ES2105287T3 - Acidos poliasparaginicos modificados, un procedimiento para su obtencion y su empleo. - Google Patents
Acidos poliasparaginicos modificados, un procedimiento para su obtencion y su empleo.Info
- Publication number
- ES2105287T3 ES2105287T3 ES93914689T ES93914689T ES2105287T3 ES 2105287 T3 ES2105287 T3 ES 2105287T3 ES 93914689 T ES93914689 T ES 93914689T ES 93914689 T ES93914689 T ES 93914689T ES 2105287 T3 ES2105287 T3 ES 2105287T3
- Authority
- ES
- Spain
- Prior art keywords
- acids
- modified
- acid
- multibasic
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002253 acid Substances 0.000 title abstract 9
- 150000007513 acids Chemical class 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- 229920000608 Polyaspartic Polymers 0.000 abstract 4
- 150000001412 amines Chemical class 0.000 abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 2
- 230000005494 condensation Effects 0.000 abstract 2
- 238000009833 condensation Methods 0.000 abstract 2
- 239000002699 waste material Substances 0.000 abstract 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 abstract 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 235000003704 aspartic acid Nutrition 0.000 abstract 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001720 carbohydrates Chemical class 0.000 abstract 1
- 235000014633 carbohydrates Nutrition 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 150000002337 glycosamines Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B30/00—Crystallisation; Crystallising apparatus; Separating crystals from mother liquors ; Evaporating or boiling sugar juice
- C13B30/02—Crystallisation; Crystallising apparatus
- C13B30/021—Crystallisation; Crystallising apparatus using chemicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/04—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonamides, polyesteramides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/10—Alpha-amino-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1092—Polysuccinimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3788—Graft polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Biochemistry (AREA)
- Polyamides (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
LA INVENCION SE REFIERE A ACIDOS POLIASPARTICOS MODIFICADOS, OBTENIBLES MEDIANTE CONDENSACION DE (A) 1 HASTA 99,9 MOL % DE ACIDO ASPARTICO CON (B) 99 HASTA 0,1 MOL % EN ACIDOS GRASOS, ACIDOS CARBOXILICOS MULTIBASICOS, ACIDOS CARBOXILICOS MULTIBASICOS ANHIDRIDOS, ACIDOS CARBOXILICOS HIDROXI MULTIBASICOS, ACIDOS CARBOXILICOS POLIHIDROXI MONOBASICOS, ALCOHOLES, AMINAS, ALCOHOLES ALCOXILADOS Y AMINAS, AZUCAR AMINO, HIDRATOS DE CARBONO, ACIDOS CARBOXILICOS DE AZUCAR Y/O ACIDOS AMINOCARBOXILICOS NO PROTEINOGENOS O SUS POLIMERIZADOS A PARTIR DE MONOMEROS NO SATURADOS MONOETILENICAMENTE EN PRESENCIA DE ACIDOS POLIASPARTICOS SEGUN EL TIPO DE UNA COPOLIMERIZACION DE INJERTO INICIADO, PROCEDIMIENTO PARA LA ELABORACION DE LOS ACIDOS POLIASPARTICOS MODIFICADOS ASI COMO UTILIZACION DE LOS ACIDOS POLIASPARTICOS MODIFICADOS COMO MEDIOS ADICIONALES PARA AGENTES DE LIMPIEZA Y LAVADO, COMO AGENTES DE TRATAMIENTO DE AGUA Y COMO INHIBIDORES DE DEPOSITO DURANTE LA CONDENSACION DE ZUMOS AZUCARADOS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4221875A DE4221875A1 (de) | 1992-07-03 | 1992-07-03 | Modifizierte Polyasparaginsäuren, Verfahren zu ihrer Herstellung und ihre Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2105287T3 true ES2105287T3 (es) | 1997-10-16 |
Family
ID=6462409
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93914689T Expired - Lifetime ES2105287T3 (es) | 1992-07-03 | 1993-06-22 | Acidos poliasparaginicos modificados, un procedimiento para su obtencion y su empleo. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5747635A (es) |
| EP (1) | EP0648241B1 (es) |
| DE (2) | DE4221875A1 (es) |
| ES (1) | ES2105287T3 (es) |
| WO (1) | WO1994001486A1 (es) |
Families Citing this family (89)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5619274A (en) * | 1990-09-10 | 1997-04-08 | Starsight Telecast, Inc. | Television schedule information transmission and utilization system and process |
| DE4239076A1 (de) * | 1992-11-20 | 1994-05-26 | Basf Ag | Mischungen aus Polymerisaten von monoethylenisch ungesättigten Dicarbonsäuren und Polymerisaten ethylenisch ungesättigter Monocarbonsäuren und/oder Polyaminocarbonsäuren und ihre Verwendung |
| DE4311854A1 (de) * | 1993-04-10 | 1994-10-13 | Basf Ag | Verwendung von Carboxylgruppen enthaltenden Umsetzungsprodukten von Proteinen oder Proteinhydrolysaten in Wasch- und Reinigungsmitteln |
| AU740017B2 (en) * | 1994-02-14 | 2001-10-25 | Bayer Aktiengesellschaft | Copolymers of polyaspartic acid and polycarboxylic acids and polyamines |
| US5726280A (en) * | 1994-08-24 | 1998-03-10 | Bayer Ag | Sulfonic acid group-containing polyaspartic acid derivatives, use thereof and prepartion thereof |
| DE4429976A1 (de) | 1994-08-24 | 1996-02-29 | Bayer Ag | Sulfonsäuregruppen enthaltende Polyasparaginsäurederivate, ihre Verwendung und Herstellung |
| DE4430520A1 (de) * | 1994-08-27 | 1996-02-29 | Basf Ag | Verfahren zur Herstellung von Salzen der Polyasparaginsäure und ihre Verwendung in Wasch- und Reinigungsmitteln |
| DE4434463A1 (de) * | 1994-09-27 | 1996-03-28 | Basf Ag | Verfahren zur Herstellung von modifizierten Polyasparaginsäuren |
| DE19511859A1 (de) * | 1995-03-31 | 1996-10-02 | Basf Ag | Verfahren zur Herstellung von Mischungen aus Polyasparaginsäuren und acylierten Polyasparaginsäuren |
| DE19512898A1 (de) * | 1995-04-06 | 1996-10-10 | Bayer Ag | Iminodisuccinat-enthaltende Polymere |
| TW425405B (en) * | 1995-04-06 | 2001-03-11 | Bayer Ag | Iminodisuccinate-containing polymers |
| DE19516399A1 (de) * | 1995-05-04 | 1996-11-07 | Bayer Ag | Verfahren zur Herstellung von Polymeren mit wiederkehrenden Succinyleinheiten |
| DE19517715A1 (de) * | 1995-05-13 | 1996-11-14 | Basf Ag | Verfahren zur Herstellung von Polycokondensaten der Asparaginsäure |
| DE19530203A1 (de) * | 1995-08-17 | 1997-02-20 | Bayer Ag | Verwendung von Polymeren mit wiederkehrenden Succinyleinheiten als Frostschutzmittel |
| DE19532717A1 (de) * | 1995-09-05 | 1997-03-06 | Basf Ag | Verwendung von modifizierten Polyasparaginsäuren in Waschmitteln |
| DE19540557B4 (de) * | 1995-10-31 | 2007-03-29 | Lanxess Deutschland Gmbh | Pigmentpräparationen mit hohem Feststoffgehalt |
| DE19545678A1 (de) * | 1995-12-07 | 1997-06-12 | Goldschmidt Ag Th | Copolymere Polyaminosäureester |
| JPH09165447A (ja) | 1995-12-15 | 1997-06-24 | Mitsubishi Chem Corp | ポリアスパラギン酸共重合体及びその製造方法 |
| DE19614565A1 (de) * | 1996-04-12 | 1997-10-16 | Henkel Kgaa | Verwendung von Asparaginsäure-haltigen Polymeren in mit Bioziden versetzten Kühlkreisläufen |
| US5869027A (en) * | 1996-04-22 | 1999-02-09 | Wood; Louis L. | Method for odor reduction |
| DE19630280A1 (de) * | 1996-07-26 | 1998-01-29 | Basf Ag | Verfahren zur Herstellung von Cokondensaten aus Asparaginsäure und Aminen |
| DE19635061A1 (de) * | 1996-08-30 | 1998-03-05 | Bayer Ag | Mittel zum Färben oder Bedrucken von Textilmaterialien |
| US6214786B1 (en) | 1997-08-08 | 2001-04-10 | The Procter & Gamble Company | Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
| US6407053B1 (en) | 1997-08-08 | 2002-06-18 | The Procter & Gamble Company | Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
| CN1272873A (zh) * | 1997-08-08 | 2000-11-08 | 普罗格特-甘布尔公司 | 具有用于提供所洗织物外观和完整性益处的基于氨基酸的聚合物的洗衣用洗涤剂组合物 |
| US6372880B1 (en) | 1997-12-25 | 2002-04-16 | Mitsui Chemicals, Inc. | Copolymer and process for preparing the same |
| DE19815025A1 (de) * | 1998-04-03 | 1999-10-07 | Bayer Ag | Verfahren zur Herstellung von Polymeren mit wiederkehrenden Succinyleinheiten unter Verwendung von Katalysatoren |
| DE19819187A1 (de) | 1998-04-30 | 1999-11-11 | Henkel Kgaa | Festes maschinelles Geschirrspülmittel mit Phosphat und kristallinen schichtförmigen Silikaten |
| DE19822599C2 (de) * | 1998-05-20 | 2003-02-06 | Goldschmidt Ag Th | Copolymere hydrophob modifizierte Polyasparaginsäureesteramide und ihre Verwendung |
| DE19822600C2 (de) * | 1998-05-20 | 2003-08-21 | Goldschmidt Ag Th | Copolymere, hydrophob modifizierte Polyasparaginsäureester mit erhöhter Molekularmasse |
| US6703030B2 (en) * | 1998-06-16 | 2004-03-09 | Marvin E. Klein | Amino fruit acid composition and method for the treatment of skin |
| DE19845639A1 (de) | 1998-10-05 | 2000-04-06 | Bayer Ag | Verfahren zur Herstellung von biologisch abbaubaren Polymeren mit wiederkehrenden Succinyleinheiten |
| US5962400A (en) * | 1998-12-22 | 1999-10-05 | National Starch And Chemical Investment Holding Corporation | Amino acid copolymers having pendent polysaccharide moieties and uses thereof |
| US20020002128A1 (en) * | 2000-03-01 | 2002-01-03 | Gernon Michael D. | Aqueous solutions containing dithionic acid and/or metal dithionate |
| MXPA02012194A (es) | 2000-06-16 | 2003-06-06 | Basf Ag | Detergente a base de un alcohol oxo. |
| US6503400B2 (en) | 2000-12-15 | 2003-01-07 | Ashland Inc. | Phosphate stabilizing compositions |
| US20060052577A1 (en) * | 2001-02-06 | 2006-03-09 | Graham Swift | Methods of synthesis of polymers and copolymers from natural products |
| US20060211843A1 (en) * | 2001-02-06 | 2006-09-21 | Graham Swift | Methods of synthesis of poly(succinimide-aspartate) polysuccinimide or polyaspartate by end capping polymerization |
| US6903181B2 (en) * | 2001-02-06 | 2005-06-07 | Folia, Inc | Methods of synthesis of polysuccinimide, copolymers of polysuccinimide and derivatives thereof |
| US7074881B2 (en) * | 2001-02-06 | 2006-07-11 | Folia, Inc | Methods of synthesis of polysuccinimide, copolymers of polysuccinimide and derivatives thereof |
| FR2855521B1 (fr) * | 2003-05-28 | 2005-08-05 | Flamel Tech Sa | Polyaminoacides fonctionnalises par au moins un groupement h ydrophobe et leurs applications notamment therapeutiques. |
| DE10334047A1 (de) * | 2003-07-25 | 2005-02-24 | Clariant Gmbh | Adsorbat aus Schichtsilicat und seine Verwendung |
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| WO2008139658A1 (ja) * | 2007-05-16 | 2008-11-20 | National Institute Of Advanced Industrial Science And Technology | 乳酸オリゴマーおよびその製造方法 |
| ES2449747T3 (es) | 2007-08-03 | 2014-03-21 | Basf Se | Dispersión de espesante asociativo |
| US7999040B2 (en) * | 2007-09-25 | 2011-08-16 | Nanochem Solutions, Inc. | Method of making graft copolymers from sodium poly(aspartate) and the resulting graft copolymer |
| AU2008322964A1 (en) | 2007-11-14 | 2009-05-22 | Basf Se | Method for producing a thickener dispersion |
| EP2062923A1 (en) * | 2007-11-22 | 2009-05-27 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Acylation of carbohydrates |
| EP2083067A1 (de) | 2008-01-25 | 2009-07-29 | Basf Aktiengesellschaft | Verwendung von organischen Komplexbildnern und/oder polymeren carbonsäuregruppenhaltigen Verbindungen in einer flüssigen Wasch- oder Reinigungsmittelzusammensetzung |
| TW201031743A (en) | 2008-12-18 | 2010-09-01 | Basf Se | Surfactant mixture comprising branched short-chain and branched long-chain components |
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| BR112012032218A2 (pt) | 2010-06-17 | 2016-11-22 | Basf Se | "copolímero, uso de um copolímero, e, composição de detergente têxtil" |
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| US8951955B2 (en) | 2011-01-13 | 2015-02-10 | Basf Se | Use of optionally oxidized thioethers of alcohol alkoxylates in washing and cleaning compositions |
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| US8846599B2 (en) | 2011-06-15 | 2014-09-30 | Basf Se | Branched polyesters with sulfonate groups |
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| CN105722890A (zh) * | 2013-09-16 | 2016-06-29 | 巴斯夫欧洲公司 | 改性聚天冬氨酸,其制备及其在衣物洗涤剂、器皿洗涤剂和清洁产品组合物中以及在水处理中作为分散剂和结垢抑制剂的用途 |
| WO2015036325A1 (de) | 2013-09-16 | 2015-03-19 | Basf Se | Verwendung modifizierter polyasparaginsäuren in spülmitteln |
| CN105555836B (zh) | 2013-09-16 | 2018-10-02 | 巴斯夫欧洲公司 | 生产聚天冬氨酸的方法 |
| BR112016019054A8 (pt) * | 2014-03-06 | 2019-12-10 | Solenis Technologies Cayman Lp | método para o controle, a prevenção e/ou a inibição da formação de incrustações e/ou depósitos em um sistema aquoso e composição |
| CN104030461B (zh) * | 2014-04-21 | 2015-09-30 | 上海电力学院 | 一种用于抑止硫酸钙垢形成的阻垢剂及其制备方法 |
| MX384950B (es) | 2014-08-08 | 2025-03-14 | Nch Corp | Composición y método para tratar óxido blanco. |
| RU2018136215A (ru) | 2016-03-16 | 2020-04-16 | Басф Се | Активные для мытья и чистки полимерные пленки, способ их получения и их применение |
| US11104587B2 (en) | 2016-04-14 | 2021-08-31 | Nch Corporation | System and method for automated control, feed, delivery verification, and inventory management of corrosion and scale treatment products for water systems |
| US11085118B2 (en) | 2016-04-14 | 2021-08-10 | Nch Corporation | Composition and method for inhibiting corrosion and scale |
| US10351453B2 (en) | 2016-04-14 | 2019-07-16 | Nch Corporation | Composition and method for inhibiting corrosion |
| CN110291120A (zh) | 2016-12-16 | 2019-09-27 | 巴斯夫欧洲公司 | 多层膜、其生产方法和用途 |
| EP3555155B1 (de) | 2016-12-16 | 2020-10-28 | Basf Se | Wasch- und reinigungsaktive mehrschichtfolien, verfahren zu ihrer herstellung und deren verwendung |
| WO2019048474A1 (en) | 2017-09-06 | 2019-03-14 | Basf Se | ACTIVE WASHING AND CLEANING POLYMER FILMS, METHOD FOR PRODUCING THE SAME, AND USE THEREOF |
| BR112020021882A2 (pt) | 2018-05-02 | 2021-01-26 | Basf Se | formulação detergente para lavagem de louça, uso, e, composição. |
| WO2020011627A1 (de) | 2018-07-11 | 2020-01-16 | Basf Se | Verfahren zur herstellung stabiler vinylimidazol-haltiger polymere |
| WO2020035567A1 (en) | 2018-08-16 | 2020-02-20 | Basf Se | Water-soluble polymer films of ethylene oxide homo- or copolymers, calendering process for the production thereof and the use thereof |
| US20220306791A1 (en) | 2019-06-14 | 2022-09-29 | Basf Se | Aqueous polymer dispersions suitable as opacifiers in liquid formulations |
| CN110980971B (zh) * | 2019-12-16 | 2022-05-13 | 武汉中新同和科技有限责任公司 | 一种工业循环水用无磷阻垢缓蚀剂及其制备方法 |
| CN113046028B (zh) * | 2021-04-09 | 2022-06-28 | 河北蓝江生物环保科技有限公司 | 高效降尘剂及其制备方法 |
| WO2023066741A1 (en) | 2021-10-20 | 2023-04-27 | Basf Se | Phosphate-free composition and methods for their manufacture and use |
| WO2024011342A1 (en) * | 2022-07-11 | 2024-01-18 | The Procter & Gamble Company | Use of graft copolymer in adjusting viscosity of laundry detergent composition |
| CN115367853B (zh) * | 2022-08-20 | 2023-08-04 | 河北择赛生物科技有限公司 | 一种污水处理用环保药剂及其制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3052655A (en) * | 1958-08-01 | 1962-09-04 | Sidney W Fox | Thermal polymerization of amino acid mixtures containing aspartic acid or a thermal precursor of aspartic acid |
| JPS4851995A (es) * | 1971-11-01 | 1973-07-21 | ||
| US3846380A (en) * | 1972-10-31 | 1974-11-05 | M Teranishi | Polyamino acid derivatives and compositions containing same |
| US4534881A (en) * | 1983-12-19 | 1985-08-13 | University Of South Alabama | Inhibition of inorganic or biological CaCO3 deposition by poly amino acid derivatives |
| JPS61218634A (ja) * | 1985-03-25 | 1986-09-29 | Fuso Kagaku Kogyo Kk | ポリアミノ酸類の製造法 |
| US4868287A (en) * | 1987-08-24 | 1989-09-19 | University Of South Alabama | Inhibition of mineral deposition by polyanionic/hydrophobic peptides and derivatives thereof having a clustered block copolymer structure |
| IT1240684B (it) * | 1990-04-26 | 1993-12-17 | Tecnopart Srl | Poliamminoacidi quali builders per formulazioni detergenti |
-
1992
- 1992-07-03 DE DE4221875A patent/DE4221875A1/de not_active Withdrawn
-
1993
- 1993-06-22 EP EP93914689A patent/EP0648241B1/de not_active Expired - Lifetime
- 1993-06-22 ES ES93914689T patent/ES2105287T3/es not_active Expired - Lifetime
- 1993-06-22 US US08/360,684 patent/US5747635A/en not_active Expired - Fee Related
- 1993-06-22 DE DE59307218T patent/DE59307218D1/de not_active Expired - Fee Related
- 1993-06-22 WO PCT/EP1993/001588 patent/WO1994001486A1/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP0648241B1 (de) | 1997-08-27 |
| EP0648241A1 (de) | 1995-04-19 |
| DE4221875A1 (de) | 1994-01-05 |
| WO1994001486A1 (de) | 1994-01-20 |
| US5747635A (en) | 1998-05-05 |
| DE59307218D1 (de) | 1997-10-02 |
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| Date | Code | Title | Description |
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| FG2A | Definitive protection |
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