ES2105528T3 - Polietilenos y copolimeros cauchutosos de etileno/propileno homogeneos. - Google Patents
Polietilenos y copolimeros cauchutosos de etileno/propileno homogeneos.Info
- Publication number
- ES2105528T3 ES2105528T3 ES94304648T ES94304648T ES2105528T3 ES 2105528 T3 ES2105528 T3 ES 2105528T3 ES 94304648 T ES94304648 T ES 94304648T ES 94304648 T ES94304648 T ES 94304648T ES 2105528 T3 ES2105528 T3 ES 2105528T3
- Authority
- ES
- Spain
- Prior art keywords
- homogeneous
- polyethylene
- propylene copolymers
- rubber ethylene
- alr
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 POLYETHYLENE Polymers 0.000 title abstract 3
- 239000004698 Polyethylene Substances 0.000 title abstract 2
- 229920000573 polyethylene Polymers 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 title 1
- 238000004435 EPR spectroscopy Methods 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/68—Vanadium, niobium, tantalum or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
UN PROCESO PARA LA PRODUCCION DE POLIETILENOS O EPRS COMPRENDE EL CONTACTO DE UNA MEZCLA QUE CONSTA DE ETILENO, UNA O MAS ALFAOLEFINAS, Y, OPCIONALMENTE, UN DIENO, CON UN CATALIZADOR QUE CONSTA DE: (A) COMO PRECURSOR EL PRODUCTO DE REACCION DE VX3 Y UN DONADOR DE ELECTRONES ; COMO MODIFICADOR ALR(3-A)XA ; Y UN SOPORTE; Y (B) COMO COCATALIZADOR ALR(3-A)XA; Y (C) COMO PROMOTOR UN HALOCARBURO ALIFATICO SATURADO O INSATURADO QUE TIENE AL MENOS 3 ATOMOS DE CARBONO Y AL MENOS 6 ATOMOS DE HALOGENO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/083,664 US5416053A (en) | 1993-06-28 | 1993-06-28 | Homogenous polyethylenes and ethylene/propylene copolymers rubbers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2105528T3 true ES2105528T3 (es) | 1997-10-16 |
Family
ID=22179890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94304648T Expired - Lifetime ES2105528T3 (es) | 1993-06-28 | 1994-06-27 | Polietilenos y copolimeros cauchutosos de etileno/propileno homogeneos. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5416053A (es) |
| EP (1) | EP0630918B1 (es) |
| JP (1) | JP2732357B2 (es) |
| KR (1) | KR950000747A (es) |
| CN (1) | CN1100431A (es) |
| AT (1) | ATE154620T1 (es) |
| BR (1) | BR9402552A (es) |
| CA (1) | CA2126798C (es) |
| DE (1) | DE69403866T2 (es) |
| ES (1) | ES2105528T3 (es) |
| GR (1) | GR3024302T3 (es) |
| MY (1) | MY130040A (es) |
| TW (1) | TW313572B (es) |
| ZA (1) | ZA944615B (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08208734A (ja) * | 1994-11-02 | 1996-08-13 | Union Carbide Chem & Plast Technol Corp | 塩化マグネシウムに担持されたバナジウム触媒を使用する均質エチレンプロピレンゴムの製造法 |
| IT1271278B (it) * | 1994-12-15 | 1997-05-27 | Enichem Elastomers | Sistema catalitico supportato per la produzione di copolimeri etilene propilene |
| US6486089B1 (en) | 1995-11-09 | 2002-11-26 | Exxonmobil Oil Corporation | Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution |
| US6417130B1 (en) | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
| WO1998002247A1 (en) | 1996-07-15 | 1998-01-22 | Mobil Oil Corporation | Comonomer pretreated bimetallic catalyst for blow molding and film applications |
| IT1284927B1 (it) * | 1996-10-08 | 1998-05-28 | Enichem Elastomers | Procedimento per la preparazione di copolimeri etilene propilene a basso tenore in cloro residuo |
| US5866661A (en) * | 1996-12-13 | 1999-02-02 | Phillips Petroleum Company | Ethylene polymerization processes and products thereof |
| US5851945A (en) * | 1997-02-07 | 1998-12-22 | Exxon Chemical Patents Inc. | Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state |
| US6153551A (en) | 1997-07-14 | 2000-11-28 | Mobil Oil Corporation | Preparation of supported catalyst using trialkylaluminum-metallocene contact products |
| US6051525A (en) | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
| WO1999025743A1 (en) * | 1997-11-17 | 1999-05-27 | Union Carbide Chemicals & Plastics Technology Corporation | Homogeneous polyethylenes and ethylene/propylene copolymer rubbers |
| WO2003048213A1 (en) * | 2001-11-30 | 2003-06-12 | Exxonmobil Chemical Patents, Inc. | Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4017669A (en) * | 1969-06-02 | 1977-04-12 | E. I. Du Pont De Nemours And Company | Functionally substituted terpolymers and tetrapolymers of alpha-olefins and process for manufacturing functional substituted copolymers |
| IT1017868B (it) * | 1974-08-02 | 1977-08-10 | Snam Progetti | Procedimento per la preparazione in alta resa di copolimeri dello etilene con 1.3 butadiene |
| CA1174800A (en) * | 1981-08-24 | 1984-09-18 | Charles Cozewith | Gas phase method for producing copolymers of ethylene and higher alpha-olefins |
| US4508842A (en) * | 1983-03-29 | 1985-04-02 | Union Carbide Corporation | Ethylene polymerization using supported vanadium catalyst |
| US4593010A (en) * | 1983-08-31 | 1986-06-03 | Exxon Research & Engineering Co. | Polyethylene with broad molecular weight distribution |
| US4755495A (en) * | 1986-02-27 | 1988-07-05 | Union Carbide Corporation | Process for activation of titanium and vanadium catalysts useful in ethylene polymerization |
| US4918038A (en) * | 1987-10-29 | 1990-04-17 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of polyethylene with a broad and/or bimodal molecular weight distribution |
| US5006618A (en) * | 1988-01-15 | 1991-04-09 | Mobil Oil Corporation | Process for preparing high density or medium density polymers |
| CA1326733C (en) * | 1988-06-08 | 1994-02-01 | Sumitomo Chemical Co., Ltd. | Ethylene-.alpha.-olefin copolymer and process for producing the same |
| US4892853A (en) * | 1988-09-30 | 1990-01-09 | Union Carbide Chemicals And Plastics Company Inc. | Ethylene polymerization catalyst |
| FR2651001B1 (fr) * | 1989-08-17 | 1993-03-12 | Bp Chemicals Sa | Procede de preparation d'un catalyseur de type ziegler-natta a base de vanadium et de titane |
| PL286827A1 (en) * | 1989-09-11 | 1992-01-13 | Union Carbide Chem Plastic | Method of obtaining ethylene-propylene-ethylidene-norbornene rubber |
-
1993
- 1993-06-28 US US08/083,664 patent/US5416053A/en not_active Expired - Fee Related
-
1994
- 1994-06-24 KR KR1019940014622A patent/KR950000747A/ko not_active Abandoned
- 1994-06-27 CA CA002126798A patent/CA2126798C/en not_active Expired - Fee Related
- 1994-06-27 BR BR9402552A patent/BR9402552A/pt not_active Application Discontinuation
- 1994-06-27 ZA ZA944615A patent/ZA944615B/xx unknown
- 1994-06-27 EP EP94304648A patent/EP0630918B1/en not_active Expired - Lifetime
- 1994-06-27 DE DE69403866T patent/DE69403866T2/de not_active Expired - Fee Related
- 1994-06-27 JP JP6165812A patent/JP2732357B2/ja not_active Expired - Lifetime
- 1994-06-27 CN CN94108923A patent/CN1100431A/zh active Pending
- 1994-06-27 MY MYPI94001666A patent/MY130040A/en unknown
- 1994-06-27 ES ES94304648T patent/ES2105528T3/es not_active Expired - Lifetime
- 1994-06-27 AT AT94304648T patent/ATE154620T1/de not_active IP Right Cessation
- 1994-08-10 TW TW083107291A patent/TW313572B/zh active
-
1997
- 1997-07-30 GR GR970401951T patent/GR3024302T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA944615B (en) | 1995-02-15 |
| JP2732357B2 (ja) | 1998-03-30 |
| TW313572B (es) | 1997-08-21 |
| KR950000747A (ko) | 1995-01-03 |
| CA2126798C (en) | 1998-08-25 |
| CN1100431A (zh) | 1995-03-22 |
| DE69403866D1 (de) | 1997-07-24 |
| EP0630918B1 (en) | 1997-06-18 |
| ATE154620T1 (de) | 1997-07-15 |
| CA2126798A1 (en) | 1994-12-29 |
| GR3024302T3 (en) | 1997-10-31 |
| US5416053A (en) | 1995-05-16 |
| MY130040A (en) | 2007-05-31 |
| JPH0725931A (ja) | 1995-01-27 |
| DE69403866T2 (de) | 1998-02-05 |
| EP0630918A1 (en) | 1994-12-28 |
| BR9402552A (pt) | 1995-03-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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