |
| DE69221146T2 (de) | 1997-11-27 |
| CA2099115A1 (en) | 1992-11-21 |
| CA2099115C (en) | 1997-10-28 |
| EP0586522B1 (en) | 1997-07-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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